CN108585991A - A kind of special compound fertilizer containing modified molecular screen of winter peach - Google Patents

A kind of special compound fertilizer containing modified molecular screen of winter peach Download PDF

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CN108585991A
CN108585991A CN201810694742.7A CN201810694742A CN108585991A CN 108585991 A CN108585991 A CN 108585991A CN 201810694742 A CN201810694742 A CN 201810694742A CN 108585991 A CN108585991 A CN 108585991A
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parts
molecular screen
leaves
modified molecular
acid
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宋金叶
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Lai An County Jintao Ecological Agriculture Co Ltd
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Lai An County Jintao Ecological Agriculture Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B1/00Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
    • C05B1/02Superphosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
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  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a kind of special compound fertilizer containing modified molecular screen of winter peach, raw material includes by weight:15 30 parts of urea, 5 11 parts of monoammonium phosphate, 8 13 parts of calcium superphosphate, 7 13 parts of potassium sulfate, 30 50 parts of organic fertilizer of fermentation, 25 parts of probiotics, 12 parts of calcium carbonate, 37 parts of montmorillonite, 5 12 parts of modified molecular screen, 0.1 0.3 parts of 2 chlorine, 6 trichloromethyl pyridine, 0.5 2 parts of auxiliary agent;The raw material of the fermentation organic fertilizer includes fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves.The special compound fertilizer containing modified molecular screen of winter peach proposed by the present invention, formula is reasonable, and slow release is good, can promote the growth of winter peach, improves the utilization rate of fertilizer.

Description

A kind of special compound fertilizer containing modified molecular screen of winter peach
Technical field
The present invention relates to technical field of fertilizers more particularly to a kind of special compound fertilizers containing modified molecular screen of winter peach.
Background technology
Winter peach head is big, quality is good, it is ripe it is late, adaptable, yielding ability is good, winter resistance is strong, storage period is long, be rich in simultaneously The trace element and nutritional ingredient of the needed by human body such as sugar, tartaric acid, multivitamin and calcium, phosphorus, iron have great market latent Power.Fertilizer is essential substance in winter peach planting process, although disclosing a variety of fertilizer in the prior art, in winter peach Fertilising during, there are still the lower defects of utilization rate, cause the waste of macronutrient and huge economic loss.
Invention content
Technical problems based on background technology, it is special containing the compound of modified molecular screen that the present invention proposes a kind of winter peach Fertilizer, formula is reasonable, and slow release is good, can promote the growth of winter peach, improves the utilization rate of fertilizer.
The special compound fertilizer containing modified molecular screen of a kind of winter peach proposed by the present invention, raw material include by weight:Urine 15-30 parts plain, 5-11 parts of monoammonium phosphate, 8-13 parts of calcium superphosphate, 7-13 parts of potassium sulfate, 30-50 parts of organic fertilizer of fermentation, probiotics 2-5 parts, 1-2 parts of calcium carbonate, 3-7 parts of montmorillonite, 5-12 parts of modified molecular screen, 0.1-0.3 parts of N-serve, 0.5-2 parts of auxiliary agent;
Wherein, it is described fermentation organic fertilizer raw material include fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, Three-bristle cudrania leaf, paulownia leaves.
Preferably, it ferments in the raw material of organic fertilizer, fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania Leaf, paulownia leaves weight ratio be 3-10:2-9:5-20:5-20:5-11:3-30:5-13:6-15.
Preferably, the fermentation organic fertilizer is prepared according to following technique:By fishbone dust, bamboo shoot skins, acid-sludge, monosodium glutamate Corynebacterium glutamicum is accessed after slag, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves drying, ferment 30- at 25-30 DEG C 50min is warming up to 70-75 DEG C, and potassium hydroxide and zinc sulfate is added, and it is 7 to adjust pH value, is stirred to react 100-200min, cooling After obtain the fermentation organic fertilizer.
Preferably, the weight of corynebacterium glutamicum be fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, The 2-5wt% of three-bristle cudrania leaf, paulownia leaves total weight;The weight of potassium hydroxide is fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, wild jujube The 1-3wt% of benevolence, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves total weight;The weight of zinc sulfate is fishbone dust, bamboo shoot skins, acid-sludge, monosodium glutamate The 2-6wt% of slag, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves total weight.
