CN108635288A - A kind of filiform gel mask and preparation method thereof - Google Patents
A kind of filiform gel mask and preparation method thereof Download PDFInfo
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- CN108635288A CN108635288A CN201810551731.3A CN201810551731A CN108635288A CN 108635288 A CN108635288 A CN 108635288A CN 201810551731 A CN201810551731 A CN 201810551731A CN 108635288 A CN108635288 A CN 108635288A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000000499 gel Substances 0.000 claims abstract description 50
- 238000009987 spinning Methods 0.000 claims abstract description 35
- 108010022355 Fibroins Proteins 0.000 claims abstract description 28
- 229920002674 hyaluronan Polymers 0.000 claims abstract description 26
- 229960003160 hyaluronic acid Drugs 0.000 claims abstract description 26
- 239000004744 fabric Substances 0.000 claims abstract description 22
- 239000000835 fiber Substances 0.000 claims abstract description 19
- 239000000017 hydrogel Substances 0.000 claims abstract description 19
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical group N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 claims abstract description 18
- 230000000694 effects Effects 0.000 claims abstract description 13
- 230000005484 gravity Effects 0.000 claims abstract description 11
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 claims abstract description 9
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 9
- 239000000243 solution Substances 0.000 claims description 34
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 10
- 239000002131 composite material Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 241001116389 Aloe Species 0.000 claims description 5
- 229920001661 Chitosan Polymers 0.000 claims description 5
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims description 5
- 229930003268 Vitamin C Natural products 0.000 claims description 5
- 235000011399 aloe vera Nutrition 0.000 claims description 5
- 238000005119 centrifugation Methods 0.000 claims description 5
- 239000012460 protein solution Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 235000019154 vitamin C Nutrition 0.000 claims description 5
- 239000011718 vitamin C Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 3
- -1 carbodiimides salt Chemical class 0.000 claims description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000004132 cross linking Methods 0.000 claims 1
- 230000001815 facial effect Effects 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 7
- 230000035699 permeability Effects 0.000 abstract description 6
- 239000002537 cosmetic Substances 0.000 abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract 2
- 230000003064 anti-oxidating effect Effects 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 210000003491 skin Anatomy 0.000 description 17
- 239000011159 matrix material Substances 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000010382 chemical cross-linking Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 229920002683 Glycosaminoglycan Polymers 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 102000003425 Tyrosinase Human genes 0.000 description 1
- 108060008724 Tyrosinase Proteins 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001413 amino acids Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000006552 photochemical reaction Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 230000009759 skin aging Effects 0.000 description 1
- 210000004927 skin cell Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 210000000106 sweat gland Anatomy 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/676—Ascorbic acid, i.e. vitamin C
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/736—Chitin; Chitosan; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9794—Liliopsida [monocotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/18—Formation of filaments, threads, or the like by means of rotating spinnerets
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Engineering & Computer Science (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Dermatology (AREA)
- Botany (AREA)
- Manufacturing & Machinery (AREA)
- Biotechnology (AREA)
- Gerontology & Geriatric Medicine (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Toxicology (AREA)
- Mechanical Engineering (AREA)
- Cosmetics (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of Filamentous gel masks and preparation method thereof,Belong to cosmetic technical field,The facial mask includes base cloth layer and hypothallus,Base cloth layer is copper ammonia fiber layer,Hypothallus is Filamentous gel layer,The filiform gel layer is the surface by the way that hydrogel filament to be deposited on to copper ammonia fiber layer under the effect of gravity,The present invention utilizes centrifugal spinning method,When spinning head reaches certain rotating speed,Crosslinking agent will be contained,The fibroin albumen hyaluronic acid spinning solution of antibacterial and antioxidant content throws away spinning head,It is cross-linked to form the Filamentous hydrogel filament of 1 5um of diameter rapidly at a temperature of 25 60 DEG C,And copper ammonia fiber base fabric layer surface is deposited under the effect of gravity,To obtain Filamentous gel mask,Facial mask prepared by this method has good antibacterial,Anti-oxidation efficacy and superior skin attachement and gas permeability,Preparation method is simple,It is easily industrialized production.
