CN108569892A - 一种能够增强上色性能的彩陶瓷坯 - Google Patents
一种能够增强上色性能的彩陶瓷坯 Download PDFInfo
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- 238000012545 processing Methods 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000010881 fly ash Substances 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 27
- 239000000243 solution Substances 0.000 claims description 20
- 229930006000 Sucrose Natural products 0.000 claims description 16
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 16
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 16
- 239000004327 boric acid Substances 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
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- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 10
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- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 claims description 9
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- RAFRTSDUWORDLA-UHFFFAOYSA-N phenyl 3-chloropropanoate Chemical compound ClCCC(=O)OC1=CC=CC=C1 RAFRTSDUWORDLA-UHFFFAOYSA-N 0.000 claims description 5
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- 239000003973 paint Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- VANHQTOUHVZHHF-IBGZPJMESA-N 5-[[5-[[(2s)-3-carboxy-1-[5-(2,6-dichlorophenyl)-1,3-oxazol-2-yl]-1-oxopropan-2-yl]carbamoyl]pyridin-2-yl]methylsulfamoyl]-2-hydroxybenzoic acid Chemical group N([C@@H](CC(=O)O)C(=O)C=1OC(=CN=1)C=1C(=CC=CC=1Cl)Cl)C(=O)C(C=N1)=CC=C1CNS(=O)(=O)C1=CC=C(O)C(C(O)=O)=C1 VANHQTOUHVZHHF-IBGZPJMESA-N 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
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- 230000001590 oxidative effect Effects 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
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Abstract
