CN108641499A - A kind of imitative lime stone cobweb coating - Google Patents

A kind of imitative lime stone cobweb coating Download PDF

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Publication number
CN108641499A
CN108641499A CN201810297754.6A CN201810297754A CN108641499A CN 108641499 A CN108641499 A CN 108641499A CN 201810297754 A CN201810297754 A CN 201810297754A CN 108641499 A CN108641499 A CN 108641499A
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China
Prior art keywords
parts
weight
added
antifoaming agent
cobweb
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Pending
Application number
CN201810297754.6A
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Chinese (zh)
Inventor
李志强
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Zhejiang Changxin Kai Shi Coatings Co Ltd
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Zhejiang Changxin Kai Shi Coatings Co Ltd
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Priority to CN201810297754.6A priority Critical patent/CN108641499A/en
Publication of CN108641499A publication Critical patent/CN108641499A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of imitative lime stone cobweb coatings, including 583.5 parts by weight water, 1.5 parts by weight preservatives, 6 parts by weight 250HBR, 1.5 parts by weight antifoaming agent, 4 parts per weight dispersing agents 5040,1.5 parts by weight X405,30 parts by weight titanium dioxides, 60 parts by weight, 1250 mesh coarse whiting, 200 parts by weight atom ashes, 17 parts by weight of propylene glycol, 17 parts by weight 8W thickeners, 2 parts by weight AMP 95,4.5 parts by weight coalescents, 70 parts by weight RS 998A and 1.5 parts by weight A10 antifoaming agent.Coating produced by the present invention has good adhesion strength, cracking resistance, surface adhesion force and wear-resisting property, suitable for promoting, the texture with natural limestone on word metope is coated, dicoration is strong, fidelity is high, while having the characteristics that weatherability, water resistance, alkali resistance.

