CN108612123A - A kind of new concrete module - Google Patents
A kind of new concrete module Download PDFInfo
- Publication number
- CN108612123A CN108612123A CN201810270407.4A CN201810270407A CN108612123A CN 108612123 A CN108612123 A CN 108612123A CN 201810270407 A CN201810270407 A CN 201810270407A CN 108612123 A CN108612123 A CN 108612123A
- Authority
- CN
- China
- Prior art keywords
- layer
- stainless steel
- heat
- new concrete
- photic zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004567 concrete Substances 0.000 title claims abstract description 35
- 239000010410 layer Substances 0.000 claims abstract description 93
- 239000002346 layers by function Substances 0.000 claims abstract description 37
- 239000010935 stainless steel Substances 0.000 claims abstract description 33
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 33
- 239000011241 protective layer Substances 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 24
- 239000011150 reinforced concrete Substances 0.000 claims abstract description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 34
- 239000003822 epoxy resin Substances 0.000 claims description 33
- 239000011521 glass Substances 0.000 claims description 29
- 239000002245 particle Substances 0.000 claims description 22
- 229920005989 resin Polymers 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 12
- 229930185605 Bisphenol Natural products 0.000 claims description 10
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000007822 coupling agent Substances 0.000 claims description 10
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 9
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 239000004593 Epoxy Substances 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- ITZGNPZZAICLKA-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) 7-oxabicyclo[4.1.0]heptane-3,4-dicarboxylate Chemical compound C1C2OC2CC(C(=O)OCC2OC2)C1C(=O)OCC1CO1 ITZGNPZZAICLKA-UHFFFAOYSA-N 0.000 claims description 6
- 125000003700 epoxy group Chemical group 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 125000002723 alicyclic group Chemical group 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000010702 perfluoropolyether Substances 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 4
- 239000005341 toughened glass Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- CMEWLCATCRTSGF-UHFFFAOYSA-N N,N-dimethyl-4-nitrosoaniline Chemical compound CN(C)C1=CC=C(N=O)C=C1 CMEWLCATCRTSGF-UHFFFAOYSA-N 0.000 claims description 3
- 230000001413 cellular effect Effects 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 229960004624 perflexane Drugs 0.000 claims description 3
- ZJIJAJXFLBMLCK-UHFFFAOYSA-N perfluorohexane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F ZJIJAJXFLBMLCK-UHFFFAOYSA-N 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 238000004381 surface treatment Methods 0.000 claims description 3
- 239000004425 Makrolon Substances 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 1
- 235000019441 ethanol Nutrition 0.000 claims 1
- 235000011187 glycerol Nutrition 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 abstract description 22
- 230000000052 comparative effect Effects 0.000 description 17
- 230000006835 compression Effects 0.000 description 16
- 238000007906 compression Methods 0.000 description 16
- 238000002834 transmittance Methods 0.000 description 16
- 238000012360 testing method Methods 0.000 description 8
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- -1 methyl tetrahydrophthalic acid Acid anhydride Chemical class 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical compound CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 description 1
- MWSKJDNQKGCKPA-UHFFFAOYSA-N 6-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1CC(C)=CC2C(=O)OC(=O)C12 MWSKJDNQKGCKPA-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- UMVBXBACMIOFDO-UHFFFAOYSA-N [N].[Si] Chemical compound [N].[Si] UMVBXBACMIOFDO-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 229910000062 azane Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- HYFLWBNQFMXCPA-UHFFFAOYSA-N o-toluene acid methyl ester Natural products CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 239000005439 thermosphere Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D27/00—Foundations as substructures
- E02D27/32—Foundations for special purposes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/043—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/18—Layered products comprising a layer of metal comprising iron or steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/061—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of metal
-
- B32B17/064—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/06—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions for securing layers together; for attaching the product to another member, e.g. to a support, or to another product, e.g. groove/tongue, interlocking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/552—Fatigue strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2607/00—Walls, panels
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Paleontology (AREA)
- Civil Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Structural Engineering (AREA)
- Photovoltaic Devices (AREA)
Abstract
The invention discloses a kind of new concrete module, the module includes photic zone, transparent protective layer, light functional layer, heat-conducting layer, stainless steel supporting layer, insulated damp-proof layer successively from top to bottom；The smooth functional layer is one kind in solar energy photovoltaic panel, LED display or luminous lamp plate；The stainless steel supporting layer is one kind in stainless steel plate, Reinforced Concrete Materials；Multiple boss are evenly arranged in the stainless steel supporting layer top surface edge, the boss height is equal to the heat-conducting layer, the sum of the thickness of light functional layer and protective layer.The present invention new concrete module have translucency is good, bearing is good, heat conductivity is good, the features such as being hardly damaged；It can be used for photovoltaic highway, be also used as light transmission pavement or park road surface, be also used as the concrete wall surface of light transmission, or be applied in non-light tight concrete display screen.
