CN106187239A - Low creep flint clay composite refractory brick and its preparation method and application - Google Patents
Low creep flint clay composite refractory brick and its preparation method and application Download PDFInfo
- Publication number
- CN106187239A CN106187239A CN201610577329.3A CN201610577329A CN106187239A CN 106187239 A CN106187239 A CN 106187239A CN 201610577329 A CN201610577329 A CN 201610577329A CN 106187239 A CN106187239 A CN 106187239A
- Authority
- CN
- China
- Prior art keywords
- flint clay
- refractory brick
- low creep
- composite refractory
- flint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D1/00—Casings; Linings; Walls; Roofs
- F27D1/04—Casings; Linings; Walls; Roofs characterised by the form, e.g. shape of the bricks or blocks used
- F27D1/06—Composite bricks or blocks, e.g. panels, modules
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5427—Particle size related information expressed by the size of the particles or aggregates thereof millimeter or submillimeter sized, i.e. larger than 0,1 mm
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5445—Particle size related information expressed by the size of the particles or aggregates thereof submicron sized, i.e. from 0,1 to 1 micron
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/77—Density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention provides a kind of low creep flint clay composite refractory brick, including major ingredient and additive, described major ingredient includes the raw material of following mass percent: flint clay large granule 5%～15%, flint clay bulky grain 15%～35%, the little granule of flint clay 10%～20%, the little granule of sillimanite 5%～15%, flint clay micropowder 15%～35%, bonding clay fine powder 10%～20%；The quality of described additive is the 4.5%～5.5% of described major ingredient quality.The present invention also provides for the preparation method and application of a kind of above-mentioned low creep flint clay composite refractory brick.The collocation of described low creep flint clay composite refractory brick composition rationally and has good thermal shock resistance, preferable heat stability and higher refractoriness under load, thus improves the carbon baking furnace service life applying described low creep flint clay composite fire brick masonry flue wall.
Description
Technical field
The invention belongs to technical field of refractory materials, specifically, relate to a kind of low creep flint clay composite refractory brick
And its preparation method and application.
Background technology
In modern carbon element industry, producing anode block with roaster the most universal, the main of carbon baking furnace is appointed
Business is roasting electrolytic aluminum anode carbon block.The baking furnace flame path wall of prior art is built by laying bricks or stones by clay brick and is formed, and fuel is in quirk
Burn, and transferred heat to the anode block closing in hopper by top load andalusite composite fire brick, sun
The roasting in the atmosphere not contacting flame of pole carbon block.So, refractory material in anode-baking furnace except to stand long-term height
Outside temperature, high pressure, still suffering from periodic variations in temperature, therefore, the requirement to refractory material is that high temperature creep rate is low, and loading is soft
Change temperature thermal shock resistance high, reasonable.
And on the market that China is current, although Refractory material for carbon furnace produces the most universal, but, no matter
Be fireclay refractory or high alumina refractories or general creep refractory material all to there is load softening point the highest, hot
The shortcomings such as shake poor stability, long-time use creep rate are big, can cause the appearance deformation that flue wall is too early, damage, anode block
Production is greatly affected.
In order to solve with present on problem, people are seeking a kind of preferably technical solution always.
Summary of the invention
It is an object of the invention to for the deficiencies in the prior art, thus provide a kind of and there is higher thermal shock resistance, higher
Refractoriness under load and the low creep flint clay composite refractory brick of preferable heat stability.
To achieve these goals, the technical solution adopted in the present invention is: include major ingredient and additive, described major ingredient bag
Include the raw material of following mass percent: flint clay large granule 5%～15%, flint clay bulky grain 15%～35%, little of flint clay
Grain 10%～20%, the little granule of sillimanite 5%～15%, flint clay micropowder 15%～35%, bonding clay fine powder 10%～20%；Described add
Add quality is described major ingredient quality the 4.5%～5.5% of agent.
Based on above-mentioned, described major ingredient includes the raw material of following mass percent: flint clay large granule 5%, flint clay bulky grain
30%, the little granule of flint clay 15%, the little granule of sillimanite 10%, flint clay micropowder 25%, bonding clay fine powder 15%.
Based on above-mentioned, the granularity of described flint clay large granule is 3 mm～4 mm；The oarse-grained granularity of described flint clay
It is 1 mm～3 mm.
