CN108611868A - A kind of antibacterial fabric and preparation method thereof - Google Patents

A kind of antibacterial fabric and preparation method thereof Download PDF

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Publication number
CN108611868A
CN108611868A CN201810418272.1A CN201810418272A CN108611868A CN 108611868 A CN108611868 A CN 108611868A CN 201810418272 A CN201810418272 A CN 201810418272A CN 108611868 A CN108611868 A CN 108611868A
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fabric
stirred
antibacterial
solution
added
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金良
金宇豪
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Jiaxing Chakesha Clothing Ltd By Share Ltd
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Jiaxing Chakesha Clothing Ltd By Share Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00Producing multi-layer textile fabrics
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/533Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/503Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms without bond between a carbon atom and a metal or a boron, silicon, selenium or tellurium atom
    • D06M13/507Organic silicon compounds without carbon-silicon bond
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/13Alginic acid or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507Polyesters
    • D06M15/513Polycarbonates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
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    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides
    • D06M2101/36Aromatic polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24Viscose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
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    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

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  • Chemical & Material Sciences (AREA)
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  • Life Sciences & Earth Sciences (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
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  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The present invention provides a kind of antibacterial fabric, including base fabric, it is characterised in that; the scrim surfaces are provided with antibiotic layer; the antibiotic layer upper surface is provided with cotton fabric layer, and matcoveredn is arranged in cotton fabric layer upper surface, and the base fabric includes the raw material of following mass percent:20 ~ 30% aramid fibers, 40 ~ 50% polyester fibers, 20 ~ 30% viscose rayons, 5 10% conductive fibers, the present invention also provides the preparation methods of the antibacterial fabric simultaneously, using environmentally friendly and low production cost technological process, the fabric with the endurable effect of good antibacterial has been obtained.

Description

A kind of antibacterial fabric and preparation method thereof
Technical field
The invention belongs to field of textiles, and in particular to arrive a kind of antibacterial fabric and preparation method thereof.
Background technology
In clothes big world, the fabric of clothes is multifarious, makes rapid progress, but generally, it is high-quality, high-grade Fabric, mostly have the characteristics that wear comfortable, sweat-absorbing breathable, several aspects such as pendency is well-pressed, vision is noble, tactile is soft, Modern times are produced on the clothes of formal social life institute wear, the good blended yarn weaved fabric of multiselect.And it is pure cotton, pure wool, pure silk, pure The natural fabric such as fiber crops has become general cloth because there is the shortcomings that easily natural fabric such as wrinkle, yielding, less as high-grade Clothes materials.Blended yarn weaved fabric has the characteristics that natural fabric sweat-absorbing breathable, softness are comfortable, and it is solid resistance to absorb chemical fiber plus material It wears, overhang the advantages that well-pressed, good luster color is vivid, there is a large amount of high-grade high-quality blended yarn weaved fabric to be developed every year, and with Improvement of living standard, people need the various functions of fabric higher and higher, traditional fabric shortage antibacterial, antistatic etc. Function, especially in extraordinary occasion, needs clothes to provide anti-antibacterial functions usually based on comfortable and easy to wear and appearance looks elegant, Therefore seek it is a kind of with antibacterial and fabric comfortable and easy to wear it is particularly important.
Invention content
Originally it is insufficient that the purpose of the present invention is to overcome the above shortcomings, provides a kind of fabric with antibacterial functions.
The object of the present invention is achieved like this:
A kind of antibacterial fabric, including base fabric, the scrim surfaces are provided with antibiotic layer, and the antibiotic layer upper surface is provided with cotton and knits Matcoveredn is arranged in nitride layer, cotton fabric layer upper surface.
The base fabric includes the raw material of following mass percent:20 ~ 30% aramid fibers, 40 ~ 50% polyester fibers, 20 ~ 30% are glued Glue fiber, 5-10% conductive fibers, generally use match as follows:20% aramid fiber, 45% polyester fiber, 25% viscose rayon, 10% conductive fiber.
