CN110112207B - Gallium oxide-based mixed PiN Schottky diode and preparation method thereof - Google Patents

Gallium oxide-based mixed PiN Schottky diode and preparation method thereof Download PDF

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CN110112207B
CN110112207B CN201910417281.3A CN201910417281A CN110112207B CN 110112207 B CN110112207 B CN 110112207B CN 201910417281 A CN201910417281 A CN 201910417281A CN 110112207 B CN110112207 B CN 110112207B
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gallium oxide
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semiconductor layer
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CN110112207A (en
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卢星
王钢
裴艳丽
陈梓敏
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National Sun Yat Sen University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/0684Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape, relative sizes or dispositions of the semiconductor regions or junctions between the regions
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/24Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only semiconductor materials not provided for in groups H01L29/16, H01L29/18, H01L29/20, H01L29/22
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/24Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only semiconductor materials not provided for in groups H01L29/16, H01L29/18, H01L29/20, H01L29/22
    • H01L29/247Amorphous materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66969Multistep manufacturing processes of devices having semiconductor bodies not comprising group 14 or group 13/15 materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/86Types of semiconductor device ; Multistep manufacturing processes therefor controllable only by variation of the electric current supplied, or only the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched
    • H01L29/861Diodes
    • H01L29/8613Mesa PN junction diodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/86Types of semiconductor device ; Multistep manufacturing processes therefor controllable only by variation of the electric current supplied, or only the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched
    • H01L29/861Diodes
    • H01L29/872Schottky diodes

Abstract

The invention discloses a gallium oxide-based mixed PiN Schottky diode and a preparation method thereof, and relates to the technical field of semiconductor devices. The method aims to solve the problems that the doping difficulty of P-type gallium oxide in the prior art is very high, and the prior art cannot achieve high enough doping concentration and cannot be applied to normal devices. A diode with a mixed PiN Schottky structure is realized by inserting a p-type oxide semiconductor layer into the surface of a gallium oxide voltage-resistant layer. The p-type doping problem of the gallium oxide material is ingeniously avoided, the reverse breakdown voltage and the leakage current of the diode are determined by the heterogeneous PN junction, and the diode has better voltage resistance while ensuring good forward opening characteristics.

