CN108611853A - 一种含氟拒水拒油整理剂 - Google Patents

一种含氟拒水拒油整理剂 Download PDF

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Publication number
CN108611853A
CN108611853A CN201810287800.4A CN201810287800A CN108611853A CN 108611853 A CN108611853 A CN 108611853A CN 201810287800 A CN201810287800 A CN 201810287800A CN 108611853 A CN108611853 A CN 108611853A
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refusing
finishing agent
oil
fluorine
containing water
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CN201810287800.4A
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Inventor
张伟
张艳
王慧玲
周彬
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Yancheng Institute of Industry Technology
Yancheng Vocational Institute of Industry Technology
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Yancheng Vocational Institute of Industry Technology
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Priority to CN201810287800.4A priority Critical patent/CN108611853A/zh
Publication of CN108611853A publication Critical patent/CN108611853A/zh
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
    • D06M13/477—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having six-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明公开了一种含氟拒水拒油整理剂，其具有如式所示的结构。该整理剂具有符合环保要求的6个碳全氟烷基长链，并能与棉、麻、粘胶织物反应结合后，实现耐久性拒水拒油整理。该整理剂工艺简单，配方成本低，并且减少了对环境的污染。

Description

一种含氟拒水拒油整理剂
技术领域
本发涉及印染助剂技术领域，特别是涉及一种环保含氟拒水拒油整理剂。
背景技术
拒水拒油整理是在织物上施加一种具有特殊分子结构的整理剂，改变纤维表面层的组成，并牢固地附着于纤维上或与纤维化学结合，使织物不再被水或有机物所润湿的加工过程。
目前市面上常见的拒水拒油剂是含氟聚合物或烷烃长链的化合物。含氟类拒水剂通常通过交联剂与纺织品发生化学反应或通过涂层与纺织品发生物理反应，且工业上使用的含氟拒水剂主要是8个碳甚至更长碳链的全氟烷基长链聚合物。研究发现，这种类型的拒水拒油剂对环境有危害，且经传统工艺整理出的纺织品耐水洗性能差。
发明内容
本发明所要解决的技术问题是提供一种拒水拒油整理剂，该产品含有6个碳全氟烷基长链，环境友好。该类整理剂使用方便，应用性能优异，主要用于棉、麻、粘胶织物的耐久性拒水拒油整理。
为了解决上述技术问题，本发明采用的技术方案是：一种含氟拒水拒油整理剂，具有如下结构：
一种含氟拒水拒油整理剂可由全氟己酸、氨水和甲醛作用生成羟甲基硬脂酰胺，再与盐酸、吡啶作用而制得。
本发明还提供了该含氟拒水拒油整理剂的使用方法，具体如下：
工艺流程：
二浸二轧（40℃，轧液率70％～80％）→烘干（低于110℃）→焙烘（120℃，5～10min或150℃，3min）→皂洗（肥皂2g/L，纯碱2g/L,50℃）→水洗→烘干。
工艺处方：
整理剂 60 g/L
酒精 60 g/L
结晶醋酸钠 10 g/L
本发明所生产的整理剂，因中含有吡啶季铵盐反应基，该反应基团在高温作用下，可以与纤维素纤维上的羟基反应形成共价键，故能实现对棉、麻、粘胶织物的耐久性拒水拒油整理。
具体实施方式
上面已对本发明含氟拒水拒油整理剂结构进行了说明，下面将通过实施例对本发明工作进一步的说明。
实施例1：
本实施例提供了式（Ⅰ）拒水拒油整理剂对棉织物的整理方法：
具体整理方法如下：
工艺流程：
二浸二轧（40℃，轧液率70％）→烘干（低于110℃）→焙烘（120℃，5min）→皂洗（肥皂2g/L，纯碱2g/L，50℃）→水洗→烘干。
工艺处方：
整理剂 60 g/L
酒精 60 g/L
结晶醋酸钠 10 g/L。

Claims (2)

1.一种含氟拒水拒油整理剂，其具有如式（Ⅰ）所示的结构：
（Ⅰ）
其中，结构式中C6F13为直链氟烷基。
2.根据权利要求1所述的含氟拒水拒油整理剂，可以用做为棉、麻、粘胶织物的耐久性拒水整理。
CN201810287800.4A 2018-03-31 2018-03-31 一种含氟拒水拒油整理剂 Pending CN108611853A (zh)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102094329A (zh) * 2009-12-09 2011-06-15 北京服装学院 一种含氟和硅拒水、拒油整理剂、制法及应用
CN103409999A (zh) * 2013-07-19 2013-11-27 浙江大学 一种含氟共聚物拒水拒油整理剂组合物及其制备方法
CN105401421A (zh) * 2015-11-22 2016-03-16 盐城工业职业技术学院 一种环境友好型拒水剂

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102094329A (zh) * 2009-12-09 2011-06-15 北京服装学院 一种含氟和硅拒水、拒油整理剂、制法及应用
CN103409999A (zh) * 2013-07-19 2013-11-27 浙江大学 一种含氟共聚物拒水拒油整理剂组合物及其制备方法
CN105401421A (zh) * 2015-11-22 2016-03-16 盐城工业职业技术学院 一种环境友好型拒水剂

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Application publication date: 20181002