CN101580282A - Alkaline aqueous solution composition and preparation method and application thereof - Google Patents

Alkaline aqueous solution composition and preparation method and application thereof Download PDF

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CN101580282A
CN101580282A CNA2009100872517A CN200910087251A CN101580282A CN 101580282 A CN101580282 A CN 101580282A CN A2009100872517 A CNA2009100872517 A CN A2009100872517A CN 200910087251 A CN200910087251 A CN 200910087251A CN 101580282 A CN101580282 A CN 101580282A
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aqueous solution
water
alkaline aqueous
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朴元哲
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Abstract

The invention provides an alkaline aqueous solution composition; wherein every 1000ml of water contains 30-40g of sodium pyrophosphate, 10-20g of calcium glycerophosphate, 25-35g of C10H12CaN2Na2O8.2H2O, 5-10g of calcium chloride, 60-70g of potassium bromide, 20-30g of potassium sorbate, 75-85g of potassium metasilicate and 15-25g of potassium chloride. The alkaline aqueous solution composition can be applied as an adding agent of dissolved oxygen in water, an acid soil improving agent and a fish feed additive.

Description

Alkaline aqueous solution composition and manufacture method thereof and purposes
Technical field
The present invention relates to alkaline aqueous solution composition and manufacture method thereof and purposes.
Background technology
In soil, owing to exist organisms such as animals and plants and microorganism, can constantly degrade, stir, stir mineral substance and organic matter in the soil, make soil form crumb structure.The generation of crumb structure has formed many bigger spaces in soil.Big space not only makes the soil air air flow bigger, increased the hold facility of soil, promoted the detoxifcation of heavy metal objectionable impurities, and can improve the temperature in the soil moisture, high temperature promotes various chemical reactions, makes the dissolved to greatest extent and absorption of various nutrients.But in recent years and since a large amount of eliminatings of various objectionable impuritiess, acid rain severe contamination water quality and destroyed the effective constituent in the soil, after acidic fertilizier and acid rain enter soil, H +Positively charged ion is followed other cationic exchange positions, the former like this potassium that is included in the soil, and calcium, nutritive elements such as magnesium are fallen by rain-out, stay the H in the soil +Ion makes soil have acidity, and H +Be combined together to form toxicant with other materials in the soil, these toxicants can't be grown the root of plant, even die, and are difficult to continuous cultivated plant, and a part of toxicant also flows to rivers, and the biology in the river has also been caused serious threat.Microorganism is killed, reduced microorganism to the degraded of soil, stir, stirring action, make the increase of soil single-grain-shaped structure.When Soil structure was simple grain, pore volume reached 47.64% during marshalling, and pore volume is 25.95% when irregular, and the space is less between soil, had reduced the air permeability of soil, had suppressed the multiplication activity of aerophil, thereby influenced the nitrogen fixing capacity of root nodule bacterium and vinelandii.This can cause gathering of salt, and the crop rhizome is compromised or absorbs composition of necessity and the phenomenon that moisture is obstructed, and hinders growth and breeding.
Simultaneously because a large amount of eliminatings, the acid rain of various objectionable impuritiess, reduced the oxygen level in the water, formation is to the unfavourable condition of fish growth, this also causes the surcharge of fishery to rise with surprising rapidity, for example: the drug expenditure that transmissible disease of fish and various diseases cause increases problem, the ight soil of food-residue and fish decomposes in water, consumes oxygen the living environment of fish is worsened.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of alkaline aqueous solution composition and manufacture method and purposes that improves water body oxygen level, improvement acid soil, improves the fish meal utilization ratio.
For solving the problems of the technologies described above, the present invention adopts following technical scheme:
A kind of alkaline aqueous solution composition has in every 1000ml water:
Diphosphate sodium 30-40 gram
Glycerol calcium phosphate 10-20 gram
EDTA calcium 2 sodium 25-35 gram
Calcium chloride 5-10 gram
Potassium Bromide 60-70 gram
Potassium sorbate 20-30 gram
Potassium silicate 75-85 gram
Repone K 15-25 gram.
Alkaline aqueous solution combination of the present invention wherein, adds the sugar of 2-3 kilogram again in per 1 liter of said composition.
Alkaline aqueous solution composition of the present invention, wherein, contain in every 1000ml water:
Diphosphate sodium 35 grams
Glycerol calcium phosphate 15 grams
EDTA calcium 2 sodium 30 grams
Calcium chloride 8 grams
Potassium Bromide 65 grams
Potassium silicate 80 grams
Potassium sorbate 10 grams
Repone K 20 grams.
The method of alkaline aqueous solution composition of the present invention, wherein, this method may further comprise the steps successively:
A. the potassium silicate of 75-85 gram is dissolved in 60-80 ℃ the 1000ml water;
B. glycerol calcium phosphate, EDTA calcium 2 sodium, calcium chloride, Potassium Bromide 60-70 gram, potassium sorbate, Repone K are put into 60-80 ℃ a solution that step forms successively, stir, stirred 15 minutes, form solution while adding;