Based on above-mentioned, the short grained granularity of described flint clay is less than 1 mm；The short grained granularity of described sillimanite is less than 1
mm。
Based on above-mentioned, the granularity of described flint clay micropowder is less than less than 0.043 mm, the granularity of described bonding clay fine powder
0.074 mm。
Based on above-mentioned, described additive is pulp-water.
Wherein, described major ingredient includes aggregate and fines, and described low creep flint clay composite refractory brick is with the burnt treasured in raw material
Stone large granule, flint clay bulky grain, the little granule of flint clay, the little granule of sillimanite are aggregate, with flint clay micropowder, bonding clay
Fine powder is fines, is mixed by described additive.
The present invention also provides for the preparation method of a kind of described low creep flint clay composite refractory brick, comprises the following steps:
(1) calculate according to above-mentioned mass percent, by flint clay large granule, flint clay bulky grain, the little granule of flint clay, silicon line
The little granule of stone and additive carry out mixed grind and prepare prefabricated pug；Then in described prefabricated pug, add flint clay micropowder, combination
Well as clay fines also carries out mixed grind and prepares mixed grind pug；
(2) described mixed grind pug is pressed into adobe, prepares described low creep flint clay after the calcining of described adobe drying and be combined
Refractory brick.
Based on above-mentioned, described step (2) including: described step (2) including: described mixed grind pug is pressed into adobe, will
Described adobe is dried 24 hours～36 hours under the conditions of temperature is 60 DEG C～130 DEG C；Then by dried described brick
Base carries out calcining 10 hours～24 hours at a temperature of 1450 DEG C～1480 DEG C, thus prepares described low creep flint clay and be combined
Refractory brick.
The present invention also provides for the application of a kind of above-mentioned low creep flint clay composite refractory brick, and described low creep flint clay is combined
Refractory brick is applied in carbon baking furnace.
In low creep flint clay composite refractory brick raw material provided by the present invention, the performance effect of each composition is as follows:
Sillimanite: sillimanite is also silimanite or sillimanite, it is a kind of brown, light green color, light blue or white glassy
Silicate mineral, is mainly composed of silicon oxide and aluminium oxide.The crystal of sillimanite is column or needle-like, and these crystal are aggregated in one
Often rise in fibrous or radial, there is gloss or the glassy lustre of silk.Become mullite after sillimanite heating, be used as height
Level refractory material.
Flint clay: also known as one-level hard paste grog, is the multiple mixture containing aluminosilicate, and main chemical compositions is
Al2O3And SiO2, with a small amount of Fe2O3Na with trace2O、K2O, has volume stability, intensity after high-temperature calcination and greatly and inhales
The characteristics such as water rate is little, its refractoriness is up to more than 1750 DEG C, so that the described low creep flint clay composite refractory brick of preparation
There is higher thermal shock resistance and preferable heat resistance.
Bonding clay: bonding clay is mainly kaolinite, silicon oxide and aluminium oxide, Se Bai and fire-resistant, for preparation china clay it
Primary raw material, is a kind of high plasticity clay.The performance of bonding clay fine powder is affected by factors, with mineralogical composition, mineral
Performance, crystallizable mineral feature, the granular size of mineral, electrolyte type, the Law of Cause of Formation of clay and processing technique etc. are because have
Close relationship.This case is chosen alumina content be 34%～37%, ferrum oxide less than 1.5% high-quality bonding clay, utilize it
Preferably caking property and plasticity makes bonding between each granule and micropowder closely and make low creep flint clay composite refractory brick
Base mouldability is higher.
Hinge structure of the present invention has prominent substantive distinguishing features and significantly progress, and specifically, the present invention will
Varigrained flint clay, sillimanite, bonding clay and additive mix so that each site component of the adobe of preparation is joined
More consistent than collocation, it is ensured that the concordance of low creep flint clay composite refractory brick each position performance of calcining gained, raw material simultaneously
In containing the prominent granularity material of a large amount of corner angle, increase critical granularity, provide firmly for low creep flint clay composite refractory brick
Framing structure make it in use be not likely to produce deformation.Meanwhile, flint clay, sillimanite, bonding clay it are utilized respectively thin
Heat shock resistance power, resistance to slag be strong, lotus having of being formed of calcination process for the resistance to burning characteristic of powder and preferable mouldability and sillimanite
The mullite that weight inversion point is high so that the low creep flint clay composite refractory brick of preparation has high RUL, low creep, highly heatproof and shockproof
Performance, thus improve the carbon baking furnace service life applying described low creep flint clay composite fire brick masonry flue wall.