Description
Technical field
The invention belongs to cosmetic technical field, it is specifically related to a kind of Filamentous gel mask and preparation method thereof.
Background technology
In recent years, as people increase skin care attention degree and the rise of electric business, facial mask is increasingly becoming the modern times all
The product that disappear soon of city's life, annual turnover are held a safe lead in skin care item industry.The principle of facial mask, be exactly in the short time by skin with
External environment is isolated, and skin temperature is made to increase, and pore expansion promotes sweat gland secretion and metabolism, while in facial mask essence
Moisture and nutritional ingredient skin cell gap is penetrated by pore, so that skin is become soft, skin nature light has bullet
Property.
Existing facial mask preparation method mostly uses greatly mask substrate dipping facial mask essence, but since base fabric is too thin, inhales
Attached Essence is limited, and during use, and Essence can drip, and causes various inconvenience；In addition the face that prepared by this method
Film poor air permeability will be removed using 15-20 minutes, otherwise can influence the eupnea of skin, lead to skin anoxic, nutrient without
Method is by normal absorption.
Fibroin albumen has the amino acid structure closest with human skin, and the glycine in fibroin albumen can be with purple
Photochemical reaction occurs for outside line, sun-proof to achieve the effect that by ultraviolet radiation absorption；By inhibiting the activity of tyrosinase to play skin
The effect of skin whitening, fibroin albumen can also be reached by the free radical of elimination skin slows down skin aging effect.
Hyaluronic acid is a kind of acid mucopolysaccharide, can carry the moisture of 500 times of own wt or more, be presently found
The best substance of moisture retention in nature, is referred to as ideal natural moisturizing factor, is widely used in cosmetic industry.
Hydrogel facial mask using hydrophilic gel as mask matrix, inside gel containing the required moisture of a large amount of skins and
Nutritional ingredient has stronger sticking nature, and non-stimulated to skin.By fibroin albumen with hyaluronic acid is compound prepares gel,
It can have a good application prospect in medical and cosmetic industry in conjunction with the advantages of the two.
Chinese patent publication No. CN106492279A, publication date are on March 15th, 2017, a kind of entitled " fibroin
The fast preparation method of albumen-hyaluronic acid plural gel ", this method are compound by crosslinking agent addition fibroin albumen-hyaluronic acid
In solution, act on forming sheet gel by chemical crosslinking at ambient temperature.This method prepares the gel required time
It is longer, and gel is sheet, although having good moisture-absorbing moisture-keeping performance, gas permeability is relatively poor.
Invention content
In view of the above problems, not only there is good moisture absorbability and moisture retentivity the purpose of the present invention is to provide one kind but also had had
Filamentous gel mask of fine air permeability and preparation method thereof, to achieve the goals above, technical solution of the invention is.
The purpose of the invention is achieved by the following technical solution：A kind of filiform gel mask, including base cloth layer and hypothallus,
The base cloth layer is copper ammonia fiber layer, and hypothallus is Filamentous gel layer, the filiform gel layer be by by hydrogel filament in weight
The surface of copper ammonia fiber layer is deposited under force effect.
Further, the thickness of the Filamentous gel layer is 0.5-2mm.
A kind of preparation method of filiform gel mask, includes the following steps：
(1) in mass ratio by the hyaluronic acid solution of the silk fibroin protein solution of concentration 10-30wt% and concentration 3-5wt%
40-70:30-60 is mixed, and forms fibroin albumen-hyaluronic acid composite solution；
(2) it is added into fibroin albumen-hyaluronic acid composite solution and accounts for fibroin albumen-hyaluronic acid gross mass 1-20%'s
The extract solution from aloe of crosslinking agent, the water soluble chitosan of 0.1-2%, the vitamin C of 0.1-2% and 0.1-2%, stirs evenly shape
At spinning solution；
(3) spinning solution is injected centrifugation to spin in spinning box, while spinning box rotating speed is increased with the rate of 50r/s, work as spinning
When tank rotating speed reaches 2000-6000r/min, spinning solution is thrown away after being crosslinked rapidly at 25-60 DEG C from spinneret orifice, forms diameter 1-
The continuous hydrogel filament of 5um, hydrogel filament deposit to copper ammonia fiber base fabric layer surface under gravity, form Filamentous gel
Facial mask.
