CN1340120A - Silicone coated fluid shield fabric - Google Patents

Silicone coated fluid shield fabric Download PDF

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Publication number
CN1340120A
CN1340120A CN00803593A CN00803593A CN1340120A CN 1340120 A CN1340120 A CN 1340120A CN 00803593 A CN00803593 A CN 00803593A CN 00803593 A CN00803593 A CN 00803593A CN 1340120 A CN1340120 A CN 1340120A
Authority
CN
China
Prior art keywords
fabric
backing
polysiloxanes
present
fabric backing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN00803593A
Other languages
Chinese (zh)
Inventor
W·C·金布雷尔
C·T·厄舍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Milliken and Co
Original Assignee
Milliken and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Milliken and Co filed Critical Milliken and Co
Publication of CN1340120A publication Critical patent/CN1340120A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/186—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials one of the layers is on one surface of the fibrous web and the other layer is on the other surface of the fibrous web
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/04—Properties of the materials having electrical or magnetic properties
    • D06N2209/046—Anti-static
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D06N2209/128—Non-permeable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/147—Stainproof, stain repellent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/14—Furniture, upholstery

Abstract

A fabric possessing both cleanability and fluid resistant properties is provided which can, if desired, be transfer printed. The fabric includes a textile substrate treated with a fluorochemical stain resist agent. The treated textile substrate is covered substantially on the back with a layer of coated silicone polymer. A process for forming the fluid shield fabric according to the present invention is also provided.

