CN108587210A - A kind of material and method making combined firework environmental protection outer barrel - Google Patents
A kind of material and method making combined firework environmental protection outer barrel Download PDFInfo
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- CN108587210A CN108587210A CN201810381353.9A CN201810381353A CN108587210A CN 108587210 A CN108587210 A CN 108587210A CN 201810381353 A CN201810381353 A CN 201810381353A CN 108587210 A CN108587210 A CN 108587210A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
A kind of material and method making combined firework environmental protection outer barrel, it is related to fireworks field, and in particular to a kind of material and method making combined firework environmental protection outer barrel.A kind of making combined firework environmental protection outer barrel, it is formulated by following raw material：Plant fiber, amylan, moisture-proof toughener；The amylan is formulated by following raw material：Starch, water, fibre finish, fungicide, releasing agent；The moisture-proof toughener is formulated by following raw material：Polyvinyl alcohol, caustic soda, stearic acid.After adopting the above technical scheme, the present invention has the beneficial effect that：It is pollution-free, environmental protection, and the raw material natural degradation period used is short, can turn waste into wealth, and can recycle, limited resources is made to maximally utilize, play maximum value.
Description
Technical field
The present invention relates to fireworks fields, and in particular to a kind of material and method making combined firework environmental protection outer barrel.
Background technology
China's fireworks and firecrackers is with a long history, of long standing and well established, has more than 1300 years history, in historical floods, combustion so far
A kind of folkways and customs that fireworks and firecrackers is Chinese common people are put, the important component of Chinese traditional culture is more become, it is this
Custom and culture continue up so far, and as the exchange of Middle Ages Chinese and Western culture walked out the gateway of a country together, has spread all over full generation
Boundary.
The fireworks and firecrackers in China is various in style, the huge market demand, and combined firework occupies half of the country, therefore combines cigarette
The firework external cylinder quantity that flower makes needs is very big, and the widely used firework external cylinder main raw material(s) calcium carbonate in present market accounts for entirely
The 60%-70% of product composition, if number of patent application be 201010208725.1, patent name be a kind of material for outer firework barrel and
Preparation method is disclosed a kind of fireworks tube making material, is expected based on paper pulp and calcium carbonate, is subject to calcium hydroxide, rice
Grass, sodium carboxymethylcellulose (CMC) are used as auxiliary material, are formula according to following quality proportioning：300-400 grams of paper pulp；Calcium carbonate
300-400 grams；10-20 grams of calcium hydroxide；80-120 grams of straw；50-80 grams of sodium carboxymethylcellulose (CMC)；The invention institute
The production method for stating material is as follows：1, blender is put into after mixing above-mentioned material according to weight proportion；According to thrown material 1：
Clear water is added in the weight proportion of 20-40, is stirred and mixes thoroughly, and entire material is made to become pulpous state；2, fireworks tube is carried out as requested
Mold, mold is placed in press, to being in the milk in mold, slurry is made to be full of entire cavity body of mould；3, pass through press
Filter-press dehydration molding is carried out, slurry is made to become the fireworks tube of required planform in mold；4, by the cigarette after dehydration forming
Cylindrical fireworks spontaneously dry or are placed in drying in drying oven, by oil temperature or electrothermal drying, become fireworks tube product, its main original
Material is the firework external cylinder of calcium carbonate, cannot be recycled after firework display, and the natural degradation period is long, generates a large amount of solid refuse,
Serious pollution also is brought to environment simultaneously, is increasingly resisted by environmental protection administration and the common people, government agencies at all levels put into effect political affairs in succession
Plan forbids selling this type molding outer barrel, it can be seen that, the combined firework outer barrel of research and development and production novel environment friendly is imperative.
Invention content
In view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of making combined firework environmental protection outer barrels
Material and method, it is pollution-free, environmental protection, and the raw material natural degradation period used is short, can turn waste into wealth, and can follow
Ring utilizes, and so that limited resources is maximally utilized, plays maximum value.
To achieve the above object, the present invention is using following technical scheme：A kind of making combined firework environmental protection outer barrel, it by
Following parts by weight raw material is formulated：It is 10-90 parts of plant fiber, 10-90 parts of amylan, toughener 2-5 parts moisture-proof；Described
Amylan is formulated by following parts by weight raw material：2-10 parts of starch, 20-80 parts of water, 2-6 parts of fibre finish, fungicide
1-3 parts, 1-4 parts of releasing agent；The moisture-proof toughener is formulated using following parts by weight raw material：1-2 parts of polyvinyl alcohol,
0.5-1 parts of caustic soda, 0.5-2 parts of stearic acid.
The plant fiber is formed using crops stalk crushing.
The fibre finish is alum.
The fungicide is sodium benzoate.
