CA2363080A1 - Silicone coated fluid shield fabric - Google Patents

Silicone coated fluid shield fabric Download PDF

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Publication number
CA2363080A1
CA2363080A1 CA002363080A CA2363080A CA2363080A1 CA 2363080 A1 CA2363080 A1 CA 2363080A1 CA 002363080 A CA002363080 A CA 002363080A CA 2363080 A CA2363080 A CA 2363080A CA 2363080 A1 CA2363080 A1 CA 2363080A1
Authority
CA
Canada
Prior art keywords
fabric
fabric substrate
silicone
agent disposed
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002363080A
Other languages
French (fr)
Inventor
Christopher Todd Usher
William Carl Kimbrell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Milliken and Co
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2363080A1 publication Critical patent/CA2363080A1/en
Abandoned legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/186Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials one of the layers is on one surface of the fibrous web and the other layer is on the other surface of the fibrous web
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/04Properties of the materials having electrical or magnetic properties
    • D06N2209/046Anti-static
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/12Permeability or impermeability properties
    • D06N2209/126Permeability to liquids, absorption
    • D06N2209/128Non-permeable
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/14Properties of the materials having chemical properties
    • D06N2209/147Stainproof, stain repellent
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • D06N2209/1671Resistance to bacteria, mildew, mould, fungi
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/14Furniture, upholstery

Abstract

A fabric possessing both cleanability and fluid resistant properties is provided which can, if desired, be transfer printed. The fabric includes a textile substrate treated with a fluorochemical stain resist agent. The treated textile substrate is covered substantially on the back with a layer of coated silicone polymer. A process for forming the fluid shield fabric according to the present invention is also provided.

Description

Description SILICONE COATED FLUID SHIELD FABRIC
Technical Field This application is a continuation-in-part of our copending prior Application Serial No. 08/799,790 entitled FLUID SHIELD FABRIC having a filing date of February 12, 1997.
The present invention relates to a fabric useful in upholstery applications and more particularly to a fabric having antimicrobial and stain resistant properties in combination with a fluid barrier coating suitable for transfer printing which does not adversely affect the tactile hand of the fabric. A method for forming such fabric is also provided.
Background Art Heretofore, a number of approaches have been taken to making fabrics both cleanable and liquid resistant so as to be more useful in environments where liquid staining is likely to occur. Vinyl coated fabrics have been most broadly accepted for these purposes due to relatively easy cleanability and fairly low cost.
However, such vinyl coated fabrics are typically rather stiff to the touch and thereby lack the desired appearance and feel for use in environments such as restaurants, nursing homes, and the like where pleasing tactile and visual perceptions by the user are considered important. Surface laminated fabrics have been utilized to enhance the aesthetic characteristics of the fabrics, but due to the generally disjunctive adherence between the laminate film and the fabric itself, these products tend to peel. crack, and delaminate after long periods of use. Such laminated products also tend to lack the generally desirable feel of standard upholstery products. Adherence of a liquid barrier film or coating to a fabric substrate is made all the more difficult when fluorochemical stain-resist treatments are applied, since such compositions by their nature tend to repel an applied coating.
The present invention overcomes these seemingly contradictory requirements of fluorochemically based stain resistance in combination with a strongly adherent fluid barrier shield through proper selection of the base textile material in combination with the selection of coating materials and application processes so as to permit a very thin layer (preferably less than 2 oz/sq. yd.) of barrier material to be applied.
Moreover, the actual material making up this barrier layer preferably possess dyeability and elastomeric properties which tend to conform substantially to those of the fabric substrate. The present invention thus represents a useful advancement over present practices.
Obiects and Summary of the Invention In light of the foregoing, it is a general object of the present invention to provide a fabric which possesses both stain resist and fluid barrier properties but which also exhibits a soft fabric hand as in traditional untreated upholstery fabrics where a soft fabric hand is understood to mean flexibility and/or lack of stiffness in the fabric itself.