The present invention also provides the preparation methods of the antibacterial fabric, include the following steps:
S1 base fabrics are weaved:
Warp yarn:Doubling frame is twisted with having by two aramid fibers, single thread of the conductive fiber proportioning between 40S ∕ 1-60S/1 simultaneously It closes, two-for-one twister twists 1200-1400T/m, and S is twisted, ingot speed 8000-9000r/min;
Weft yams:Doubling frame is twisted with having by single thread between 30S ∕ 1-50S/1 of two polyester fibers, viscose rayon and conjunction, Two-for-one twister twists 1400-1500T/m, and Z is twisted, ingot speed 7000-8000r/min;
Using rapier loom or air-jet loom weaving, 2 colors or 4 colors select latitude, 315 ° of angles of opening time automatically;
Fabric specification:Breadth 165cm, 350/10cm of weft density on machine;
The processing of S2 scrim surfaces:
Configure antimicrobial treatment solution:Using following materials in percentage by mass, 40 ~ 50% chitosans, 30 ~ 40% carvacrols, 20 ~ 30% sodium alginate, 0.1 ~ 1% nano silver;
Whole chitosan powder are dissolved in acetum, PH is 5 ~ 6.5,5 ~ 7h is stirred at room temperature, at deacetylated Chitin solution;
Whole carvacrol powder are dissolved in ethanol solution, 5 ~ 7h is stirred at room temperature, at Sheep's-parsley phenol solution;
Whole sodium alginates are dissolved in deionized water, 5 ~ 7h is stirred at room temperature, at annex solution;
Chitosan solution and Sheep's-parsley phenol solution are mixed, 10min, mixing speed 900r/min are stirred, is then added Enter sodium chloride, stir 10min at 35 DEG C, form blended liquid, be then added glycerine, the volume ratio of blended liquid and glycerine is 1: 0.2,15min is stirred at room temperature, annex solution and whole nano silvers is then added, 15min is stirred at room temperature, then presses 5 DEG C/speed of min is warming up to 75 DEG C, 5min is stirred at a temperature of 75 DEG C, forms antibacterial glue;
Base fabric is immersed in antibacterial glue, using an immersing and rolling(Liquid carrying rate 80 ~ 90%)Surface dip dyeing is carried out, is dried at 85 DEG C, Drying time is 5min.
The processing of S3 cotton fabric layer surfaces:
Pre-treatment:It is 1 by volume ratio:1 ~ 1.5 ethyl alcohol and ammonium hydroxide mixing, 30min is stirred at 20 DEG C, forms ethyl alcohol, ammonia Water mixed liquid, it is 1 to be then added with ethyl alcohol, ammonia water mixture volume ratio:20 tetraethyl orthosilicate stirs 60min and stands 30min forms pretreatment liquid, cotton fabric layer is immersed in pre-treatment, using an immersing and rolling(Liquid carrying rate 70 ~ 80%)Carry out surface Dip dyeing, is dried, drying time 3min at 80 DEG C, completes pre-treatment;
Post-processing:It is 1 by content ratio:1:1 octyl trimethoxy silane, dodecyltrimethoxysilane, cetyl three Methoxy silane is added in ethyl alcohol, and acetic acid and deionized water are added while agitating, 35min is stirred at 25 DEG C, is formed Then cotton fabric Jing Guo pre-treatment is immersed in aftertreatment fluid and stands 90min by aftertreatment fluid, be placed in after air-drying at normal temperatures In baking oven, 30min is dried at 120 DEG C, completes post-processing.
Glue molding between the base fabric and cotton fabric layer, adhesive use general fabric adhesive.
In conclusion the present invention has the following advantages:
(1)Antibacterial fabric provided by the invention, has base cloth layer and cotton fabric layer, and base cloth layer has wear-resisting, antibacterial, antistatic The features such as, cotton fabric layer has the characteristics that comfortable feel and warming, and cotton fabric layer increases tool by surface treatment on surface Have waterproof, wind-shielding function protective layer, further coordinate base fabric antibiotic property, avoid bacterium from entering.
