CN108585766A - A kind of daily ceramic whiteware of high light transmission and its manufacturing process - Google Patents
A kind of daily ceramic whiteware of high light transmission and its manufacturing process Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/442—Carbonates
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Abstract
The present invention provides a kind of daily ceramic whiteware of high light transmission and its manufacturing process, is made of with the glaze layer for imposing on billet surface green body, the green body includes the raw material of following parts by weight：20 ~ 30 parts of kaolin, 10 ~ 15 parts of sericite in powder, 10 ~ 15 parts of mullite, 5 ~ 10 parts of shepardite, 3 ~ 5 parts of dry powder, 3 ~ 5 parts of dolomite dust, 1 ~ 3 part of sodium oxide molybdena, 1 ~ 3 part of potassium oxide；The glaze layer includes the raw material of following parts by weight：10 ~ 15 parts of silica, 10 ~ 15 parts of aluminium oxide, 5 ~ 8 parts of fluxing material, 1 ~ 3 part of spodumene, 0.5 ~ 1.2 part of titanium oxide, wherein it is 1 ~ 3 that the fluxing material, which is weight ratio,：1~3：1 ~ 5 sodium oxide molybdena, the mixture of porcelain powder and sodium metasilicate.Using the daily white pottery porcelain of method provided by the invention and technique manufacture, tire matter is fine and smooth, glaze colours is white and moist, glaze light jade-like stone profit, and whiteness is at 78 ° or more, and glossiness is 105 or more, and light transmittance is 70% or more.
Description
Technical field
The invention belongs to ceramic technology fields, and in particular to a kind of daily ceramic whiteware of high light transmission and its manufacturing process.
Background technology
Ceramic whiteware is one kind of Chinese tradition porcelain, usually with the low porcelain billet of iron-holder, is fired after imposing pure clear frit
It forms, because not having in glaze or the photoghraphic coupler of only denier, the white porcelain of kiln high temperature firing is entered after green compact rest.Ceramic whiteware because
Its color and luster is pure white, can reflect millet paste color and luster, therefore liked deeply by numerous people, can be prepared as the days such as bowl, dish, cup, small cup
Articles for use also can be prepared as exquisite craftwork, therefore have very high application and reserve value.
The performances such as whiteness, glossiness, the light transmittance of ceramic whiteware are to evaluate the weight factor of ceramic whiteware quality, therefore provide a kind of white
The all high daily white pottery porcelain of degree, glossiness, light transmittance has very high market significance.
Invention content
Based on the above prior art, the purpose of the present invention is to provide a kind of daily ceramic whiteware of high light transmission and its manufacturing process,
Using the daily white pottery porcelain of formula provided by the invention and technique manufacture, tire matter is fine and smooth, colour purity is extremely hard in vain, and glaze colours is white
Profit, glaze light jade-like stone profit, are high-quality white ceramics, whiteness is at 78 ° or more, and glossiness is 105 or more, and light transmittance is 70% or more.
In order to achieve the goal above, the technical solution adopted by the present invention is：A kind of daily ceramic whiteware of high light transmission, by green body with apply
It is constituted in the glaze layer of billet surface, the green body includes the raw material of following parts by weight：20~30 parts of kaolin, sericite in powder 10~
15 parts, 10~15 parts of mullite, 5~10 parts of shepardite, 3~5 parts of dry powder, 3~5 parts of dolomite dust, 1~3 part of sodium oxide molybdena, oxygen
Change 1~3 part of potassium；The glaze layer includes the raw material of following parts by weight：10~15 parts of silica, 10~15 parts of aluminium oxide, fluxing material 5
~8 parts, 1~3 part of spodumene, 0.5~1.2 part of titanium oxide, wherein it is 1~3 that the fluxing material, which is weight ratio,：1~3：1~5
The mixture of sodium oxide molybdena, porcelain powder and sodium metasilicate.
Preferably, the green body includes the raw material of following parts by weight：25 parts of kaolin, 12 parts of sericite in powder, mullite
12 parts, 7 parts of shepardite, 4 parts of dry powder, 4 parts of dolomite dust, 2 parts of sodium oxide molybdena, 2 parts of potassium oxide；The glaze layer includes following weight
The raw material of part：13 parts of silica, 12 parts of aluminium oxide, 7 parts of fluxing material, 2 parts of spodumene, 0.9 part of titanium oxide, wherein described fluxing
It is 2 that material, which is weight ratio,：2：3 sodium oxide molybdena, the mixture of porcelain powder and sodium metasilicate.