It is a more particular object of the present invention to provide a fabric wherein a barrier coating of polymeric material is adhered in stable relation to a fluorochemically treated surface.
It is yet a more particular object of the present invention to provide a fluid shield fabric useful in upholstery applications possessing a barrier coating of silicone polymer material in stable relation to a fluorochemically treated surface of a woven, knitted, or nonwoven fabric substrate.
Other objects, advantages and features of the present invention will, no doubt, occur to those skilled in the art upon reading of the following specification. Thus, while the invention will be described and disclosed in connection with certain preferred embodiments and procedures, it is by no means intended to limit the invention to such specific embodiments and procedures. Rather, it is intended to cover all such alternative embodiments, procedures, and modifications thereto as may fall within the true spirit and scope of the invention as defined only by the appended claims and equivalents thereto.
A fluid shield fabric is provided which may be transfer printed. The fabric exhibits a good hand while maintaining intimate adhesion between the base fabric and the polymeric barrier material despite the use of an intermediate fluorochemical composition.
In the potentially preferred practice of the present invention, a fabric substrate is treated with a fluorochemical stain resist agent and thereafter coated substantially on the back side (i.e. the surface which is not to undergo printing) with a layer of polymeric material so as to yield a final construction which exhibits both fluid and stain resistant properties.
The fabric substrate is preferably a woven material although it is contemplated that tightly formed knitted materials and/or nonwovens as are known to those of skill in the art may likewise be used if desired. Such fabric substrates are preferably formed from polyester yarns although it is contemplated that other materials including, by way of example only and not limitation, cotton-polyester blends, nylon, and polypropylene may also be utilized.
In one particularly preferred embodiment, it has been found that the use of a calendering procedure to flatten the fabric on the side to be coated reduces the required amount of polymeric material to achieve the desired barrier properties when knife coating is used to apply the polymeric material across the woven fabric substrate. It has been further found that through the use of an appropriate silicone polymer that high degrees of flexibility can be achieved without the occurrence of delamination. Coating materials which may be preferred include by way of example only, PDMS silicone compositions sold by Wacker Chemical in Adrian Michigan including a cross-linking agent and inhibitor as a two component kit under the trade designation LR3003-l0A and B.
The use of a tightly woven fabric with albi yarn enhances adhesion between the fabric substrate and the polymeric material. The polymeric material has such properties to allow heat transfer printing at temperatures ranging from 350°F to 450°F without damage to the polymeric coating. The invention may be further understood and illustrated through reference to the following non limiting example.

The following example describes the preparation of fabric according to the present invention intended for dye application.

A woven fabric having a weave density of about 68 ends per inch by 46 picks per inch was formed from two ply textured albi polyester yarn to yield a 100% plain weave polyester woven fabric. The fabric was scoured in a 180 - 200°F 7-8 pH bath. The fabric was thereafter padded to a pick-up of 50% on both sides with a solution containing about 1 % -40% (about 6.6% preferred) of a fluorochemical such as MILLIGUARDTM BK 96 a fluoroacrylate copolymer emulsion from Milliken Chemical in Spartanburg, South Carolina;
about 0.5% - 5.0% (about 3.0% preferred) ULTRA-FRESHTM NM; about 0.05% - 1.0%
(about 1.0% preferred) ULTRA-FRESHTM 40 available from Thompson Research; and 0.5%-5.0% (3.0% preferred) of an anti-static such as Antistat 993, an ester salt from Sybron Chemical, in Welford, South Carolina.
While in the preferred practice, this solution will include both antimicrobial and anti-static components, it is to be understood and appreciated that one or more of these additional components may be eliminated if desired. Following the padding application of this preparation solution, the fabric is cured at a temperature of about 225°F to 425°F preferably about 350°F for 60 seconds. The woven fabric substrate with applied fluorochemical stain resist agent is thereafter passed through a calendering operation so as to flatten at least one side of the fabric. The calendering operation is preferably carried out at a pressure of about 200N/mm with a calendering roll temperature of about 392°F.
In the preferred practice, a PDMS silicone composition is knife coated across the calendered surface of the fabric thereby forming an effective barrier layer.
Although the surface for application is preferably calendered it may also be uncalendered.
In the preferred practice, the total weight of the applied barrier layer is less than about 2 oz/sq. yd., preferably less than l.~ oz/sq. yd. and most preferably about 0.8 to 1.2 oz/sq. yd.
Following the coating procedure the fabric is then preferably passed through an oven to set the silicone barrier layer. This operation preferably takes place at a temperature of about 390°F for a period of about 80 seconds.
It is contemplated that additional performance enhancing constituents may be incorporated within the polymeric materials which are coated onto the fabric substrate. These performance enhancing constituents may include, by way of example only and not limitation, antimicrobial compositions; flame retardants, antistats and/or ultraviolet stabilizing agents such as are known to those of skill in the art.
In light of the above disclosure of potentially preferred embodiments and processes, it will be appreciated that the general principal of invention disclosed herein may be applied in a variety of ways. Therefore, it is contemplated by the appended claims to cover anv such modifications and other embodiment as incorporate the features of this invention within the broadest allowable scope thereof.