(2)Antibacterial fabric provided by the invention, base fabric include aramid fiber, polyester fiber, viscose rayon and conductive fibre Dimension, has gathered that polyester fiber is strong durable and wash and wear, viscose rayon are soft ventilative and antistatic, Moisture Sorption of Aromatic Polyamide Fibers Property the good and shock resistance and anlistatig feature of conductive fiber, uniformly divided in the fabric using conductive fiber using conductive fiber Cloth, it is whole to reduce fabric volume resistivity, charge buildup is reduced, eliminates electrostatic, conductive fiber is generally referred in 20 DEG C 6 of temperature Under the conditions of 5%RH, resistivity is less than the fiber of 108Qcm, and under the action of electrostatic field, air is fine by the conduction in fabric Dimension effect, which generates, ionizes and is formed negative ions, and one of which ion is with fabric institute static electrification lotus on the contrary, to mutually neutralize;Separately A kind of outer electrostatic charge with environment or in the earth neutralizes, and electrostatic is eliminated with this, obtains having the advantages that above-mentioned and beyond above-mentioned excellent The base fabric of point, it is both comfortable and easy to wear and antistatic.
(3)Antibacterial fabric provided by the invention has carried out antimicrobial treatment to base fabric, has obtained with good anti-microbial property Base fabric, and the treatment process environment-friendly and green used is pollution-free, belongs to environmentally friendly product.
(4)Antibacterial fabric provided by the invention also adds surface treated cotton fabric layer outside base cloth layer, passes through Treated cotton fabric layer surface water proof wind proof further prevents bacterium to pass through wind or rainwater etc. and invades human body, coordinates antibacterial Base fabric, it is whole to reach antibacterial effect outstanding.
Specific implementation mode
With reference to related embodiment, the specific implementation mode of the present invention is described in further detail.Following embodiment For illustrating the present invention, but it is not limited to the scope of the present invention.
Embodiment 1
A kind of antibacterial fabric, including base fabric, the scrim surfaces are provided with antibiotic layer, and the antibiotic layer upper surface is provided with cotton and knits Matcoveredn is arranged in nitride layer, cotton fabric layer upper surface, and base fabric includes the raw material of following mass percent:20% aramid fiber, 45% polyester fiber, 25% viscose rayon, 10% conductive fiber.
The antibacterial fabric includes following preparation process:
Be base fabric weaving first, first manufacture warp thread and weft yarn, wherein warp yarn with have twirl doubling frame by two aramid fibers, Single thread and conjunction of the conductive fiber proportioning in 60S/1, two-for-one twister twist 1400T/m, and S is twisted, ingot speed 9000r/min;Weft yams are used There are the single thread and conjunction for twisting doubling frame by two polyester fibers, viscose rayon in 50S/1, two-for-one twister to twist 1500T/m, Z is twisted, ingot speed Then 8000r/min uses rapier loom or air-jet loom to be weaved, 2 colors or 4 colors select latitude, 315 ° of angles of opening time automatically; Fabric specification:Breadth 165cm, 350/10cm of weft density on machine.
Followed by scrim surfaces antimicrobial treatment:
The first step is configuration antimicrobial treatment solution:Using following materials in percentage by mass, 40% chitosan, 30% carvacrol, 30% sodium alginate, 1% nano silver;First whole chitosan powder are dissolved in acetum, PH 6 is stirred at room temperature 5h is mixed, at chitosan solution;Then whole carvacrol powder are dissolved in ethanol solution, 5h is stirred at room temperature, at Sheep's-parsley phenol solution;Whole sodium alginates are dissolved in deionized water, 6h is stirred at room temperature, at annex solution;It then will be deacetylated Chitin solution and the mixing of Sheep's-parsley phenol solution, stir 10min, then sodium chloride is added, 35 in mixing speed 900r/min It stirs 10min at DEG C, forms blended liquid, be then added glycerine, the volume ratio of blended liquid and glycerine is 1:0.2, at room temperature 15min is stirred, annex solution and whole nano silvers is then added, 15min is stirred at room temperature, then presses the speed of 5 DEG C/min 75 DEG C are warming up to, 5min is stirred at a temperature of 75 DEG C, forms antibacterial glue;
Second cloth is antimicrobial treatment:Base fabric is immersed in antibacterial glue, using an immersing and rolling(Liquid carrying rate 80 ~ 90%)Carry out surface Dip dyeing, is dried at 85 DEG C, and drying time is 5min to get to the base fabric with antibacterial functions.
