CN107502134A - For metro shield section of jurisdiction anti-corrosive and waterproof paint and preparation method thereof - Google Patents
For metro shield section of jurisdiction anti-corrosive and waterproof paint and preparation method thereof Download PDFInfo
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- CN107502134A CN107502134A CN201710695312.2A CN201710695312A CN107502134A CN 107502134 A CN107502134 A CN 107502134A CN 201710695312 A CN201710695312 A CN 201710695312A CN 107502134 A CN107502134 A CN 107502134A
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- parts
- corrosive
- added
- waterproof paint
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to building coating technical field, and in particular to one kind is used for metro shield section of jurisdiction anti-corrosive and waterproof paint and preparation method thereof;Its composition is by weight:Epoxy resin, water-base fluorocarbon emulsion resin, phenolic resin, cocoanut fatty acid diethanolamide, diatomite, calcium carbonate, talcum powder, Nano zinc dioxide impact-resistant, 1-hydroxy ethylidene-1,1-diphosphonic acid, surfactant, defoamer, thickener, coalescents and appropriate amount of deionized water;Coating prepared by the present invention has the advantages that heatproof cold resistance is good, resistance to ag(e)ing and corrosion resistance are strong, elongation percentage is high, solid content is high and bond effect is good, coating prepared by the present invention also has high-low temperature resistant, the equal energy normal use under conditions of 30 DEG C and 80 DEG C, also have the advantages that water resistance is good and wearability is strong, it is adapted to over strait, river-spanning bridge splash zone anti-corrosion and resistant abrasion, the anti-corrosion of the be particularly suitable for use in impervious anti-corrosion of shield duct piece, the anti-corrosion of large-sized concrete aqueduct and petrochemical industry concrete facility in subway construction.
Description
Technical field
The present invention relates to building coating technical field, and in particular to one kind be used for metro shield section of jurisdiction anti-corrosive and waterproof paint and
Its preparation method.
Background technology
Coating, in the entitled paint of Chinese tradition.So-called coating is to be coated in the body surface protected or decorated, and
The continuous film of firm attachment can be formed with coated article, typically based on resin or oil or emulsion, adds or does not add face
Material, filler, add corresponding additive, the thick liquid being formulated with organic solvent or water.
Chinese coating circle is more authoritative《Coating process》What one book was defined as:" coating is a kind of material, this material
Material can be coated in object surface with different construction technologies, and it is firm, thin with some strength, continuous solid-state to form adhesion
Film.The film common name film so formed, also known as paint film or coating.The service life of coating is depending on different products, liquid
State reason stone texture product uses modified organic silicone resin emulsion as base-material, and with special coating technology, assorted colored paint is overmolding to
Gluey hydrate colour particle, is uniformly and stably suspended in specific water-borne dispersions, and various colored particles form and aspect keep constant,
Coloring pigment will not separate out in water.The service life of so this exterior coating is about 15 years.
The quality of currently marketed coating still has much room for improvement, for example, currently marketed coating do not only exist bad adhesion,
The shortcomings that resistance to ag(e)ing and poor water resistance, wearability and corrosion-resistant also be present, not the shortcomings of high-low temperature resistant, what this also made shows
Compare limitation in the use range of commercially available paint vehicle.
The content of the invention
In view of the shortcomings of the prior art, the invention provides one kind to be used for metro shield section of jurisdiction anti-corrosive and waterproof paint, not only
It is also strong with wearability and corrosion resistance with caking property is strong, resistance to ag(e)ing and water resistance are strong, the advantages that high-low temperature resistant.
To realize object above, the present invention is achieved by the following technical programs:
One kind is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, and its composition is by weight:Epoxy resin 75-88 parts, water
Property fluorine carbon emulsion resin 23-29 parts, phenolic resin 20-26 parts, cocoanut fatty acid diethanolamide 18-23 parts, diatomite 15-
21 parts, calcium carbonate 13-17 parts, talcum powder 11-15 parts, Nano zinc dioxide impact-resistant 9-12 parts, 1-hydroxy ethylidene-1,1-diphosphonic acid 10-16 parts, table
Face activating agent 7.6-9.2 parts, defoamer 5.7-7.3 parts, thickener 4.8-6.5 parts, coalescents 4.1-5.8 parts and it is appropriate go from
Sub- water.