C. diphosphate sodium is put into the formed solution of b step, stir, stirred 15 minutes, form solution while adding.
Alkaline aqueous solution composition of the present invention is used as oxygen in water dose, acid soil improving agent and fish feed additive.
The proterties of component of the present invention, physical properties and uses thereof is as follows:
(1) diphosphate sodium (sodium pyrophosphate, Na 4P 2O 710H 2O)
This product is anhydrous, and colourless transparent crystals, proportion are 1.82, and the pH value of the aqueous solution is 10.0-10.2.Being heated becomes anhydride under 100 ℃ of conditions, the tool purposes is for being used for liquid detergent, sanitising agent, washing, water treatment, medicine, foodstuff additive, nutrition agent etc.
(2) glycerol calcium phosphate (C 3H 7CaO 6P)
This product is a white, crystalline, powder.The reinforcer that is used for calcium, pharmaceuticals etc., it dissolves in 50 times water.
(3) EDTA calcium 2 sodium (C 10H 12CaN 2Na 2O 82H 2O)
This product is white or oyster white crystal powder, is used for foodstuff additive (prevent variable color, oxidation is rotted, and keeps delicate flavour), curing food, refreshment drink etc.Soluble in water under the normal temperature condition, (aqueous ph value 6.5-8.0 solubleness 30%)
(4) calcium chloride (CaCl 2)
This product is a white crystal, and the body weight of powder is 2.15.Be used for reinforcer, bean-curd product is brewageed agent, starter, siccative, nutrition stiffeners etc.34.0 grams when solubleness is followed successively by subzero 20 ℃ under different condition in the 100 gram water, 53.5 grams in the time of 40 ℃, 57.7 grams in the time of 60 ℃, 59.3 grams in the time of 80 ℃.
(5) Potassium Bromide (KBr)
This product is a white crystal, and the proportion of powder is 2.756.Be used for pharmaceutical raw material, pharmaceuticals, medicated soap etc.Be soluble in (pH value neutrality) in glycerine or the water
(6) potassium sorbate (sorbic acid, C 6H 7KO 2)
This product is the crystalline powder of white or lavender, and proportion is 1.363, and odorless has alcohol fragrance.Because to mould, the growth of bacterium has tangible interception, therefore be used for storage food meat, fresh fish dry products, Food preservation agent etc. more.Dissolving 67.6 grams in the 100Cc water under 20 ℃ of conditions.Under the normal temperature condition, dissolving 5.8 grams in propylene glycol, dissolving 0.3 gram in the ethanol, concentration is dissolving 47.5 grams in 5% the salt, dissolving 51 grams in 25% the syrup
(7) Repone K (KCl)
This product is clear crystal or white powder, is used for foodstuff additive, curing food, can etc.Soluble in water, its aqueous solution is neutral.
(8) potassium silicate (K 2OnSiO 2)
This product is colourless or the alkaline liquid of color slightly, is used for the soap batching, SYNTHETIC OPTICAL WHITNER, liquid detergent etc.Potassium silicate potassium (composition of K is high more, and solvability is good more) soluble in water, but be insoluble in the alcohol.
Advantage of the present invention is: 1, can improve the dissolving of oxygen in water significantly, increase the oxygen level in the water; 2, the present invention is alkalescence, can improve acid soil, singlegrained structure in the soil is become crumb structure, simultaneously because the present invention increases water oxygen content, so can promote microbial growth in the soil, mineral substance and the organic matter in the soil constantly degraded, stirs, stirred to microorganism, promotes that further the singlegrained structure in the soil changes crumb structure into; 3, the present invention can improve the utilization ratio of feed as the additive of fish meal, reduces the pollution of the ight soil of swill and fish to water body.
Embodiment
Embodiment 1
Alkaline aqueous solution composition, wherein, contain in the 1000ml water:
Diphosphate sodium 30 grams
Glycerol calcium phosphate 10 grams
EDTA calcium 2 sodium 25 grams
Calcium chloride 5 grams
Potassium Bromide 60 grams
Potassium sorbate 20 grams
Potassium silicate 75 grams
Repone K 15 grams.
In the preparation process, the amount of each compound is the amount in the above-mentioned prescription, and preparation method is, may further comprise the steps successively:
A. potassium silicate is dissolved in 60 ℃ the 1000ml water;
B. glycerol calcium phosphate, EDTA calcium 2 sodium, calcium chloride, Potassium Bromide, potassium sorbate, Repone K are put into 60-80 ℃ a solution that step forms successively, stir, stirred 18 minutes, form solution while adding;
C. diphosphate sodium is put into the formed solution of b step, stir, stirred 18 minutes, form solution while adding;
Embodiment 2
Alkaline aqueous solution composition of the present invention, wherein, contain in the 1000ml water:
Diphosphate sodium 35 grams
Glycerol calcium phosphate 15 grams
EDTA calcium 2 sodium 30 grams
Calcium chloride 8 grams
Potassium Bromide 65 grams
Potassium silicate 80 grams
Potassium sorbate 10 grams
Repone K 20 grams
In the preparation process, the amount of each compound is the amount in the above-mentioned prescription, and preparation method is, may further comprise the steps successively:
A. potassium silicate is dissolved in 70 ℃ the 1000ml water;
B. glycerol calcium phosphate, EDTA calcium 2 sodium, calcium chloride, Potassium Bromide, potassium sorbate, Repone K are put into 60-80 ℃ a solution that step forms successively, stir, stirred 15 minutes, form solution while adding;
C. diphosphate sodium is put into the formed solution of b step, stir, stirred 15 minutes, form solution while adding;
Embodiment 3
A kind of alkaline aqueous solution composition, wherein, contain in the 1000ml water:
Diphosphate sodium 40 grams
Glycerol calcium phosphate 20 grams
EDTA calcium 2 sodium 35 grams
Calcium chloride 10 grams
Potassium Bromide 70 grams
Potassium sorbate 30 grams
Potassium silicate 85 grams
Repone K 25 grams
In the preparation process, the amount of each compound is the amount in the above-mentioned prescription, and preparation method is, may further comprise the steps successively:
A. potassium silicate is dissolved in 80 ℃ the 1000ml water;
B. glycerol calcium phosphate, EDTA calcium 2 sodium, calcium chloride, Potassium Bromide, potassium sorbate, Repone K are put into 60-80 ℃ a solution that step forms successively, stir, stirred 20 minutes, form solution while adding;
C. diphosphate sodium is put into the formed solution of b step, stir, stirred 20 minutes, form solution while adding;
Embodiment 4
With the present invention by the composition stoste of embodiment 1 gained as test portion (test portion is the abbreviation of test with material) with diluting in the pure water, the variation of dissolved oxygen and PH is as follows in back 30 seconds to the 5 minutes process of dilution:
Table one
Figure A20091008725100071
Table one experimental data is to adopt to go up the CEN0128-DO dissolved oxygen meter mensuration that the peaceful Environmental Protection Technology Co., Ltd in Haicheng produces, and as mentioned above, adds a small amount of present composition, can make dissolved oxygen that remarkable increase is arranged, and its solution pH value is alkalescence.Pure water is that dissolved oxygen is the 6-6.5 mg/litre, spring is 7 mg/litre, and the increase of dissolved oxygen can be quickened the oxidation rate of pollutent in the water body, improves water quality, even, expect to have more significant effect through the long-time back of using so add a spot of present composition at every turn.
Embodiment 5
600 milliliters of the embodiment of the invention 2 resulting stostes and white sugar 1800 are restrained in the water that is added in 300 liters, be sprayed at according to 200 milliliters every square metre sprinkling amounts on 1333 square metres the soil, sprayed the 2nd time every 7 days, the PH that surveyed soil on the 14th day once more is 7.01, and the former PH of this soil is 5.7.
The acid soil primary structure is a simple grain, and pore volume reaches 47.64% during marshalling, and pore volume is 25.95% when irregular, the space is less between soil, reduce the air permeability of soil, suppressed the multiplication activity of aerophil, thereby influenced the nitrogen fixing capacity of root nodule bacterium and vinelandii.After using the present invention, acid soil is changed into neutrality, and can make the glued mutually coacervate that together forms of simple grain in the soil, i.e. crumb structure.Can form bigger space between the crumb structure of soil, pore volume reaches 72.58% during marshalling, reach 45.17% when irregular, space between soil is bigger, has increased the content of carbon and oxygen, makes the aerobism microorganism obtain breeding, and anerobe killed, the more important thing is that mineral substance and the organic matter in the soil can further constantly be degraded, be stirred, stir to microbiological degradation product and the flora in the soil, makes singlegrained structure change crumb structure into.Owing to formed a large amount of spaces between the granule of soil, the flowability and the water-permeable of air have not only been improved, also can increase the ability of preserving moisture, promote the growth of crop root, the detoxifcation of favourable heavy metal objectionable impurities, increase ground temperature, promote various chemical reactions, make the dissolved to greatest extent and absorption of various nutrients.
Embodiment 6
Trial period be on April 25th, 2008 to May 25, the selection carp is an experimental subjects, with the prepared stoste of the embodiment of the invention 3 as the fodder additives shoal of fish and each 100000 tail of control group.
Experimental group is thrown something and fed with the preparation method of feed:
With the stoste of the embodiment of the invention 3 gained as fodder additives, the white sugar of double centner is dissolved in 50 kilograms the fodder additives, the water that adds double centner stirs, gained liquid is sprinkled in 1 ton of rice bran, ferment, fermentation time is 8 days, and the rice bran fermented feed with gained adds in the uncooked feed in 4% ratio afterwards, obtain powder feed, this feed is directly thrown in the test shoal of fish of plant.
Do not add fodder additives of the present invention in the feed of control group.
As a result, the feed uptake ratio of control group is 60%, and the feed uptake ratio of the experiment shoal of fish is 90%, improves 30%, and does not produce residue or throw out in the test fish pond, has greatly reduced the pollution of water quality.
Test pool, shoal of fish place 14 talentes need change water one time, and the contrast shoal of fish will be changed water in 3 days one time, and the internal reference shoal of fish has been thrown in microbiotic for 3 times during one month, and the test shoal of fish is not thrown in any microbiotic, and the test shoal of fish does not suffer from any disease yet.
Above-described embodiment is described preferred implementation of the present invention; be not that scope of the present invention is limited; design under the prerequisite of spirit not breaking away from the present invention; various distortion and improvement that those of ordinary skills make technical scheme of the present invention all should fall in the definite protection domain of claims of the present invention.