Followed by the processing of cotton fabric layer surface:Including pre-treatment and post-processing, it is 1 that pre-treatment, which is by volume ratio,:1.5 Ethyl alcohol and ammonium hydroxide mixing, 30min is stirred at 20 DEG C, forms ethyl alcohol, ammonia water mixture, is then added mixed with ethyl alcohol, ammonium hydroxide It is 1 to close liquid volume ratio:20 tetraethyl orthosilicate stirs 60min and stands 30min, forms pretreatment liquid, cotton fabric layer is soaked Enter in pre-treatment, using an immersing and rolling(Liquid carrying rate 70 ~ 80%)Surface dip dyeing is carried out, is dried at 80 DEG C, drying time is 3min completes pre-treatment;It is 1 that post-processing, which is by content ratio,:1:1 octyl trimethoxy silane, dodecyl trimethoxy silicon Alkane, hexadecyl trimethoxy silane are added in ethyl alcohol, and acetic acid and deionized water are added while agitating, is stirred at 25 DEG C 35min is mixed, aftertreatment fluid is formed, then the cotton fabric Jing Guo pre-treatment is immersed in aftertreatment fluid and stands 90min, at normal temperatures After air-drying in merging baking oven, 30min is dried at 120 DEG C, is completed post-processing and is knitted to get to the cotton with water proof wind proof function Nitride layer.
It is finally the bonding of fabric, base cloth layer and cotton fabric layer is bonded using common fabric adhesive and complete to be somebody's turn to do It is prepared by the production of fabric.
Embodiment 2
A kind of antibacterial fabric, including base fabric, the scrim surfaces are provided with antibiotic layer, and the antibiotic layer upper surface is provided with cotton and knits Matcoveredn is arranged in nitride layer, cotton fabric layer upper surface, and base fabric includes the raw material of following mass percent:20% aramid fiber, 45% polyester fiber, 25% viscose rayon, 10% conductive fiber.
The antibacterial fabric includes following preparation process:
Be base fabric weaving first, first manufacture warp thread and weft yarn, wherein warp yarn with have twirl doubling frame by two aramid fibers, Single thread and conjunction of the conductive fiber proportioning in 60S/1, two-for-one twister twist 1200T/m, and S is twisted, ingot speed 9000r/min;Weft yams are used There are the single thread and conjunction for twisting doubling frame by two polyester fibers, viscose rayon in 40S/1, two-for-one twister to twist 1400T/m, Z is twisted, ingot speed Then 8000r/min uses rapier loom or air-jet loom to be weaved, 2 colors or 4 colors select latitude, 315 ° of angles of opening time automatically; Fabric specification:Breadth 165cm, 350/10cm of weft density on machine.