A method of combined firework environmental protection outer barrel is made, is included the following steps：
One, stalk is crushed using pulverizer to obtain plant fiber；
Two, amylan raw material will be made to be mixed in proportion, stirs evenly rear stand for standby use；
Three, the raw material for making moisture-proof toughener is mixed in proportion, stirs evenly rear stand for standby use；
Four, plant fiber and amylan, moisture-proof toughener are mixed in proportion, stirs 1-5 minutes, stirs evenly；
Five, the above-mentioned mixture stirred evenly is put and is squeezed out in an extruder, feeding bar rotating speed is controlled at 25 revs/min or so,
Blanking bar rotating speed is controlled at 30 revs/min or so；
Six, the firework external cylinder squeezed out from extruder is detected, firework external cylinder is subjected to packing and binding after detection is qualified.
The plant fiber need to place in water 3-5 hours at plant fiber pulp.Plant fiber needs to place in water
Fabric fibre can be softened within 3-5 hours to starch, can be used for paper mill and continue papermaking, limited resources is made to maximally utilize, played maximum
Value.
After adopting the above technical scheme, the present invention has the beneficial effect that：It is pollution-free, environmental protection, and the raw material used is natural
Degradation cycle is short, can turn waste into wealth, and can recycle, and limited resources is made to maximally utilize, and plays maximum value.
Specific implementation mode
Embodiment 1
A kind of making combined firework environmental protection outer barrel, it is formulated by following parts by weight raw material：10 parts of plant fiber, amylan
10 parts, 2 parts of moisture-proof toughener；The amylan is formulated by following parts by weight raw material：2 parts of starch, 20 parts of water, fiber
2 parts of inorganic agent, 1 part of fungicide, 1 part of releasing agent；The moisture-proof toughener is formulated by following parts by weight raw material：Poly- second
1 part of dilute alcohol, 0.5 part of caustic soda, 0.5 part of stearic acid.
Embodiment 2
A kind of making combined firework environmental protection outer barrel, it is formulated by following parts by weight raw material：50 parts of plant fiber, amylan
50 parts, 3 parts of moisture-proof toughener；The amylan is formulated by following parts by weight raw material：6 parts of starch, 50 parts of water, fiber
4 parts of inorganic agent, 5 parts of fungicide, 2.5 parts of releasing agent；The moisture-proof toughener is formulated by following parts by weight raw material：It is poly-
1.5 parts of second dilute alcohol, 0.7 part of caustic soda, 1.3 parts of stearic acid.
Embodiment 3
A kind of making combined firework environmental protection outer barrel, it is formulated by following parts by weight raw material：90 parts of plant fiber, amylan
90 parts, 5 parts of moisture-proof toughener；The amylan is formulated by following parts by weight raw material：10 parts of starch, 80 parts of water, fibre
Tie up 6 parts of inorganic agent, 3 parts of fungicide, 4 parts of releasing agent；The moisture-proof toughener is formulated by following parts by weight raw material：It is poly-
2 parts of second dilute alcohol, 1 part of caustic soda, 2 parts of stearic acid.
The plant fiber is formed using crops stalk crushing.
The fibre finish is alum.Alum is colourless crystallization or powder, odorlessness, slightly sweet and have puckery
Taste has convergence, in dry air weathering lose the crystallization water, dissolved in humid air and drop down water, be soluble in glycerine, can be dissolved in
Water, aqueous solution react acid, and have aluminium hydroxide glue object precipitation after hydrolysis.
The fungicide is sodium benzoate.Sodium benzoate is a kind of white particle or crystal powder, odorless or micro-strip peace
Fragrance taste is ceased, taste is slightly sweet, has astringent taste, also referred to as sodium benzoate, relative molecular mass 144.12 is stable in the air, readily soluble
The PH values of Yu Shui, aqueous solution are 8, are dissolved in ethyl alcohol, increase its sterilization, inhibitory effect enhancing with acidity of medium, in alkalinity
Sterilization, bacteriostasis are then lost in medium.
A kind of making combined firework environmental protection outer barrel method, includes the following steps：
One, stalk is crushed using pulverizer to obtain plant fiber；
Two, amylan raw material will be made to be mixed in proportion, stirs evenly rear stand for standby use；
Three, the raw material for making moisture-proof toughener is mixed in proportion, stirs evenly rear stand for standby use；
Four, plant fiber and amylan, moisture-proof toughener are mixed in proportion, stirs 1-5 minutes, stirs evenly；
Five, the above-mentioned mixture stirred evenly is put and is squeezed out in an extruder, feeding bar rotating speed is controlled at 25 revs/min or so,
Blanking bar rotating speed is controlled at 30 revs/min or so；
Six, the firework external cylinder squeezed out from extruder is detected, firework external cylinder is subjected to packing and binding after detection is qualified.