The daily ceramic whiteware of high light transmission provided by the invention, using kaolin, sericite in powder, mullite, shepardite, dry powder,
Dolomite dust, sodium oxide molybdena, potassium oxide are as blank raw material, wherein it is white, sticky that kaolin, mullite bonded can be obtained color and luster
Green body pug that is good, being easy to sizing, but its white is more inflexible, and color and luster is dim and without exquisitely carved sense；Sericite in powder is in silky luster,
Its chemical property is stable, abrasion resistance, heat resistance is high, is accordingly used in promoting the gloss of green body, moreover it is possible to by the intensity of green body
And wearability, thermal stability are promoted；Shepardite whiteness is high, intensity is high, can further increase the whiteness of ceramic body,
The intensity and water-resistance of firing white pottery porcelain can also be enhanced；Dry powder combined with dolomite dust after can by the brightening of shepardite, enhance
Effect is promoted, make the whiteness higher of green body of ceramics, intensity be more preferable, blank raw material combine it is closer and then fixed in green body
Type and not easy to wear, cracking after drying, after using glaze glaze waterborne, glaze layer is also more easy to be attached on green body, and then increases and burn
At the light transmittance of white pottery porcelain, dry powder can will also be burnt into glossiness and the light transmission of white pottery porcelain after being combined with sericite in powder, shepardite
Degree is promoted；Sodium oxide molybdena and potassium oxide are for fluxing, during carrying out ceramic sintering using hot conditions, sodium oxide molybdena with
It is filled among the hole of blank raw material after oxidation potash fusion, to the bonding for keeping each raw material even closer, and then promotes firing
The consistency of white pottery porcelain.
The daily ceramic whiteware of high light transmission provided by the invention, using silica, aluminium oxide, fluxing material, spodumene, titanium oxide conduct
Glaze layer raw material, wherein silica, aluminium oxide, titanium oxide make glaze layer be transparent after combining, moreover it is possible to make that glaze layer is wear-resisting, waterproof,
Disadvantage is after high temperature cigarette firing ceramics in temperature-fall period, if rate of temperature fall is too fast, is burnt into the transparent glaze layer of white pottery porcelain then
Crackle is had, to reduce the quality of firing white pottery porcelain；The fusing point of fluxing material is low, is mainly used for making the high-melting-point in glaze layer raw material
Raw material is combined, and during high-temperature firing white pottery porcelain, fluxing material melts and is filled in the seam of other not molten raw materials at first
Among gap, each raw material is made to combine closely, in addition, fluxing material makes glaze layer have certain mobility during high-temperature firing and glue
Knot property, enables glaze layer to be closely attached at billet surface, during high-temperature firing, glaze layer is made to keep almost the same with green body
Dilatancy and shrinkage, to solve the problems, such as glaze layer cracking；Spodumene can reduce the burning of ceramics after being combined with fluxing material
At temperature, to save the energy, further, the temperature flowing of fluxing material is adjusted in spodumene, makes its mobility
Will not be excessive and cause glaze to steep, and then help that the glaze of firing white pottery porcelain is made to have excellent glossiness and flatness, in addition,
The combination of spodumene and fluxing material can also promote the thermal stability of firing white pottery porcelain, and then promote the quality of ceramics；Above-mentioned glaze layer
Raw material obtains the transparent glaze layer of high-quality that glossiness is high, wearability is strong, water-resistance is strong, thermostabilization is good after combining.
As an optimization, the glaze layer raw material further includes the rubber powder of 1~3 parts by weight, further includes the silicone oil of 0.8~1 parts by weight,
Rubber powder can further promote the glossiness and light transmittance of firing white pottery porcelain with silicone oil.
The present invention also provides a kind of techniques of the high daily ceramic whiteware of light transmission of manufacture, include the following steps：
Step 1 weighs each raw material according to parts by weight respectively, spare；
Step 2, blank raw material is mixed after according to 1：1~2 weight ratio is mixed with water, is then carried out ball milling and is sieved,
After through pugging, except iron, shape, dry, obtain green body after sharp base, green body is fired under the conditions of 650~800 DEG C 5 hours with
On obtain biscuit；
Step 3, by glaze layer raw material mix after according to 1：1.5~3 weight ratio is mixed with water, is then carried out ball milling and is sieved
Glaze water is obtained, glaze water is imposed on the biscuit that step 2 obtains, high-temperature firing 10 is small under the conditions of 1250~1400 DEG C after drying
When more than, be then naturally cooling to room temperature and obtain the daily ceramic whiteware of high light transmission.
As an optimization, the technique of progress ball milling is specially in the step 2, step 3：Using alumina balls as ball-milling medium,
Wherein, raw material：The weight ratio of ball is 1：1~2, ball milling speed is 120~180r/min, and the time of ball milling is 30 minutes or more.
As an optimization, the sieving technique in the step 2, step 3 is carried out using the above sieves of 120 mesh.
As an optimization, the sieving technique in the step 2, step 3 is carried out using plastic filter sieve, using metallic sieve
Metal impurities may be mixed into raw material by words, to reduce the whiteness of firing white pottery porcelain.
As an optimization, for the rate that pugging technique uses in the step 2 for 180~300r/min, the pugging time is 3 hours
More than, it was advisable with 5~6 hours.
As an optimization, the condition dried in step 2, step 3 is：Temperature be 40~60 DEG C, humidity be 20% hereinafter,
Flash-off time is 4 hours or more, it is preferred to use 45~50 DEG C, humidity dry in the air under conditions of being 13~15% system 40~50 hours, adopt
Technique is dried when long with this relative low temperature, though the used time is longer, the case where green body internal cleavage in dry process can be reduced,
To improve yield rate.
As an optimization, the base thickness in the step 2 after green body sizing is 0.1~0.3cm, and glazing is carried out in the step 3
The thickness of wet glaze is 0.1~0.5mm afterwards.
As an optimization, it carries out carrying out using existing deironing apparatus in the market except the process of iron in the step 3.