Followed by scrim surfaces antimicrobial treatment:
The first step is configuration antimicrobial treatment solution:Using following materials in percentage by mass, 45% chitosan, 35% carvacrol, 20% sodium alginate, 1% nano silver;First whole chitosan powder are dissolved in acetum, PH 5.5, at room temperature 5h is stirred, at chitosan solution;Then whole carvacrol powder are dissolved in ethanol solution, 5h are stirred at room temperature, At Sheep's-parsley phenol solution;Whole sodium alginates are dissolved in deionized water, 6h is stirred at room temperature, at annex solution;Then by de- second Acyl chitin solution and the mixing of Sheep's-parsley phenol solution, stir 10min, then sodium chloride is added in mixing speed 900r/min, It stirs 10min at 35 DEG C, forms blended liquid, be then added glycerine, the volume ratio of blended liquid and glycerine is 1:0.2, in room temperature Then lower stirring 15min is added annex solution and whole nano silvers, 15min is stirred at room temperature, then presses the speed of 5 DEG C/min Degree is warming up to 75 DEG C, and 5min is stirred at a temperature of 75 DEG C, forms antibacterial glue;
Second cloth is antimicrobial treatment:Base fabric is immersed in antibacterial glue, using an immersing and rolling(Liquid carrying rate 80 ~ 90%)Carry out surface Dip dyeing, is dried at 85 DEG C, and drying time is 5min to get to the base fabric with antibacterial functions.
Followed by the processing of cotton fabric layer surface:Including pre-treatment and post-processing, it is 1 that pre-treatment, which is by volume ratio,:1.5 Ethyl alcohol and ammonium hydroxide mixing, 30min is stirred at 20 DEG C, forms ethyl alcohol, ammonia water mixture, is then added mixed with ethyl alcohol, ammonium hydroxide It is 1 to close liquid volume ratio:20 tetraethyl orthosilicate stirs 60min and stands 30min, forms pretreatment liquid, cotton fabric layer is soaked Enter in pre-treatment, using an immersing and rolling(Liquid carrying rate 70 ~ 80%)Surface dip dyeing is carried out, is dried at 80 DEG C, drying time is 3min completes pre-treatment;It is 1 that post-processing, which is by content ratio,:1:1 octyl trimethoxy silane, dodecyl trimethoxy silicon Alkane, hexadecyl trimethoxy silane are added in ethyl alcohol, and acetic acid and deionized water are added while agitating, is stirred at 25 DEG C 35min is mixed, aftertreatment fluid is formed, then the cotton fabric Jing Guo pre-treatment is immersed in aftertreatment fluid and stands 90min, at normal temperatures After air-drying in merging baking oven, 30min is dried at 120 DEG C, is completed post-processing and is knitted to get to the cotton with water proof wind proof function Nitride layer.
The bonding such as embodiment 1 of last fabric.
Embodiment 3
A kind of antibacterial fabric, including base fabric, the scrim surfaces are provided with antibiotic layer, and the antibiotic layer upper surface is provided with cotton and knits Matcoveredn is arranged in nitride layer, cotton fabric layer upper surface, and base fabric includes the raw material of following mass percent:20% aramid fiber, 45% polyester fiber, 25% viscose rayon, 10% conductive fiber.
The antibacterial fabric includes following preparation process:
Be base fabric weaving first, first manufacture warp thread and weft yarn, wherein warp yarn with have twirl doubling frame by two aramid fibers, Single thread and conjunction of the conductive fiber proportioning in 60S/1, two-for-one twister twist 1400T/m, and S is twisted, ingot speed 9000r/min;Weft yams are used There are the single thread and conjunction for twisting doubling frame by two polyester fibers, viscose rayon in 50S/1, two-for-one twister to twist 1500T/m, Z is twisted, ingot speed Then 8000r/min uses rapier loom or air-jet loom to be weaved, 2 colors or 4 colors select latitude, 315 ° of angles of opening time automatically; Fabric specification:Breadth 165cm, 350/10cm of weft density on machine.