Preferably, a kind of to be used for metro shield section of jurisdiction anti-corrosive and waterproof paint, its preparation method comprises the following steps:
A, phenolic resin, diatomite, calcium carbonate and talcum powder are placed in pulverizer respectively and crushed, then by grinding
Grinding machine is ground, and gained each component powder is retained separately, standby;
B, the phenolic resin obtained by step a is added in organic solvent, is warming up to 35-45 DEG C and stirs 20-30min,
Obtained component is designated as blending ingredients A;
C, epoxy resin is added in liquid material a mixing bowl, surfactant is then added thereto, while stirring to it
Middle diatomite, calcium carbonate and the talcum powder powder added obtained by step a, then by water-base fluorocarbon emulsion resin, coconut oil fat
Sour diglycollic amide, 1-hydroxy ethylidene-1,1-diphosphonic acid and quality are added thereto simultaneously for the 24-36% of epoxy resin quality deionized water
It will be vacuumized in liquid material a mixing bowl, and 5-10min stirred with 460-600r/min speed, obtained component is designated as blending ingredients B;
D, blending ingredients A is added in blending ingredients B, then remaining raw material is added thereto and stirs 50-70min,
Get product.
Preferably, the surfactant selects neopelex.
Preferably, the defoamer selects silicone emulsion.
Preferably, the thickener by polyethylene glycol oxide and sodium carboxymethylcellulose according to mass ratio 1:1 mixes.
Preferably, the coalescents select propandiol butyl ether.
Beneficial effect:
The present invention is with epoxy resin, water-base fluorocarbon emulsion resin, phenolic resin, cocoanut fatty acid diethanolamide, silicon
Diatomaceous earth, calcium carbonate, talcum powder, Nano zinc dioxide impact-resistant and 1-hydroxy ethylidene-1,1-diphosphonic acid are as the raw material for preparing coating, prepared painting
Material has the advantages that heatproof cold resistance is good, resistance to ag(e)ing and corrosion resistance are strong, elongation percentage is high, solid content is high and bond effect is good.
Coating prepared by the other present invention also has high-low temperature resistant, the energy normal use, but also have under conditions of -30 DEG C and 80 DEG C
Have the advantages that water resistance is good and wearability is strong, be adapted to over strait, river-spanning bridge splash zone anti-corrosion and resistant abrasion, be particularly suitable for use in
The impervious anti-corrosion of shield duct piece in subway construction, the anti-corrosion of large-sized concrete aqueduct and petrochemical industry concrete facility it is anti-
It is rotten.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under the premise of creative work, belongs to the scope of protection of the invention.
Embodiment 1:
One kind is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, and its composition is by weight:75 parts of epoxy resin, water-based fluorine
25 parts of carbon emulsion resin, 20 parts of phenolic resin, 19 parts of cocoanut fatty acid diethanolamide, 15 parts of diatomite, 14 parts of calcium carbonate,
11 parts of talcum powder, 10 parts of Nano zinc dioxide impact-resistant, 11 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 7.6 parts of surfactant, 6.2 parts of defoamer, increasing
Thick dose 4.8 parts, 4.6 parts of coalescents and appropriate amount of deionized water.
One kind is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, and its preparation method comprises the following steps:
A, phenolic resin, diatomite, calcium carbonate and talcum powder are placed in pulverizer respectively and crushed, then by grinding
Grinding machine is ground, and gained each component powder is retained separately, standby;
B, the phenolic resin obtained by step a is added in organic solvent, is warming up to 35 DEG C and stirs 20min, gained group
Minute mark is blending ingredients A;
C, epoxy resin is added in liquid material a mixing bowl, surfactant is then added thereto, while stirring to it
Middle diatomite, calcium carbonate and the talcum powder powder added obtained by step a, then by water-base fluorocarbon emulsion resin, coconut oil fat
Sour diglycollic amide, 1-hydroxy ethylidene-1,1-diphosphonic acid and quality are added thereto for 24% deionized water of epoxy resin quality and by liquid
Vacuumized in material a mixing bowl, and 5min is stirred with 460r/min speed, obtained component is designated as blending ingredients B;
D, blending ingredients A is added in blending ingredients B, then remaining raw material is added thereto and stirs 50min, is produced
Finished product.