Description

The waterproof fabric of polysiloxane coated
Technical field
The application is following part continuation application in first to file, and the patent application serial numbers of 1997.2.12 application is that 08/799,790 title is the application of " waterproof fabric (fluid shield fabric) ".
The present invention relates to a kind of indoor decoration fabric, more particularly, relate to a kind of fabric that has antibiotic property and pollution resistance and be suitable for the fluid isolation coating of transfer printing, this fluid isolation coating can not influence the sense of touch of fabric conversely.The present invention also provides a kind of method that forms this fabric.
Background technology
Once adopted multiple making not only to have dedusting but also have the method for the fabric of liquid isolation in the past, may exist in the environment of liquid stain with more convenient being applied to.Quite be easy to dedusting and relatively cheap price because the fabric of vinyl coating coating has, therefore be widely used in most in these purposes.Yet the feel of the fabric of these vinyl coating coatings is stone usually, therefore lacks to be applied to for example needed desirable outward appearance of environment such as hotel, sanatorium and feel, thinks that this user comfort feel and visual experience are important.The fabric of surface laminated is used to increase the aesthetic feeling of this fabric, but because the bonding force that separates between laminated film and the fabric, so these goods are long-term is easy to peel off after using, crack and layering.These laminated products also lack the needed sensation of standard chamber interior trim goods usually easily.When having carried out the processing of fluoride anti-soil, liquid barrier layer or coating are to the bonding difficulty more that will become of fabric backing, and this is because the character of said composition tends to repel this coating.
The present invention makes the separation layer of coating extremely thin (preferably less than 2 ounce per square yard) by weave former material and coating material and coating process of suitable selection, has overcome the requirement that seems contradiction in the liquid barrier layer based on the pollution resistance of fluoride and good bond.In addition, the suitable material of making this liquid barrier layer preferably has stainability and elasticity, and this is consistent with these performances in the fabric backing basically.Therefore the present invention has useful improvement than prior art.
Goal of the invention and summary
In view of above some, general purpose of the present invention provides a kind of fabric that had not only had pollution resistance but also had the liquid isolation, and compare with the untreated indoor decorative fabric of tradition and also to have the soft fabric feel, wherein Rou Ruan fabric feeling should be understood to be meant the pliability of fabric self and/or lacks rigidity.
The present invention's purpose more specifically provides a kind of fabric, and wherein the polymeric material barrier coat is glued fast on the surface of fluoride processing.
Of the present invention another more specifically purpose provide a kind of waterproof fabric (fluid shield fabric) that interior decoration is used that is used for, this fabric has the polysiloxane polymer barrier coat, is glued fast on the surface of woven, the knitting or bondedfibre fabric base fabric that fluoride handles.
Undoubtedly, those skilled in the art just can know other purpose of the present invention, advantage and feature behind the specification of having read the back.Therefore, although the present invention will preferred embodiment be described and illustrate with method, the absolute meaning that the present invention is not limited to some concrete embodiment and method in conjunction with some.On the contrary, this invention is intended to all other embodiments, method and change within the real spirit and scope of the present invention that letter lid following claim and its equivalence transformation limited.
The invention provides a kind of waterproof fabric that can transfer printing.Although used the intermediate fluoride composition, this fabric keeps also having good feel in the close adhesion between base fabric and polymerization isolated material.
In the possible preferred implementation of the present invention, fabric backing is handled with the fluoride anti-fouling agent, use then one deck polymeric material overleaf (surface of promptly not printing) be coated with fully to produce a kind of final structure that prevents liquid but also have anti-soil stain performance that not only had.
Although expection if desired, those skilled in the art will know that the knit materials and/or the bondedfibre fabric that can use dense formation, preferred fabric backing is woven material.Although expection also can be used other material, the example of its indefiniteness comprises cotton-polyester mixture, nylon and polypropylene, and preferred this fabric backing is thread by polyester yarn.
In an especially preferred embodiment, have found that, when using scraper to be coated on the woven fabric base fabric coating polymeric material, use calendering technology to flatten the coated side fabric, minimizing is reached the consumption of the needed polymeric material of desirable isolation performance.Also find,, can under the prerequisite that layering does not take place, obtain high degree of flexibility by using suitable polysiloxane polymer.Preferred coating materials comprises that illustrating trade mark is two kinds of component packings of LR3003-10A and B, at the PDMS polysiloxane composition that contains crosslinking agent and polymerization inhibitor of the Wacker of Adrian Michigan Chemical sale.
The close woven fabric of use A Erbin (albi) yarn has increased the bonding force between fabric backing and the polymeric material.This polymeric material has thermal transfer printing between 350-450 and does not damage polymer coated performance.The present invention can also understand with reference to the embodiment of detail description and illustrate.
Specific embodiment 1
The following examples have been described the preparation of the fabric that the present invention is used to dye.
Density is that the woven fabric of about 68 warp thread of per inch and 46 weft yarns is made by two strands of distortion A Erbin polyester yarns, obtains one 100% plain weave polyester woven fabric.This fabric is washed in the bath of 7-8 180-200 following pH value.Subsequently this fabric is padded the two sides in following solution, pick up is 50%, and wherein this solution contains the fluoride of about 1%-40% (preferably approximately 6.6%), for example MILLIGUARD TMBK96 is available from a kind of fluorate acrylic acid ester copolymer emulsion of the Milliken Chemical of the Spartanburg that is positioned at South Carolina; The about ULTRA-FRESH of 0.5%-5.0% (preferably approximately 3.0%) TMNM; The about ULTRA-FRESH of 0.05%-1.0% (preferably approximately 1.0%) available from Thompson Research TM40; And the antistatic additive of 0.5%-5.0% (preferred 3.0%), Antistat993 for example is available from a kind of ester of the Sybron Chemical of the Welford that is positioned at South Carolina.
Although preferred embodiment, this solution not only comprises antiseptic but also comprise antistatic additive, is to be understood that and what be familiar with is also can omit these if desired and add in components one or more.Padded after this preparation solution, at about 225 °F-425 °F, preferably approximately 350 °F solidified 60 seconds down with this fabric.Subsequently, the woven fabric base fabric that this has been applied the fluoride anti-staining agent is operated with the pressing of one side at least with fabric by calendering.The calendering operation preferably is approximately 200N/mm at pressure, and roller temperature is approximately under 392 °F and carries out.
In the preferred embodiment, PDMS polysiloxane composition scraper is applied on the calendering surface of fabric, forms effective separation layer thus.Although calendering is preferably passed through on the surface of coating, also can not calendering.
In the preferred implementation, the gross weight of the separation layer of coating is less than about 2 ounce per square yard, preferably less than 1.5 ounce per square yard, and about 0.8-1.2 ounce per square yard most preferably.
After the coating, this fabric is preferably by curing oven polysiloxanes separation layer then.This operation was preferably carried out under about 390 °F about 80 seconds.
Expection improves other component of performance and can use by the polymeric material on being coated in fabric backing.These components that improve performance comprise that the example of its indefiniteness is for well known to a person skilled in the art antimicrobial composition, fire retardant, antistatic additive and/or ultra-violet stabilizer.
In view of top description, it should be understood that main principle of the present invention disclosed herein can implement with multiple mode to possible preferred implementation and method.Therefore, following claim of the present invention is intended to cover any this change and combines other embodiment of feature in the wideest allowed band of the present invention.

Claims (15)

