CN108608791A - A kind of decoration texture enamel plate and preparation method thereof - Google Patents
A kind of decoration texture enamel plate and preparation method thereof Download PDFInfo
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- CN108608791A CN108608791A CN201810614460.1A CN201810614460A CN108608791A CN 108608791 A CN108608791 A CN 108608791A CN 201810614460 A CN201810614460 A CN 201810614460A CN 108608791 A CN108608791 A CN 108608791A
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- 210000003298 dental enamel Anatomy 0.000 title claims abstract description 63
- 238000005034 decoration Methods 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000001035 drying Methods 0.000 claims abstract description 30
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 27
- 239000010959 steel Substances 0.000 claims abstract description 27
- 230000000994 depressogenic effect Effects 0.000 claims abstract description 26
- 238000005507 spraying Methods 0.000 claims abstract description 14
- 238000010304 firing Methods 0.000 claims abstract description 11
- 239000011248 coating agent Substances 0.000 claims abstract description 10
- 238000000576 coating method Methods 0.000 claims abstract description 10
- 238000005498 polishing Methods 0.000 claims abstract description 10
- 238000000465 moulding Methods 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 230000001680 brushing effect Effects 0.000 abstract description 9
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 8
- 241000736199 Paeonia Species 0.000 description 5
- 235000006484 Paeonia officinalis Nutrition 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 241000233805 Phoenix Species 0.000 description 3
- 238000007373 indentation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 206010068052 Mosaicism Diseases 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- 210000001161 mammalian embryo Anatomy 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000011017 operating method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 210000003765 sex chromosome Anatomy 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- SBNFWQZLDJGRLK-UHFFFAOYSA-N phenothrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
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- 230000000750 progressive effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/0415—Ornamental plaques, e.g. decorative panels, decorative veneers containing metallic elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/02—Superimposing layers
- B44C3/025—Superimposing layers to produce ornamental relief structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/0446—Ornamental plaques, e.g. decorative panels, decorative veneers bearing graphical information
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- Finishing Walls (AREA)
Abstract
The invention discloses a kind of decoration texture enamel plate and preparation method thereof, the decoration texture enamel plate, including：Steel plate；Glaze layer, glaze include glazed colour layer and transparent glaze layer layer by layer, and glazed colour layer coating is on the steel plate and the texture thereon with depressed area formation, transparent glaze layer are filled in depressed area, are obtained especially by following steps：Surface spraying colored glaze on the steel plate；Moulding mould extrudes texture on glazed colour layer；Carry out first time drying；First time firing is carried out, enamel plate original paper is made；Clear frit is sprayed in enamel plate original paper upper surface；Second is carried out to dry；It polishes the enamel plate original paper after drying, the clear frit in addition to positioned at recess textured pattern is polished and is removed；It carries out firing for second after polishing, texture enamel plate is made.It is different from the silk-screen and air brushing that existing enamel artistic plate uses, the silk-screen of pattern or air brushing are changed into and form required pattern using the glazed colour layer of recess, manufacture craft is simple, and cost of manufacture and operation difficulty is greatly saved.
Description
Technical field
The present invention relates to enamel plate and preparation method thereof, more particularly to a kind of decoration texture enamel plate and its system
Preparation Method.
Background technology
Currently, the enamel artistic plate making in existing market is substantially divided to two classes, it is air brushing that one kind, which is silk-screen, one kind,；So
And either silk-screen or air brushing, when carrying out pattern making, operating procedure is more complicated, and operation difficulty is also higher, needs
It expends considerable time and effort, generally requires the cost of manufacture of great number；Therefore, how a kind of pattern is provided and makes simple, system
The preparation method for making lower-cost enamel artistic plate becomes a problem of those skilled in the art's urgent need to resolve.
Invention content
In view of this, the present invention provides a kind of decoration texture enamel plates, including：
Steel plate；
Glaze layer, the glaze include glazed colour layer and transparent glaze layer layer by layer, and the glazed colour layer is coated on the steel plate and thereon
With the texture that depressed area is formed, the transparent glaze layer is filled in the depressed area.