Description

Gallium oxide-based mixed PiN Schottky diode and preparation method thereof
Technical Field
The invention relates to the technical field of semiconductor devices, in particular to a gallium oxide-based mixed PiN Schottky diode and a preparation method thereof.
Background
Rectifier diodes are widely used in switching power supplies, frequency converters, drivers, and other circuits. Gallium oxide (Ga)2O3) The semiconductor has an ultra-wide forbidden band of up to 4.8eV and an ultra-large breakdown field strength of 8MV/cm, and a large-size single crystal substrate can be prepared by a low-cost melting growth method, so that the semiconductor is an ideal material for preparing a high-power rectifier diode. However, since there is no reliable method for p-type doping of gallium oxide material, the existing gallium oxide-based diodes mostly adopt Schottky barrier structures (see documents k. konishi, et al.,1-kV vertical Ga2O3 field-planar Schottky barrier diodes, applied physics Letters 110(10),103506,2017 and chinese patent CN 106876484 a). Compared with PN junction diode, Schottky barrier diode has low forward turn-on voltage and short reverse recovery time, but has large reverse leakage current and low breakdown voltageAnd the temperature characteristics of the schottky barrier diode are relatively poor.
Although some patent documents cover diodes made of p-type gallium oxide materials, the diodes are all of a single anode structure, and a mixed PiN dual anode structure cannot be realized. Meanwhile, the doping difficulty of the P-type gallium oxide is very high, and the existing technology cannot achieve high enough doping concentration, so that the P-type gallium oxide can not be applied to normal devices at all.
Disclosure of Invention
In order to solve the problems in the prior art, the present invention aims to provide a gallium oxide-based mixed PiN schottky diode with a sufficiently high current density and a method for manufacturing the same.
The invention relates to a gallium oxide-based mixed PiN Schottky diode, which comprises: the gallium oxide voltage-withstanding layer is provided with a plurality of steps extending through the p-type oxide semiconductor layer on one side close to the p-type oxide semiconductor layer, and the steps penetrate through the p-type oxide semiconductor layer and then are contacted with the anode layer; the anode layer is in Schottky contact with the step of the gallium oxide voltage-withstanding layer; the anode layer is in Schottky or ohmic contact with the p-type oxide semiconductor layer.
Preferably, the anode layer comprises a first anode electrode and a second anode electrode, and the first anode electrode is in schottky or ohmic contact with the p-type oxide semiconductor layer; the second anode electrode is in Schottky contact with the step; the second anode electrode is coated outside the first anode electrode.
Preferably, the gallium oxide voltage-withstanding layer is of an n-type doped single crystal structure.
Preferably, the doping concentration of the gallium oxide voltage-withstanding layer is 5 × 1014cm-3To 1X 1018cm-3
Preferably, the thickness of the gallium oxide pressure-resistant layer is 2 μm-5 mm.
Preferably, the p-type oxide semiconductor layer has an amorphous or polycrystalline structure and holesThe concentration is 1X 1017/cm3~1×1020/cm3
Preferably, the doping concentration of the n-type doped gallium oxide substrate is 5 x 1017cm-3~1×1020cm-3
A preparation method of a gallium oxide-based mixed PiN Schottky diode comprises a preparation step of a gallium oxide-based wafer, a step of preparing an electrode on the gallium oxide-based wafer, a step of etching a plurality of steps on the gallium oxide-based wafer, and a step of filling a p-type oxide semiconductor layer between the steps; so that the anode is in Schottky contact with the gallium oxide-based wafer and in Schottky or ohmic contact with the p-type oxide semiconductor layer.
Preferably, the preparation step of the gallium oxide-based wafer is to epitaxially grow an n-type doped gallium oxide voltage-withstanding layer on an n-type doped gallium oxide substrate; the step is obtained by etching the gallium oxide voltage-withstanding layer at the side far away from the n-type doped gallium oxide substrate.
Preferably, the step of preparing an electrode on the gallium oxide-based wafer comprises: depositing metal on the p-type oxide semiconductor layer to form ohmic contact or Schottky contact to prepare a first anode electrode; and depositing metal on the first anode electrode and the gallium oxide voltage-withstanding layer to form Schottky contact with the gallium oxide voltage-withstanding layer, so as to obtain a second anode electrode.
The gallium oxide-based mixed PiN Schottky diode and the preparation method thereof have the advantages that a heterogeneous PN junction is formed by adopting the amorphous or polycrystalline p-type oxide semiconductor and the single-crystal gallium oxide, the p-type doping problem of the gallium oxide material is ingeniously avoided, the reverse breakdown voltage and the leakage current of the diode are determined by the heterogeneous PN junction, and the diode has better withstand voltage characteristic while ensuring good forward opening characteristic. The size design of the step is related to parameters such as doping concentration and design withstand voltage of the device, mainly inversely related to the concentration of the gallium oxide withstand voltage layer, positively related to the design withstand voltage of the device, and simultaneously positively related to the concentration of the p-type oxide semiconductor layer. The size of the step is as long as the condition is satisfied: under reverse bias, the heterojunction PN junction depletion regions communicate with each other.
Drawings
Fig. 1 is a schematic structural diagram of a gallium oxide-based hybrid PiN schottky diode according to the present invention;
FIG. 2 is a schematic diagram of a longitudinal cross-sectional structure of a gallium oxide-based hybrid PiN Schottky diode according to the present invention;
fig. 3 is a cross-sectional view at a-a in fig. 2.
Fig. 4 is a schematic diagram comparing forward current curves of a gallium oxide based hybrid PiN schottky diode of the present invention with a conventional gallium oxide based schottky barrier diode;
fig. 5 is a schematic diagram comparing reverse current curves of the gallium oxide-based hybrid PiN schottky diode of the present invention and a conventional gallium oxide-based schottky barrier diode.
Reference numerals: 101-cathode electrode, 102-n type doped gallium oxide substrate, 103-gallium oxide voltage-withstanding layer, 104-p type oxide semiconductor layer, 105-first anode electrode, 106-second anode electrode.