本发明涉及陶瓷烧制产业领域,公开了一种能够增强上色性能的彩陶瓷坯,采用黑土为主要原料,按照设定比例掺杂粉煤灰,可显著降低陶瓷坯加工用水量和烧结瓷化后的尺寸稳定性,解决了陶瓷坯吸潮膨胀、易开裂的问题,再与剩余物料共同研磨制备得到的坯料在设定温度下瓷化后,硬度好和孔隙率低,能够使得坯体表面变得光滑,使用颜料绘画时,对颜料的吸附性强,呈现颜料原有的色彩,上色率得到显著增强,并且持久度高,本发明提供了一种实现提高彩陶陶瓷坯上色性能的一种有效方式,制备原料易获取,制作过程简单,效率高,具有操作方便,安全可靠,具有抗水、抗腐蚀、耐高温等优点,维持寿命长等优点,对彩陶文化推广应用具有重要意义,是一种极为值得推广使用的技术方案。
Description
技术领域
本发明属于陶瓷烧制产业技术领域,具体涉及一种能够增强上色性能的彩陶瓷坯。
背景技术
彩陶是指在打磨光滑的橙红色陶坯上,以天然的矿物质颜料进行描绘,用赭石和氧化锰作呈色元素,然后入窑烧制。在橙红色的胎体上呈现出赭红、黑、白、诸种颜色的美丽图案,形成纹样与器物造型高度统一,达到装饰美化效果的陶器。
彩陶制作精美,以泥质陶为主,质地细腻,因之既是实用器皿,又具有很高的艺术价值。由于色彩绘于烧制前,故和陶器一起焙烧后,色彩和陶胎结合紧密,不易发生脱落。彩绘的形式总体上可分为图案和图画两大类。
彩陶在加工过程中,颜料的性能决定了图案色泽的好坏,但好的颜料在不同质感的陶瓷坯上着色性能不一,陶瓷坯进一步决定了彩陶加工的好坏。现有的陶瓷坯多采用粘土加工得到,而由于粘土中含有大量的碱金属化合物和硫酸盐,不仅会造成对颜料色彩的改变,还会造成氧化剥落,上色不易的问题。
发明内容
本发明的目的是针对现有的问题,提供了一种能够增强上色性能的彩陶瓷坯,上色率得到显著增强,并且持久度高。
本发明是通过以下技术方案实现的:
一种能够增强上色性能的彩陶瓷坯,按照重量份计由以下成分制成:黑土100-110份、粉煤灰25-35份、磷酸二氢铵4.5-5.0份、氧化镁3.0-3.5份、硅酸钠1.0-1.5份、羟丙基甲基纤维素0.4-0.5份、蔗糖溶液8-10份、亚硝酸钙阻锈剂0.3-0.4份、无水乙醇80-90份、三乙醇胺油酸钠2.0-3.0份、硼酸水溶液40-50份、去离子水55-65份,包括以下步骤:
(1)将黑土和粉煤灰置于无水乙醇中,加热至50-60℃,以400-500转/分钟的速度搅拌30-40分钟,然后加入三乙醇胺油酸钠和硼酸水溶液,继续在900-1000转/分钟下搅拌45-55分钟,在40-50℃下密封护养护2-3天,得到的混合浆料置于旋转蒸发仪中蒸发除去乙醇;
(2)将蒸发得到的黑土混合物置于去离子水中搅拌均匀,加入蔗糖溶液混合搅拌1-2小时,加压浸渍处理60-70分钟,然后加入剩余物料,搅拌混合,将物料混合均匀后置于球磨机中球磨,球磨时间为35-45分钟,球磨后过100-120目筛,得到浆料在低速下搅拌40-60秒,然后在高速下搅拌120-150秒,制成均匀浆料;
(3)将制备得到的浆料加工塑型为所需形状的陶瓷坯,以140-150℃的温火预热2-3小时,然后在960-980℃下烧制,瓷化3.5-4.0小时,以6-8℃/分钟的速度降温至室温,得到的陶瓷瓷坯在相对湿度为45-55%,温度为23-25℃的条件下养护5-7天即可进入下一道工序。
作为对上述方案的进一步描述,所述硼酸水溶液质量浓度为8-10%。
作为对上述方案的进一步描述,所述蔗糖溶液质量浓度为30-40%。
作为对上述方案的进一步描述,步骤(1)所述旋转蒸发温度为60-70℃。
作为对上述方案的进一步描述,步骤(2)所述加压浸渍处理中,压力为5-6MPa,温度为28-30℃。
作为对上述方案的进一步描述,步骤(2)所述低速搅拌速度为350-400转/分钟,高速下搅拌速度为1200-1400转/分钟。
本发明相比现有技术具有以下优点:为了解决现有彩陶磁坯着上性能差的问题,本发明提供了一种能够增强上色性能的彩陶瓷坯,采用黑土为主要原料,按照设定比例掺杂粉煤灰,可显著降低陶瓷坯加工用水量和烧结瓷化后的尺寸稳定性,解决了陶瓷坯吸潮膨胀、易开裂的问题,再与剩余物料共同研磨制备得到的坯料在设定温度下瓷化后,硬度好和孔隙率低,能够使得坯体表面变得光滑,使用颜料绘画时,对颜料的吸附性强,呈现颜料原有的色彩,上色率得到显著增强,并且持久度高,本发明提供了一种实现提高彩陶陶瓷坯上色性能的一种有效方式,制备原料易获取,制作过程简单,效率高,具有操作方便,安全可靠,具有抗水、抗腐蚀、耐高温等优点,维持寿命长等优点,对彩陶文化推广应用具有重要意义,是一种极为值得推广使用的技术方案。