Description
Technical field
The invention belongs to civil engineering material technical fields, and in particular to a kind of new concrete module.
Background technology
Epoxy resin is widely used since it is with many excellent performances in civil engineering and building field, can be with
Substitute many traditional materials.It since epoxy resin has good translucency, can be also used in transparent concrete material, make
At translucent concrete, indoor building material can be used as with transmitted light, it is possible to reduce energy is saved in the use of indoor light
Source；Transparent material layer as photovoltaic highway can improve light utilization efficiency.But be above not mature enough in these applications at present, it deposits
In more disadvantage.
CN106549629A discloses a kind of assembled solar energy power generating road surface module and its application wherein uses ring
Oxygen resin, glass particle and curing agent prepare light transmission antiskid wearing layer, but which use a large amount of glass particle or tempering
Glass particle, and used the adhesive strength between less amount of epoxy resin and glass relatively low, according to being formulated in embodiment
Be made concrete, test its intensity find using single epoxide resin material there are lower temperature resistance difference and humidity resistance difference lack
Point.Since the bonding strength between glass particle in the invention is poor wear-resisting there is no water proof anti-soil is carried out additionally, due to its surface
Processing, causes surface to be easy to scratch, also becomes easily infected by spot, cause light transmittance lower.Due to disclosed in the patent application too
Positive energy photovoltaic panel is easy fever after extinction, and hot soak condition can influence the service life of photovoltaic panel.And the mould
There is no the supporting layer of high intensity and high tenacity in block, if being chronically at high load capacity loaded state is easy to cause module fracture.
Invention content
The present invention is to overcome above-mentioned problem of the prior art, provides a kind of new concrete module, has good light transmission
Property, bearing is good, and has heat-conducting layer, and module is hardly damaged, and service life is long.
Technical scheme is as follows：A kind of new concrete module, the module include light transmission successively from top to bottom
Layer, transparent protective layer, light functional layer, heat-conducting layer, stainless steel supporting layer, insulated damp-proof layer；The smooth functional layer is solar energy
One kind in photovoltaic panel, LED display or luminous lamp plate；The stainless steel supporting layer is stainless steel plate, Reinforced Concrete Materials
In one kind；Multiple boss are evenly arranged in the stainless steel supporting layer top surface edge, the boss height is equal to described
The sum of the thickness of heat-conducting layer, light functional layer and protective layer.Each layer can be separated and is molded in module of the present invention, then use asphalt mixtures modified by epoxy resin
Each layer is bonded to form integral module by the materials such as fat, neutral silicone weather-resistant glue, and the euphotic material can also directly cure
On the protective layer, there is good adhesive effect therewith.
The photic zone of the present invention can with transmitted light, in light functional layer setting can pass through the protective layer of light, the guarantor
Sheath and photic zone duplicate protection can be impaired to avoid light functional layer, heat-conducting layer are arranged under light functional layer, the heat generated
Stainless steel supporting layer is passed to, prevents light functional layer hot soak condition, the stainless steel supporting layer from can also ensure to mix
Solidifying clay model block has high intensity, can with long-time bearing high load capacity, the boss on stainless steel supporting layer directly and photic zone contact can
The stress of light transmission layer surface is passed to stainless steel supporting layer, disperses surface stress, make module load-bearing bigger.
Preferably, the concrete modular is long 40-80cm, and the side of the cuboid of wide 30-60cm, module is equipped with quickly
Connecting element, the rapid splicing component are hemispheric columnar projections and right side and rear side by the one end in front side and left side
One end is constituted for hemispheric indented in columnar.Fast interface ease of assembly grafting is set in the module of this programme, with the scene of improving
Construction efficiency.The hemispherical rapid splicing component, facilitates installation, stress intensity big.