As an optimization, the technique of progress high-temperature firing is specially in the step 3：Biscuit after glazing is placed in high temperature furnace
Furnace chamber in, close fire door, by high temperature furnace temperature control system control furnace chamber in temperature be warming up to the rate of 8~10 DEG C/min
1250~1400 DEG C, then keep the temperature 10 hours or more, it is then switched off temperature control system, after in-furnace temperature is down to 600~700 DEG C,
Will be door opened, specially fire door is pulled open to the position for opening one third or so, is allowed to continue to be cooled to room temperature, the height
Warm stove uses the commercially available common high temperature furnace with temperature control system, it is preferred to use the larger high temperature furnace of furnace chamber, in this way
Can in the same furnace chamber the multiple small volumes of one-time sintering technology white pottery ceramic products, improve the utilization rate of high temperature furnace.
Advantageous effect
Beneficial effects of the present invention are as follows：
(1), the daily ceramic whiteware of high light transmission provided by the invention, using kaolin, sericite in powder, mullite, shepardite, round trip flight
Powder, dolomite dust, sodium oxide molybdena, potassium oxide are as blank raw material, wherein it is white, viscous that kaolin, mullite bonded can be obtained color and luster
Property green body pug good, that be easy to sizing, sericite in powder promotes the intensity of green body and wearability, thermal stability；Water magnesium
Stone increases the whiteness, intensity and water-resistance of ceramic body；Dry powder makes the whiteness of ceramic green body more with dolomite dust
It is high, intensity is more preferable, blank raw material combines closer, and then the not easy to wear, cracking after green body shape and is dried, using glaze water
After glazing, glaze layer is also more easy to be attached on green body, and then increases the light transmittance of firing white pottery porcelain, dry powder and sericite in powder,
Shepardite can also promote the glossiness for being burnt into white pottery porcelain with light transmittance after combining；Sodium oxide molybdena is with potassium oxide in refractory ceramics
It is filled among the hole of blank raw material after being melted during firing, to promote the consistency of firing white pottery porcelain, above-mentioned base
The white ceramic body that consistency is high, whiteness is high, translucency is good, intensity is high is made in body raw material after combining.
(2), the daily ceramic whiteware of high light transmission provided by the invention, using silica, aluminium oxide, fluxing material, spodumene, titanium oxide
As glaze layer raw material, wherein so that glaze layer is transparent after silica, aluminium oxide, titanium oxide combination, wear-resisting, waterproof, burnt in high temperature
During white pottery porcelain processed, fluxing material is melted and is filled among the gap of other not molten raw materials at first, and each raw material is made closely to tie
It closes, glaze layer is enable closely to be attached at billet surface, during high-temperature firing, glaze layer is made to keep almost the same with green body
Dilatancy and shrinkage；The temperature flowing of fluxing material is adjusted in spodumene, makes its mobility will not be excessive and causes glaze
Bubble, and then help that the glaze of firing white pottery porcelain is made to have excellent glossiness and flatness, moreover it is possible to promote firing white pottery porcelain
Thermal stability, and then promote the quality of ceramics；Above-mentioned glaze layer raw material obtained after combining glossiness is high, wearability is strong, water-resistance is strong,
The transparent glaze layer of the good high-quality of thermostabilization.
(3), the daily white pottery porcelain of high light transmission provided by the invention, tire matter is fine and smooth, colour purity is extremely hard in vain, and glaze colours is white
Profit, glaze light jade-like stone profit, are high-quality white ceramics, whiteness is at 78 ° or more, and glossiness is 105 or more, and light transmittance is 70% or more.
Specific implementation mode
With reference to specific embodiment, invention is further described in detail.
Embodiment 1
The present embodiment provides a kind of high daily ceramic whitewares of light transmission, are made of with the glaze layer for imposing on billet surface green body, the base
Body includes the raw material of following parts by weight：20 parts of kaolin, 10 parts of sericite in powder, 10 parts of mullite, 5 parts of shepardite, dry powder 3
Part, 3 parts of dolomite dust, 1 part of sodium oxide molybdena, 1 part of potassium oxide；The glaze layer includes the raw material of following parts by weight：10 parts of silica, oxygen
Change 10 parts of aluminium, 5 parts of fluxing material, 1 part of spodumene, 0.5 part of titanium oxide, wherein it is 1 that the fluxing material, which is weight ratio,：1：1 oxidation
The mixture of sodium, porcelain powder and sodium metasilicate.