And the raw material that the method uses is easy to get, composition collocation is reasonable, preparation process is simple.
Detailed description of the invention
Below by detailed description of the invention, technical scheme is described in further detail.
Embodiment 1
The present embodiment provides a kind of low creep flint clay composite refractory brick, and it includes aggregate, fines and pulp-water, wherein, described
The quality of pulp-water is described aggregate and the 4.5% of described fines gross mass；Described aggregate and described fines include following quality hundred
The raw material of mark: flint clay large granule 5%, flint clay bulky grain 30%, the little granule of flint clay 15%, the little granule of sillimanite 10%,
Flint clay micropowder 25%, bonding clay fine powder 15%.
Wherein, the granularity of described flint clay large granule is 3 mm～4 mm, the oarse-grained granularity of described flint clay are 1
Mm～3 mm, the short grained granularity of described flint clay are less than 1 mm, described less than 1 mm, the short grained granularity of described sillimanite
The granularity of the flint clay micropowder granularity less than 0.043 mm, described bonding clay fine powder is less than 0.074 mm.Change in each raw material
Study point as shown in table 1.
Table 1, each raw material main chemical compositions
| Raw material | Al2O3 | Fe2O3 | K2O+NaO | SiO2 |
| The little granule of sillimanite | 55%～58% | ≤1.1% | ≤1.0% | -- |
| Flint clay large granule, bulky grain, little granule, micropowder | ≥45% | ≤1.0% | ≤1.0% | -- |
| Bonding clay fine powder | 34%～37% | ≤1.5% | ≤0.5% | -- |
The present embodiment also provides for the preparation method of a kind of described low creep flint clay composite refractory brick, and concrete preparation process includes:
Respectively sillimanite, flint clay, bonding clay are carried out pulverizing the raw material of prepared above-mentioned granularity.
By the flint clay large granule of above-mentioned mass percent, flint clay bulky grain, the little granule of flint clay, little of sillimanite
Grain and pulp-water 4.5% carry out mixed grind 3 minutes～5 minutes and prepare prefabricated pug；Then in described prefabricated pug, described Jiao is added
Gem micropowder, described bonding clay fine powder also carry out mixed grind 10 minutes～20 minutes, prepare mixed grind pug.
The pressure tonnage brickmaking machine more than 315 tons is used described mixed grind pug to be pressed into adobe, then by described adobe
Putting into and be dried in tunnel type drying hole 24 hours, the inlet temperature wherein controlling described tunnel type drying hole is 60 DEG C, goes out
Mouth temperature is 130 DEG C；It is little by dried described adobe loading fuel gas tunnel kiln carries out calcining 10 at a temperature of 1480 DEG C
Time, thus prepare described low creep flint clay composite refractory brick.After testing, the described low creep flint clay that the present embodiment prepares is multiple
Closing refractory brick density is 2.31 g/cm3。
Low creep flint clay composite refractory brick prepared by the preparation method provided by the present embodiment, can be applicable to build carbon element by laying bricks or stones
Baking furnace flame path wall.
Embodiment 2
The present embodiment provides a kind of low creep flint clay composite refractory brick, and concrete material composition is roughly the same with embodiment 1, different
Part be, in the present embodiment, the quality of described pulp-water is described aggregate and the 5% of described fines gross mass, described aggregate and
Described fines includes the raw material of following mass percent: flint clay large granule 6%, flint clay bulky grain 29%, little of flint clay
Grain 16%, the little granule of sillimanite 11%, flint clay micropowder 22%, bonding clay fine powder 16%.
The preparation method of the low creep flint clay composite refractory brick described in the present embodiment is big with the preparation method in embodiment 1
Causing identical, difference is: described mixed grind pug is pressed into adobe, then described adobe is put in tunnel type drying hole
Be dried 30 hours, wherein control the inlet temperature of described tunnel type drying hole be 60 DEG C, outlet temperature be 130 DEG C；Will be dry
Described adobe loading fuel gas tunnel kiln after dry carries out calcining 12 hours at a temperature of 1470 DEG C；Thus prepare described low compacted
Zoom gem composite refractory brick.After testing, the described low creep flint clay composite refractory brick density that the present embodiment prepares is 2.29
g/cm3。
Low creep flint clay composite refractory brick prepared by the preparation method provided by the present embodiment, can be applicable to build carbon element by laying bricks or stones
Baking furnace flame path wall.