Preferably, the probiotics be saccharomycete, bacillus subtilis mixture, and saccharomycete, bacillus subtilis Weight ratio be 2-9:4-11.
Preferably, the montmorillonite is the montmorillonite that polylysine is modified.
Preferably, the modified molecular screen is prepared according to following technique:MCM-41 molecular sieves are added in toluene, so 3- aminopropyl triethoxysilanes are added afterwards and react 3-8h at 95-105 DEG C under nitrogen protection, through centrifugation, washing, drying Obtain material A;Material A, tannic acid are mixed with water, vibrate 15-20h at room temperature, centrifuges, be dried to obtain material B;By material B is added to the water, and ultrasonic disperse after urea is added, and iron chloride is then added, and stirring 3-5min obtains the modified molecular screen.
Preferably, MCM-41 molecular sieves, 3- aminopropyl triethoxysilanes weight ratio be 3-10:2-6;Material A, tannin The weight ratio of acid is 0.1-0.3:8-13;Material B, urea, iron chloride weight ratio be 30-50:2-5:5-12.
Preferably, the auxiliary agent is the mixture of sulfonated melamine compound condensation product, 2- sodium naphthalene sulfonates, DA-6 crude oil, And the weight ratio of sulfonated melamine compound condensation product, 2- sodium naphthalene sulfonates, DA-6 crude oil is 5-12:3-9:4-11.
The special compound fertilizer containing modified molecular screen of winter peach of the present invention can prepare work according to conventional compound fertilizer Skill is prepared.
The special compound fertilizer containing modified molecular screen of winter peach of the present invention, in raw material, with fishbone dust, bamboo shoot skins, vinegar Slag, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves are organic fertilizer raw material, and are fermented, and keep gained fermentation organic Fertilizer containing multiple biological activities enzyme, amino acid and organic matter etc., and react under potassium hydroxide and zinc sulfate generation poly- enzyme, Potassium/zinc isoreactivity ingredient is chelated, is coordinated with urea, monoammonium phosphate, calcium superphosphate, potassium sulfate, each ingredient synergistic effect is apparent, has Effect promotes the development of winter peach root system, so that winter peach is adsorbed root system periphery nutrient for its absorption, improves utilization rate of fertilizer, play The effect of volume increase;In the preparation process of modified molecular screen, first by MCM-41 molecular sieves and 3- aminopropyl-triethoxy silicon Alkane mixes, under the action of nitrogen, by three ethoxy of 3- aminopropyls under the premise of holding MCM-41 molecular sieves hexagonal mesoporous structure Amino bonded in base silane has arrived the surface of MCM-41 molecular sieves, has obtained material A;It, will after material A is mixed with tannic acid Tannic acid has been adsorbed onto in material A, has obtained material B;Material B is mixed with urea and iron chloride later, on the one hand, in material B Existing meso-hole structure can adsorb iron ion and urea, and on the other hand, the phenolic hydroxyl group in material B is complexed with iron ion With urea hydrogen bond action occurs for reaction, and iron and urea have been introduced into material B by various effects, and it is mesoporous to have obtained modification Molecular sieve is added into system, on the one hand, meso-hole structure hinders the diffusion of water and urea being in direct contact with urea, together When iron ion have the function of Physical crosslinking agent, further hinder the diffusion and dissolving of urea, urea and iron played excellent Different slow releasing function coordinates with montmorillonite and calcium carbonate, during winter peach grows can slow longer time offer To the nutrient needed for winter peach, the growth of winter peach is promoted, improves the utilization rate of fertilizer, while avoiding fertilizer heap and manufacturing At burn seedlings phenomenon;Using sulfonated melamine compound condensation product, 2- sodium naphthalene sulfonates, DA-6 crude oil mixture as auxiliary agent, with The compatibility of ecological environment is good, promotes the growth of root system, promotes the absorption to N P and K, improves the utilization rate of fertilizer, The content for improving the nutritional ingredients such as protein in winter peach, amino acid, vitamin, sugar simultaneously, improves the quality of winter peach.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
The special compound fertilizer containing modified molecular screen of a kind of winter peach proposed by the present invention, raw material include by weight:Urine Element 30 parts, 5 parts of monoammonium phosphate, 13 parts of calcium superphosphate, 7 parts of potassium sulfate, fermentation 50 parts of organic fertilizer, 2 parts of probiotics, 2 parts of calcium carbonate, 3 parts of montmorillonite, 12 parts of modified molecular screen, 0.1 part of N-serve, 2 parts of auxiliary agent;
Wherein, it is described fermentation organic fertilizer raw material include fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, Three-bristle cudrania leaf, paulownia leaves.