The present embodiment also provides a kind of technique of the high daily ceramic whiteware of light transmission of manufacture, includes the following steps：
Step 1 weighs each raw material according to parts by weight respectively, spare；
Step 2, blank raw material is mixed after according to 1：1 weight ratio is mixed with water, is then carried out ball milling and is sieved,
In, using alumina balls as ball-milling medium in mechanical milling process, raw material：The weight ratio of ball is 1：1, ball milling speed 120r/min, ball
The time of mill is 30 minutes；Technique of being sieved is carried out using the plastic filter sieve of 120 mesh, after through pugging, except iron, shape, dry,
Obtain green body after sharp base, green body fired 5 hours under the conditions of 800 DEG C and obtains biscuit, wherein the rate that pugging technique uses for
180r/min, pugging time are 3 hours, dry technique to be 40 DEG C in temperature, and humidity is dried in the air under conditions of being 20% to be made 4 hours；
The base thickness of green body after sizing is 0.3cm；
Step 3, by glaze layer raw material mix after according to 1：1.5 weight ratio is mixed with water, is then carried out ball milling and is sieved
To glaze water, glaze water is imposed on the biscuit that step 2 obtains, the thickness of wet glaze is 0.1mm after glazing, is 40 DEG C in temperature, wet
Degree be 20%, dry in the air system 4 hours, after drying under the conditions of 1250 DEG C high-temperature firing 12 hours, be then naturally cooling to room temperature and obtain
The high daily ceramic whiteware of light transmission；Wherein, the technique for carrying out high-temperature firing is specially:Biscuit after glazing is placed in the furnace chamber of high temperature furnace
In, fire door is closed, control the temperature in furnace chamber by high temperature furnace temperature control system is warming up to 1250 DEG C with the rate of 8 DEG C/min, so
Keep the temperature 12 hours afterwards, be then switched off temperature control system, after in-furnace temperature is down to 600 DEG C, by fire door pull open to be opened into three/
One or so position is allowed to continue to be cooled to room temperature.
Embodiment 2
The present embodiment provides a kind of high daily ceramic whitewares of light transmission, are made of with the glaze layer for imposing on billet surface green body, the base
Body includes the raw material of following parts by weight：The green body includes the raw material of following parts by weight：22 parts of kaolin, 11 parts of sericite in powder,
11 parts of mullite, 6 parts of shepardite, 3 parts of dry powder, 4 parts of dolomite dust, 1 part of sodium oxide molybdena, 2 parts of potassium oxide；The glaze layer include with
The raw material of lower parts by weight：12 parts of silica, 11 parts of aluminium oxide, 6 parts of fluxing material, 1 part of spodumene, 0.7 part of titanium oxide, wherein institute
It is 1 that state fluxing material, which be weight ratio,：2：3 sodium oxide molybdena, the mixture of porcelain powder and sodium metasilicate.
The present embodiment also provides a kind of technique of the high daily ceramic whiteware of light transmission of manufacture, includes the following steps：
Step 1 weighs each raw material according to parts by weight respectively, spare；
Step 2, blank raw material is mixed after according to 1：1.2 weight ratio is mixed with water, is then carried out ball milling and is sieved,
In, using alumina balls as ball-milling medium in mechanical milling process, raw material：The weight ratio of ball is 1：1.2, ball milling speed 130r/min,
The time of ball milling is 50 minutes；Technique of being sieved is carried out using the plastic filter sieve of 130 mesh, after through pugging, except iron, shape, dry in the air
Green body is obtained after dry, sharp base, green body is fired 8 hours under the conditions of 750 DEG C, wherein the rate that pugging technique uses is 200r/
Min, pugging time are 3.5 hours, dry technique to be 42 DEG C in temperature, and humidity is dried in the air under conditions of being 15% to be made 8 hours；Sizing
The base thickness of green body afterwards is 0.3cm；
Step 3, by glaze layer raw material mix after according to 1：1.5 weight ratio is mixed with water, is then carried out ball milling and is sieved
To glaze water, glaze water is imposed on the biscuit that step 2 obtains, the thickness of wet glaze is 0.1mm after glazing, is 40 DEG C in temperature, wet
Degree is the system of drying in the air under conditions of 20% 10 hours, after drying under the conditions of 1300 DEG C high-temperature firing 15 hours, be then naturally cooling to
Room temperature obtains the daily ceramic whiteware of high light transmission；Wherein, the technique for carrying out high-temperature firing is specially:Biscuit after glazing is placed in high temperature furnace
Furnace chamber in, close fire door, by high temperature furnace temperature control system control furnace chamber in temperature be warming up to the rate of 8.5 DEG C/min
1300 DEG C, 15 hours then are kept the temperature, temperature control system is then switched off, after in-furnace temperature is down to 620 DEG C, fire door is pulled open to unlatching
To the position of one third or so, it is allowed to continue to be cooled to room temperature.
Embodiment 3
The present embodiment provides a kind of high daily ceramic whitewares of light transmission, are made of with the glaze layer for imposing on billet surface green body, the base
Body includes the raw material of following parts by weight：25 parts of kaolin, 12 parts of sericite in powder, 12 parts of mullite, 7 parts of shepardite, dry powder 4
Part, 4 parts of dolomite dust, 2 parts of sodium oxide molybdena, 2 parts of potassium oxide；The glaze layer includes the raw material of following parts by weight：13 parts of silica, oxygen
Change 12 parts of aluminium, 7 parts of fluxing material, 2 parts of spodumene, 0.9 part of titanium oxide, wherein it is 2 that the fluxing material, which is weight ratio,：2：3 oxidation
The mixture of sodium, porcelain powder and sodium metasilicate.