Embodiment 3
The present embodiment provides a kind of low creep flint clay composite refractory brick, and concrete material composition is roughly the same with embodiment 1, different
Part is, in the present embodiment, the quality of described pulp-water is described aggregate and the 5.5% of described fines gross mass, described aggregate
With the raw material that described fines includes following mass percent: flint clay large granule 7%, flint clay bulky grain 30%, flint clay are little
The little granule of granule 18%, sillimanite 10%, flint clay micropowder 23%, bonding clay fine powder 12%.
The preparation method of the low creep flint clay composite refractory brick described in the present embodiment is big with the preparation method in embodiment 1
Causing identical, difference is: described mixed grind pug is pressed into adobe, then described adobe is put in tunnel type drying hole
Be dried 24 hours, wherein control the inlet temperature of described tunnel type drying hole be 60 DEG C, outlet temperature be 130 DEG C；Then
Carry out calcining at a temperature of 1450 DEG C 20 hours by dried adobe, thus prepare described low creep flint clay composite fire
Brick.After testing, the described low creep flint clay composite refractory brick density that the present embodiment prepares is 2.32 g/cm3。
Low creep flint clay composite refractory brick prepared by the preparation method provided by the present embodiment, can be applicable to build carbon element by laying bricks or stones
Baking furnace flame path wall.
Low creep flint clay composite refractory brick performance detects: be combined the low creep flint clay of embodiment 1～3 preparation respectively
Al in refractory brick2O3、Fe2O3Content, apparent porosity, cold crushing strength and 1350 DEG C of high temperature break resistant intensity performances detect,
And detect in 0.2MPa pressure, 1280 DEG C of calcinings creep rate of 25 hours and 50 hours, testing result is as shown in table 2.
Table 2, low creep flint clay composite refractory brick performance detect
As can be seen from the above table: the softening point of the low creep flint clay composite refractory brick that embodiment 1～3 provides is more than 1450
DEG C, cold crushing strength more than 54MPa, creep rate absolute value less than 0.4%, apparent porosity is between 13%～15%, thermal expansion
Rate is less than 0.7%, and the most described low creep flint clay composite refractory brick property indices meets GB/T3994-2013 regulation
Index, described low creep flint clay composite refractory brick has the high and low creep of load softening temperature, the performance of highly heatproof and shockproof, can answer
Baked for producing anode block is carried out for building carbon baking furnace flame path wall by laying bricks or stones.
Finally should be noted that: above example is only in order to illustrate that technical scheme is not intended to limit；To the greatest extent
The present invention has been described in detail by pipe with reference to preferred embodiment, and those of ordinary skill in the field are it is understood that still
The detailed description of the invention of the present invention can be modified or portion of techniques feature is carried out equivalent；Without deviating from this
The spirit of bright technical scheme, it all should be contained in the middle of the technical scheme scope that the present invention is claimed.
Claims (9)
1. a low creep flint clay composite refractory brick, including major ingredient and additive, it is characterised in that described major ingredient includes following
The raw material of mass percent: flint clay large granule 5%～15%, flint clay bulky grain 15%～35%, the little granule of flint clay 10%～
20%, the little granule of sillimanite 5%～15%, flint clay micropowder 15%～35%, bonding clay fine powder 10%～20%；Described additive
Quality is the 4.5%～5.5% of described major ingredient quality.
Low creep flint clay composite refractory brick the most according to claim 1, it is characterised in that described major ingredient includes following matter
The raw material of amount percent: flint clay large granule 5%, flint clay bulky grain 30%, the little granule of flint clay 15%, the little granule of sillimanite
10%, flint clay micropowder 25%, bonding clay fine powder 15%.
Low creep flint clay composite refractory brick the most according to claim 1 and 2, it is characterised in that described flint clay super large
The granularity of granule is 3 mm～4 mm；The oarse-grained granularity of described flint clay is 1 mm～3 mm.
Low creep flint clay composite refractory brick the most according to claim 3, it is characterised in that described flint clay is short grained
Granularity is less than 1 mm；The short grained granularity of described sillimanite is less than 1 mm.
Low creep flint clay composite refractory brick the most according to claim 4, it is characterised in that the grain of described flint clay micropowder
The degree granularity less than 0.043 mm, described bonding clay fine powder is less than 0.074 mm.