After tested, (25 DEG C) of the surface drying time of the coating prepared by embodiment 1 is 86min, under conditions of 84 DEG C not
Occur melting phenomenon, do not occur embrittlement phenomenon, shear strength 0.89MPa, adhesion strength 0.37MPa under conditions of -28 DEG C,
50h in coating is immersed in 20 DEG C, mass concentration is 3% salt solution is not had found that cracking, aliquation or obscission occur for coating.
Embodiment 2:
One kind is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, and its composition is by weight:80 parts of epoxy resin, water-based fluorine
23 parts of carbon emulsion resin, 22 parts of phenolic resin, 18 parts of cocoanut fatty acid diethanolamide, 17 parts of diatomite, 13 parts of calcium carbonate,
12 parts of talcum powder, 9 parts of Nano zinc dioxide impact-resistant, 10 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 8.3 parts of surfactant, 5.7 parts of defoamer, increasing
Thick dose 5.4 parts, 4.1 parts of coalescents and appropriate amount of deionized water.
One kind is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, and its preparation method comprises the following steps:
A, phenolic resin, diatomite, calcium carbonate and talcum powder are placed in pulverizer respectively and crushed, then by grinding
Grinding machine is ground, and gained each component powder is retained separately, standby;
B, the phenolic resin obtained by step a is added in organic solvent, is warming up to 38 DEG C and stirs 25min, gained group
Minute mark is blending ingredients A;
C, epoxy resin is added in liquid material a mixing bowl, surfactant is then added thereto, while stirring to it
Middle diatomite, calcium carbonate and the talcum powder powder added obtained by step a, then by water-base fluorocarbon emulsion resin, coconut oil fat
Sour diglycollic amide, 1-hydroxy ethylidene-1,1-diphosphonic acid and quality are added thereto for 28% deionized water of epoxy resin quality and by liquid
Vacuumized in material a mixing bowl, and 7min is stirred with 520r/min speed, obtained component is designated as blending ingredients B;
D, blending ingredients A is added in blending ingredients B, then remaining raw material is added thereto and stirs 57min, is produced
Finished product.
After tested, (25 DEG C) of the surface drying time of the coating prepared by embodiment 2 is 97min, under conditions of 80 DEG C not
Occur melting phenomenon, do not occur embrittlement phenomenon, shear strength 0.82MPa, adhesion strength 0.34MPa under conditions of -30 DEG C,
50h in coating is immersed in 20 DEG C, mass concentration is 4% salt solution is not had found that cracking, aliquation or obscission occur for coating.
Embodiment 3:
One kind is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, and its composition is by weight:84 parts of epoxy resin, water-based fluorine
29 parts of carbon emulsion resin, 24 parts of phenolic resin, 23 parts of cocoanut fatty acid diethanolamide, 19 parts of diatomite, 17 parts of calcium carbonate,
14 parts of talcum powder, 12 parts of Nano zinc dioxide impact-resistant, 16 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 8.8 parts of surfactant, 7.3 parts of defoamer, increasing
Thick dose 6.0 parts, 5.8 parts of coalescents and appropriate amount of deionized water.
One kind is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, and its preparation method comprises the following steps:
A, phenolic resin, diatomite, calcium carbonate and talcum powder are placed in pulverizer respectively and crushed, then by grinding
Grinding machine is ground, and gained each component powder is retained separately, standby;
B, the phenolic resin obtained by step a is added in organic solvent, is warming up to 42 DEG C and stirs 28min, gained group
Minute mark is blending ingredients A;
C, epoxy resin is added in liquid material a mixing bowl, surfactant is then added thereto, while stirring to it
Middle diatomite, calcium carbonate and the talcum powder powder added obtained by step a, then by water-base fluorocarbon emulsion resin, coconut oil fat
Sour diglycollic amide, 1-hydroxy ethylidene-1,1-diphosphonic acid and quality are added thereto for 32% deionized water of epoxy resin quality and by liquid
Vacuumized in material a mixing bowl, and 8min is stirred with 560r/min speed, obtained component is designated as blending ingredients B;
D, blending ingredients A is added in blending ingredients B, then remaining raw material is added thereto and stirs 65min, is produced
Finished product.