The present embodiment also provides a kind of technique of the high daily ceramic whiteware of light transmission of manufacture, includes the following steps：
Step 1 weighs each raw material according to parts by weight respectively, spare；
Step 2, blank raw material is mixed after according to 1：1.5 weight ratio is mixed with water, is then carried out ball milling and is sieved,
In, using alumina balls as ball-milling medium in mechanical milling process, raw material：The weight ratio of ball is 1：1.5, ball milling speed 150r/min,
The time of ball milling is 60 minutes；Technique of being sieved is carried out using the plastic filter sieve of 140 mesh, after through pugging, except iron, shape, dry in the air
Green body is obtained after dry, sharp base, high-temperature firing obtains biscuit in 10 hours under the conditions of 720 DEG C by green body, wherein pugging technique uses
Rate be 230r/min, the pugging time is 5 hours, and it in temperature is 48 DEG C to dry technique to be, humidity is dried in the air under conditions of being 14%
The base thickness of system 42 hours, the green body after sizing is 0.2cm；
Step 3, by glaze layer raw material mix after according to 1：2.2 weight ratio is mixed with water, is then carried out ball milling and is sieved
To glaze water, glaze water is imposed on the biscuit that step 2 obtains, the thickness of wet glaze is 0.2mm after glazing, is 48 DEG C in temperature, wet
The system of drying in the air 20 hours, fires 12 hours under the conditions of 1310 DEG C after drying, is then naturally cooling to room temperature under conditions of degree is 14%
Obtain the daily ceramic whiteware of high light transmission；Wherein, the technique for carrying out high-temperature firing is specially:Biscuit after glazing is placed in the stove of high temperature furnace
In chamber, fire door is closed, control the temperature in furnace chamber by high temperature furnace temperature control system is warming up to 1310 DEG C with the rate of 9 DEG C/min,
Then 12 hours are kept the temperature, is then switched off temperature control system, after in-furnace temperature is down to 650 DEG C, fire door is pulled open to being opened into three points
One of left and right position, be allowed to continue to be cooled to room temperature.
Embodiment 4
The present embodiment provides a kind of high daily ceramic whitewares of light transmission, are made of with the glaze layer for imposing on billet surface green body, the base
Body includes the raw material of following parts by weight：The green body includes the raw material of following parts by weight：27 parts of kaolin, 14 parts of sericite in powder,
15 parts of mullite, 5 parts of shepardite, 4 parts of dry powder, 5 parts of dolomite dust, 2 parts of sodium oxide molybdena, 1 part of potassium oxide；The glaze layer include with
The raw material of lower parts by weight：14 parts of silica, 14 parts of aluminium oxide, 7 parts of fluxing material, 3 parts of spodumene, 1.0 parts of titanium oxide, wherein institute
It is 2 that state fluxing material, which be weight ratio,：3：5 sodium oxide molybdena, the mixture of porcelain powder and sodium metasilicate.
The present embodiment also provides a kind of technique of the high daily ceramic whiteware of light transmission of manufacture, includes the following steps：
Step 1 weighs each raw material according to parts by weight respectively, spare；
Step 2, blank raw material is mixed after according to 1：1.8 weight ratio is mixed with water, is then carried out ball milling and is sieved,
In, using alumina balls as ball-milling medium in mechanical milling process, raw material：The weight ratio of ball is 1：1.5, ball milling speed 170r/min,
The time of ball milling is 30 minutes or more；Technique of being sieved is carried out using plastic filter sieves more than 120 mesh, after through pugging, except iron,
It shapes, dry, obtaining green body after sharp base, high-temperature firing obtains biscuit in 9 hours under the conditions of 670 DEG C by green body, wherein pugging work
For the rate that skill uses for 180~300r/min, the pugging time is 3 hours or more, dries technique to be 55 DEG C in temperature, humidity is
The system of drying in the air under conditions of 17% 10 hours；The base thickness of green body after sizing is 0.2cm；
Step 3, by glaze layer raw material mix after according to 1：2.6 weight ratio is mixed with water, is then carried out ball milling and is sieved
To glaze water, glaze water is imposed on the biscuit that step 2 obtains, the thickness of wet glaze is 0.2mm after glazing, is 55 DEG C in temperature, wet
The system of drying in the air 12 hours, fires 16 hours under the conditions of 1350 DEG C after drying, is then naturally cooling to room temperature under conditions of degree is 20%
Obtain the daily ceramic whiteware of high light transmission；Wherein, the technique for carrying out high-temperature firing is specially:Biscuit after glazing is placed in the stove of high temperature furnace
In chamber, fire door is closed, control the temperature in furnace chamber by high temperature furnace temperature control system is warming up to 1350 with the rate of 9.8 DEG C/min
DEG C, 16 hours then are kept the temperature, is then switched off temperature control system, after in-furnace temperature is down to 680 DEG C, fire door is pulled open to being opened into three
/ mono- or so position is allowed to continue to be cooled to room temperature.
Embodiment 5
The present embodiment provides a kind of high daily ceramic whitewares of light transmission, are made of with the glaze layer for imposing on billet surface green body, the base
Body includes the raw material of following parts by weight：30 parts of kaolin, 15 parts of sericite in powder, 15 parts of mullite, 10 parts of shepardite, dry powder 5
Part, 5 parts of dolomite dust, 3 parts of sodium oxide molybdena, 3 parts of potassium oxide；The glaze layer includes the raw material of following parts by weight：Silica 10~15
Part, 15 parts of aluminium oxide, 8 parts of fluxing material, 3 parts of spodumene, 1.2 parts of titanium oxide, wherein it is 3 that the fluxing material, which is weight ratio,：3：5
Sodium oxide molybdena, porcelain powder and sodium metasilicate mixture.