The beneficial effects of the invention are as follows：It is different from the silk-screen of existing enamel plate and air brushing, have on enamel plate in the present invention
Glazed colour layer contacts to form depressed area by plastics or rubber anode membrane on glazed colour layer with glazed colour layer, is sprayed in depressed area transparent
Glaze forms the strong texture structure of three-dimensional sense, and the structure operation is simple, easy to make, and cost of manufacture and operation is greatly saved
Difficulty.
Preferably, the depressed area is multiple, multiple depressed area arrangeds in a manner of constituting pattern.The present invention
It is arranged to pattern only by by the protrusion of anode membrane, you can depressed area is formed pattern, that is to say, that by the silk of tradition design
Print or air brushing mode are changed into forms required pattern using the depressed area of glazed colour layer, recycles clear frit filling, can both obtain
The super strong pattern of good appearance, three-dimensional sense, and silk-screen or air brushing mode can be obtained cannot obtain pattern effect.
Preferably, ground glaze layer and cover coat are also equipped between the steel plate and the glazed colour layer successively.
Preferably, the thickness of the glazed colour layer is 100-250 μm, it is highly preferred that glazed colour layer is 150 μm.Experiment shows coloured silk
Glaze layer coating thickness is blocked up, easy tos produce adhesion effect, and pattern mould can be caused due to adhesion when carrying out the making of depressed area
Paste；Glazed colour layer coating thickness is excessively thin, can not form clearly grain effect.
Preferably, 80-180 μm of the transparent glazed thickness.I.e. the depth of depressed area is 80-180 μm, it is highly preferred that
Transparent glaze layer is 100 μm.The depth determines the quality of the textured pattern of the formation of product, and therefore, too deep exposed bottom material can influence
The aesthetics of textured pattern；It crosses shallow also due to adhesion causes dim pattern, clearly textured pattern can not be formed, that is, formed
Textured pattern is more fuzzy.
Preferably, the upper surface of the transparent glaze layer is concordant with the upper surface of the glazed colour layer.Using transparent glaze layer to coloured silk
Glaze layer carries out effective protection, and colored glaze is not easy to fade after firing, color lasting stability.
Preferably, the steel plate can be any one in plate, cylindrical, the cubic bodily form.
Preferably, the longitudinal section shape of the depressed area is semicircle, any one or several combinations of trapezoidal or triangle.
The present invention also provides a kind of preparation methods of decoration texture enamel plate, include the following steps：
(1) surface spraying colored glaze on the steel plate；
(2) by the upper surface of steel plate after spraying colored glaze in texture moulding mould imprint step (1),
Form recess textured pattern；
(3) first time drying is carried out to the steel plate after coining in step (2)；
(4) first time firing is carried out to the steel plate after drying in step (3), enamel plate original paper is made；
(5) clear frit is sprayed in the enamel plate original paper upper surface；
(6) second is carried out to the enamel plate original paper of spraying clear frit in the step (5) to dry；
(7) it polishes the enamel plate original paper after drying in step (6), it will be transparent in addition to positioned at recess textured pattern
Glaze polishing removal；
(1) it carries out second to the enamel plate original paper after polishing in step (7) to fire, texture enamel plate is made.
The present invention is different from silk-screen and air brushing that existing enamel artistic plate uses, and the present invention selects in the manufacture craft of pattern
It selects texture moulding mould to suppress, the very big difficulty for reducing manufacturing technology of patterns, it is upper with production powdered frit in raw material materials
Identical, feeding is convenient, does not have to the matching sex chromosome mosaicism for worrying the ground-coat enamel of glaze and bottom embryo, overglaze, furthermore it is also possible to using polishing off
Production clout carry out the making of next workpiece, effectively reduce production cost.
Preferably, texture moulding mould uses convex shaped textural shape, and recess textured pattern is formed after imprinting enamel plate.
Preferably, the coating thickness of colored glaze is 100-250 μm in the step (1).Colored glaze coating thickness is blocked up, is easy
It is sticked on texture moulding mould, dim pattern can be caused；Colored glaze coating thickness is excessively thin, can not form clearly grain effect.This
It invents preferred coating thickness and has effectively evaded the above problem for 100-250 μm.
Preferably, 80-180 μm of transparent glazed thickness in the step (2), i.e., the depth of depressed area is 80-180 μm.