Claims (5)

1, a kind of alkaline aqueous solution composition is characterized in that, contains in every 1000ml water:
Diphosphate sodium 30-40 gram
Glycerol calcium phosphate 10-20 gram
EDTA calcium 2 sodium 25-35 gram
Calcium chloride 5-10 gram
Potassium Bromide 60-70 gram
Potassium sorbate 20-30 gram
Potassium silicate 75-85 gram
Repone K 15-25 gram.
2, alkaline aqueous solution composition as claimed in claim 1 is characterized in that, adds the sugar that the 2-3 kilogram is arranged in per 1 liter of said composition again.
3, alkaline aqueous solution composition as claimed in claim 1 is characterized in that, contains in every 1000ml water:
Diphosphate sodium 35 grams
Glycerol calcium phosphate 15 grams
EDTA calcium 2 sodium 30 grams
Calcium chloride 8 grams
Potassium Bromide 65 grams
Potassium silicate 80 grams
Potassium sorbate 10 grams
Repone K 20 grams.
4, the method for preparation alkaline aqueous solution composition as claimed in claim 1 is characterized in that this method may further comprise the steps successively:
A. the potassium silicate of 75-85 gram is dissolved in 60-80 ℃ the 1000ml water;
B. glycerol calcium phosphate, EDTA calcium 2 sodium, calcium chloride, Potassium Bromide, potassium sorbate, Repone K are put into 60-80 ℃ a solution that step forms successively, stir, stirred 15-20 minute, form solution while adding;
C. diphosphate sodium is put into the formed solution of b step, stir, stirred 15-20 minute, form solution while adding.
5, as of the application of described any one alkaline aqueous solution composition of claim 1 to 4 as oxygen in water dose, acid soil improving agent and fish feed additive.
CNA2009100872517A 2009-06-19 2009-06-19 Alkaline aqueous solution composition and preparation method and application thereof Pending CN101580282A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104671997A (en) * 2015-01-30 2015-06-03 姜明光 Biological liquid compound fertilizer containing monosilicic acid, N, P and K
CN108424256A (en) * 2018-05-09 2018-08-21 巴夫特(潍坊)化工有限公司 Overcome soil acidification hardened and promotes the composition of plant growth
CN108659849A (en) * 2018-05-09 2018-10-16 巴夫特(潍坊)化工有限公司 Overcome the composition that soil acidification is hardened

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104671997A (en) * 2015-01-30 2015-06-03 姜明光 Biological liquid compound fertilizer containing monosilicic acid, N, P and K
CN108424256A (en) * 2018-05-09 2018-08-21 巴夫特(潍坊)化工有限公司 Overcome soil acidification hardened and promotes the composition of plant growth
CN108659849A (en) * 2018-05-09 2018-10-16 巴夫特(潍坊)化工有限公司 Overcome the composition that soil acidification is hardened

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Open date: 20091118