After tested, (25 DEG C) of the surface drying time of the coating prepared by embodiment 3 is 94min, under conditions of 76 DEG C not
Occur melting phenomenon, do not occur embrittlement phenomenon, shear strength 0.93MPa, adhesion strength 0.41MPa under conditions of -33 DEG C,
50h in coating is immersed in 20 DEG C, mass concentration is 6% salt solution is not had found that cracking, aliquation or obscission occur for coating.
Embodiment 4:
One kind is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, and its composition is by weight:88 parts of epoxy resin, water-based fluorine
27 parts of carbon emulsion resin, 26 parts of phenolic resin, 22 parts of cocoanut fatty acid diethanolamide, 21 parts of diatomite, 16 parts of calcium carbonate,
15 parts of talcum powder, 11 parts of Nano zinc dioxide impact-resistant, 14 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, 9.2 parts of surfactant, 6.7 parts of defoamer, increasing
Thick dose 6.5 parts, 5.1 parts of coalescents and appropriate amount of deionized water.
One kind is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, and its preparation method comprises the following steps:
A, phenolic resin, diatomite, calcium carbonate and talcum powder are placed in pulverizer respectively and crushed, then by grinding
Grinding machine is ground, and gained each component powder is retained separately, standby;
B, the phenolic resin obtained by step a is added in organic solvent, is warming up to 45 DEG C and stirs 30min, gained group
Minute mark is blending ingredients A;
C, epoxy resin is added in liquid material a mixing bowl, surfactant is then added thereto, while stirring to it
Middle diatomite, calcium carbonate and the talcum powder powder added obtained by step a, then by water-base fluorocarbon emulsion resin, coconut oil fat
Sour diglycollic amide, 1-hydroxy ethylidene-1,1-diphosphonic acid and quality are added thereto for 36% deionized water of epoxy resin quality and by liquid
Vacuumized in material a mixing bowl, and 10min is stirred with 600r/min speed, obtained component is designated as blending ingredients B;
D, blending ingredients A is added in blending ingredients B, then remaining raw material is added thereto and stirs 70min, is produced
Finished product.
After tested, (25 DEG C) of the surface drying time of the coating prepared by embodiment 4 is 101min, under conditions of 85 DEG C not
Occur melting phenomenon, do not occur embrittlement phenomenon, shear strength 0.78MPa, adhesion strength 0.29MPa under conditions of -26 DEG C,
50h in coating is immersed in 20 DEG C, mass concentration is 7% salt solution is not had found that cracking, aliquation or obscission occur for coating.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality
Body or operation make a distinction with another entity or operation, and not necessarily require or imply and deposited between these entities or operation
In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to
Nonexcludability includes, so that process, method, article or equipment including a series of elements not only will including those
Element, but also the other element including being not expressly set out, or it is this process, method, article or equipment also to include
Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that
Other identical element also be present in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments
The present invention is described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic;And these modification or
Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (6)
1. one kind is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, it is characterised in that its composition is by weight:Epoxy resin
75-88 parts, water-base fluorocarbon emulsion resin 23-29 parts, phenolic resin 20-26 parts, cocoanut fatty acid diethanolamide 18-23
Part, diatomite 15-21 parts, calcium carbonate 13-17 parts, talcum powder 11-15 parts, Nano zinc dioxide impact-resistant 9-12 parts, 1-hydroxy ethylene-1,1-diphosphonic
Sour 10-16 parts, surfactant 7.6-9.2 parts, defoamer 5.7-7.3 parts, thickener 4.8-6.5 parts, coalescents 4.1-5.8
Part and appropriate amount of deionized water.
2. one kind according to claim 1 is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, it is characterised in that its preparation side
Method comprises the following steps:
A, phenolic resin, diatomite, calcium carbonate and talcum powder are placed in pulverizer respectively and crushed, then by grinder
Grinding, gained each component powder is retained separately, standby;
B, the phenolic resin obtained by step a is added in organic solvent, is warming up to 35-45 DEG C and stirs 20-30min, gained
Component is designated as blending ingredients A;
C, epoxy resin is added in liquid material a mixing bowl, then adds surfactant thereto, added thereto while stirring
Enter diatomite, calcium carbonate and the talcum powder powder obtained by step a, then by water-base fluorocarbon emulsion resin, coco-nut oil fatty acid two
Glycollic amide, 1-hydroxy ethylidene-1,1-diphosphonic acid and quality are added thereto for the 24-36% of epoxy resin quality deionized water and by liquid
Vacuumized in material a mixing bowl, and 5-10min is stirred with 460-600r/min speed, obtained component is designated as blending ingredients B;
D, blending ingredients A is added in blending ingredients B, then remaining raw material is added thereto and stirs 50-70min, is produced
Finished product.