Followed by scrim surfaces antimicrobial treatment:
The first step is configuration antimicrobial treatment solution:Using following materials in percentage by mass, 50% chitosan, 30% carvacrol, 20% sodium alginate, 1% nano silver;First whole chitosan powder are dissolved in acetum, PH 6 is stirred at room temperature 5h is mixed, at chitosan solution;Then whole carvacrol powder are dissolved in ethanol solution, 5h is stirred at room temperature, at Sheep's-parsley phenol solution;Whole sodium alginates are dissolved in deionized water, 6h is stirred at room temperature, at annex solution;It then will be deacetylated Chitin solution and the mixing of Sheep's-parsley phenol solution, stir 10min, then sodium chloride is added, 35 in mixing speed 900r/min It stirs 10min at DEG C, forms blended liquid, be then added glycerine, the volume ratio of blended liquid and glycerine is 1:0.2, at room temperature 15min is stirred, annex solution and whole nano silvers is then added, 15min is stirred at room temperature, then presses the speed of 5 DEG C/min 75 DEG C are warming up to, 5min is stirred at a temperature of 75 DEG C, forms antibacterial glue;
Second cloth is antimicrobial treatment:Base fabric is immersed in antibacterial glue, using an immersing and rolling(Liquid carrying rate 80 ~ 90%)Carry out surface Dip dyeing, is dried at 85 DEG C, and drying time is 5min to get to the base fabric with antibacterial functions.
Followed by the processing of cotton fabric layer surface:Including pre-treatment and post-processing, it is 1 that pre-treatment, which is by volume ratio,: 1.5 Ethyl alcohol and ammonium hydroxide mixing, stir 30min at 20 DEG C, form ethyl alcohol, ammonia water mixture, be then added and ethyl alcohol, ammonium hydroxide Mixeding liquid volume ratio is 1:20 tetraethyl orthosilicate stirs 60min and stands 30min, pretreatment liquid formed, by cotton fabric layer It immerses in pre-treatment, using an immersing and rolling(Liquid carrying rate 70 ~ 80%)Surface dip dyeing is carried out, is dried at 80 DEG C, drying time is 3min completes pre-treatment;It is 1 that post-processing, which is by content ratio,:1:1 octyl trimethoxy silane, dodecyl trimethoxy silicon Alkane, hexadecyl trimethoxy silane are added in ethyl alcohol, and acetic acid and deionized water are added while agitating, is stirred at 25 DEG C 35min is mixed, aftertreatment fluid is formed, then the cotton fabric Jing Guo pre-treatment is immersed in aftertreatment fluid and stands 90min, at normal temperatures After air-drying in merging baking oven, 30min is dried at 120 DEG C, is completed post-processing and is knitted to get to the cotton with water proof wind proof function Nitride layer.
The bonding such as embodiment 1 of last fabric.
Embodiment 4
A kind of antibacterial fabric, including base fabric, the scrim surfaces are provided with antibiotic layer, and the antibiotic layer upper surface is provided with cotton and knits Matcoveredn is arranged in nitride layer, cotton fabric layer upper surface, and base fabric includes the raw material of following mass percent:25% aramid fiber, 40% polyester fiber, 30% viscose rayon, 5% conductive fiber.
The antibacterial fabric includes following preparation process:
Be base fabric weaving first, first manufacture warp thread and weft yarn, wherein warp yarn with have twirl doubling frame by two aramid fibers, Single thread and conjunction of the conductive fiber proportioning in 60S/1, two-for-one twister twist 1400T/m, and S is twisted, ingot speed 9000r/min;Weft yams are used There are the single thread and conjunction for twisting doubling frame by two polyester fibers, viscose rayon in 50S/1, two-for-one twister to twist 1500T/m, Z is twisted, ingot speed Then 8000r/min uses rapier loom or air-jet loom to be weaved, 2 colors or 4 colors select latitude, 315 ° of angles of opening time automatically; Fabric specification:Breadth 165cm, 350/10cm of weft density on machine.
