CN108550622A - A kind of gallium nitride schottky barrier diode and its manufacturing method - Google Patents

A kind of gallium nitride schottky barrier diode and its manufacturing method Download PDF

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Publication number
CN108550622A
CN108550622A CN201810218852.6A CN201810218852A CN108550622A CN 108550622 A CN108550622 A CN 108550622A CN 201810218852 A CN201810218852 A CN 201810218852A CN 108550622 A CN108550622 A CN 108550622A
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Prior art keywords
epitaxial layer
gallium nitride
schottky
barrier diode
schottky barrier
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CN201810218852.6A
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Inventor
敖金平
李小波
邵春林
林岳明
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Jiangxi Yuhongjin Chip Technology Co., Ltd.
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Yangzhou Kosun Wei Semiconductor Co Ltd
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Priority to CN201810218852.6A priority Critical patent/CN108550622A/en
Publication of CN108550622A publication Critical patent/CN108550622A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/86Types of semiconductor device ; Multistep manufacturing processes therefor controllable only by variation of the electric current supplied, or only the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched
    • H01L29/861Diodes
    • H01L29/872Schottky diodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/285Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
    • H01L21/28506Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
    • H01L21/28575Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising AIIIBV compounds
    • H01L21/28581Deposition of Schottky electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/43Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/47Schottky barrier electrodes
    • H01L29/475Schottky barrier electrodes on AIII-BV compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66083Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by variation of the electric current supplied or the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched, e.g. two-terminal devices
    • H01L29/6609Diodes
    • H01L29/66143Schottky diodes

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrodes Of Semiconductors (AREA)

Abstract

The present invention discloses a kind of gallium nitride schottky barrier diode and its manufacturing method, include the epitaxial layer of substrate and growth on substrate, it is provided with Ohmic electrode and Schottky electrode on the epitaxial layer, invention additionally discloses its manufacturing methods, in nitrogen and argon gas atmosphere, nickel oxide film layer is formed using reactive magnetron sputtering method on the Schottky electrode region on epitaxial layer, then stripping method is used, form Schottky contacts, as Schottky electrode, by replacing nickel metal to be used as Schottky contacts by nickel oxide film layer, it is not good enough that the present invention solves diode stability in the prior art, the larger technical problem of reverse leakage current.