Low creep flint clay composite refractory brick the most according to claim 5, it is characterised in that described additive is paper pulp
Water.
7. a preparation method for described low creep flint clay composite refractory brick, comprises the following steps:
(1) calculate according to the low creep flint clay composite refractory brick raw materials quality percent described in any one of claim 1～6,
Flint clay large granule, flint clay bulky grain, the little granule of flint clay, the little granule of sillimanite and additive are carried out mixed grind and prepares pre-
Pug processed；Then in described prefabricated pug, add flint clay micropowder, bonding clay fine powder and carry out mixed grind and prepare mixed grind pug；
(2) described mixed grind pug is pressed into adobe, prepares described low creep flint clay after the calcining of described adobe drying and be combined
Refractory brick.
The preparation method of low creep flint clay composite refractory brick the most according to claim 7, it is characterised in that described step
(2) including: described mixed grind pug is pressed into adobe, described adobe is dried under the conditions of temperature is 60 DEG C～130 DEG C
24 hours～36 hours；Then carry out dried described adobe at a temperature of 1450 DEG C～1480 DEG C calcining 10 hours～
24 hours, thus prepare described low creep flint clay composite refractory brick.
9. the application of the low creep flint clay composite refractory brick described in an any one of claim 1～6, it is characterised in that institute
State low creep flint clay composite refractory brick to be applied in carbon baking furnace.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610577329.3A CN106187239A (en) | 2016-07-21 | 2016-07-21 | Low creep flint clay composite refractory brick and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610577329.3A CN106187239A (en) | 2016-07-21 | 2016-07-21 | Low creep flint clay composite refractory brick and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106187239A true CN106187239A (en) | 2016-12-07 |
Family
ID=57492020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610577329.3A Pending CN106187239A (en) | 2016-07-21 | 2016-07-21 | Low creep flint clay composite refractory brick and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106187239A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108503375A (en) * | 2018-03-08 | 2018-09-07 | 山东嘉腾实业有限公司 | High intensity ultra-large type keeps the temperature the preparation method of syphon |
| CN109053153A (en) * | 2018-09-11 | 2018-12-21 | 郑州荣盛窑炉耐火材料有限公司 | Low stomata clay brick of a kind of resisting temperature sudden turn of events chipping resistance and preparation method thereof |
| CN111056850A (en) * | 2019-11-06 | 2020-04-24 | 郑州市奥达耐火材料有限公司 | Quasi-sillimanite brick for glass melting furnace |
| CN111056851A (en) * | 2019-11-06 | 2020-04-24 | 郑州市奥达耐火材料有限公司 | Super low-porosity brick |
| CN111635238A (en) * | 2020-06-23 | 2020-09-08 | 郑州凯翔耐火材料有限公司 | Low-porosity high-thermal-shock-resistance clay brick and preparation method thereof |
| CN111675546A (en) * | 2020-06-23 | 2020-09-18 | 郑州凯翔耐火材料有限公司 | Thermal shock resistant high-alumina brick and preparation method thereof |
| CN111718200A (en) * | 2020-05-29 | 2020-09-29 | 郑州安耐克实业有限公司 | Bottom creep clay brick for hot blast stove and preparation method thereof |
| CN111892410A (en) * | 2020-08-04 | 2020-11-06 | 山东嘉和耐火材料有限责任公司 | Preparation process and equipment of novel low-creep inorganic nonmetal new material |
| CN117902909A (en) * | 2024-03-19 | 2024-04-19 | 阳城县圣利安建材有限公司 | Flint clay brick and manufacturing method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101863675A (en) * | 2010-06-07 | 2010-10-20 | 浙江大学 | High-alumina structure heat-insulation integrated composite brick and preparation method |
| CN103641491A (en) * | 2013-11-20 | 2014-03-19 | 河南省新密正泰耐材有限公司 | Slurry combined matrix-homogenized high-alumina brick and making method thereof |
-
2016
- 2016-07-21 CN CN201610577329.3A patent/CN106187239A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101863675A (en) * | 2010-06-07 | 2010-10-20 | 浙江大学 | High-alumina structure heat-insulation integrated composite brick and preparation method |