Preferably, the photic zone is made of the raw material including following mass percent：The amine ring of 2-8% polyfunctionalities
The mixed type epoxy resin for having both alicyclic epoxy group and glycidol ester group, the 5-15% bisphenol A-types of oxygen resin, 10-30%
128 resins, 10-20% epoxy curing agents, 35-48% transparent glass particle, 2-8% silane coupling agents；The glass
The grain size of particle is 0.1-0.9mm；The amine epoxy resin of the polyfunctionality has both alicyclic epoxy group and ethylene oxidic ester
The percentage that the mixed type epoxy resin of base, the total amount of 128 resin of bisphenol A-type account for all raw materials is 30-40%.Use this programme
Preferred each raw material, proportionally sequential feeds cure after mixing can be obtained photic zone of the invention.This programme it is saturating
Photosphere translucency is excellent, can improve light utilization efficiency.The light transmission layer material of this programme can directly in light functional layer surface cure,
There is good cementability with multiple material, it is especially very high with glass adhesive strength.
Preferably, the photic zone is made of the raw material of following mass percent：5%AFG-90 epoxy resin, 20%
TDE-85 epoxy resin, 10% bisphenol A-type, 128 resin, 15% epoxy curing agent, 40% glass particle, 2%KH560 are even
Join agent, 3%KH512 coupling agents and 5%N, accelerine.This programme is preferably formulated with glass with higher Nian Jie strong
Degree, light transmittance are more preferable, it may have good ageing-resistant performance.
Preferably, the heat-conducting layer is at least one in heat-conducting metal, thermal conductive ceramic, heat-conducting resin or heat-conductive composite material
Kind.The heat-conducting layer can be processed into the shape fitted closely with light functional layer and stainless steel supporting layer, make light functional layer
Heat is quickly transmitted to stainless steel supporting layer, prevents light functional layer from being damaged because long term high temperature works.
Preferably, the insulated damp-proof layer and the protective layer are integrally formed using identical material is made, the protection
Layer is any one in transparent epoxy resin, tempered glass, organic glass or makrolon；The smooth functional layer, heat-conducting layer
It is packaged in the insulated damp-proof layer and the protective layer with stainless steel supporting layer.The protective layer of the protective layer selected materials
Light transmittance is good, and intensity is preferable, can protect light functional layer well.This programme integrated molding can seal light functional layer
Come, isolation external moisture etc. further protects light functional layer.
Preferably, the euphotic upper surface be equipped with several protrusions, everywhere protrusion all from euphotic upper table towards
Upper extension.
Preferably, the protrusion is arranged in cellular interleaved order, and the spacing of projection diameter 2-4mm, adjacent protrusion are
0.5-2cm, height of projection 1.2-2.5mm.The shape for the protrusion that the present invention is preferably provided with can effectively prevent skidding, especially suitable
For pavement and park road surface.
Preferably, the photic zone upper surface is handled by waterproof antiwear.This programme carries out photic zone at waterproof antiwear
Reason can use existing waterproof antiwear coating to spray or be vapor-deposited and form waterproof antiwear film.
Preferably, the waterproof antiwear processing uses following steps：(A) by grain size be 10-20nm nano silicon dioxide,
Absolute ethyl alcohol, silane coupling agent KH570 are with 4:20:1 mass ratio mixing, is dispersed with stirring and uniformly obtains silicon dioxde solution；(B)
It is in the nano zirconium dioxide of 30-40nm, absolute ethyl alcohol by grain size, silane coupling agent KH570 is with 4:40:3 mass ratio mixing,
It is dispersed with stirring and uniformly obtains zirconium dioxide solution；(C) by two silicon nitrogen of above-mentioned silicon dioxde solution, zirconium dioxide solution and hexamethyl
Alkane is with 50:47:3 mass ratioes mix, and are dispersed with stirring when vacuumizing and uniformly obtain surface treatment liquid；(D) by above-mentioned mixed processing
Liquid high pressure sprays to the euphotic upper surface after cleaning, drying in right amount；(E) 0.2% perfluoropolyether alkoxyl silicone will be contained
The perflexane solution of alkane sprays to euphotic upper surface in right amount, dry, is cleaned again to get to by waterproof antiwear surface
The photic zone of processing.It is preferable to use the processing of above-mentioned processing step to make one layer of oxidation titanyl of light transmission layer surface even application for this programme
Novel perfluoropolyether alkoxysilane is sprayed after SiClx coating again, the processing operation step of this programme is simple, uses two silicon of hexamethyl
The suitable nanosilica solution of azane collocation and zirconium dioxide solution, can not only reduce the dosage of silica, and can
To form stable anti-reflection film on glass particle surface, collocation novel perfluoropolyether alkoxysilane water-repellent paint uses, and is formed anti-
Water wear-resistant coating, not only has the effect of waterproof antiwear, can also improve light transmittance.