Followed by scrim surfaces antimicrobial treatment:
The first step is configuration antimicrobial treatment solution:Using following materials in percentage by mass, 50% chitosan, 30% carvacrol, 20% sodium alginate, 1% nano silver;First whole chitosan powder are dissolved in acetum, PH 6 is stirred at room temperature 5h is mixed, at chitosan solution;Then whole carvacrol powder are dissolved in ethanol solution, 5h is stirred at room temperature, at Sheep's-parsley phenol solution;Whole sodium alginates are dissolved in deionized water, 6h is stirred at room temperature, at annex solution;It then will be deacetylated Chitin solution and the mixing of Sheep's-parsley phenol solution, stir 10min, then sodium chloride is added, 35 in mixing speed 900r/min It stirs 10min at DEG C, forms blended liquid, be then added glycerine, the volume ratio of blended liquid and glycerine is 1:0.2, at room temperature 15min is stirred, annex solution and whole nano silvers is then added, 15min is stirred at room temperature, then presses the speed of 5 DEG C/min 75 DEG C are warming up to, 5min is stirred at a temperature of 75 DEG C, forms antibacterial glue;
Second cloth is antimicrobial treatment:Base fabric is immersed in antibacterial glue, using an immersing and rolling(Liquid carrying rate 80 ~ 90%)Carry out surface Dip dyeing, is dried at 85 DEG C, and drying time is 5min to get to the base fabric with antibacterial functions.
Followed by the processing of cotton fabric layer surface:Including pre-treatment and post-processing, it is 1 that pre-treatment, which is by volume ratio,: 1.5 Ethyl alcohol and ammonium hydroxide mixing, stir 30min at 20 DEG C, form ethyl alcohol, ammonia water mixture, be then added and ethyl alcohol, ammonium hydroxide Mixeding liquid volume ratio is 1:20 tetraethyl orthosilicate stirs 60min and stands 30min, pretreatment liquid formed, by cotton fabric layer It immerses in pre-treatment, using an immersing and rolling(Liquid carrying rate 70 ~ 80%)Surface dip dyeing is carried out, is dried at 80 DEG C, drying time is 3min completes pre-treatment;It is 1 that post-processing, which is by content ratio,:1:1 octyl trimethoxy silane, dodecyl trimethoxy silicon Alkane, hexadecyl trimethoxy silane are added in ethyl alcohol, and acetic acid and deionized water are added while agitating, is stirred at 25 DEG C 35min is mixed, aftertreatment fluid is formed, then the cotton fabric Jing Guo pre-treatment is immersed in aftertreatment fluid and stands 90min, at normal temperatures After air-drying in merging baking oven, 30min is dried at 120 DEG C, is completed post-processing and is knitted to get to the cotton with water proof wind proof function Nitride layer.
The bonding such as embodiment 1 of last fabric.
In conclusion the above embodiment is not the restricted embodiment for being the present invention, all those skilled in the art The modification carried out on the basis of the substantive content of the present invention or equivalent deformation, the technology scope in the present invention.

Claims (5)

1. a kind of antibacterial fabric, including base fabric, which is characterized in that the scrim surfaces are provided with antibiotic layer, on the antibiotic layer Surface is provided with cotton fabric layer, and matcoveredn is arranged in cotton fabric layer upper surface.
2. a kind of antibacterial fabric according to claim 1, which is characterized in that the base fabric includes the original of following mass percent Material:20 ~ 30% aramid fibers, 40 ~ 50% polyester fibers, 20 ~ 30% viscose rayons, 5-10% conductive fibers.
3. a kind of antibacterial fabric according to claim 1, which is characterized in that the base fabric includes the original of following mass percent Material:20% aramid fiber, 45% polyester fiber, 25% viscose rayon, 10% conductive fiber.