For the clarity for the textured pattern that ensures to be recessed after imprinting, the depth of coining can not it is too deep also can not be excessively shallow.It need to be controlled when coining
The uniformity of speed of imprint ensures that the depth of indentation of enamel plate entirety is roughly the same.
Preferably, the temperature of drying is 20-70 DEG C for the first time in the step (3), it is highly preferred that the temperature of drying for the first time
Degree is 50 DEG C.Since recess textured pattern is made up of coining, the reset condition of glazed colour layer is destroyed, therefore, if drying
Temperature it is excessively high, can cause to crack in drying course or colored glaze partial exfoliation.
Preferably, the temperature fired for the first time in the step (4) is 700-900 DEG C, and the time is 2-8 minutes.
Preferably, the coating thickness of clear frit is 80-180 μm in the step (5).The spraying of clear frit is to fill pressure
Print is formed by recess textured pattern, and therefore, recess is completely covered in the coating thickness needs of clear frit, but the thickness of clear frit is not
It is preferably blocked up, it can increase unnecessary processing time in subsequent grinding process in this way, also will produce the waste of clear frit.
Preferably, the temperature of second of drying is 100-150 DEG C in the step (6).
Preferably, the temperature that second is fired in the step (8) is 790-840 DEG C, and the time is 2-5 minutes.
Description of the drawings
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below
There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
The embodiment of invention for those of ordinary skill in the art without creative efforts, can also basis
The attached drawing of offer obtains other attached drawings.
Fig. 1 attached drawings are structural schematic diagram provided by the invention.
In figure, 1- steel plates, 2- glazed colour layers, the transparent glaze layers of 3-, the depressed areas 4-, 5- ground glaze layers, 6- cover coats.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
The every other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects
It encloses.
The embodiment of the invention discloses a kind of decoration texture enamel plates, including：
Steel plate 1；
Glaze layer, glaze layer include ground glaze layer 5, cover coat 6, glazed colour layer 2 and transparent glaze layer 3, and glazed colour layer 2 is coated on steel plate 1
And the texture formed thereon with depressed area 4,3 layers of clear frit are filled in depressed area 4.
According to embodiments of the present invention, the thickness of glazed colour layer 2 is 100-250 μm.
According to embodiments of the present invention, the depth of depressed area 4 is up to the thickness of glazed colour layer 2, in some instances, recess
The depth in area 4 is 80-180 μm.
In some embodiments, the upper surface of transparent glaze layer 3 is concordant with the upper surface of glazed colour layer 2.
In some embodiments, steel plate 1 can be any one in plate, cylindrical, the cubic bodily form.
In some embodiments, the longitudinal section shape of depressed area 4 is semicircle, trapezoidal or triangle is any one or several
Combination.
Embodiment 1
The present embodiment provides a kind of methods preparing " blue peony " texture enamel plate, are as follows：
(1) 150 μm of surface spraying blue colored glaze on the steel plate；
(2) pass through the glazed colour layer upper surface after spraying colored glaze in " peony " texture moulding mould imprint step (1), coining
Process speed is uniform, and depth of indentation is 90 μm, " peony " recess textured pattern of formation；
(3) first time drying is carried out to the steel plate after coining in step (2), drying temperature is 50 DEG C；
(4) first time firing being carried out to the steel plate after drying in step (3), firing temperature is 820 DEG C, and the time is 5 minutes,
Enamel plate original paper is made；
(5) clear frit is sprayed in the enamel plate original paper upper surface, the thickness of clear frit is 100 μm；
(6) it carries out second to the enamel plate original paper of spraying clear frit in the step (5) to dry, drying temperature 120
℃；
(7) it polishes the enamel plate original paper after drying in step (6), it will be transparent in addition to positioned at recess textured pattern
Glaze polishing removal；
(8) it carries out second to the enamel plate original paper after polishing in step (7) to fire, firing temperature is 820 DEG C, the time
It is 4 minutes, " blue peony " texture enamel plate is made.