Photovoltaic battery panel or LED light etc. are all connected using conducting wire with adjacent module in the light functional layer of the present invention, then
Connect electrical circuitry.
Compared with prior art, the beneficial effects of the present invention are：(1) the bonding effect of photic zone light transmittance height and glass
Fruit is good, ageing-resistant；(2) module bearing is good；(3) anti-skidding (4) good heat conductivity of waterproof antiwear；(5) light functional layer is hardly damaged,
Service life is long.
The new concrete module of the present invention is due to excellent comprehensive performance, having broad application prospects：This hair
Bright module can assembled making on road surface, can be used for photovoltaic highway, be also used as light transmission pavement or park road surface,
It can also be assembled into metope, as the concrete wall surface of light transmission, or be applied in non-light tight concrete display screen.It can be with when use
The materials such as material, such as epoxy resin, neutral silicone weather-resistant glue of switching performance are laid on existing road surface by module assembled simultaneously
Bonding is laid on existing road surface or constitutes wall.
Description of the drawings
Fig. 1 is the positive structure schematic of 1 new concrete module of embodiment；
Fig. 2 is the overlooking structure diagram of 1 new concrete module of embodiment；
Fig. 3 is the light transmission layer surface enlarged diagram of 1 new concrete module of embodiment；
In figure：1, photic zone；2, protective layer；3, light functional layer；4, heat-conducting layer；5, stainless steel supporting layer；6, insulation and moisture
Layer；7, boss；8, rapid splicing component.
Specific implementation mode
Photic zone is made of the raw material including following mass percent in the embodiment of the present invention：30%-40% asphalt mixtures modified by epoxy resin,
10-20% epoxy curing agents, 35-48% transparent glass particle, 2-8% silane coupling agents；The epoxy resin is by such as
Three kinds of epoxy resin of hundred ratio of lower quality form：The amine epoxy resins of 2-8% polyfunctionalities, 10-30% have both it is alicyclic
The mixed type epoxy resin of epoxy group and glycidol ester group, 128 resin of 5-15% bisphenol A-types；The grain size of the glass particle
For 0.1-0.9mm.
The photic zone processing curing of the embodiment of the present invention is as follows：After mixing by three kinds of epoxy resin, glass is added
Glass particle, stirs evenly, and curing agent and coupling agent and optional n,N-Dimethylaniline is added, and vacuumizes to fall after stirring evenly
Enter the silica gel mould of suitable shape, 70 DEG C of solidification 2h and then again 120 DEG C of deep cure 3h demould up to photic zone.It can also incite somebody to action
Light functional layer or protective layer etc. are put into silica gel mould, reinject the euphotic raw material, are allowed to be directly solderable to light functional layer
Or protective layer.The groove or depression that specific shape can also be arranged on silica gel mould make the light transmission layer surface shape after solidification
At the protrusion of correspondingly-shaped.
The embodiment of the present invention sample and comparative example carry out the test under the same terms, including photic zone light transmission
Degree, compression strength, adhesive strength, skin-friction coefficient etc..
Clear, complete description is carried out to each technical solution of the present invention with reference to embodiments, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiment of the present invention, this field is common
Technical staff's obtained all other embodiment without making creative work belongs to the present invention and is protected
Range.Those skilled in the art are according to the equivalent transformation of method, process route, function made by following implementation or replace
Generation, all belong to the scope of protection of the present invention within.