Description

A kind of gallium nitride schottky barrier diode and its manufacturing method
Technical field
The present invention relates to technical field of semiconductors more particularly to a kind of gallium nitride schottky barrier diode and its manufacturers Method.
Background technology
Schottky-barrier diode (SBD) is the Primary Component of antenna rectifier (RECTIFYING ANTENNA) circuit, is widely used in In microwave wireless transmission system, including electric powered motor charging, energy acquisition, ubiquitous power supply, and in building Wireless power distribution.However traditional GaAs and Si base commercialized Schottky barrier diodes cannot meet microwave wireless transmission technology The requirement of high conversion efficiency is needed under high-frequency and high-voltage.And GaN base material has big band gap, high breakdown fields, the movement of high electronics Property and the features such as high electron saturation velocities, therefore, GaN base SBD obtains wide in terms of the efficiency for improving microwave wireless transmission system General concern;In the prior art, diode is usually all that nickel metal is contacted with epitaxial layer, and such stability is not good enough, and lets out Leakage current is larger, to influence the efficiency of commutation system.
Invention content
The object of the present invention is to provide a kind of gallium nitride schottky barrier diode and its manufacturing methods, solve existing skill Diode stability in art is not good enough, and reverse leakage current is larger, thus the technical issues of influencing the efficiency of commutation system.
A kind of gallium nitride schottky barrier diode includes the epitaxial layer of substrate and growth on substrate, which is characterized in that It is provided with Ohmic electrode and Schottky electrode on the epitaxial layer.
Based on the above technical solution, the present invention can also be improved as follows:
Further, the epitaxial layer is n-GaN layers, and the advantageous effect using this step, which is gallium nitride-based material, to be had greatly The characteristics of band gap, high breakdown fields, high electron mobility and high electron saturation velocities, this gallium nitride material surface and nickel oxide shape At Schottky barrier constitute the present invention device, the efficiency of microwave wireless transmission system can be improved using this device.
Further, the Schottky electrode includes nickel oxide film layer, and the advantageous effect using this step is to pass through nitridation Nickel film layer replaces nickel metal as Schottky contacts, can improve stability in this way and reduce leakage current.
The present invention also provides a kind of manufacturing methods of gallium nitride schottky barrier diode, include the following steps:
S1:The epitaxial layer of n-GaN is formed using Metalorganic Chemical Vapor Deposition growth substrates surface;
S2:Titanium/aluminium/titanium/gold multiple layer metal is sequentially formed on epitaxial layer using magnetron sputtering method, then uses stripping side Method is by the metal-stripping on epitaxial layer outside Ohmic electrode region to be formed, and in nitrogen atmosphere, carries out thermal anneal process, is formed Ohmic contact;
S3:Nickel oxide film layer is formed using reactive magnetron sputtering method on the Schottky electrode region on epitaxial layer, Schottky contacts are formed, Schottky electrode is become.
In the manufacturing method, n-GaN layers of the doping concentration is 5.0*1015-6.0*1017cm-3
Further, the reactive magnetron sputtering method in the step S3 is that nitrogen progress is poured in argon gas atmosphere 's.
Beneficial effects of the present invention:
A kind of Schottky-barrier diode of present invention offer and its manufacturing method replace nickel metal by nickel oxide film layer Layer is used as Schottky contacts, has higher stability and lower leakage current in this way, can simultaneously be effectively improves rectification The efficiency of system is more suitable for harsh environment;Diode produced by the invention compares more conventional diode, reverse leakage electricity Stream reduces two orders of magnitude, can effectively improve the efficiency of commutation system in this way.
Description of the drawings
It, below will be to specific in order to illustrate more clearly of the specific embodiment of the invention or technical solution in the prior art Embodiment or attached drawing needed to be used in the description of the prior art are briefly described, it should be apparent that, in being described below Attached drawing is some embodiments of the present invention, for those of ordinary skill in the art, before not making the creative labor It puts, other drawings may also be obtained based on these drawings.
Fig. 1 is a kind of structural schematic diagram of gallium nitride schottky barrier diode described in the specific embodiment of the invention;