The present embodiment also provides a kind of technique of the high daily ceramic whiteware of light transmission of manufacture, includes the following steps：
Step 1 weighs each raw material according to parts by weight respectively, spare；
Step 2, blank raw material is mixed after according to 1：2 weight ratio is mixed with water, is then carried out ball milling and is sieved,
In, using alumina balls as ball-milling medium in mechanical milling process, raw material：The weight ratio of ball is 1：2, ball milling speed 180r/min, ball
The time of mill is 45 minutes；Technique of being sieved is carried out using the plastic filter sieve of 125 mesh, after through pugging, except iron, shape, dry,
Green body is obtained after sharp base, high-temperature firing obtains biscuit in 5 hours under the conditions of 650 DEG C by green body, wherein the speed that pugging technique uses
Rate is 300r/min, and the pugging time is 3 hours, dries technique to be 60 DEG C in temperature, the system of drying in the air 5 is small under conditions of humidity is 20%
When；The base thickness of green body after sizing is 0.3cm；
Step 3, by glaze layer raw material mix after according to 1：3 weight ratio is mixed with water, then carries out ball milling and be sieved to obtain
Glaze water imposes on glaze water on the biscuit that step 2 obtains, and the thickness of wet glaze is 0.5mm after glazing, is 55 DEG C in temperature, humidity
It is made 4 hours for 20% hereinafter, drying in the air, fires 12 under the conditions of 1250 DEG C after drying, be then naturally cooling to room temperature and obtain high light transmission
Daily ceramic whiteware；Wherein, the technique for carrying out high-temperature firing is specially:Biscuit after glazing is placed in the furnace chamber of high temperature furnace, is closed
Fire door controls the temperature in furnace chamber by high temperature furnace temperature control system and is warming up to 1250 DEG C with the rate of 10 DEG C/min, then keeps the temperature 2
Hour, it is then switched off temperature control system, after in-furnace temperature is down to 700 DEG C, fire door is pulled open to being opened into one third or so
Position is allowed to continue to be cooled to room temperature.
Raw material and parts by weight used by the white pottery ceramic products being burnt into above-described embodiment 1 to 5 are as shown in table 1 below：
1 raw material of table and parts by weight
White pottery ceramic products made from above-described embodiment 1 to 5 are carried out with the test of whiteness, glossiness, light transmittance, test side
Method is as follows：
Whiteness test：According to national standards《GB/T 3298-1991 domestic ceramics device thermal stability determination methods》In rule
Surely whiteness test is carried out, be ground to aperture using white pottery ceramic products fragment as sample, after clean, drying sieves for 0.104mm, it
Dry 1h under the conditions of 105~110 DEG C again afterwards when test, takes a certain amount of powder to flow into powder sample-pressing device, it is flat to be pressed into surface
Whole, flawless and sample board without fault, test its whiteness value, whiteness value is higher, and sample is whiter using whiteness instrument later.
Glossiness is tested：According to national standards《45 ° of mirror luster degree test methods of GB/T 3295-1996 ceramics》
In regulation carry out, tested using Grossmeters.
Light transmittance is tested：According to national standards《The assay method of GB 3296-1982 domestic ceramics device light transmittances》In rule
It is fixed to carry out, by three block sizes about 15 × 15mm2The white pottery ceramic products fragment of r as sample, be milled to respectively thickness close to 0.500,
1.000 and 1.500mm is tested using light transmittance instrument, and with incident intensity for 100, the sample for being 1 millimeter by thickness is saturating
Penetrate the light transmittance that light percentage intensity carrys out representing sample.
To the common white ceramic of white pottery ceramic products made from above-described embodiment 1 to 5 and example as a contrast carry out whiteness,
The result of the test of glossiness, light transmittance is as shown in table 2 below：
Table 2 is tested and result
| Test result | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Reference examples |
| Whiteness test | 80° | 80° | 85° | 80° | 81° | 55~75 ° |
| Glossiness | 105 | 108 | 120 | 111 | 109 | 80~97 |
| Light transmittance | 78% | 82% | 89% | 81% | 82% | 50~70% |
White pottery ceramic products obtained in above-described embodiment 1 to 5, tire matter is fine and smooth, glaze colours is white and moist, glaze light jade-like stone profit, whiteness,
Glossiness, translucency are all higher than common white ceramic on the market, wherein each with white pottery ceramic products obtained in embodiment 3
Item performance is best, is most preferred embodiment.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
With technical scheme described in the above embodiments is modified or equivalent replacement of some of the technical features.
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention's
Within protection domain.