Detailed Description
As shown in fig. 1-3, a cathode electrode 101, an n-type doped gallium oxide substrate 102, a gallium oxide voltage-withstanding layer 103, a p-type oxide semiconductor layer 104, and an anode layer are sequentially stacked, wherein a plurality of steps extending through the p-type oxide semiconductor layer 104 are disposed on one side of the gallium oxide voltage-withstanding layer 103 close to the p-type oxide semiconductor layer 104, and the steps extend through the p-type oxide semiconductor layer 104 and then contact the anode layer; the anode layer is in Schottky contact with the step of the gallium oxide voltage-withstanding layer 103; the anode layer is in schottky or ohmic contact with the p-type oxide semiconductor layer 104. The n-type doped gallium oxide substrate 102 and the cathode electrode 101 are in ohmic contact. The anode layer comprises a first anode electrode 105 and a second anode electrode 106, wherein the first anode electrode 105 is in Schottky or ohmic contact with the p-type oxide semiconductor layer 104; the second anode electrode 106 is in schottky contact with the step; the second anode electrode 106 is coated outside the first anode electrode 105. Said oxidationThe gallium voltage-withstanding layer 103 is of an n-type doped single crystal structure with a doping concentration of 5 × 1014cm-3To 1X 1018cm-3The thickness is 2 mu m-5 mm. The thickness includes the height of the step. The p-type oxide semiconductor layer 104 has an amorphous or polycrystalline structure and a hole concentration of 1 × 1017/cm3~1×1020/cm3. The doping concentration of the n-type doped gallium oxide substrate 102 is 5 multiplied by 1017cm-3~1×1020cm-3
By adopting the amorphous or polycrystalline p-type oxide semiconductor and the single crystal gallium oxide to form the heterogeneous PN junction, the p-type doping problem of the gallium oxide material is ingeniously avoided, and the high electric field is shielded by the heterogeneous PN junction, so that the whole device has the forward turn-on characteristic of a Schottky diode and has the reverse withstand voltage characteristic similar to a Pin diode. The reverse breakdown voltage and the leakage current of the diode are determined by the heterojunction PN junction, and the diode has better voltage resistance while ensuring good forward starting characteristic. The dimension of the step is designed in such a way that the dimension is related to parameters such as doping concentration and design withstand voltage of the device, mainly inversely related to the concentration of the gallium oxide withstand voltage layer 103, positively related to the design withstand voltage of the device, and also positively related to the concentration of the p-type oxide semiconductor layer 104. The size of the step is as long as the condition is satisfied: under reverse bias, the heterojunction PN junction depletion regions communicate with each other. Under the technical conception provided by the invention, a person skilled in the art can completely obtain the step size meeting the requirements of certain parameters through limited times of tests without creative labor. The particular step size is therefore a technical measure clear to the skilled person. Such as: the concentration of the gallium oxide voltage-withstanding layer 103 is 8 × 1015cm-3The designed withstand voltage was 2kV, and the concentration of the p-type oxide semiconductor layer 104 was 1.5X 1018cm-3In the case of (2), the height of the step may be 500nm and the step pitch may be 2 μm.
The p-type oxide semiconductor layer 104 corresponds to p in the mixed PiN structure, the gallium oxide voltage-withstanding layer 103 corresponds to i layer in the PiN structure, and the n-type doped gallium oxide substrate 102 corresponds to n in the mixed PiN structure.
As shown in fig. 4 and 5, which are forward and reverse comparisons between the gan-based hybrid PiN schottky diode of the present invention and the conventional gan-based schottky barrier diode, the abscissa is the bias voltage applied to the diode device and the ordinate is the current of the device, and it can be seen that the gan-based hybrid PiN schottky diode of the present invention has smaller reverse leakage current and higher breakdown voltage than the conventional gan-based schottky barrier diode, while maintaining excellent forward turn-on characteristics of low turn-on voltage and high on-current.
The invention also provides a method for preparing the gallium oxide-based mixed PiN Schottky diode, which comprises the following steps:
epitaxially growing an n-type doped gallium oxide voltage-withstanding layer 103 on the n-type doped gallium oxide substrate 102 to obtain a gallium oxide-based wafer;
etching a groove on one side of the gallium oxide voltage-resisting layer 103 far away from the n-type doped gallium oxide substrate 102, and isolating the upper part of the gallium oxide voltage-resisting layer 103 into a plurality of steps separated from each other;
depositing an amorphous or polycrystalline p-type oxide semiconductor in the groove to obtain a p-type oxide semiconductor layer 104, and forming a heterojunction PN junction with the gallium oxide voltage-withstanding layer 103; the p-type oxide semiconductor layer 104 can be NiO or Cu prepared by magnetron sputtering, solution method, metal oxide method, physical or chemical vapor deposition and the like2O or other p-type oxide semiconductor material with single layer or multiple layers;
depositing metal on the upper surface of the p-type oxide semiconductor layer 104 to form ohmic contact or Schottky contact, and preparing a first anode electrode 105; the first anode electrode 105 can be made of Ni/Au alloy or Pt/Au alloy deposited by adopting a magnetron sputtering or electron beam evaporation method;
depositing metal on the upper surfaces of the first anode electrode 105 and the gallium oxide voltage-withstanding layer 103, and forming Schottky contact with the surface of the gallium oxide voltage-withstanding layer 103 to obtain a second anode electrode 106; the second anode electrode 106 can be made of Ni/Au alloy or Pt/Au alloy by magnetron sputtering or electron beam evaporation;
etching or grinding to thin the n-type doped gallium oxide substrate 102, and depositing metal on the lower surface of the n-type doped gallium oxide substrate 102 to form ohmic contact to prepare a cathode electrode 101; the cathode 101 may be made of Ti/Au alloy or Ti/Al/Ni/Au alloy deposited by magnetron sputtering or electron beam evaporation.
It will be apparent to those skilled in the art that various other changes and modifications may be made in the above-described embodiments and concepts and all such changes and modifications are intended to be within the scope of the appended claims.