Fig. 2 shows current-voltage (I-V) characteristic of NiN/n-GaN and Ni/n-GaN Schottky diodes.
1- substrates;2- epitaxial layers;3- Ohmic electrodes;4- Schottky electrodes.
Specific implementation mode
The embodiment of technical solution of the present invention is described in detail below in conjunction with attached drawing.Following embodiment is only used for Clearly illustrate technical scheme of the present invention, therefore be only used as example, and the protection model of the present invention cannot be limited with this It encloses.
It should be noted that unless otherwise indicated, technical term or scientific terminology used in this application should be this hair The ordinary meaning that bright one of ordinary skill in the art are understood.
In the description of the present application, it is to be understood that the orientation or positional relationship of the instructions such as term "upper", "lower" is base It in orientation or positional relationship shown in the drawings, is merely for convenience of description of the present invention and simplification of the description, rather than indicates or imply Signified device or element must have a particular orientation, with specific azimuth configuration and operation, therefore should not be understood as to this The limitation of invention.
Embodiment 1:
As shown in Figure 1, a kind of gallium nitride schottky barrier diode provided by the present invention, including substrate and it is grown in lining Epitaxial layer on bottom is provided with Ohmic electrode and Schottky electrode on the epitaxial layer, and the Schottky electrode in the present embodiment can Think circle, or other arbitrary shapes.
For the substrate used in the present invention for sapphire substrates, epitaxial layer is n-GaN layers, and the Ohmic electrode on epitaxial layer is Multiple layer metal is followed successively by titanium/aluminium/titanium/gold from bottom to top, and the titanium layer is contacted with epitaxial layer, and Ohmic electrode is located at Schottky electricity The periphery of pole.
Wherein, the Schottky electrode includes nickel oxide film layer, and the present invention replaces nickel metal by nickel oxide film layer As Schottky contacts, stability can be improved in this way and reduces leakage current.
Wherein, the epitaxial layer is n-GaN layers, because gallium nitride-based material has big band gap, high breakdown fields, high electronics The Schottky barrier that the characteristics of mobility and high electron saturation velocities, this gallium nitride material surface and nickel oxide are formed constitutes The device of the present invention, the efficiency of microwave wireless transmission system can be improved using this device.
The present invention also provides the manufacturing methods of above-mentioned gallium nitride schottky barrier diode, include the following steps:
S1:The epitaxial layer of n-GaN is formed using Metalorganic Chemical Vapor Deposition growth substrates surface;
S2:Titanium/aluminium/titanium/gold multiple layer metal is sequentially formed on epitaxial layer using magnetron sputtering method, then uses stripping side Method is by the metal-stripping on epitaxial layer outside Ohmic electrode region to be formed, and in nitrogen atmosphere, carries out thermal anneal process, is formed Ohmic contact;
S3:Nickel oxide film layer is formed using reactive magnetron sputtering method on the Schottky electrode region on epitaxial layer, Schottky contacts are formed, Schottky electrode is become.
Wherein, in step S1, n-GaN layers of doping concentration is 5.0*1015
Wherein, the reactive magnetron sputtering method in the step S3 is to pour nitrogen in argon gas atmosphere to carry out, this The NiN film layers formed in inventive step S3 can be NiN, Ni2N and Ni3The mixing of N.
Fig. 2 shows current-voltage (I-V) characteristic of NiN/n-GaN and Ni/n-GaN Schottky diodes.With Ni Schottky Diode is compared, and the anti-leakage current of NiN Schottky diodes is reduced by about two orders of magnitude.
The operating methods such as Metalorganic Chemical Vapor Deposition, magnetron sputtering method, stripping method in the present invention are existing Technology, details are not described herein again.
Embodiment 2
A kind of gallium nitride schottky barrier diode provided by the present invention includes the extension of substrate and growth on substrate Layer, it is provided with Ohmic electrode and Schottky electrode on the epitaxial layer, the Schottky electrode in the present embodiment can be circle, Can be other arbitrary shapes.
Wherein, the Schottky electrode includes nickel oxide film layer, and the present invention replaces nickel metal by nickel oxide film layer As Schottky contacts, stability can be improved in this way and reduces leakage current.
Wherein, the epitaxial layer is n-GaN layers.
The present invention also provides a kind of manufacturing methods of gallium nitride schottky barrier diode, include the following steps:
S1:The epitaxial layer of n-GaN is formed using Metalorganic Chemical Vapor Deposition growth substrates surface;
S2:Titanium/aluminium/titanium/gold multiple layer metal is sequentially formed on epitaxial layer using magnetron sputtering method, then uses stripping side Method is by the metal-stripping on epitaxial layer outside Ohmic electrode region to be formed, and in nitrogen atmosphere, carries out thermal anneal process, is formed Ohmic contact;
S3:Nickel oxide film layer is formed using reactive magnetron sputtering method on the Schottky electrode region on epitaxial layer, Schottky contacts are formed, Schottky electrode is become.
Wherein, in step S1, n-GaN layers of doping concentration is 6.0*1017cm-3
Wherein, the reactive magnetron sputtering method in the step S3 is to pour nitrogen in argon gas atmosphere to carry out, this The NiN film layers formed in inventive step S3 can be NiN, Ni2N and Ni3The mixing of N.
The operating methods such as Metalorganic Chemical Vapor Deposition, magnetron sputtering method, stripping method in the present invention are existing Technology, details are not described herein again.
Embodiment 3:
A kind of gallium nitride schottky barrier diode provided by the present invention includes the extension of substrate and growth on substrate Layer, it is provided with Ohmic electrode and Schottky electrode on the epitaxial layer, the Schottky electrode in the present embodiment can be circle, Can be other arbitrary shapes.
Wherein, the Schottky electrode includes nickel oxide film layer, and the present invention replaces nickel metal by nickel oxide film layer As Schottky contacts, stability can be improved in this way and reduces leakage current.
Wherein, the epitaxial layer is n-GaN layers.
The present invention also provides a kind of manufacturing methods of gallium nitride schottky barrier diode, include the following steps:
S1:The epitaxial layer of n-GaN is formed using Metalorganic Chemical Vapor Deposition growth substrates surface;
S2:Titanium/aluminium/titanium/gold multiple layer metal is sequentially formed on epitaxial layer using magnetron sputtering method, then uses stripping side Method is by the metal-stripping on epitaxial layer outside Ohmic electrode region to be formed, and in nitrogen atmosphere, carries out thermal anneal process, is formed Ohmic contact;
S3:Nickel oxide film layer is formed using reactive magnetron sputtering method on the Schottky electrode region on epitaxial layer, Schottky contacts are formed, Schottky electrode is become.
Wherein, in step S1, n-GaN layers of doping concentration is 6.0*1016cm-3
Wherein, the reactive magnetron sputtering method in the step S3 is to pour nitrogen in argon gas atmosphere to carry out, this The NiN film layers formed in inventive step S3 can be NiN, Ni2N and Ni3The mixing of N.
Fig. 2 shows current-voltage (I-V) characteristic of NiN/n-GaN and Ni/n-GaN Schottky diodes.With Ni Schottky Diode is compared, and the anti-leakage current of NiN Schottky diodes is reduced by about two orders of magnitude.
The operating methods such as Metalorganic Chemical Vapor Deposition, magnetron sputtering method, stripping method in the present invention are existing Technology, details are not described herein again.
In the specification of the present invention, numerous specific details are set forth.It is to be appreciated, however, that the embodiment of the present invention can be with It puts into practice without these specific details.In some instances, well known method, structure and skill is not been shown in detail Art, so as not to obscure the understanding of this description.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example Point is included at least one embodiment or example of the invention.In the present specification, schematic expression of the above terms are not It must be directed to identical embodiment or example.Moreover, particular features, structures, materials, or characteristics described can be in office It can be combined in any suitable manner in one or more embodiments or example.In addition, without conflicting with each other, the skill of this field Art personnel can tie the feature of different embodiments or examples described in this specification and different embodiments or examples It closes and combines.
Finally it should be noted that:The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations;To the greatest extent Present invention has been described in detail with reference to the aforementioned embodiments for pipe, it will be understood by those of ordinary skill in the art that:Its according to So can with technical scheme described in the above embodiments is modified, either to which part or all technical features into Row equivalent replacement;And these modifications or replacements, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution The range of scheme should all cover in the claim of the present invention and the range of specification.