Further, the crosslinking agent described in step (2) is in glutaraldehyde or carbodiimides salt or diglycidyl ether
One kind.
The beneficial effects of the present invention are：The Filamentous gel mask that the present invention announces use fibroin albumen and hyaluronic acid for
Raw material, no sensitization and irritation make the filiform gel mask have good moisture absorbability and moisture retentivity and resist in conjunction with the advantages of the two
Oxidative function, and large quantity of moisture is rich in Filamentous gel, is the several times of common facial mask, for a long time using not will produce back suction skin
Skin moisture phenomenon, energy long-acting slow-release moisturizing water lock keep skin water profit state moistening effect good, in use, Essence is not easy
It falls；The preparation method of the present invention prepares hydrogel filament using centrifugal spinning, simple for process, makees in conjunction with the physical shear of spinneret orifice
With and crosslinking agent chemical crosslinking effect, at a certain temperature, quickly form gel；Gelatinous fibre diameter is thin, large specific surface area,
Good with skin attachement, porosity is high, has good gas permeability, solves the problems, such as existing facial mask poor air permeability.
Specific implementation mode
Embodiment 1
A kind of filiform gel mask, including base cloth layer and hypothallus, the base cloth layer are copper ammonia fiber layer, hypothallus is silk
Shape gel layer, the filiform gel layer are the surfaces by the way that hydrogel filament to be deposited on to copper ammonia fiber layer under the effect of gravity.
Further, the thickness of the Filamentous gel layer is 2mm.
A kind of preparation method of filiform gel mask, includes the following steps：
(1) by the hyaluronic acid solution of the silk fibroin protein solution of concentration 10wt% and concentration 3wt% in mass ratio 70:30 is mixed
It closes, forms fibroin albumen-hyaluronic acid composite solution；
(2) it is added into fibroin albumen-hyaluronic acid composite solution and accounts for the penta of fibroin albumen-hyaluronic acid gross mass 10%
Dialdehyde, 0.1% water soluble chitosan, 0.1% vitamin C and 0.1% extract solution from aloe, stir evenly to form spinning
Liquid；
(3) spinning solution is injected centrifugation to spin in spinning box, while spinning box rotating speed is increased with the rate of 50r/s, work as spinning
When tank rotating speed reaches 5000r/min, spinning solution is thrown away from spinneret orifice, is cross-linked to form the company of diameter 5um rapidly at 25 DEG C of temperature
Continue hydrogel filament, hydrogel filament deposits to copper ammonia fiber base fabric layer surface under gravity, forms the matrix of thickness 2mm
Layer, base cloth layer and hypothallus form Filamentous gel mask.
Further, the crosslinking agent described in step (2) is glutaraldehyde.
Embodiment 2
A kind of filiform gel mask, including base cloth layer and hypothallus, the base cloth layer are copper ammonia fiber layer, hypothallus is silk
Shape gel layer, the filiform gel layer are the surfaces by the way that hydrogel filament to be deposited on to copper ammonia fiber layer under the effect of gravity.
Further, the thickness of the Filamentous gel layer is 1mm.
A kind of preparation method of filiform gel mask, includes the following steps：
(1) by the hyaluronic acid solution of the silk fibroin protein solution of concentration 20wt% and concentration 4wt% in mass ratio 60:40 is mixed
It closes, forms fibroin albumen-hyaluronic acid composite solution；
(2) carbon for accounting for fibroin albumen-hyaluronic acid gross mass 15% is added into fibroin albumen-hyaluronic acid composite solution
Change diimmonium salt, 1% water soluble chitosan, 1% vitamin C and 1% extract solution from aloe, stir evenly to form spinning
Liquid；
(3) spinning solution is injected centrifugation to spin in spinning box, while spinning box rotating speed is increased with the rate of 50r/s, work as spinning
When tank rotating speed reaches 5500r/min, spinning solution is thrown away from spinneret orifice, is cross-linked to form the company of diameter 3um rapidly at 40 DEG C of temperature
Continue hydrogel filament, hydrogel filament deposits to copper ammonia fiber base fabric layer surface under gravity, forms the matrix of thickness 1mm
Layer, base cloth layer and hypothallus form Filamentous gel mask.