Embodiment 1
A kind of new concrete module of the present embodiment, the module from top to bottom successively include photic zone 1, protective layer 2,
Light functional layer 3, heat-conducting layer 4, stainless steel supporting layer 5, insulated damp-proof layer 6；The smooth functional layer is solar energy photovoltaic panel.It is described
Photosphere is made of the raw material of following mass percent：5%AFG-90 epoxy resin, 20%TDE-85 epoxy resin, 10% bisphenol-A
128 resin of type, 15% epoxy curing agent, 40% glass particle, 2%KH560 coupling agents, 3%KH512 coupling agents and 5%
N,N-Dimethylaniline；The grain size of the glass particle is 0.4-0.5mm.
As shown in Fig. 1 to 3, concrete modular described in the present embodiment is long 60cm, the cuboid of wide 40cm；The stainless steel
Supporting layer upper surface quadrangle is each provided with a boss 7, and the boss height is equal to the heat-conducting layer, light functional layer and protective layer
The sum of thickness, each boss just contacts with photic zone, and single contact area is 16cm2。
The side of module is equipped with rapid splicing component 8, and the rapid splicing component is hemisphere by the one end in front side and left side
The columnar projections of shape and right side and one end of rear side are constituted for hemispheric indented in columnar.
The light transmission layer thickness is 5mm, and the euphotic upper surface is equipped with several protrusions, and the protrusion is in cellular friendship
Mistake is ranked sequentially, projection diameter 3mm, and the spacing of adjacent protrusion is 1cm, height of projection 2mm.
The heat-conducting layer is heat conducting nano carbon aluminium foil, thickness 1mm.The steel plate that the stainless steel support layer thickness is 8mm.
The protective layer and the insulated damp-proof layer and rapid splicing component are tempered glass, are integrally formed, the light
Functional layer, heat-conducting layer and stainless steel supporting layer are packaged in the insulated damp-proof layer and the protective layer, then by photic zone material
Material is directly fixed in protective layer.It is laid on road surface using epoxy resin adhesive bonding when module assembled.
The euphotic light transmittance of the present embodiment is 96.2%, compression strength 69.1MPa, is with protective layer adhesion strength
41.0MPa, skin-friction coefficient 0.81.It is only 1 DEG C that 4 hours temperature of photovoltaic panel work, which increase,.2cm*2cm is big among to module
Area at be continuously applied the pressure 10min of 400 kgfs, module includes in solar energy photovoltaic panel without damaged and crackle.
In addition the photic zone of the present embodiment is passed through respectively wet 90% in 90% humidity, 90 DEG C of high-temperature process and 48h for 24 hours
Compression strength is tested after -40 DEG C of low-temperature treatments of degree again, compression strength, which reduces, is no more than 5%, the photic zone material of the present embodiment
Material has good wet-heat resisting and cryogenic property.
Embodiment 2
Photic zone upper surface described in the present embodiment uses following steps by waterproof antiwear processing compared with Example 1：(A)
It is the nano silicon dioxide of 10-20nm, absolute ethyl alcohol, silane coupling agent KH570 with 4 by grain size:20:1 mass ratio mixing, is stirred
It mixes and is uniformly dispersed to obtain silicon dioxde solution；(B) be in the nano zirconium dioxide of 30-40nm, absolute ethyl alcohol by grain size, silane it is even
Join agent KH570 with 4:40:3 mass ratio mixing, is dispersed with stirring and uniformly obtains zirconium dioxide solution；(C) by above-mentioned silica
Solution, zirconium dioxide solution and hexamethyldisilazane are with 50:47:3 mass ratioes mix, and uniform obtain is dispersed with stirring when vacuumizing
To surface treatment liquid；(D) above-mentioned mixed treating liquid high pressure is sprayed to the euphotic upper surface after cleaning, drying in right amount；(E)
Perflexane solution containing 0.2% novel perfluoropolyether alkoxysilane is sprayed into euphotic upper surface in right amount, it is dry, then
Secondary cleaning is to get the photic zone being surface-treated to process waterproof antiwear.It is other same as Example 1.
The euphotic light transmittance of the present embodiment is 96.3%, skin-friction coefficient 0.83.