Claims (9)

1. A gallium oxide-based hybrid PiN Schottky diode, comprising: the GaN-based light-emitting diode comprises a cathode electrode (101), an n-type doped GaN substrate (102), a GaN voltage-withstanding layer (103), a p-type oxide semiconductor layer (104) and an anode layer which are sequentially stacked, wherein one side, close to the p-type oxide semiconductor layer (104), of the GaN voltage-withstanding layer (103) is provided with a plurality of steps which extend through the p-type oxide semiconductor layer (104), and the steps penetrate through the p-type oxide semiconductor layer (104) and then are in contact with the anode layer; the anode layer is in Schottky contact with the step of the gallium oxide voltage-withstanding layer (103); the anode layer is in Schottky or ohmic contact with the p-type oxide semiconductor layer (104); the anode layer comprises a first anode electrode (105) and a second anode electrode (106), wherein the first anode electrode (105) is in Schottky or ohmic contact with the p-type oxide semiconductor layer (104); the second anode electrode (106) is in Schottky contact with the step; the second anode electrode (106) is coated outside the first anode electrode (105).
2. The gallium oxide-based hybrid PiN Schottky diode according to claim 1, wherein the gallium oxide voltage-withstanding layer (103) is of an n-type doped single crystal structure.
3. The gan-based hybrid PiN schottky diode of claim 2 wherein the gan voltage barrier (103) is doped at a concentration of 5 x 1014cm-3To 1X 1018cm-3
4. The gallium oxide-based hybrid PiN Schottky diode according to claim 1, wherein the thickness of the gallium oxide voltage-withstanding layer (103) is 2 μm-5 mm.
5. The gan-based hybrid PiN schottky diode of claim 1 wherein the p-type oxide semiconductor layer (104) is amorphous or polycrystalline with a hole concentration of 1 x 1017/cm3~1×1020/cm3
6. The gan-based hybrid PiN schottky diode of claim 1 wherein the n-type doped gan substrate (102) is doped at a concentration of 5 x 1017cm-3~1×1020cm-3
7. A preparation method of a gallium oxide-based mixed PiN Schottky diode comprises a preparation step of a gallium oxide-based wafer and a step of preparing an electrode on the gallium oxide-based wafer, and is characterized by further comprising a step of etching a plurality of steps on the gallium oxide-based wafer and a step of filling a p-type oxide semiconductor layer (104) between the steps; making the anode in Schottky contact with the gallium oxide-based wafer and in Schottky or ohmic contact with the p-type oxide semiconductor layer (104); the gallium oxide-based wafer is formed by laminating an n-type doped gallium oxide substrate (102) and a gallium oxide voltage-withstanding layer (103).
8. The preparation method of the gallium oxide-based mixed Pin Schottky diode according to claim 7, wherein the preparation step of the gallium oxide-based wafer is to epitaxially grow an n-type doped gallium oxide voltage-withstanding layer (103) on an n-type doped gallium oxide substrate (102); the step is obtained by etching the side of the gallium oxide voltage-withstanding layer (103) far away from the n-type doped gallium oxide substrate (102).
9. The method of claim 8, wherein the step of fabricating an electrode on the gallium oxide-based wafer comprises: depositing metal on the p-type oxide semiconductor layer (104) to form ohmic contact or Schottky contact to prepare a first anode electrode (105); and depositing metal on the first anode electrode (105) and the gallium oxide voltage-withstanding layer (103) to form Schottky contact with the gallium oxide voltage-withstanding layer (103) to obtain a second anode electrode (106).
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