The plant fiber need to place in water 3-5 hours at plant fiber pulp.Plant fiber needs to place in water
Fabric fibre can be softened within 3-5 hours to starch, can be used for paper mill and continue papermaking, limited resources is made to maximally utilize, played maximum
Value.
The invention has the advantages that or advantageous effect：
（1）Fireworks inner tank can fry into powder with firework display, it is difficult to recycle, under firework external cylinder can preserve substantially in setting off
Come, in fireworks production, firework external cylinder output is big, and it is main former material that the present invention, which changes the widely used calcium carbonate of existing market,
The present situation that the combined firework outer barrel that material makes cannot recycle, using plant fiber, amylan and moisture-proof toughener as master
Raw material is wanted, former peasant, which burns harvested agricultural crop straw, can cause environmental pollution, the combined firework outer barrel that the present invention makes
10%-90% containing plant fiber can also turn waste into wealth while reducing environmental pollution, increase farmers' income；
（2）By plant fiber be primary raw material make novel environment friendly outer barrel after setting off, being recovered into water can soften for 3-5 hours
At plant fiber pulp, it can be used for paper mill and continue papermaking, so that limited resources is maximally utilized, play maximum value；
（3）Appliable plant fiber is the outer cylinder size of the combined firework novel environment friendly more specification of main material making, endoporus is more smooth,
Crushing resistance is stronger, is applied in combined firework product, can reduce fried cylinder, the low security risks such as fried, improve product quality and
Safety；
（4）Appliable plant fiber is that the combined firework novel environment friendly outer barrel anti-corrosion that main material makes and humidity resistance are more preferable, production
Quality is more secure.
After adopting the above technical scheme, the present invention has the beneficial effect that：It is pollution-free, environmental protection, and the raw material used is natural
Degradation cycle is short, can turn waste into wealth, and can recycle, and limited resources is made to maximally utilize, and plays maximum value.
The above is merely illustrative of the technical solution of the present invention and unrestricted, and those of ordinary skill in the art are to this hair
The other modifications or equivalent replacement that bright technical solution is made, as long as it does not depart from the spirit and scope of the technical scheme of the present invention,
It is intended to be within the scope of the claims of the invention.
Claims (9)
1. a kind of material making combined firework environmental protection outer barrel, it is characterised in that it is formulated by following parts by weight raw material：
It is 10-90 parts of plant fiber, 10-90 parts of amylan, toughener 2-5 parts moisture-proof；The amylan is by following parts by weight raw material
It is formulated：2-10 parts of starch, 20-80 parts of water, 2-6 parts of fibre finish, 1-3 parts of fungicide, 1-4 parts of releasing agent；Described
Moisture-proof toughener is formulated by following parts by weight raw material：1-2 parts of polyvinyl alcohol, 0.5-1 parts of caustic soda, 0.5-2 parts of stearic acid.
2. a kind of method making combined firework environmental protection outer barrel, it is characterised in that it is formulated by following steps：
One, stalk is crushed using pulverizer to obtain plant fiber；
Two, amylan raw material will be made to be mixed in proportion, stirs evenly rear stand for standby use；
Three, the raw material for making moisture-proof toughener is mixed in proportion, stirs evenly rear stand for standby use；
Four, plant fiber and amylan, moisture-proof toughener are mixed in proportion, stirs 1-5 minutes, stirs evenly；
Five, the above-mentioned mixture stirred evenly is put and is squeezed out in an extruder, feeding bar rotating speed is controlled at 25 revs/min or so,
Blanking bar rotating speed is controlled at 30 revs/min or so；
Six, the firework external cylinder squeezed out from extruder is detected, firework external cylinder is subjected to packing and binding after detection is qualified.
3. a kind of material making combined firework environmental protection outer barrel according to claim 1, it is characterised in that it is by following heavy
Amount number raw material is formulated：10 parts of plant fiber, 10 parts of amylan, 2 parts of moisture-proof toughener；The amylan is by following heavy
Amount number raw material is formulated：2 parts of starch, 20 parts of water, 2 parts of fibre finish, 1 part of fungicide, 1 part of releasing agent；Described is anti-
Damp toughener is formulated by following parts by weight raw material：1 part of polyvinyl alcohol, 0.5 part of caustic soda, 0.5 part of stearic acid.
4. a kind of material making combined firework environmental protection outer barrel according to claim 1, it is characterised in that it is by following heavy
Amount number raw material is formulated：50 parts of plant fiber, 50 parts of amylan, 3 parts of moisture-proof toughener；The amylan is by following heavy
Amount number raw material is formulated：6 parts of starch, 50 parts of water, 4 parts of fibre finish, 5 parts of fungicide, 2.5 parts of releasing agent；Described
Moisture-proof toughener is formulated by following parts by weight raw material：1.5 parts of polyvinyl alcohol, 0.7 part of caustic soda, 1.3 parts of stearic acid.