Embodiment 2
The present embodiment provides a kind of methods of " red phoenix " texture enamel plate, are as follows：
(1) 160 μm of surface spraying blue colored glaze on the steel plate；
(2) it by the glazed colour layer upper surface after spraying colored glaze in " phoenix " texture moulding mould imprint step (1), imprinted
Cheng Sudu is uniform, and depth of indentation is 100 μm and forms uniform " peony " recess textured pattern；
(3) first time drying is carried out to the steel plate after coining in step (2), drying temperature is 60 DEG C；
(4) first time firing being carried out to the steel plate after drying in step (3), firing temperature is 810 DEG C, and the time is 6 minutes,
Enamel plate original paper is made；
(5) clear frit is sprayed in the enamel plate original paper upper surface, the thickness of clear frit is 110 μm；
(6) it carries out second to the enamel plate original paper of spraying clear frit in the step (5) to dry, drying temperature 130
℃；
(7) it polishes the enamel plate original paper after drying in step (6), it will be transparent in addition to positioned at recess textured pattern
Glaze polishing removal；
(8) it carries out second to the enamel plate original paper after polishing in step (7) to fire, firing temperature is 800 DEG C, the time
It is 3 minutes, " red phoenix " texture enamel plate is made.
Embodiment 3 is to embodiment 5
Embodiment 3-5 is provided which a kind of method being printed on scenery with hills and waters pattern texture enamel plate, and preparation process is the same as above-described embodiment 1
Or embodiment 2, wherein colored glaze thickness, clear frit thickness and drying temperature are as follows：
| Colored glaze thickness (μm) | Clear frit thickness (μm) | First time drying temperature (DEG C) | |
| Embodiment 3 | 180 | 150 | 50 |
| Embodiment 4 | 150 | 120 | 55 |
| Embodiment 5 | 160 | 130 | 60 |
Comparative example 1-3
Comparative example 1-3 equally provides a kind of method being printed on scenery with hills and waters pattern texture enamel plate, and preparation process is the same as above-mentioned
Wherein, colored glaze thickness, clear frit thickness and drying temperature are as follows for embodiment 1 or embodiment 2：
| Colored glaze thickness (μm) | Clear frit thickness (μm) | First time drying temperature (DEG C) | |
| Comparative example 1 | 300 | 150 | 60 |
| Comparative example 2 | 100 | 85 | 55 |
| Comparative example 3 | 160 | 130 | 120 |
Those skilled in the art are as follows to decoration texture enamel plate ocular estimate result：
Every result scoring full marks are 10 points, score height respectively represent that texture definition is good, colored glaze integrity degree is good and
Crackle or the degree that falls off are relatively low；The above items score is the average mark numerical value that at least 10 professionals carry out evaluation score.
The present invention provides a kind of preparation method of decoration texture enamel plate, is imprinted by texture moulding mould and makes recess line
Pattern is managed, compared with silk-screen and air brushing, operation difficulty substantially reduces, and operating procedure greatly reduces, and draws materials upper in raw material and produces
Powdered frit is identical, and feeding is convenient, does not have to the matching sex chromosome mosaicism for worrying the ground-coat enamel of glaze and bottom embryo, overglaze, furthermore it is also possible to using beating
The production clout that grinds off carries out the making of next workpiece, effectively reduces production cost.
Each embodiment is described by the way of progressive in this specification, the highlights of each of the examples are with other
The difference of embodiment, just to refer each other for identical similar portion between each embodiment.For device disclosed in embodiment
For, since it is corresponded to the methods disclosed in the examples, so description is fairly simple, related place is said referring to method part
It is bright.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be apparent to those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest range caused.
Claims (10)
1. a kind of decorative ornament texture enamel plate, which is characterized in that including：
Steel plate (1)；
Glaze layer, the glaze layer include glazed colour layer (2) and transparent glaze layer (3), and the glazed colour layer (2) is coated on the steel plate (1)
And the texture formed thereon with depressed area (4), the transparent glaze layer (3) are filled in the depressed area (4).
2. a kind of decoration texture enamel plate according to claim 1, which is characterized in that the depressed area (4) be it is multiple, it is more
A depressed area (4) arranged in a manner of constituting pattern.
3. a kind of decoration texture enamel plate according to claim 1, which is characterized in that the thickness of the glazed colour layer (2) is
100-250μm。
4. a kind of decoration texture enamel plate according to any one of claims 1 to 3, which is characterized in that the transparent glaze layer
80-180 μm of thickness or the depth of depressed area are 80-180 μm.