Claims (9)
1. a kind of daily ceramic whiteware of high light transmission is made of green body with the glaze layer for imposing on billet surface, which is characterized in that the green body packet
Include the raw material of following parts by weight：20 ~ 30 parts of kaolin, 10 ~ 15 parts of sericite in powder, 10 ~ 15 parts of mullite, 5 ~ 10 parts of shepardite,
3 ~ 5 parts of dry powder, 3 ~ 5 parts of dolomite dust, 1 ~ 3 part of sodium oxide molybdena, 1 ~ 3 part of potassium oxide；The glaze layer includes the original of following parts by weight
Material：10 ~ 15 parts of silica, 10 ~ 15 parts of aluminium oxide, 5 ~ 8 parts of fluxing material, 1 ~ 3 part of spodumene, 0.5 ~ 1.2 part of titanium oxide, wherein
It is 1 ~ 3 that the fluxing material, which is weight ratio,：1~3：1 ~ 5 sodium oxide molybdena, the mixture of porcelain powder and sodium metasilicate.
2. the daily ceramic whiteware of high light transmission according to claim 1, which is characterized in that the green body includes the original of following parts by weight
Material：25 parts of kaolin, 12 parts of sericite in powder, 12 parts of mullite, 7 parts of shepardite, 4 parts of dry powder, 4 parts of dolomite dust, sodium oxide molybdena 2
Part, 2 parts of potassium oxide；The glaze layer includes the raw material of following parts by weight：13 parts of silica, 12 parts of aluminium oxide, 7 parts of fluxing material, lithium
2 parts of pyroxene, 0.9 part of titanium oxide, wherein it is 2 that the fluxing material, which is weight ratio,：2：The mixing of 3 sodium oxide molybdena, porcelain powder and sodium metasilicate
Object.
3. the daily ceramic whiteware of high light transmission according to claim 1, which is characterized in that the glaze layer raw material further includes 1 ~ 3 weight
The rubber powder of part.
4. the daily ceramic whiteware of high light transmission according to claim 1, which is characterized in that the glaze layer raw material further includes 0.8 ~ 1 weight
Measure the silicone oil of part.
5. a kind of technique of the high daily ceramic whiteware of light transmission of manufacturing claims 1 to 4, which is characterized in that include the following steps：
Step 1 weighs each raw material according to parts by weight respectively, spare；
Step 2, blank raw material is mixed after according to 1：1 ~ 2 weight ratio is mixed with water, then carries out ball milling and being sieved, after pass through
Pugging, except iron, shape, dry, obtain green body after sharp base, green body is fired into 5 hours elements derived above under the conditions of 650 ~ 800 DEG C
Base；
Step 3, by glaze layer raw material mix after according to 1：1.5 ~ 3 weight ratio is mixed with water, then carries out ball milling and be sieved to obtain
Glaze water imposes on glaze water on the biscuit that step 2 obtains, after drying under the conditions of 1250 ~ 1400 DEG C high-temperature firing 10 hours with
On, it is then naturally cooling to room temperature and obtains the daily ceramic whiteware of high light transmission.
6. the technique of the high daily ceramic whiteware of light transmission of manufacture according to claim 5, which is characterized in that the step 2, step 3
It is middle carry out ball milling technique be specially：Using alumina balls as ball-milling medium, wherein raw material：The weight ratio of ball is 1：1 ~ 2, ball milling
Rate is 120 ~ 180r/min, and the time of ball milling is 30 minutes or more.
7. the technique of the high daily ceramic whiteware of light transmission of manufacture according to claim 5, which is characterized in that the step 2, step 3
In sieving technique carried out using the above sieves of 120 mesh.
8. the technique of the high daily ceramic whiteware of light transmission of manufacture according to claim 5 or 7, which is characterized in that the step 2, step
Sieving technique in rapid 3 is carried out using plastic filter sieve.
9. the technique of the high daily ceramic whiteware of light transmission of manufacture according to claim 5, which is characterized in that carried out in the step 3
The technique of high-temperature firing is specially:Biscuit after glazing is placed in the furnace chamber of high temperature furnace, fire door is closed, passes through high temperature furnace temperature control
Temperature in system control furnace chamber is warming up to 1250 ~ 1400 DEG C with the rate of 8 ~ 10 DEG C/min, then keep the temperature 10 hours or more, it connects
Closing temperature control system, will be door opened after in-furnace temperature is down to 600 ~ 700 DEG C, it is allowed to continue to be cooled to room temperature.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110041045A (en) * | 2019-05-13 | 2019-07-23 | 福建省德化县中国白陶瓷有限责任公司 | High whiteness ceramic with heat-resisting quantity and preparation method thereof |