具体实施方式
为使本发明的目的、技术方案及效果更加清楚、明确,下面结合具体实施例对本发明作进一步说明,应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明所提供的技术方案。
实施例1
一种能够增强上色性能的彩陶瓷坯,按照重量份计由以下成分制成:黑土100份、粉煤灰25份、磷酸二氢铵4.5份、氧化镁3.0份、硅酸钠1.0份、羟丙基甲基纤维素0.4份、蔗糖溶液8份、亚硝酸钙阻锈剂0.3份、无水乙醇80份、三乙醇胺油酸钠2.0份、硼酸水溶液40份、去离子水55份,包括以下步骤:
(1)将黑土和粉煤灰置于无水乙醇中,加热至50℃,以400转/分钟的速度搅拌30分钟,然后加入三乙醇胺油酸钠和硼酸水溶液,继续在900转/分钟下搅拌45分钟,在40℃下密封护养护2天,得到的混合浆料置于旋转蒸发仪中蒸发除去乙醇;
(2)将蒸发得到的黑土混合物置于去离子水中搅拌均匀,加入蔗糖溶液混合搅拌1小时,加压浸渍处理60分钟,然后加入剩余物料,搅拌混合,将物料混合均匀后置于球磨机中球磨,球磨时间为35分钟,球磨后过100目筛,得到浆料在低速下搅拌40秒,然后在高速下搅拌120秒,制成均匀浆料;
(3)将制备得到的浆料加工塑型为所需形状的陶瓷坯,以140℃的温火预热2小时,然后在960℃下烧制,瓷化3.5小时,以6℃/分钟的速度降温至室温,得到的陶瓷瓷坯在相对湿度为45%,温度为23℃的条件下养护5天即可进入下一道工序。
作为对上述方案的进一步描述,所述硼酸水溶液质量浓度为8%。
作为对上述方案的进一步描述,所述蔗糖溶液质量浓度为30%。
作为对上述方案的进一步描述,步骤(1)所述旋转蒸发温度为60℃。
作为对上述方案的进一步描述,步骤(2)所述加压浸渍处理中,压力为5MPa,温度为28℃。
作为对上述方案的进一步描述,步骤(2)所述低速搅拌速度为350转/分钟,高速下搅拌速度为1200转/分钟。
实施例2
一种能够增强上色性能的彩陶瓷坯,按照重量份计由以下成分制成:黑土105份、粉煤灰30份、磷酸二氢铵4.8份、氧化镁3.3份、硅酸钠1.2份、羟丙基甲基纤维素0.45份、蔗糖溶液9份、亚硝酸钙阻锈剂0.35份、无水乙醇85份、三乙醇胺油酸钠2.5份、硼酸水溶液45份、去离子水60份,包括以下步骤:
(1)将黑土和粉煤灰置于无水乙醇中,加热至55℃,以450转/分钟的速度搅拌35分钟,然后加入三乙醇胺油酸钠和硼酸水溶液,继续在950转/分钟下搅拌50分钟,在45℃下密封护养护2天,得到的混合浆料置于旋转蒸发仪中蒸发除去乙醇;
(2)将蒸发得到的黑土混合物置于去离子水中搅拌均匀,加入蔗糖溶液混合搅拌1.5小时,加压浸渍处理65分钟,然后加入剩余物料,搅拌混合,将物料混合均匀后置于球磨机中球磨,球磨时间为40分钟,球磨后过110目筛,得到浆料在低速下搅拌50秒,然后在高速下搅拌130秒,制成均匀浆料;
(3)将制备得到的浆料加工塑型为所需形状的陶瓷坯,以145℃的温火预热2.5小时,然后在970℃下烧制,瓷化3.8小时,以7℃/分钟的速度降温至室温,得到的陶瓷瓷坯在相对湿度为50%,温度为24℃的条件下养护6天即可进入下一道工序。
作为对上述方案的进一步描述,所述硼酸水溶液质量浓度为9%。
作为对上述方案的进一步描述,所述蔗糖溶液质量浓度为35%。
作为对上述方案的进一步描述,步骤(1)所述旋转蒸发温度为65℃。
作为对上述方案的进一步描述,步骤(2)所述加压浸渍处理中,压力为5.5MPa,温度为29℃。
作为对上述方案的进一步描述,步骤(2)所述低速搅拌速度为380转/分钟,高速下搅拌速度为1300转/分钟。
实施例3
一种能够增强上色性能的彩陶瓷坯,按照重量份计由以下成分制成:黑土110份、粉煤灰35份、磷酸二氢铵5.0份、氧化镁3.5份、硅酸钠1.5份、羟丙基甲基纤维素0.5份、蔗糖溶液10份、亚硝酸钙阻锈剂0.4份、无水乙醇90份、三乙醇胺油酸钠3.0份、硼酸水溶液50份、去离子水65份,包括以下步骤:
(1)将黑土和粉煤灰置于无水乙醇中,加热至60℃,以500转/分钟的速度搅拌40分钟,然后加入三乙醇胺油酸钠和硼酸水溶液,继续在1000转/分钟下搅拌55分钟,在50℃下密封护养护3天,得到的混合浆料置于旋转蒸发仪中蒸发除去乙醇;