5. a kind of material making combined firework environmental protection outer barrel according to claim 1, it is characterised in that it is by following heavy
Amount number raw material is formulated：90 parts of plant fiber, 90 parts of amylan, 5 parts of moisture-proof toughener；The amylan is by following heavy
Amount number raw material is formulated：10 parts of starch, 80 parts of water, 6 parts of fibre finish, 3 parts of fungicide, 4 parts of releasing agent；Described is anti-
Damp toughener is formulated by following parts by weight raw material：2 parts of polyvinyl alcohol, 1 part of caustic soda, 2 parts of stearic acid.
6. a kind of material making combined firework environmental protection outer barrel according to claim 1, it is characterised in that：The plant is fine
Dimension is formed using crops stalk crushing.
7. a kind of material making combined firework environmental protection outer barrel according to claim 1, it is characterised in that：The fiber
Inorganic agent is alum.
8. a kind of material making combined firework environmental protection outer barrel according to claim 1, it is characterised in that：The sterilization
Agent is sodium benzoate.
9. a kind of method making combined firework environmental protection outer barrel according to claim 2, it is characterised in that：The plant
Fiber needs to place forms plant fiber pulp in 3-5 hours in water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810381353.9A CN108587210A (en) | 2018-04-25 | 2018-04-25 | A kind of material and method making combined firework environmental protection outer barrel |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810381353.9A CN108587210A (en) | 2018-04-25 | 2018-04-25 | A kind of material and method making combined firework environmental protection outer barrel |
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| CN108587210A true CN108587210A (en) | 2018-09-28 |
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| CN201810381353.9A Pending CN108587210A (en) | 2018-04-25 | 2018-04-25 | A kind of material and method making combined firework environmental protection outer barrel |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109211021A (en) * | 2018-10-13 | 2019-01-15 | 湖南妙音农业开发有限公司 | A kind of fireworks seat and its manufacturing method |
| CN109336460A (en) * | 2018-10-19 | 2019-02-15 | 萍乡市集美环保新材料制造有限公司 | A kind of firework external cylinder and preparation method thereof |
| CN111995874A (en) * | 2020-07-14 | 2020-11-27 | 广州至简通用设备制造有限公司 | Naturally degradable polymeric material and preparation method thereof |
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| CN1056912A (en) * | 1990-05-25 | 1991-12-11 | 段有福 | Cylinder-type article made from paper fibres and its manufacture method and former thereof |
| CN101377395A (en) * | 2008-09-04 | 2009-03-04 | 黄明初 | Pressure forming firework external cylinder and fireworks display marble casing and manufacturing method thereof |
| CN103232719A (en) * | 2013-05-02 | 2013-08-07 | 汤华荣 | Firework cylinder material and preparation method thereof |
| CN105333773A (en) * | 2015-10-14 | 2016-02-17 | 浏阳市华冠出口花炮有限公司 | New material and method for manufacturing outer barrel of firework |
| CN105352372A (en) * | 2015-10-14 | 2016-02-24 | 浏阳市华冠出口花炮有限公司 | New material and method for manufacturing firework internal cylinder |
-
2018
- 2018-04-25 CN CN201810381353.9A patent/CN108587210A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1056912A (en) * | 1990-05-25 | 1991-12-11 | 段有福 | Cylinder-type article made from paper fibres and its manufacture method and former thereof |
| CN101377395A (en) * | 2008-09-04 | 2009-03-04 | 黄明初 | Pressure forming firework external cylinder and fireworks display marble casing and manufacturing method thereof |
| CN103232719A (en) * | 2013-05-02 | 2013-08-07 | 汤华荣 | Firework cylinder material and preparation method thereof |
| CN105333773A (en) * | 2015-10-14 | 2016-02-17 | 浏阳市华冠出口花炮有限公司 | New material and method for manufacturing outer barrel of firework |
| CN105352372A (en) * | 2015-10-14 | 2016-02-24 | 浏阳市华冠出口花炮有限公司 | New material and method for manufacturing firework internal cylinder |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109211021A (en) * | 2018-10-13 | 2019-01-15 | 湖南妙音农业开发有限公司 | A kind of fireworks seat and its manufacturing method |
| WO2020073819A1 (en) * | 2018-10-13 | 2020-04-16 | 湖南妙音农业开发有限公司 | Firework base and manufacturing method therefor |
| CN109336460A (en) * | 2018-10-19 | 2019-02-15 | 萍乡市集美环保新材料制造有限公司 | A kind of firework external cylinder and preparation method thereof |
| CN111995874A (en) * | 2020-07-14 | 2020-11-27 | 广州至简通用设备制造有限公司 | Naturally degradable polymeric material and preparation method thereof |
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Application publication date: 20180928 |