Description

A kind of imitative lime stone cobweb coating
Technical field
The invention belongs to coating process fields, specifically, being related to a kind of imitative lime stone cobweb coating.
Background technology
Coating, in the entitled paint of Chinese tradition, so-called coating be coated in the body surface being protected or decorated, and The continuous film of firm attachment can be formed with coated article, typically based on resin or oil or lotion, add or do not add face Material, filler add corresponding additive, the thick liquid being formulated with organic solvent or water.
Lime stone is a kind of lithotome, currently, when people are to building decoration, it is exquisite using lime stone decorative appearance, more Come more universal, and lime stone is directly used in decoration, and not only cost is high, and material cost is big, and there are security risks.
Invention content
In view of the above-mentioned problems, the present invention provides a kind of imitative lime stone cobweb coating, the coating produced directly coats On metope, the appearance of color spot type lime stone can be formed, can either meet the needs of people, and greatly reduce and be built into This.
The technical solution adopted by the present invention is:
A kind of imitative lime stone cobweb coating, including 583.5 parts by weight water, 1.5 parts by weight preservatives, 6 parts by weight 250HBR, 1.5 parts by weight antifoaming agent, 4 parts per weight dispersing agents 5040,1.5 parts by weight X405,30 parts by weight titanium dioxides, 60 parts by weight, 1250 mesh Coarse whiting, 200 parts by weight atom ashes, 17 parts by weight of propylene glycol, 17 parts by weight 8W thickeners, 2 parts by weight AMP-95,4.5 weight Part coalescents, 70 parts by weight RS-998A and 1.5 parts by weight A10 antifoaming agent.
Preferably, the preparation method of the antifoaming agent is:First, ointment is prepared, by the proportion ingredient of following component, with Weight part ratio meter, White Mineral Oil:White carbon:Polyethers:Polyether polyol:Castor oil=(10-45) part:(2-10) part:(10-35) Part:(10-30) part:(10-35) part;Then above-mentioned dispensing is added into the reaction kettle equipped with stirring slurry, motor and heating system, It will be uniformly mixed under dispensing room temperature, stir 1 hour blowing;80 parts of the ointment that above-mentioned Recipe is worked it out is taken, is added certainly Each 20 parts of newborn silicone oil, tributyl phosphate, 10 parts of blended emulsifier stir evenly, and 280 parts of water is then added and makes its phase inversion, turns 16 parts of thickener is added after mutually complete and is used for thickening tune viscosity to 1500CS-2000CS, then discharging is packaged dress, you can is disappeared Infusion.
Preferably, the preparation method of the preservative is:By the dodecyl dimethyl Benzylmagnesium chloride of weight Ammonium, myristyl benzyl dimethyl ammonium chloride, cetalkonium chloride and octadecyl dimethyl benzyl chlorination The composition and didecyl Dimethy ammonium chloride of one or more of ammonium are put into blender and are stirred, stirring Time is 30-120 minutes;When needing that stabilizer is added, stabilizer is added in deionized water and is dissolved, then will be dissolved with The deionized water solution of stabilizer is poured into the blender and is stirred, and mixing time is 30-120 minutes;It only needs to be added When deionized water, directly deionized water is poured into the blender and is stirred, mixing time is similarly 30-120 minutes;So By finished product head tank is pumped into after filtering, analysis qualification, it is put into clean empty bottle in Irrigation Machine or slack tank starts filling and screw capping, Obtain preservative.
Coating produced by the present invention has good adhesion strength, cracking resistance, surface adhesion force and wear-resisting property, suitable It promotes, coats the texture with natural limestone on word metope, decorative strong, fidelity is high, while having weatherability, water-fast The features such as property, alkali resistance.
Specific implementation mode
The present invention is described in further detail below by specific embodiment.
Embodiment
A kind of imitative lime stone cobweb coating, including 583.5 parts by weight water, 1.5 parts by weight preservatives, 6 parts by weight 250HBR, 1.5 parts by weight antifoaming agent, 4 parts per weight dispersing agents 5040,1.5 parts by weight X405,30 parts by weight titanium dioxides, 60 parts by weight, 1250 mesh Coarse whiting, 200 parts by weight atom ashes, 17 parts by weight of propylene glycol, 17 parts by weight 8W thickeners, 2 parts by weight AMP-95,4.5 weight Part coalescents, 70 parts by weight RS-998A and 1.5 parts by weight A10 antifoaming agent.
Preparation method includes the following steps:
1), by 583.5 parts by weight water, 1.5 parts by weight preservatives, 6 parts by weight 250HBR, 1.5 parts by weight antifoaming agent, 4 weights Amount part dispersant 5040 and 1.5 parts by weight X405 are added in reaction kettle, with the rotating speed of 800-1000r/min at 15-25 DEG C Stirring 5-10 minutes, obtains mixed liquor A;
2) 30 parts by weight titanium dioxides, 60 parts by weight, 1250 mesh coarse whiting and 200 parts by weight atom ashes, are added to mixed liquor In A, is stirred 25-35 minutes with the rotating speed of 800-1000r/min at 15-25 DEG C, obtain mixed liquid B;
3), by 17 parts by weight of propylene glycol, 17 parts by weight 8W thickeners, 2 parts by weight AMP-95,4.5 parts by weight coalescents, 70 parts by weight RS-998A and 1.5 parts by weight A10 antifoaming agent are added in mixed liquid B, with 400-500r/min at 15-25 DEG C Rotating speed stir 5-10 minutes, obtain mixed liquor C;
4) mixed liquor C, is stood 2-3 hours, obtains finished product.
The preparation method of the antifoaming agent is:First, ointment is prepared, by the proportion ingredient of following component, with weight part ratio Meter, White Mineral Oil:White carbon:Polyethers:Polyether polyol:Castor oil=(10-45) part:(2-10) part:(10-35) part:(10-30) Part:(10-35) part;Then above-mentioned dispensing is added into the reaction kettle equipped with stirring slurry, motor and heating system, by dispensing room temperature It is lower to be uniformly mixed, stir 1 hour blowing;80 parts of the ointment that above-mentioned Recipe is worked it out is taken, is added from newborn silicone oil, phosphoric acid Each 20 parts of tributyl, 10 parts of blended emulsifier stir evenly, and 280 parts of water is then added and makes its phase inversion, 16 are added after phase inversion is complete The thickener of part, which is used for thickening, adjusts viscosity to 1500CS-2000CS, and then discharging, which is packaged, fills, you can obtains antifoaming agent.
The preparation method of the preservative is:By the dodecyl benzyl dimethyl ammonium chloride of weight, the tetradecane One kind in base dimethyl benzyl ammonium chloride, cetalkonium chloride and stearyl dimethyl benzyl ammonium chloride Or two or more compositions and didecyl Dimethy ammonium chloride is put into blender and is stirred, mixing time 30- 120 minutes;When needing that stabilizer is added, stabilizer is added in deionized water and is dissolved, it then will be dissolved with stabilizer Deionized water solution is poured into the blender and is stirred, and mixing time is 30-120 minutes;It only needs that deionized water is added When, directly deionized water is poured into the blender and is stirred, mixing time is similarly 30-120 minutes;Then pass through Be pumped into finished product head tank after filter, analysis are qualified, be put into clean empty bottle in Irrigation Machine or slack tank start filling and screw capping to get to Preservative.