Further, the crosslinking agent described in step (2) is carbodiimides salt.
Embodiment 3
A kind of filiform gel mask, including base cloth layer and hypothallus, the base cloth layer are copper ammonia fiber layer, hypothallus is silk
Shape gel layer, the filiform gel layer are the surfaces by the way that hydrogel filament to be deposited on to copper ammonia fiber layer under the effect of gravity.
Further, the thickness of the Filamentous gel layer is 0.5mm.
A kind of preparation method of filiform gel mask, includes the following steps：
(1) by the hyaluronic acid solution of the silk fibroin protein solution of concentration 30wt% and concentration 5wt% in mass ratio 50:50 is mixed
It closes, forms fibroin albumen-hyaluronic acid composite solution；
(2) it is added into fibroin albumen-hyaluronic acid composite solution and accounts for the two of fibroin albumen-hyaluronic acid gross mass 20%
Glycidol ether, 2% water soluble chitosan, 2% vitamin C and 2% extract solution from aloe, stir evenly to form spinning
Liquid；
(3) spinning solution is injected centrifugation to spin in spinning box, while spinning box rotating speed is increased with the rate of 50r/s, work as spinning
When tank rotating speed reaches 6000r/min, spinning solution is thrown away from spinneret orifice, is cross-linked to form the company of diameter 1um rapidly under temperature 60 C
Continue hydrogel filament, hydrogel filament deposits to copper ammonia fiber base fabric layer surface under gravity, forms the matrix of thickness 0.5mm
Layer, base cloth layer and hypothallus form Filamentous gel mask.
Further, the crosslinking agent described in step (2) is diglycidyl ether.
Above-described embodiment is the preferable implementation of the present invention, and in addition to this, the present invention can be realized with other manner,
Any obvious replacement is not departed under the premise of present inventive concept within protection scope of the present invention.
Claims (4)
1. a kind of filiform gel mask, including base cloth layer and hypothallus, which is characterized in that the base cloth layer is copper ammonia fiber layer,
Hypothallus is Filamentous gel layer, and the filiform gel layer is by the way that hydrogel filament to be deposited on to copper ammonia fiber layer under the effect of gravity
Surface.
2. a kind of Filamentous gel mask according to claim 1, it is characterised in that：It is described filiform gel layer thickness be
0.5-2mm。
3. a kind of preparation method of filiform gel mask, which is characterized in that include the following steps：
(1) by the hyaluronic acid solution of the silk fibroin protein solution of concentration 10-30wt% and concentration 3-5wt% 40-70 in mass ratio:
30-60 is mixed, and forms fibroin albumen-hyaluronic acid composite solution；
(2) crosslinking for accounting for fibroin albumen-hyaluronic acid gross mass 1-20% is added into fibroin albumen-hyaluronic acid composite solution
Agent, the water soluble chitosan of 0.1-2%, the vitamin C of 0.1-2% and 0.1-2% extract solution from aloe, stir evenly to form spinning
Silk liquid；
(3) spinning solution is injected centrifugation to spin in spinning box, while spinning box rotating speed is increased with the rate of 50r/s, when spinning box turns
When speed reaches 2000-6000r/min, spinning solution is thrown away after being crosslinked rapidly at 25-60 DEG C from spinneret orifice, forms diameter 1-5um
Continuous hydrogel filament, hydrogel filament deposits to copper ammonia fiber base fabric layer surface, forms Filamentous gel face under gravity
Film.
4. a kind of preparation method of Filamentous gel mask according to claim 3, which is characterized in that described in step (2)
Crosslinking agent be one kind in glutaraldehyde or carbodiimides salt or diglycidyl ether.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810551731.3A CN108635288B (en) | 2018-05-31 | 2018-05-31 | Filamentous gel mask and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810551731.3A CN108635288B (en) | 2018-05-31 | 2018-05-31 | Filamentous gel mask and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111870541A (en) * | 2020-09-01 | 2020-11-03 | 江西建昌帮药业有限公司 | Herbal whitening compound composition, mask and preparation method thereof |
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