| CN110040964A (en) * | 2019-05-13 | 2019-07-23 | 福建省德化县中国白陶瓷有限责任公司 | Clear frit and the method for preparing high white pottery ceramic products thoroughly with it |
| CN110342906A (en) * | 2019-07-29 | 2019-10-18 | 福建省德化县三诺陶瓷有限公司 | A kind of manufacturing method of white pottery ceramic products |
| CN111423118A (en) * | 2020-04-02 | 2020-07-17 | 福建省威尔陶瓷股份有限公司 | Easy-to-clean household ceramic product and preparation method thereof |
| CN114671610A (en) * | 2019-08-26 | 2022-06-28 | 福建省德化县天俊陶瓷有限公司 | Low-temperature transparent glazed ceramic product and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102464488A (en) * | 2010-11-04 | 2012-05-23 | 福建省泉州龙鹏集团有限公司 | Medium-temperature-oxidized high-whiteness blue jade porcelain and preparation method thereof |
| CN105481357A (en) * | 2014-09-19 | 2016-04-13 | 广东顺祥陶瓷有限公司 | Household porcelain and preparation method thereof |
| CN106219981A (en) * | 2016-08-05 | 2016-12-14 | 福建省德化县杰艺陶瓷有限公司 | High white ceramic glaze thoroughly and the method making high ceramic whiteware thoroughly with it |
| CN107216119A (en) * | 2017-06-21 | 2017-09-29 | 泉州市陶瓷科学技术研究所 | Ceramic whiteware and its preparation technology are built in Dehua |
| CN107266038A (en) * | 2017-06-16 | 2017-10-20 | 福建泉州顺美集团有限责任公司 | Moisten ceramic whiteware and its preparation and preparation technology |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3967971A (en) * | 1971-07-09 | 1976-07-06 | Scm Corporation | Translucent ceramic whiteware products |
| EP0036558A1 (en) * | 1980-03-22 | 1981-09-30 | Bayer Ag | Coated metal article and method of manufacturing the same |
| CN101659542B (en) * | 2009-09-11 | 2012-06-06 | 淄博泰山瓷业有限公司 | Crystal ceramic and preparation method thereof |
| CN103739278B (en) * | 2014-01-10 | 2015-03-04 | 江西省源通陶瓷科技有限公司 | Ceramic matrix material stably bonded with metal base coatings and products thereof |
| CN105753515B (en) * | 2016-04-01 | 2018-02-09 | 江苏高淳陶瓷股份有限公司 | A kind of preparation method of speckled glaze |
| CN105906326A (en) * | 2016-04-21 | 2016-08-31 | 福建省德化县晖龙陶瓷有限公司 | High-whiteness autogenous glaze creamy porcelain, preparation method and production process thereof |
| CN106699146B (en) * | 2016-12-28 | 2020-06-30 | 佛山市三水新明珠建陶工业有限公司 | Semi-polished ceramic glazed tile with fluorescence effect and manufacturing method thereof |
| CN107365077A (en) * | 2017-09-05 | 2017-11-21 | 赵永强 | A kind of pottery glaze |
| CN107698233B (en) * | 2017-09-27 | 2020-07-28 | 禹州市正玉钧窑有限公司 | Jun porcelain appliance with purifying and viewing functions and preparation method thereof |
| CN107793028B (en) * | 2017-10-12 | 2020-03-31 | 福建省德化云水窑陶瓷有限公司 | One-time fired partial glaze relief ceramic product and preparation process thereof |
-
2018
- 2018-03-22 CN CN201810238744.5A patent/CN108585766B/en active Active
- 2018-03-22 CN CN202011008966.1A patent/CN112125519B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102464488A (en) * | 2010-11-04 | 2012-05-23 | 福建省泉州龙鹏集团有限公司 | Medium-temperature-oxidized high-whiteness blue jade porcelain and preparation method thereof |
| CN105481357A (en) * | 2014-09-19 | 2016-04-13 | 广东顺祥陶瓷有限公司 | Household porcelain and preparation method thereof |
| CN106219981A (en) * | 2016-08-05 | 2016-12-14 | 福建省德化县杰艺陶瓷有限公司 | High white ceramic glaze thoroughly and the method making high ceramic whiteware thoroughly with it |
| CN107266038A (en) * | 2017-06-16 | 2017-10-20 | 福建泉州顺美集团有限责任公司 | Moisten ceramic whiteware and its preparation and preparation technology |
| CN107216119A (en) * | 2017-06-21 | 2017-09-29 | 泉州市陶瓷科学技术研究所 | Ceramic whiteware and its preparation technology are built in Dehua |
Non-Patent Citations (1)
| Title |
|---|
| 王瑞生: "用国产原料研制高档卫生瓷白釉", 《中国陶瓷》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110041045A (en) * | 2019-05-13 | 2019-07-23 | 福建省德化县中国白陶瓷有限责任公司 | High whiteness ceramic with heat-resisting quantity and preparation method thereof |
| CN110040964A (en) * | 2019-05-13 | 2019-07-23 | 福建省德化县中国白陶瓷有限责任公司 | Clear frit and the method for preparing high white pottery ceramic products thoroughly with it |
| CN110342906A (en) * | 2019-07-29 | 2019-10-18 | 福建省德化县三诺陶瓷有限公司 | A kind of manufacturing method of white pottery ceramic products |
| CN114671610A (en) * | 2019-08-26 | 2022-06-28 | 福建省德化县天俊陶瓷有限公司 | Low-temperature transparent glazed ceramic product and preparation method thereof |
| CN114671610B (en) * | 2019-08-26 | 2023-05-23 | 福建省德化县天俊陶瓷有限公司 | Low-temperature transparent glaze ceramic product and preparation method thereof |
| CN111423118A (en) * | 2020-04-02 | 2020-07-17 | 福建省威尔陶瓷股份有限公司 | Easy-to-clean household ceramic product and preparation method thereof |
| CN111423118B (en) * | 2020-04-02 | 2022-09-13 | 福建省威尔陶瓷股份有限公司 | Easy-to-clean household ceramic product and preparation method thereof |
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| CN112125519B (en) | 2022-04-26 |
| CN112125519A (en) | 2020-12-25 |
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