Embodiment 2
The special compound fertilizer containing modified molecular screen of a kind of winter peach proposed by the present invention, raw material include by weight:Urine 15 parts of element, 11 parts of monoammonium phosphate, 8 parts of calcium superphosphate, 13 parts of potassium sulfate, 30 parts of organic fertilizer of fermentation, 5 parts of probiotics, calcium carbonate 1 Part, 7 parts of montmorillonite, 5 parts of modified molecular screen, 0.3 part of N-serve, 0.5 part of auxiliary agent;
Wherein, it is described fermentation organic fertilizer raw material include fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, Three-bristle cudrania leaf, paulownia leaves.
Embodiment 3
The special compound fertilizer containing modified molecular screen of a kind of winter peach proposed by the present invention, raw material include by weight:Urine 26 parts of element, 7 parts of monoammonium phosphate, 11 parts of calcium superphosphate, 8 parts of potassium sulfate, 43 parts of organic fertilizer of fermentation, 3 parts of probiotics, calcium carbonate 1.8 Part, 4.2 parts of montmorillonite, 11 parts of modified molecular screen, 0.12 part of N-serve, 1.6 parts of auxiliary agent;
Wherein, it is described fermentation organic fertilizer raw material include fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, Three-bristle cudrania leaf, paulownia leaves, and the weight ratio of fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves It is 3:9:5:20:5:30:5:15;
The fermentation organic fertilizer is prepared according to following technique:By fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, wild jujube Corynebacterium glutamicum is accessed after benevolence, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves drying, ferment 50min at 25 DEG C, is warming up to 70 DEG C, Potassium hydroxide and zinc sulfate is added, it is 7 to adjust pH value, is stirred to react 200min, the fermentation organic fertilizer is obtained after cooling;Its In, the weight of corynebacterium glutamicum is fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, paulownia The 2wt% of leaf total weight;The weight of potassium hydroxide is fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, Zhe Shu The 3wt% of leaf, paulownia leaves total weight;The weight of zinc sulfate be fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, The 2wt% of three-bristle cudrania leaf, paulownia leaves total weight;
The probiotics be saccharomycete, bacillus subtilis mixture, and the weight ratio of saccharomycete, bacillus subtilis It is 9:4;
The montmorillonite is the montmorillonite that polylysine is modified;
The modified molecular screen is prepared according to following technique:MCM-41 molecular sieves are added in toluene, are then added 3- aminopropyl triethoxysilanes react 8h at 95 DEG C under nitrogen protection, through centrifugation, wash, are dried to obtain material A;It will Material A, tannic acid are mixed with water, vibrate 15h at room temperature, are centrifuged, are dried to obtain material B;Material B is added to the water, is added Ultrasonic disperse after urea, is then added iron chloride, and stirring 5min obtains the modified molecular screen;Wherein, MCM-41 molecular sieves, 3- The weight ratio of aminopropyl triethoxysilane is 10:2;Material A, the weight ratio of tannic acid are 0.1:13;Material B, urea, chlorination The weight ratio of iron is 30:5:5;
The auxiliary agent is the mixture of sulfonated melamine compound condensation product, 2- sodium naphthalene sulfonates, DA-6 crude oil, and sulfonation three Melamine-formaldehyde condensation product, 2- sodium naphthalene sulfonates, DA-6 crude oil weight ratio be 12:3:11.