(2)将蒸发得到的黑土混合物置于去离子水中搅拌均匀,加入蔗糖溶液混合搅拌2小时,加压浸渍处理70分钟,然后加入剩余物料,搅拌混合,将物料混合均匀后置于球磨机中球磨,球磨时间为45分钟,球磨后过120目筛,得到浆料在低速下搅拌60秒,然后在高速下搅拌150秒,制成均匀浆料;
(3)将制备得到的浆料加工塑型为所需形状的陶瓷坯,以150℃的温火预热3小时,然后在980℃下烧制,瓷化4.0小时,以8℃/分钟的速度降温至室温,得到的陶瓷瓷坯在相对湿度为55%,温度为25℃的条件下养护7天即可进入下一道工序。
作为对上述方案的进一步描述,所述硼酸水溶液质量浓度为10%。
作为对上述方案的进一步描述,所述蔗糖溶液质量浓度为40%。
作为对上述方案的进一步描述,步骤(1)所述旋转蒸发温度为70℃。
作为对上述方案的进一步描述,步骤(2)所述加压浸渍处理中,压力为6MPa,温度为30℃。
作为对上述方案的进一步描述,步骤(2)所述低速搅拌速度为400转/分钟,高速下搅拌速度为1400转/分钟。
对比例1
与实施例1的区别仅在于,所述黑土与粉煤灰的质量比为2:1,其余保持一致。
对比例2
与实施例2的区别仅在于,省略硼酸水溶液的添加,其余保持一致。
对比例3
与实施例3的区别仅在于,省略步骤(1)中的养护处理过程,其余保持一致。
对比例4
与实施例3的区别仅在于,省略步骤(2)中蔗糖溶液的添加以及加压浸渍处理过程,其余保持一致。
对比试验
分别使用实施例1-3和对比例1-4的方法加工制备彩陶陶瓷坯,同时以现有的以粘土烧制得到的陶瓷坯作为对照组,将各组陶瓷坯采用相同方法进一步加工成相应的彩陶样品,保持试验中无关变量一致,对各组加工产品进行性能比较,结果如下表所述:
本发明提供了一种实现提高彩陶陶瓷坯上色性能的一种有效方式,制备原料易获取,制作过程简单,效率高,具有操作方便,安全可靠,具有抗水、抗腐蚀、耐高温等优点,维持寿命长等优点,对彩陶文化推广应用具有重要意义,是一种极为值得推广使用的技术方案。
Claims (6)
1.一种能够增强上色性能的彩陶瓷坯,其特征在于,按照重量份计由以下成分制成:黑土100-110份、粉煤灰25-35份、磷酸二氢铵4.5-5.0份、氧化镁3.0-3.5份、硅酸钠1.0-1.5份、羟丙基甲基纤维素0.4-0.5份、蔗糖溶液8-10份、亚硝酸钙阻锈剂0.3-0.4份、无水乙醇80-90份、三乙醇胺油酸钠2.0-3.0份、硼酸水溶液40-50份、去离子水55-65份,包括以下步骤:
(1)将黑土和粉煤灰置于无水乙醇中,加热至50-60℃,以400-500转/分钟的速度搅拌30-40分钟,然后加入三乙醇胺油酸钠和硼酸水溶液,继续在900-1000转/分钟下搅拌45-55分钟,在40-50℃下密封护养护2-3天,得到的混合浆料置于旋转蒸发仪中蒸发除去乙醇;
(2)将蒸发得到的黑土混合物置于去离子水中搅拌均匀,加入蔗糖溶液混合搅拌1-2小时,加压浸渍处理60-70分钟,然后加入剩余物料,搅拌混合,将物料混合均匀后置于球磨机中球磨,球磨时间为35-45分钟,球磨后过100-120目筛,得到浆料在低速下搅拌40-60秒,然后在高速下搅拌120-150秒,制成均匀浆料;
(3)将制备得到的浆料加工塑型为所需形状的陶瓷坯,以140-150℃的温火预热2-3小时,然后在960-980℃下烧制,瓷化3.5-4.0小时,以6-8℃/分钟的速度降温至室温,得到的陶瓷瓷坯在相对湿度为45-55%,温度为23-25℃的条件下养护5-7天即可进入下一道工序。
2.如权利要求1所述一种能够增强上色性能的彩陶瓷坯,其特征在于,所述硼酸水溶液质量浓度为8-10%。
3.如权利要求1所述一种能够增强上色性能的彩陶瓷坯,其特征在于,所述蔗糖溶液质量浓度为30-40%。
4.如权利要求1所述一种能够增强上色性能的彩陶瓷坯,其特征在于,步骤(1)所述旋转蒸发温度为60-70℃。
5.如权利要求1所述一种能够增强上色性能的彩陶瓷坯,其特征在于,步骤(2)所述加压浸渍处理中,压力为5-6MPa,温度为28-30℃。
6.如权利要求1所述一种能够增强上色性能的彩陶瓷坯,其特征在于,步骤(2)所述低速搅拌速度为350-400转/分钟,高速下搅拌速度为1200-1400转/分钟。
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Application publication date: 20180925 |