4. a kind of preparation method of antibacterial fabric, which is characterized in that include the following steps:
S1 base fabrics are weaved:
Warp yarn:Doubling frame is twisted with having by two aramid fibers, single thread of the conductive fiber proportioning between 40S ∕ 1-60S/1 simultaneously It closes, two-for-one twister twists 1200-1400T/m, and S is twisted, ingot speed 8000-9000r/min;
Weft yams:Doubling frame is twisted with having by single thread between 30S ∕ 1-50S/1 of two polyester fibers, viscose rayon and conjunction, Two-for-one twister twists 1400-1500T/m, and Z is twisted, ingot speed 7000-8000r/min;
Using rapier loom or air-jet loom weaving, 2 colors or 4 colors select latitude, 315 ° of angles of opening time automatically;
Fabric specification:Breadth 165cm, 350/10cm of weft density on machine;
The processing of S2 scrim surfaces:
Configure antimicrobial treatment solution:Using following materials in percentage by mass, 40 ~ 50% chitosans, 30 ~ 40% carvacrols, 20 ~ 30% sodium alginate, 0.1 ~ 1% nano silver;
Whole chitosan powder are dissolved in acetum, PH is 5 ~ 6.5,5 ~ 7h is stirred at room temperature, at deacetylated Chitin solution;
Whole carvacrol powder are dissolved in ethanol solution, 5 ~ 7h is stirred at room temperature, at Sheep's-parsley phenol solution;
Whole sodium alginates are dissolved in deionized water, 5 ~ 7h is stirred at room temperature, at annex solution;
Chitosan solution and Sheep's-parsley phenol solution are mixed, 10min, mixing speed 900r/min are stirred, is then added Enter sodium chloride, stir 10min at 35 DEG C, form blended liquid, be then added glycerine, the volume ratio of blended liquid and glycerine is 1: 0.2,15min is stirred at room temperature, annex solution and whole nano silvers is then added, 15min is stirred at room temperature, then presses 5 DEG C/speed of min is warming up to 75 DEG C, 5min is stirred at a temperature of 75 DEG C, forms antibacterial glue;
Base fabric is immersed in antibacterial glue, using an immersing and rolling(Liquid carrying rate 80 ~ 90%)Surface dip dyeing is carried out, is dried at 85 DEG C, Drying time is 5min;
The processing of S3 cotton fabric layer surfaces:
Pre-treatment:It is 1 by volume ratio:1 ~ 1.5 ethyl alcohol and ammonium hydroxide mixing, 30min is stirred at 20 DEG C, forms ethyl alcohol, ammonia Water mixed liquid, it is 1 to be then added with ethyl alcohol, ammonia water mixture volume ratio:20 tetraethyl orthosilicate stirs 60min and stands 30min forms pretreatment liquid, cotton fabric layer is immersed in pre-treatment, using an immersing and rolling(Liquid carrying rate 70 ~ 80%)Carry out surface Dip dyeing, is dried, drying time 3min at 80 DEG C, completes pre-treatment;
S4 is post-processed:It is 1 by content ratio:1:1 octyl trimethoxy silane, dodecyltrimethoxysilane, cetyl Trimethoxy silane is added in ethyl alcohol, and acetic acid and deionized water are added while agitating, 35min, shape are stirred at 25 DEG C At aftertreatment fluid, then the cotton fabric Jing Guo pre-treatment is immersed in aftertreatment fluid and stands 90min, at normal temperatures air-dried postposition Enter in baking oven, 30min is dried at 120 DEG C, completes post-processing.
5. a kind of preparation method of antibacterial fabric according to claim 4, which is characterized in that the base fabric and cotton fabric layer it Between glue molding.
CN201810418272.1A 2018-05-04 2018-05-04 A kind of antibacterial fabric and preparation method thereof Pending CN108611868A (en)

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CN109898339A (en) * 2019-03-12 2019-06-18 武汉市鸿盛华航旅服务股份有限公司 The production method of high-strength abrasion-proof waterproof and breathable antibacterial fabric
CN110016805A (en) * 2019-04-28 2019-07-16 无锡迈克斯纺织品有限公司 A kind of preparation method of Mildewproof antibiotic fabric
CN114481632A (en) * 2022-02-28 2022-05-13 江苏锐晟纺织科技有限公司 Long-acting biological antibacterial washable rayon crepe and preparation method thereof
CN114481632B (en) * 2022-02-28 2023-11-28 江苏锐晟纺织科技有限公司 Long-acting biological antibacterial washable human cotton crepe and preparation method thereof

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Application publication date: 20181002