The wearability that photic zone face coat is tested using reciprocating abrasion-resistant testing machine, using rubber 10kgf in light transmission
After layer surface carries out reciprocal 1000 frictions, the light transmittance after testing friction is 96.0%, skin-friction coefficient 0.83, with
Light transmittance and friction coefficient vary less before wear-resisting test, illustrate that the wearability of face coat is good.
Embodiment 3
Light transmission layer thickness described in the present embodiment is 5mm compared with Example 1, and the euphotic upper surface is equipped with several convex
Rise, it is described it is convex be parallel striped, the spacing of adjacent protrusion striped is 3cm, ledge width 3mm, is highly 0.5mm.
The euphotic light transmittance of the present embodiment is 97.5%, skin-friction coefficient 0.78.
Embodiment 4
The photic zone of the present embodiment is made of the raw material of following mass percent compared with Example 1：2%AFG-90 epoxies
Resin, 30%TDE-85 epoxy resin, 8% bisphenol A-type, 128 resin, 35% glass particle, 5% methyl tetrahydrophthalic acid
Acid anhydride, 5% diethyl toluene diamine, 5% dicyandiamide, 2%KH560 coupling agents, 3%KH512 coupling agents and 5%N, N- dimethyl benzene
Amine；The grain size of the glass particle is 0.6-0.9mm.
The euphotic light transmittance of the present embodiment is 95.6%, compression strength 67.2MPa, is with protective layer adhesion strength
38.4MPa, skin-friction coefficient 0.80.
Embodiment 5
A kind of new concrete module of the present embodiment, the module include photic zone, transparency protected successively from top to bottom
Layer, light functional layer, heat-conducting layer, stainless steel supporting layer, insulated damp-proof layer；The smooth functional layer is LED display；The stainless steel
Multiple boss are evenly arranged in supporting layer top surface edge, the boss height is equal to the heat-conducting layer, light functional layer and guarantor
The sum of thickness of sheath.The photic zone is made of the raw material of following mass percent：8%AFG-90 epoxy resin, 10%
TDE-85 epoxy resin, 15% bisphenol A-type, 128 resin, 42% glass particle, 5% methyl tetrahydrophthalic anhydride, 5% 2
Ethyltoluene diamines, 5% dicyandiamide, 2%KH560 coupling agents, 3%KH512 coupling agents and 5%N, accelerine；It is described
The grain size of glass particle is 0.1-0.3mm.Photic zone upper surface described in the present embodiment is handled by waterproof antiwear, with embodiment 2
Middle processing method is identical.
The concrete modular is long 80cm, and the floor space of the cuboid of wide 60cm, each layer of the present embodiment is all long 80cm,
The rectangle of wide 60cm.Stainless steel supporting layer upper surface quadrangle is each provided with a boss, and each boss sectional area is
20cm2。
The light transmission layer thickness is 4mm.
The heat-conducting layer is heat-conducting silicon rubber, thickness 1mm.The stainless steel supporting layer is the concrete containing bar-mat reinforcement
Layer, thickness 4mm.The insulated damp-proof layer is waterproof ceramic tile.Each layer of the present embodiment seals glue sticking by transparent silicone.
The euphotic light transmittance of the present embodiment is 97.0%, compression strength 66.4MPa, with light functional layer adhesion strength
For 37.1MPa, LED display continue working 8h, temperature increases 2 DEG C.
In addition the photic zone of the present embodiment is passed through respectively wet 90% in 90% humidity, 90 DEG C of high-temperature process and 48h for 24 hours
Compression strength is tested after -40 DEG C of low-temperature treatments of degree again, compression strength, which reduces, is no more than 5%, the photic zone material of the present embodiment
Material has good wet-heat resisting and cryogenic property.
The wearability that photic zone face coat is tested using reciprocating abrasion-resistant testing machine, using rubber 10kgf in light transmission
After layer surface carries out reciprocal 1000 frictions, the light transmittance after testing friction is light transmittance change before 96.2%, with wear-resisting test
Change very little, illustrates that the wearability of face coat is good.
The static contact angle of Modular surface and water is 110 °, has good water proofing property.