Claims (7)

1. a kind of gallium nitride schottky barrier diode includes the epitaxial layer of substrate and growth on substrate, which is characterized in that institute It states and is provided with Ohmic electrode and Schottky electrode on epitaxial layer.
2. a kind of gallium nitride schottky barrier diode according to claim 1, which is characterized in that the epitaxial layer is n- GaN layer.
3. a kind of gallium nitride schottky barrier diode according to claim 1, which is characterized in that the Schottky electrode Including nickel oxide film layer, the nickel oxide film layer is contacted with the epitaxial layer.
4. a kind of manufacturing method of any gallium nitride schottky barrier diodes of claim 1-3, which is characterized in that packet Include following steps:
S1:The epitaxial layer of n-GaN is formed in substrate surface using Metalorganic Chemical Vapor Deposition;
S2:Titanium/aluminium/titanium/gold multiple layer metal is sequentially formed on epitaxial layer using magnetron sputtering method, then uses stripping means will Metal-stripping on epitaxial layer outside Ohmic electrode region to be formed carries out thermal anneal process in nitrogen atmosphere, forms ohm Contact;
S3:Nickel oxide film layer is formed using reactive magnetron sputtering method on the Schottky electrode region on epitaxial layer, is formed Schottky contacts become Schottky electrode.
5. a kind of manufacturing method of gallium nitride schottky barrier diode according to claim 4, which is characterized in that step N-GaN layers of doping concentration is 5.0*10 in S115-6.0*1017cm-3
6. a kind of manufacturing method of gallium nitride schottky barrier diode according to claim 4, which is characterized in that described The sputtering target that reactive magnetron sputtering method in step S3 uses is nickel target.
7. a kind of manufacturing method of gallium nitride schottky barrier diode according to claim 5, which is characterized in that described Reactive magnetron sputtering method in step S3 is to pour nitrogen in argon gas atmosphere to carry out.
CN201810218852.6A 2018-03-16 2018-03-16 A kind of gallium nitride schottky barrier diode and its manufacturing method Pending CN108550622A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110931570A (en) * 2019-12-13 2020-03-27 西安电子科技大学 Gallium nitride Schottky barrier diode and manufacturing method thereof
CN111293173A (en) * 2018-12-10 2020-06-16 黄山学院 Silicon-based gallium nitride enhanced HEMT device and preparation method thereof
CN111293179A (en) * 2018-12-10 2020-06-16 黄山学院 Silicon-based gallium nitride Schottky diode and preparation method thereof
CN111987814A (en) * 2019-05-23 2020-11-24 国立大学法人德岛大学 Medical microwave power supply system, power receiving circuit, and schottky barrier diode
CN114335169A (en) * 2021-11-25 2022-04-12 江西誉鸿锦材料科技有限公司 Gallium nitride Schottky barrier diode and manufacturing method thereof
CN115360235A (en) * 2022-08-09 2022-11-18 江南大学 Gallium nitride Schottky barrier diode and manufacturing method thereof

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CN1675775A (en) * 2002-06-17 2005-09-28 日本电气株式会社 Semiconductor device having Schottky junction electrode
CN100373634C (en) * 2001-07-23 2008-03-05 美商克立股份有限公司 Gallium nitride based diodes with low forward voltage and low reverse current operation
CN101351898A (en) * 2005-12-27 2009-01-21 三星电子株式会社 Group-III nitride-based light emitting device
CN102097492A (en) * 2010-12-24 2011-06-15 中山大学 Hetetrostructure field effect diode and manufacturing method thereof
CN107221565A (en) * 2017-05-23 2017-09-29 江南大学 The preparation method of high-gain gallium nitride Schottky diode is realized based on ion implanting fluorine

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CN100373634C (en) * 2001-07-23 2008-03-05 美商克立股份有限公司 Gallium nitride based diodes with low forward voltage and low reverse current operation
CN1675775A (en) * 2002-06-17 2005-09-28 日本电气株式会社 Semiconductor device having Schottky junction electrode
CN101351898A (en) * 2005-12-27 2009-01-21 三星电子株式会社 Group-III nitride-based light emitting device
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111293173A (en) * 2018-12-10 2020-06-16 黄山学院 Silicon-based gallium nitride enhanced HEMT device and preparation method thereof
CN111293179A (en) * 2018-12-10 2020-06-16 黄山学院 Silicon-based gallium nitride Schottky diode and preparation method thereof
CN111987814A (en) * 2019-05-23 2020-11-24 国立大学法人德岛大学 Medical microwave power supply system, power receiving circuit, and schottky barrier diode
CN111987814B (en) * 2019-05-23 2021-07-06 国立大学法人德岛大学 Medical microwave power supply system, power receiving circuit, and schottky barrier diode
CN110931570A (en) * 2019-12-13 2020-03-27 西安电子科技大学 Gallium nitride Schottky barrier diode and manufacturing method thereof
CN110931570B (en) * 2019-12-13 2021-05-18 西安电子科技大学 Gallium nitride Schottky barrier diode and manufacturing method thereof
CN114335169A (en) * 2021-11-25 2022-04-12 江西誉鸿锦材料科技有限公司 Gallium nitride Schottky barrier diode and manufacturing method thereof
CN115360235A (en) * 2022-08-09 2022-11-18 江南大学 Gallium nitride Schottky barrier diode and manufacturing method thereof
CN115360235B (en) * 2022-08-09 2024-04-09 江南大学 Gallium nitride Schottky barrier diode and manufacturing method thereof

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Application publication date: 20180918