Claims (3)

1. a kind of imitative lime stone cobweb coating, which is characterized in that including 583.5 parts by weight water, 1.5 parts by weight preservatives, 6 weight Part 250HBR, 1.5 parts by weight antifoaming agent, 4 parts per weight dispersing agents 5040,1.5 parts by weight X405,30 parts by weight titanium dioxides, 60 weights Measure 1250 mesh coarse whiting of part, 200 parts by weight atom ashes, 17 parts by weight of propylene glycol, 17 parts by weight 8W thickeners, 2 parts by weight AMP- 95,4.5 parts by weight coalescents, 70 parts by weight RS-998A and 1.5 parts by weight A10 antifoaming agent.
2. a kind of imitative lime stone cobweb coating according to claim 1, which is characterized in that the preparation method of the antifoaming agent For:First, ointment is prepared, by the proportion ingredient of following component, in terms of weight part ratio, White Mineral Oil:White carbon:Polyethers:Polyethers is more First alcohol:Castor oil=(10-45) part:(2-10) part:(10-35) part:(10-30) part:(10-35) part;Then to equipped with stirring Above-mentioned dispensing is added in the reaction kettle of slurry, motor and heating system, will be uniformly mixed under dispensing room temperature, 1 hour blowing of stirring is It can;80 parts of the ointment that above-mentioned Recipe is worked it out is taken, is added from newborn silicone oil, each 20 parts of tributyl phosphate, blended emulsifier 10 Part, it stirs evenly, 280 parts of water, which is then added, makes its phase inversion, and 16 parts of thickener is added after phase inversion is complete and is used for thickening tune viscosity To 1500CS-2000CS, then discharging is packaged dress, you can obtains antifoaming agent.
3. a kind of imitative lime stone cobweb coating according to claim 1, which is characterized in that the preparation method of the preservative For:By the dodecyl benzyl dimethyl ammonium chloride of weight, myristyl benzyl dimethyl ammonium chloride, cetyl two The composition and double ten alkane of one or more of methylbenzyl ammonium chloride and stearyl dimethyl benzyl ammonium chloride Base alkyl dimethyl ammonium chloride, which is put into blender, to be stirred, and mixing time is 30-120 minutes;It, will be steady when needing that stabilizer is added Determine agent be added deionized water in dissolved, then by the deionized water solution dissolved with stabilizer pour into the blender into Row stirring, mixing time are 30-120 minutes;When only needing that deionized water is added, deionized water is directly poured into the blender In be stirred, mixing time is similarly 30-120 minutes;Then it is pumped into finished product head tank after filtering, analyzing qualification, is filling It irrigates and is put into clean empty bottle on machine or slack tank starts filling and screw capping to get to preservative.
CN201810297754.6A 2018-03-30 2018-03-30 A kind of imitative lime stone cobweb coating Pending CN108641499A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040535A (en) * 2019-12-02 2020-04-21 嘉宝莉化工集团股份有限公司 Stone-imitated textured paint and preparation method thereof
CN111704833A (en) * 2020-07-09 2020-09-25 湖州金强涂料厂 Preparation method of limestone coating and material increasing structure thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104591598A (en) * 2013-10-31 2015-05-06 北新集团建材股份有限公司 Real stone paint, and preparation method and construction method thereof
CN107652726A (en) * 2017-10-30 2018-02-02 惠州市华昱美实业有限公司 A kind of stone-like coating and its preparation technology

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104591598A (en) * 2013-10-31 2015-05-06 北新集团建材股份有限公司 Real stone paint, and preparation method and construction method thereof
CN107652726A (en) * 2017-10-30 2018-02-02 惠州市华昱美实业有限公司 A kind of stone-like coating and its preparation technology

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040535A (en) * 2019-12-02 2020-04-21 嘉宝莉化工集团股份有限公司 Stone-imitated textured paint and preparation method thereof
CN111704833A (en) * 2020-07-09 2020-09-25 湖州金强涂料厂 Preparation method of limestone coating and material increasing structure thereof

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Application publication date: 20181012

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