Embodiment 4
The special compound fertilizer containing modified molecular screen of a kind of winter peach proposed by the present invention, raw material include by weight:Urine 17 parts of element, 10 parts of monoammonium phosphate, 9 parts of calcium superphosphate, 12 parts of potassium sulfate, 34 parts of organic fertilizer of fermentation, 4 parts of probiotics, calcium carbonate 1.2 Part, 6.3 parts of montmorillonite, 7 parts of modified molecular screen, 0.26 part of N-serve, 1 part of auxiliary agent;
Wherein, it is described fermentation organic fertilizer raw material include fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, Three-bristle cudrania leaf, paulownia leaves, and the weight ratio of fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves It is 10:2:20:5:11:3:13:6;
The fermentation organic fertilizer is prepared according to following technique:By fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, wild jujube Corynebacterium glutamicum is accessed after benevolence, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves drying, ferment 30min at 30 DEG C, is warming up to 75 DEG C, Potassium hydroxide and zinc sulfate is added, it is 7 to adjust pH value, is stirred to react 100min, the fermentation organic fertilizer is obtained after cooling;Its In, the weight of corynebacterium glutamicum is fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, paulownia The 5wt% of leaf total weight;The weight of potassium hydroxide is fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, Zhe Shu The 1wt% of leaf, paulownia leaves total weight;The weight of zinc sulfate be fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, The 6wt% of three-bristle cudrania leaf, paulownia leaves total weight;
The probiotics be saccharomycete, bacillus subtilis mixture, and the weight ratio of saccharomycete, bacillus subtilis It is 2:11;
The montmorillonite is the montmorillonite that polylysine is modified;
The modified molecular screen is prepared according to following technique:MCM-41 molecular sieves are added in toluene, are then added 3- aminopropyl triethoxysilanes react 3h at 105 DEG C under nitrogen protection, through centrifugation, wash, are dried to obtain material A; Material A, tannic acid are mixed with water, vibrate 20h at room temperature, centrifuges, be dried to obtain material B;Material B is added to the water, is added Enter ultrasonic disperse after urea, iron chloride is then added, stirring 3min obtains the modified molecular screen;Wherein, MCM-41 molecular sieves, The weight ratio of 3- aminopropyl triethoxysilanes is 3:6;Material A, the weight ratio of tannic acid are 0.3:8;Material B, urea, chlorination The weight ratio of iron is 50:2:12;
The auxiliary agent is the mixture of sulfonated melamine compound condensation product, 2- sodium naphthalene sulfonates, DA-6 crude oil, and sulfonation three Melamine-formaldehyde condensation product, 2- sodium naphthalene sulfonates, DA-6 crude oil weight ratio be 5:9:4.
Embodiment 5
The special compound fertilizer containing modified molecular screen of a kind of winter peach proposed by the present invention, raw material include by weight:Urine 21 parts of element, 8 parts of monoammonium phosphate, 10 parts of calcium superphosphate, 11 parts of potassium sulfate, 40 parts of organic fertilizer of fermentation, 3 parts of probiotics, calcium carbonate 1.5 Part, 5 parts of montmorillonite, 10 parts of modified molecular screen, 0.2 part of N-serve, 1.5 parts of auxiliary agent;
Wherein, it is described fermentation organic fertilizer raw material include fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, Three-bristle cudrania leaf, paulownia leaves;
It ferments in the raw material of organic fertilizer, fishbone dust, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, is steeped bamboo shoot skins The weight ratio of paulownia leaf is 7:6:11:15:8:19:10:11;
The fermentation organic fertilizer is prepared according to following technique:By fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, wild jujube Corynebacterium glutamicum is accessed after benevolence, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves drying, ferment 40min at 28 DEG C, is warming up to 73 DEG C, Potassium hydroxide and zinc sulfate is added, it is 7 to adjust pH value, is stirred to react 150min, the fermentation organic fertilizer is obtained after cooling;
The weight of corynebacterium glutamicum be fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, The 4wt% of paulownia leaves total weight;The weight of potassium hydroxide be fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, The 2wt% of three-bristle cudrania leaf, paulownia leaves total weight;The weight of zinc sulfate is fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, mountain The 5wt% of short, bristly hair or beard leaf, three-bristle cudrania leaf, paulownia leaves total weight;
The probiotics be saccharomycete, bacillus subtilis mixture, and the weight ratio of saccharomycete, bacillus subtilis It is 6:7;
The montmorillonite is the montmorillonite that polylysine is modified;
The modified molecular screen is prepared according to following technique:MCM-41 molecular sieves are added in toluene, are then added 3- aminopropyl triethoxysilanes react 5h at 100 DEG C under nitrogen protection, through centrifugation, wash, are dried to obtain material A; Material A, tannic acid are mixed with water, vibrate 17h at room temperature, centrifuges, be dried to obtain material B;Material B is added to the water, is added Enter ultrasonic disperse after urea, iron chloride is then added, stirring 4min obtains the modified molecular screen;
MCM-41 molecular sieves, 3- aminopropyl triethoxysilanes weight ratio be 7:5;Material A, the weight ratio of tannic acid are 0.2:11;Material B, urea, iron chloride weight ratio be 40:3:9;
The auxiliary agent is the mixture of sulfonated melamine compound condensation product, 2- sodium naphthalene sulfonates, DA-6 crude oil, and sulfonation three Melamine-formaldehyde condensation product, 2- sodium naphthalene sulfonates, DA-6 crude oil weight ratio be 8:6:7.