| CN103641491A (en) * | 2013-11-20 | 2014-03-19 | 河南省新密正泰耐材有限公司 | Slurry combined matrix-homogenized high-alumina brick and making method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 任永增 等: "优质热风炉粘土砖的研制", 《山东冶金》 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108503375A (en) * | 2018-03-08 | 2018-09-07 | 山东嘉腾实业有限公司 | High intensity ultra-large type keeps the temperature the preparation method of syphon |
| CN109053153A (en) * | 2018-09-11 | 2018-12-21 | 郑州荣盛窑炉耐火材料有限公司 | Low stomata clay brick of a kind of resisting temperature sudden turn of events chipping resistance and preparation method thereof |
| CN111056850A (en) * | 2019-11-06 | 2020-04-24 | 郑州市奥达耐火材料有限公司 | Quasi-sillimanite brick for glass melting furnace |
| CN111056851A (en) * | 2019-11-06 | 2020-04-24 | 郑州市奥达耐火材料有限公司 | Super low-porosity brick |
| CN111718200A (en) * | 2020-05-29 | 2020-09-29 | 郑州安耐克实业有限公司 | Bottom creep clay brick for hot blast stove and preparation method thereof |
| CN111635238A (en) * | 2020-06-23 | 2020-09-08 | 郑州凯翔耐火材料有限公司 | Low-porosity high-thermal-shock-resistance clay brick and preparation method thereof |
| CN111675546A (en) * | 2020-06-23 | 2020-09-18 | 郑州凯翔耐火材料有限公司 | Thermal shock resistant high-alumina brick and preparation method thereof |
| CN111892410A (en) * | 2020-08-04 | 2020-11-06 | 山东嘉和耐火材料有限责任公司 | Preparation process and equipment of novel low-creep inorganic nonmetal new material |
| CN117902909A (en) * | 2024-03-19 | 2024-04-19 | 阳城县圣利安建材有限公司 | Flint clay brick and manufacturing method |
| CN117902909B (en) * | 2024-03-19 | 2024-06-11 | 阳城县圣利安建材有限公司 | Flint clay brick and manufacturing method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106187239A (en) | Low creep flint clay composite refractory brick and its preparation method and application | |
| CN106187238A (en) | Bauxite composite refractory brick and its preparation method and application | |
| CN106187240A (en) | Low-creep refractory brick and its preparation method and application | |
| CN106187236A (en) | Flint clay composite refractory brick and its preparation method and application | |
| CN106187241A (en) | Low creep high RUL refractory brick and its preparation method and application | |
| CN106242593A (en) | Low creep andalusite composite refractory brick and its preparation method and application | |
| CN105418098A (en) | Heat-conductive and energy-saving refractory brick used for fire path wall in carbon roasting furnace and preparation method thereof | |
| CN106278299A (en) | Andalusite composite refractory brick and its preparation method and application | |
| CN103771905A (en) | Ruyao celeste glaze, and processing method and application thereof | |
| CN104119081B (en) | Coke oven high thermal conductive silicon brick | |
| CN206291720U (en) | A kind of novel ceramic tile baking furnace | |
| CN104744059A (en) | Dry-quenched mullite brick and preparation method thereof | |
| CN104555982A (en) | Method for calcining high sulfur petroleum coke and special pot calciner and pot wall tile | |
| CN108083765A (en) | Low heat conduction anti-strip brick and preparation method thereof | |
| CN102249655A (en) | Ductile mullite brick for pipelines of hot blast stoves and manufacturing method thereof | |
| CN106242542A (en) | Mullite composite refractory brick and its preparation method and application | |
| CN105523769A (en) | Low-heat-conductivity magnesia-hercynite brick used for cement rotary kiln and production method thereof | |
| CN104876605A (en) | Refractory brick for boiler | |
| CN106278202A (en) | Light fire brick and preparation method thereof | |
| CN108017397A (en) | Refractory brick containing quartz sand and preparation method thereof | |
| CN106220155A (en) | High RUL andalusite composite refractory brick and its preparation method and application | |
| CN107867868A (en) | A kind of super fine and close high heat conduction silica brick and preparation method thereof | |
| CN104387096A (en) | Corundum spinel unburned brick for smelting steel ladle and preparation method of corundum spinel unburned brick | |
| CN108002851A (en) | Refractory brick containing mullite and preparation method thereof | |
| CN106495708A (en) | High refractory brick of a kind of refractoriness under load and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |
|
| RJ01 | Rejection of invention patent application after publication |