5. a kind of preparation method of decoration texture enamel plate, which is characterized in that include the following steps：
(1) surface spraying colored glaze on the steel plate；
(2) by the upper surface of steel plate after spraying colored glaze in texture moulding mould imprint step (1), depressed area is formed；
(3) first time drying is carried out to the steel plate after coining in step (2)；
(4) first time firing is carried out to the steel plate after drying in step (3), enamel plate original paper is made；
(5) clear frit is sprayed in the enamel plate original paper upper surface；
(6) second is carried out to the enamel plate original paper of spraying clear frit in the step (5) to dry；
(7) it polishes the enamel plate original paper after drying in step (6), the clear frit polishing in addition to positioned at depressed area is gone
It removes；
(8) it carries out second to the enamel plate original paper after polishing in step (7) to fire, texture enamel plate is made.
6. a kind of preparation method of decoration texture enamel plate according to claim 5, which is characterized in that the step (3)
The temperature of middle first time drying is 20-70 DEG C.
7. a kind of preparation method of decoration texture enamel plate according to claim 5, which is characterized in that the step (4)
The temperature that middle first time fires is 700-900 DEG C, and the time is 2-8 minutes.
8. a kind of preparation method of decoration texture enamel plate according to claim 5, which is characterized in that the step (5)
The coating thickness of middle clear frit is 80-180 μm.
9. a kind of preparation method of decoration texture enamel plate according to claim 5, which is characterized in that the step (6)
In the temperature of second drying be 100-150 DEG C, drying time.
10. a kind of preparation method of decoration texture enamel plate according to claim 5, which is characterized in that the step (8)
In second temperature fired be 790-840 DEG C, the time is 2-5 minutes.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810614460.1A CN108608791A (en) | 2018-06-14 | 2018-06-14 | A kind of decoration texture enamel plate and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810614460.1A CN108608791A (en) | 2018-06-14 | 2018-06-14 | A kind of decoration texture enamel plate and preparation method thereof |
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| CN108608791A true CN108608791A (en) | 2018-10-02 |
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| CN201810614460.1A Pending CN108608791A (en) | 2018-06-14 | 2018-06-14 | A kind of decoration texture enamel plate and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109747312A (en) * | 2019-01-18 | 2019-05-14 | 深圳市中宝盈珠宝科技有限公司 | The component for applying enamel of decoration |
| CN110027076A (en) * | 2019-04-26 | 2019-07-19 | 舒雄鹰 | A kind of matouqin process of surface treatment |
| CN110735139A (en) * | 2019-11-05 | 2020-01-31 | 深圳宝福珠宝有限公司 | composite enamel processing method applied to metal surface |
| CN113854719A (en) * | 2021-09-17 | 2021-12-31 | 广东顺德周大福珠宝制造有限公司 | Jewelry and surface treatment method thereof |
| WO2022041787A1 (en) * | 2020-08-24 | 2022-03-03 | 浙江开尔新材料股份有限公司 | Manufacturing method of enamel decorative panel having jade-like texture and mirror surface effect |
| CN114231981A (en) * | 2021-12-21 | 2022-03-25 | 浙江开尔新材料股份有限公司 | Enamel plate with texture on surface and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109747312A (en) * | 2019-01-18 | 2019-05-14 | 深圳市中宝盈珠宝科技有限公司 | The component for applying enamel of decoration |
| CN110027076A (en) * | 2019-04-26 | 2019-07-19 | 舒雄鹰 | A kind of matouqin process of surface treatment |
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| WO2022041787A1 (en) * | 2020-08-24 | 2022-03-03 | 浙江开尔新材料股份有限公司 | Manufacturing method of enamel decorative panel having jade-like texture and mirror surface effect |
| CN113854719A (en) * | 2021-09-17 | 2021-12-31 | 广东顺德周大福珠宝制造有限公司 | Jewelry and surface treatment method thereof |
| CN113854719B (en) * | 2021-09-17 | 2023-07-28 | 广东顺德周大福珠宝制造有限公司 | Jewelry and surface treatment method thereof |
| CN114231981A (en) * | 2021-12-21 | 2022-03-25 | 浙江开尔新材料股份有限公司 | Enamel plate with texture on surface and preparation method thereof |
| CN114231981B (en) * | 2021-12-21 | 2024-01-26 | 浙江开尔新材料股份有限公司 | Enamel plate with surface textures and preparation method |
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