The special compound fertilizer containing modified molecular screen of winter peach of the present invention is impregnated 24 hours in 25 DEG C of hydrostatic, just Phase nutrient release rate is 12-12.8%, accumulates within 28 days nutrient release rate for 70-71%, preparation is in fertilizer releasing period 94.2-95.3%, fertilizer nutrient effective rate of utilization improve 43.2% or more, and usage amount and the fertilising time of fertilizer can be greatly decreased Number, improves the effective rate of utilization of fertilizer, meets the regulation of slow release fertilizer standard GB/T-T23348-2009.
It is 1 mu of peach garden as experimental plot to select one area of Laian County, the peach garden that another area is 1 mu field as a contrast, Wherein, experimental plot and the peach tree in control field, age of tree all same, experimental plot are real according to the amount application present invention of 2000kg per acre Apply the special compound fertilizer containing modified molecular screen of winter peach in example 1, the winter peach fertilizer of control field application commercialization, wherein examination The per mu yield for testing field is 2856kg, and the per mu yield for compareing field is 2235kg.
From the above data, the special compound fertilizer slow release containing modified molecular screen of winter peach of the present invention is good, utilizes Rate is high, and effect of increasing production is excellent.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (9)

1. a kind of special compound fertilizer containing modified molecular screen of winter peach, which is characterized in that its raw material includes by weight:Urea 15-30 parts, 5-11 parts of monoammonium phosphate, 8-13 parts of calcium superphosphate, 7-13 parts of potassium sulfate, fermentation 30-50 parts of organic fertilizer, probiotics 2- 5 parts, 1-2 parts of calcium carbonate, 3-7 parts of montmorillonite, 5-12 parts of modified molecular screen, 0.1-0.3 parts of N-serve, help 0.5-2 parts of agent;
Wherein, the raw material of the fermentation organic fertilizer includes fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, Zhe Shu Leaf, paulownia leaves.
2. the special compound fertilizer containing modified molecular screen of winter peach according to claim 1, which is characterized in that ferment organic fertilizer In raw material, fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves weight ratio be 3-10:2- 9:5-20:5-20:5-11:3-30:5-13:6-15.
3. the special compound fertilizer containing modified molecular screen of winter peach according to claim 1 or claim 2, which is characterized in that the fermentation Organic fertilizer is prepared according to following technique:By fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, Corynebacterium glutamicum is accessed after paulownia leaves drying, ferment 30-50min at 25-30 DEG C, is warming up to 70-75 DEG C, and hydrogen-oxygen is added Change potassium and zinc sulfate, it is 7 to adjust pH value, is stirred to react 100-200min, the fermentation organic fertilizer is obtained after cooling.
4. the special compound fertilizer containing modified molecular screen of winter peach according to claim 3, which is characterized in that glutamic acid rod-like stem The weight of bacterium be fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves total weight 2- 5wt%;The weight of potassium hydroxide is that fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, paulownia leaves are total The 1-3wt% of weight;The weight of zinc sulfate is fishbone dust, bamboo shoot skins, acid-sludge, residue of monosodium glutamate, spina date seed, leaves of Hawthorn, three-bristle cudrania leaf, bubble The 2-6wt% of paulownia leaf total weight.