1. waterproof fabric, it comprises: a fabric backing covers the fluoride anti-staining agent of described fabric backing basically and covers described fabric backing basically so that the thermosetting silicone layer of the separation layer that prevents that liquid from flowing through to be provided.
2. the fabric of claim 1, wherein said fabric backing is a polyester.
3. the fabric of claim 1, wherein said fabric backing is a nylon.
4. the fabric of claim 1, wherein said fabric backing is a polypropylene.
5. the fabric of claim 1, wherein said fabric backing is a woven fabric.
6. the fabric of claim 1, wherein said fabric backing is a knitted fabric.
7. the fabric of claim 1, wherein said fabric backing is a bondedfibre fabric.
8. the fabric of claim 1, wherein said fabric backing comprises smooth calendering face.
9. the fabric of claim 1 further comprises the fire retardant that is configured in the described fabric backing.
10. the fabric of claim 1 further comprises the antiseptic that is configured in the described fabric backing.
11. the fabric of claim 1, wherein said polysiloxanes comprises the fire retardant that is configured in wherein.
12. the fabric of claim 1, wherein said polysiloxanes comprises the ultra-violet stabilizer that is configured in wherein.
13. the fabric of claim 1, wherein said polysiloxanes comprises the antiseptic that is configured in wherein.
14. the fabric of claim 1, wherein said polysiloxanes comprises the antistatic additive that is configured in wherein.
15. the fabric of claim 1, the content of wherein said polysiloxanes are approximately 2 ounce per square yard or still less.
CN00803593A 1999-02-22 2000-02-22 Silicone coated fluid shield fabric Pending CN1340120A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US25514199A 1999-02-22 1999-02-22
US09/255,141 1999-02-22

Publications (1)

Publication Number Publication Date
CN1340120A true CN1340120A (en) 2002-03-13

Family

ID=22967017

Family Applications (1)

Application Number Title Priority Date Filing Date
CN00803593A Pending CN1340120A (en) 1999-02-22 2000-02-22 Silicone coated fluid shield fabric

Country Status (8)

Country Link
EP (1) EP1161590A1 (en)
JP (1) JP2002537496A (en)
KR (1) KR20020000767A (en)
CN (1) CN1340120A (en)
AU (1) AU3633100A (en)
BR (1) BR0008392A (en)
CA (1) CA2363080A1 (en)
WO (1) WO2000049221A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1717324B (en) * 2002-11-27 2010-06-16 美利肯公司 Barrier fabric
CN102712828A (en) * 2010-01-07 2012-10-03 道康宁东丽株式会社 Cured organopolysiloxane resin film having gas barrier properties and method of producing the same
CN104674554A (en) * 2015-03-06 2015-06-03 苏州爱立方服饰有限公司 Waterproof finishing agent for fabric and preparation method of waterproof finishing agent
CN108611868A (en) * 2018-05-04 2018-10-02 嘉兴市卡秋莎服装股份有限公司 A kind of antibacterial fabric and preparation method thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020019183A1 (en) * 1997-02-12 2002-02-14 Demott Roy P. Release barrier fabrics
US9534343B2 (en) 2012-10-18 2017-01-03 The Chemours Company Fc, Llc Partially fluorinated copolymer emulsions containing fatty acids and esters
KR102238956B1 (en) 2014-06-24 2021-04-13 삼성전자주식회사 Fluid Analysis Sheet, Fluid Analysis Cartridge Having the Same and Method of Manufacturing the Fluid Analysis Cartridge

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Publication number Priority date Publication date Assignee Title
UST896018I4 (en) * 1971-02-01 1972-03-07 Defensive publication
US4678681A (en) * 1984-10-05 1987-07-07 Hiraoka & Co. Ltd. Process for preparation of water-proof sheets
JPS61138776A (en) * 1984-12-07 1986-06-26 第一工業製薬株式会社 Production of moisture permeable and water-proof coated cloth
WO1989008554A1 (en) * 1988-03-14 1989-09-21 Sili-Tex, Inc. Silicone polymer-internally coated webs
US5899783A (en) * 1997-02-12 1999-05-04 Milliken & Company Fluid shield fabric
FR2765897B1 (en) * 1997-07-11 2001-03-16 Dhj Internat PROCESS FOR THE PREPARATION OF A TEXTILE COATED WITH A PRINTED PATTERN, PRINTED TEXTILE AND THE USE THEREOF

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1717324B (en) * 2002-11-27 2010-06-16 美利肯公司 Barrier fabric
CN102712828A (en) * 2010-01-07 2012-10-03 道康宁东丽株式会社 Cured organopolysiloxane resin film having gas barrier properties and method of producing the same
CN104674554A (en) * 2015-03-06 2015-06-03 苏州爱立方服饰有限公司 Waterproof finishing agent for fabric and preparation method of waterproof finishing agent
CN104674554B (en) * 2015-03-06 2016-08-24 苏州爱立方服饰有限公司 A kind of fabric waterproof finishing agent and preparation method thereof
CN108611868A (en) * 2018-05-04 2018-10-02 嘉兴市卡秋莎服装股份有限公司 A kind of antibacterial fabric and preparation method thereof

Also Published As

Publication number Publication date
KR20020000767A (en) 2002-01-05
BR0008392A (en) 2002-09-24
EP1161590A1 (en) 2001-12-12
WO2000049221A1 (en) 2000-08-24
AU3633100A (en) 2000-09-04
CA2363080A1 (en) 2000-08-24
JP2002537496A (en) 2002-11-05

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