The module of the present embodiment has high intensity suitable for the outdoor display screen wall as displaying or publicity, and
It is moisture-proof that LED screen is water-fast, and service life is long, Modular surface waterproof antiwear, convenient for cleaning.
Comparative example 1
The photic zone of this comparative example of this comparative example compared with Example 1 is made of the raw material of following mass percent：2%
E42 types epoxy resin, 97.4% toughened glass grains, 0.6% ethylenediamine.Light transmission layer surface is not provided with protrusion, and is not provided with leading
Thermosphere.It is other same as Example 1.
The euphotic light transmittance of this comparative example is 97.6%, compression strength 32.5MPa, is with protective layer adhesion strength
14.2MPa, skin-friction coefficient 0.41.4 hours temperature of photovoltaic panel work increase 6 DEG C under the conditions of same as Example 1
This illustrates that embodiment 1 and 2 relative contrast's example 1 of embodiment have good translucency, bonding strength and compression strength, table
Face friction coefficient is big, and skid resistance is good, and thermal conductivity is more preferable, and photovoltaic module is hardly damaged.
In addition the photic zone of this comparative example is passed through respectively wet 90% in 90% humidity, 90 DEG C of high-temperature process and 48h for 24 hours
Compression strength is tested after -40 DEG C of low-temperature treatments of degree again, compression strength is reduced more than 30%, the light transmission layer material of the present embodiment
With good wet-heat resisting and cryogenic property.
Comparative example 2
The photic zone of this comparative example compared with Example 5 is made of the raw material of following mass percent：2%AFG-90 rings
Oxygen resin, 5%TDE-85 epoxy resin, 5% bisphenol A-type, 128 resin, 80% glass particle, 8% methyl tetrahydrophthalic acid
Acid anhydride；The grain size of the glass particle is 0.4-0.5mm.Light transmission layer surface is not provided with protrusion, and is not provided with heat-conducting layer.It is other with it is real
It is identical to apply example 1.
The euphotic light transmittance of this comparative example is 75.1%, compression strength 31.5MPa, is with light functional layer adhesion strength
13.2MPa.LED display continue working 8h under the conditions of same as Example 5, temperature increase 8 DEG C.
This illustrates that 5 relative contrast's example 2 of embodiment has good translucency, adhesive strength and compression strength, and thermal conductivity is more preferable,
LED display is hardly damaged.
In addition the photic zone of this comparative example is passed through respectively wet 90% in 90% humidity, 90 DEG C of high-temperature process and 48h for 24 hours
Compression strength is tested after -40 DEG C of low-temperature treatments of degree again, compression strength is reduced more than 30%, the light transmission layer material of the present embodiment
With good wet-heat resisting and cryogenic property.
Comparative example 3
The stainless steel supporting layer of this comparative example is not provided with boss compared with Example 1, other same as Example 1.
Continue the pressure 10min of 400 kgfs of application at the big areas of 2cm*2cm, solar energy photovoltaic panel among to module
And occurs larger amount of damaged and crackle in photic zone.
Comparative example 4
This comparative example is not provided with stainless steel supporting layer compared with Example 1.Continue the big areas of 2cm*2cm among to module
Place applies the pressure 10min of 400 kgfs, solar energy photovoltaic panel and photic zone and the equal extensive disruption of protective layer.
In conjunction with the result of comparative example 1 and comparative example 3 and comparative example 4, it can be seen that stainless steel supporting layer can carry
High module anti-pressure ability, with boss stainless steel supporting layer can preferably dispersed modules surface pressure, pressure is passed to
To bottom so that the pressure of surface and light functional layer is dispersed, and can be very good protection light functional layer and surface photic zone.
Above although an embodiment of the present invention has been shown and described, for the ordinary skill in the art,
It is appreciated that a variety of to the progress of these embodiments can change without departing from the principles and spirit of the present invention, change,
Replacement and modification, the scope of the present invention is defined by the appended.
Claims (10)
1. a kind of new concrete module, which is characterized in that the module includes photic zone, transparent protection successively from top to bottom
Layer, light functional layer, heat-conducting layer, stainless steel supporting layer, insulated damp-proof layer；The smooth functional layer is solar energy photovoltaic panel, LED is shown
One kind in screen or luminous lamp plate；The stainless steel supporting layer is one kind in stainless steel plate, Reinforced Concrete Materials；It is described
Multiple boss are evenly arranged in stainless steel supporting layer top surface edge, the boss height is equal to the heat-conducting layer, light function
The sum of the thickness of layer and protective layer.