Claims (15)

Claims WHAT IS CLAIMED IS:
1. A fluid shield fabric comprising:
a fabric substrate, a fluorochemical stain resist agent substantially covering said fabric substrate, and a layer of thermosetting silicone substantially covering said fabric substrate so as to provide a barrier layer against liquid passage.
2. The invention as in Claim 1, wherein said fabric substrate is polyester.
3. The invention as in Claim 1, wherein said fabric substrate is nylon.
4. The invention as in Claim 1, wherein said fabric substrate is polypropylene.
5. The invention as in Claim 1, wherein said fabric substrate is a woven fabric.
6. The invention as in Claim 1, wherein said fabric substrate is a knit fabric.
7. The invention as in Claim 1, wherein said fabric substrate is a nonwoven fabric.
8. The invention as in Claim 1, wherein said fabric substrate comprises a smooth calendered surface.
9. The invention as in Claim 1, further including a flame retarding agent disposed across said fabric substrate.
10. The invention as in Claim 1, further including an antimicrobial agent disposed across said fabric substrate.
11. The invention as in Claim 1, wherein said silicone includes a flame retarding agent disposed therein.
12. The invention as in Claim 1, wherein said silicone includes an ultraviolet stabilizing agent disposed therein.
13. The invention as in Claim 1, wherein said silicone includes an antimicrobial agent disposed therein.
14. The invention as in Claim 1, wherein said silicone includes an antistatic agent disposed therein.
15. The invention as in Claim 1, wherein said silicone is present at a level of about 2 oz/sq. yd. or less.
CA002363080A 1999-02-22 2000-02-22 Silicone coated fluid shield fabric Abandoned CA2363080A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US25514199A 1999-02-22 1999-02-22
US09/255,141 1999-02-22
PCT/US2000/040036 WO2000049221A1 (en) 1999-02-22 2000-02-22 Silicone coated fluid shield fabric

Publications (1)

Publication Number Publication Date
CA2363080A1 true CA2363080A1 (en) 2000-08-24

Family

ID=22967017

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002363080A Abandoned CA2363080A1 (en) 1999-02-22 2000-02-22 Silicone coated fluid shield fabric

Country Status (8)

Country Link
EP (1) EP1161590A1 (en)
JP (1) JP2002537496A (en)
KR (1) KR20020000767A (en)
CN (1) CN1340120A (en)
AU (1) AU3633100A (en)
BR (1) BR0008392A (en)
CA (1) CA2363080A1 (en)
WO (1) WO2000049221A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020019183A1 (en) * 1997-02-12 2002-02-14 Demott Roy P. Release barrier fabrics
US6833335B2 (en) * 2002-11-27 2004-12-21 Milliken & Company Barrier fabric
KR20120112739A (en) * 2010-01-07 2012-10-11 다우 코닝 코포레이션 Cured organopolysiloxane resin film having gas barrier properties and method of producing the same
US9534343B2 (en) 2012-10-18 2017-01-03 The Chemours Company Fc, Llc Partially fluorinated copolymer emulsions containing fatty acids and esters
KR102238956B1 (en) 2014-06-24 2021-04-13 삼성전자주식회사 Fluid Analysis Sheet, Fluid Analysis Cartridge Having the Same and Method of Manufacturing the Fluid Analysis Cartridge
CN104674554B (en) * 2015-03-06 2016-08-24 苏州爱立方服饰有限公司 A kind of fabric waterproof finishing agent and preparation method thereof
CN108611868A (en) * 2018-05-04 2018-10-02 嘉兴市卡秋莎服装股份有限公司 A kind of antibacterial fabric and preparation method thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
UST896018I4 (en) * 1971-02-01 1972-03-07 Defensive publication
US4678681A (en) * 1984-10-05 1987-07-07 Hiraoka & Co. Ltd. Process for preparation of water-proof sheets
JPS61138776A (en) * 1984-12-07 1986-06-26 第一工業製薬株式会社 Production of moisture permeable and water-proof coated cloth
KR970002936B1 (en) * 1988-03-14 1997-03-13 넥스텍 애플리케이션즈 인코포레이티드 Silicone polymer fiber encapsulated webs
US5899783A (en) * 1997-02-12 1999-05-04 Milliken & Company Fluid shield fabric
FR2765897B1 (en) * 1997-07-11 2001-03-16 Dhj Internat PROCESS FOR THE PREPARATION OF A TEXTILE COATED WITH A PRINTED PATTERN, PRINTED TEXTILE AND THE USE THEREOF

Also Published As

Publication number Publication date
JP2002537496A (en) 2002-11-05
BR0008392A (en) 2002-09-24
CN1340120A (en) 2002-03-13
KR20020000767A (en) 2002-01-05
AU3633100A (en) 2000-09-04
EP1161590A1 (en) 2001-12-12
WO2000049221A1 (en) 2000-08-24

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