3. one kind according to claim 1 is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, it is characterised in that:The surface
Activating agent selects neopelex.
4. one kind according to claim 1 is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, it is characterised in that:The defoaming
Silicone emulsion is selected in agent.
5. one kind according to claim 1 is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, it is characterised in that:The thickening
Agent is by polyethylene glycol oxide and sodium carboxymethylcellulose according to mass ratio 1:1 mixes.
6. one kind according to claim 1 is used for metro shield section of jurisdiction anti-corrosive and waterproof paint, it is characterised in that:The film forming
Selection of auxiliary propandiol butyl ether.
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CN201710695312.2A CN107502134A (en) | 2017-08-15 | 2017-08-15 | For metro shield section of jurisdiction anti-corrosive and waterproof paint and preparation method thereof |
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CN201710695312.2A CN107502134A (en) | 2017-08-15 | 2017-08-15 | For metro shield section of jurisdiction anti-corrosive and waterproof paint and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111231051A (en) * | 2020-03-16 | 2020-06-05 | 南通铁建建设构件有限公司 | Shield segment production process with corrosion resistance and shear resistance functions |
CN116200094A (en) * | 2021-11-30 | 2023-06-02 | 中国石油化工股份有限公司 | High-barrier nano coating and preparation method thereof |
CN116554758A (en) * | 2023-05-24 | 2023-08-08 | 上海固密特新材料科技有限公司 | Fluorine modified high polymer roughening-reducing protective coating suitable for hydraulic building |
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CN104119734A (en) * | 2014-06-26 | 2014-10-29 | 安徽快来防水防腐有限公司 | Environment-friendly waterproof paint |
CN104292908A (en) * | 2014-09-04 | 2015-01-21 | 青岛佳尚创意文化有限公司 | Wear resistant paint |
CN105295584A (en) * | 2015-11-20 | 2016-02-03 | 天津美士邦涂料化工有限公司 | Heat-resistant anticorrosive coating |
CN106854415A (en) * | 2016-12-13 | 2017-06-16 | 沈荣存 | A kind of anti-corrosive properties and the good intelligent road-lamp of thermal diffusivity |
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2017
- 2017-08-15 CN CN201710695312.2A patent/CN107502134A/en active Pending
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CN1616567A (en) * | 2004-10-13 | 2005-05-18 | 浙江努奥罗散热器有限公司 | Water anti-corrosion paint and its preparing method |
CN104119734A (en) * | 2014-06-26 | 2014-10-29 | 安徽快来防水防腐有限公司 | Environment-friendly waterproof paint |
CN104292908A (en) * | 2014-09-04 | 2015-01-21 | 青岛佳尚创意文化有限公司 | Wear resistant paint |
CN105295584A (en) * | 2015-11-20 | 2016-02-03 | 天津美士邦涂料化工有限公司 | Heat-resistant anticorrosive coating |
CN106854415A (en) * | 2016-12-13 | 2017-06-16 | 沈荣存 | A kind of anti-corrosive properties and the good intelligent road-lamp of thermal diffusivity |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111231051A (en) * | 2020-03-16 | 2020-06-05 | 南通铁建建设构件有限公司 | Shield segment production process with corrosion resistance and shear resistance functions |
CN116200094A (en) * | 2021-11-30 | 2023-06-02 | 中国石油化工股份有限公司 | High-barrier nano coating and preparation method thereof |
CN116200094B (en) * | 2021-11-30 | 2023-11-10 | 中国石油化工股份有限公司 | High-barrier nano coating and preparation method thereof |
CN116554758A (en) * | 2023-05-24 | 2023-08-08 | 上海固密特新材料科技有限公司 | Fluorine modified high polymer roughening-reducing protective coating suitable for hydraulic building |
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