2. a kind of new concrete module according to claim 1, which is characterized in that the concrete modular is long 40-
The side of 80cm, the cuboid of wide 30-60cm, module are equipped with rapid splicing component, and the rapid splicing component is by front side and a left side
One end of side is that one end of hemispheric columnar projections and right side and rear side is that hemispheric indented in columnar is constituted.
3. a kind of new concrete module according to claim 1, which is characterized in that the photic zone is by including following matter
The raw material of amount percentage is made：The amine epoxy resins of 2-8% polyfunctionalities, 10-30% have both alicyclic epoxy group and contracting
Mixed type epoxy resin, 128 resin of 5-15% bisphenol A-types, 10-20% epoxy curing agents, the 35-48% of water glycerine ester group
Transparent glass particle, 2-8% silane coupling agents；The grain size of the glass particle is 0.1-0.9mm；The amine of the polyfunctionality
Based epoxy resin, the mixed type epoxy resin for having both alicyclic epoxy group and glycidol ester group, 128 resin of bisphenol A-type it is total
The percentage that amount accounts for all raw materials is 30-40%.
4. a kind of new concrete module according to claim 3, which is characterized in that the photic zone is by following quality hundred
The raw material of ratio is divided to be made：5%AFG-90 epoxy resin, 20%TDE-85 epoxy resin, 10% bisphenol A-type, 128 resin, 15% ring
Oxygen resin curing agent, 40% glass particle, 2%KH560 coupling agents, 3%KH512 coupling agents and 5%N, accelerine.
5. a kind of new concrete module according to claim 1, which is characterized in that the heat-conducting layer be heat-conducting metal,
At least one of thermal conductive ceramic, heat-conducting resin or heat-conductive composite material.
6. a kind of new concrete module according to claim 1, which is characterized in that the insulated damp-proof layer and the guarantor
Sheath using identical material be integrally formed be made, the protective layer be transparent epoxy resin, tempered glass, organic glass or
Any one in makrolon；The smooth functional layer, heat-conducting layer and stainless steel supporting layer be packaged in the insulated damp-proof layer and
In the protective layer.
7. a kind of new concrete module according to claim 1, which is characterized in that the euphotic upper surface is equipped with
Several protrusions, everywhere protrusion are all upwardly extended from euphotic upper surface.
8. a kind of new concrete module according to claim 7, which is characterized in that the protrusion is in cellular staggeredly suitable
Sequence arranges, projection diameter 2-4mm, and the spacing of adjacent protrusion is 0.5-2cm, height of projection 1.2-2.5mm.
9. according to a kind of new concrete module of claim 1 to 8 any one of them, which is characterized in that on the photic zone
Surface is handled by waterproof antiwear.
10. a kind of new concrete module according to claim 9, which is characterized in that the waterproof antiwear processing uses
Following steps：(A) it is the nano silicon dioxide of 10-20nm, absolute ethyl alcohol, silane coupling agent KH570 with 4 by grain size:20:1
Mass ratio mixes, and is dispersed with stirring and uniformly obtains silicon dioxde solution；(B) by nano zirconium dioxide, anhydrous that grain size is 30-40nm
In ethyl alcohol, silane coupling agent KH570 is with 4:40:3 mass ratio mixing, is dispersed with stirring and uniformly obtains zirconium dioxide solution；(C) will
Above-mentioned silicon dioxde solution, zirconium dioxide solution and hexamethyldisilazane are with 50:47:3 mass ratioes mix, and are stirred when vacuumizing
It mixes and is uniformly dispersed to obtain surface treatment liquid；(D) by above-mentioned mixed treating liquid high pressure in right amount spray to cleaning after it is euphotic on
Surface, drying；(E) the perflexane solution containing 0.2% novel perfluoropolyether alkoxysilane is sprayed in right amount euphotic
Upper surface is dried, and is cleaned again to get the photic zone being surface-treated to process waterproof antiwear.
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