5. according to the special compound fertilizer containing modified molecular screen of any one of the claim 1-4 winter peaches, which is characterized in that institute Probiotics is stated as saccharomycete, the mixture of bacillus subtilis, and the weight ratio of saccharomycete, bacillus subtilis is 2-9:4- 11。
6. according to the special compound fertilizer containing modified molecular screen of any one of the claim 1-5 winter peaches, which is characterized in that institute It is the montmorillonite that polylysine is modified to state montmorillonite.
7. according to the special compound fertilizer containing modified molecular screen of any one of the claim 1-6 winter peaches, which is characterized in that institute Modified molecular screen is stated to be prepared according to following technique:MCM-41 molecular sieves are added in toluene, 3- aminopropyls three are then added Ethoxysilane reacts 3-8h at 95-105 DEG C under nitrogen protection, through centrifugation, washs, is dried to obtain material A;By material A, tannic acid is mixed with water, vibrates 15-20h at room temperature, is centrifuged, is dried to obtain material B;Material B is added to the water, urine is added Ultrasonic disperse after element, is then added iron chloride, and stirring 3-5min obtains the modified molecular screen.
8. the special compound fertilizer containing modified molecular screen of winter peach according to claim 7, which is characterized in that MCM-41 molecules It sieves, the weight ratio of 3- aminopropyl triethoxysilanes is 3-10:2-6;Material A, the weight ratio of tannic acid are 0.1-0.3:8-13; Material B, urea, iron chloride weight ratio be 30-50:2-5:5-12.
9. according to the special compound fertilizer containing modified molecular screen of any one of the claim 1-8 winter peaches, which is characterized in that institute State the mixture that auxiliary agent is sulfonated melamine compound condensation product, 2- sodium naphthalene sulfonates, DA-6 crude oil, and sulfonated melamine compound Condensation product, 2- sodium naphthalene sulfonates, DA-6 crude oil weight ratio be 5-12:3-9:4-11.
CN201810694742.7A 2018-06-29 2018-06-29 A kind of special compound fertilizer containing modified molecular screen of winter peach Withdrawn CN108585991A (en)

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CN106577736A (en) * 2016-12-28 2017-04-26 王欣 Chlorpyrifos micro-capsule suspending agent adopting meso-porous silicon molecular sieve as carrier and preparation method thereof
CN106673842A (en) * 2016-12-30 2017-05-17 北京中农富源生物工程技术有限公司 Preparation method of biological nanometer fertilizer
CN107253878A (en) * 2017-06-30 2017-10-17 来安县世外桃园生态农业专业合作社 A kind of peach organic slow-release fertilizer and preparation method thereof
CN107739252A (en) * 2017-11-25 2018-02-27 安徽正丰农业科技有限公司 A kind of rice breeding special production-increase slow release fertilizer
CN107778088A (en) * 2017-11-25 2018-03-09 安徽正丰农业科技有限公司 A kind of rice breeding dedicated fertilizer

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CN103539568A (en) * 2013-10-31 2014-01-29 河南中威高科技化工有限公司 Nutrient synergistic anti-caking compound fertilizer and preparation method thereof
CN104151084A (en) * 2014-08-27 2014-11-19 成都新柯力化工科技有限公司 Powdery fertilizer additive and application thereof
CN106220308A (en) * 2016-07-13 2016-12-14 石欣 A kind of fertilizer auxiliary agent and this fertilizer auxiliary agent application in preparing concentrated fertilizer
CN106577736A (en) * 2016-12-28 2017-04-26 王欣 Chlorpyrifos micro-capsule suspending agent adopting meso-porous silicon molecular sieve as carrier and preparation method thereof
CN106673842A (en) * 2016-12-30 2017-05-17 北京中农富源生物工程技术有限公司 Preparation method of biological nanometer fertilizer
CN107253878A (en) * 2017-06-30 2017-10-17 来安县世外桃园生态农业专业合作社 A kind of peach organic slow-release fertilizer and preparation method thereof
CN107739252A (en) * 2017-11-25 2018-02-27 安徽正丰农业科技有限公司 A kind of rice breeding special production-increase slow release fertilizer
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CN114731927A (en) * 2022-05-09 2022-07-12 黑龙江省农业科学院经济作物研究所 Culture medium for soybean cultivation and preparation method thereof

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