CN108538932A - A kind of photovoltaic glass - Google Patents

A kind of photovoltaic glass Download PDF

Info

Publication number
CN108538932A
CN108538932A CN201810279834.9A CN201810279834A CN108538932A CN 108538932 A CN108538932 A CN 108538932A CN 201810279834 A CN201810279834 A CN 201810279834A CN 108538932 A CN108538932 A CN 108538932A
Authority
CN
China
Prior art keywords
layer
reflecting layer
layers
glass
antireflection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810279834.9A
Other languages
Chinese (zh)
Inventor
马俊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Gerun Intelligent Photovoltaic Co Ltd
Original Assignee
Nantong Gerun Intelligent Photovoltaic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Gerun Intelligent Photovoltaic Co Ltd filed Critical Nantong Gerun Intelligent Photovoltaic Co Ltd
Priority to CN201810279834.9A priority Critical patent/CN108538932A/en
Publication of CN108538932A publication Critical patent/CN108538932A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0488Double glass encapsulation, e.g. photovoltaic cells arranged between front and rear glass sheets
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0216Coatings
    • H01L31/02161Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02167Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • H01L31/02168Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells the coatings being antireflective or having enhancing optical properties for the solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0236Special surface textures
    • H01L31/02366Special surface textures of the substrate or of a layer on the substrate, e.g. textured ITO/glass substrate or superstrate, textured polymer layer on glass substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/054Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
    • H01L31/0547Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means comprising light concentrating means of the reflecting type, e.g. parabolic mirrors, concentrators using total internal reflection
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/52PV systems with concentrators

Abstract

The invention discloses a kind of photovoltaic glass, including AR antireflection layers and reflecting layer, AR antireflection layers are arranged in glass body upper surface, reflecting layer is arranged inside glass body, reflecting layer uses the reflecting layer with matte catoptric arrangement, the light-receiving surface in reflecting layer has certain matte catoptric arrangement, the matte catoptric arrangement, be conducive to the light for being incident on reflecting layer, cell piece surface is entered after secondary or multiple reflections, the present invention provides a kind of photovoltaic glass, the reflecting layer having inside it, rise to the ray density up to photovoltaic module internal cell piece, being promoted to the output power of photovoltaic module has positive effect.

Description

A kind of photovoltaic glass
Technical field
The present invention relates to photovoltaic glass technical field, specially a kind of photovoltaic glass.
Background technology
Photovoltaic module(Also it is solar panel)It is the core in solar power system and solar power generation Most important part in system.It is to convert solar energy into electrical energy, and be sent in accumulator and store, or push negative that it, which is acted on, Carry work.But with the use of Miniature inverter, can the current source of photovoltaic module directly be transformed into 40V's or so Voltage source, so that it may to drive in our life of appliance applications;Meanwhile photovoltaic module is being constantly brought forth new ideas, due to photovoltaic module It is called made in China in the field of business, it should have Created in China, and then the upgrading innovative product of photovoltaic module occur, as photovoltaic is made pottery Ceramic tiles, photovoltaic color steel tile, this kind of product can directly replace traditional construction material tile, also have the function of photovoltaic module, once step Enter common market, certain impact will be caused to photovoltaic module and traditional construction material.
In photovoltaic industry, in order to obtain electric current, voltage and the output power needed for photovoltaic generation unit, and also to Protect the battery from mechanical damage and environmental nuisance, it is necessary to several monolithic battery connection in series-parallel be connected and be packaged into photovoltaic module. Under normal circumstances, the output power of the photovoltaic module after encapsulation(Actual power)Less than the sum of the performance number of all cell pieces(Reason By power), this is because light is after being irradiated to photovoltaic module surface, it may occur that and reflection and absorption, meanwhile, photovoltaic module light In region, have a certain proportion of region be can not power generation region, which is used, original generating capacity is not being influenced In the case of, make the region have must secondary reflection ability, be capable of the intensity of illumination in lifting assembly Partial discharge region, to Lifting assembly output current, and then promote photoelectric conversion efficiency.
Currently, had been applied in photovoltaic module using the welding and welding pad pasting with matte catoptric arrangement, but There is certain difficulty in process in it.The principle of the two is again by the interconnecting strip for being emitted onto cell piece connection Glazed thread improves generating efficiency through secondary reflecting on cell piece.Based on above-mentioned background, the present invention program is that will have reflection knot The reflecting layer of structure is combined with photovoltaic glass, need not increase the complexity of photovoltaic module production procedure, and is ensured simultaneously secondary Reflection power gain effect.
Invention content
The purpose of the present invention is to provide a kind of photovoltaic glass, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides the following technical solutions:A kind of photovoltaic glass, including AR antireflection layers and anti- Layer is penetrated, the AR antireflection layers setting is in glass body upper surface, and the reflecting layer is arranged inside glass body, the reflection Layer has certain matte catoptric arrangement using the reflecting layer with matte catoptric arrangement, the light-receiving surface in the reflecting layer.
Preferably, the AR antireflection layers are constituted using gadolinium oxide;The AR antireflection layers thickness is 100-150 nanometers.
Preferably, the AR antireflection layers preparation method includes following method:Existed using organic chemical vapor deposition method Deposited oxide gadolinium antireflection layer on the N type diffusion layers of glass body, and made annealing treatment, expand in antireflection layer and N types Silica buffer layer is formed between scattered layer, completes the preparation of AR antireflection layers.
Preferably, the reflecting layer includes dielectric stack, Ni layers of centre, the reflecting layer Ag and metal laminated, the medium Lamination includes alternately stacked silicon dioxide layer and titanium pentoxide layer, wherein the bottom of the dielectric stack is silica Layer;Described intermediate Ni layers, it is incorporated into dielectric stack surface;The reflecting layer Ag are incorporated into the intermediate Ni layer surfaces; It is described metal laminated, including alternately stacked Ni layers and Ag layers, wherein the metal laminated top layer is Ni layers.
Preferably, production method includes the following steps:
A, photovoltaic glass is embedded to several reflections with matte catoptric arrangement in advance in glass manufacturing stage by certain mode Layer;
B, the reflecting layer of embedment is in any position in addition to glass outer surface, meanwhile, relative to cell piece, the reflecting layer position with Battery grid line position consistency.
Compared with prior art, the beneficial effects of the invention are as follows:In the present invention, the light-receiving surface in reflecting layer has certain suede Face catoptric arrangement, the matte catoptric arrangement, is conducive to the light for being incident on reflecting layer, and electricity is entered after secondary or multiple reflections Pond piece surface, the present invention provide a kind of photovoltaic glass, inside the reflecting layer that has, rise to up to photovoltaic module internal cell The ray density of piece, being promoted to the output power of photovoltaic module has positive effect.
Description of the drawings
Fig. 1 is sectional view of the present invention;
Fig. 2 is reflecting layer enlarged drawing of the present invention;
Fig. 3 is the distribution schematic diagram of reflecting layer in glass in the present invention.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
- 2 are please referred to Fig.1, the present invention provides a kind of technical solution:A kind of photovoltaic glass, including AR antireflection layers 1 and reflection Layer 2, in 3 upper surface of glass body, the reflecting layer 2 is arranged inside glass body 3, described for the setting of AR antireflection layers 1 Reflecting layer 2 has certain matte reflection knot using the reflecting layer with matte catoptric arrangement, the light-receiving surface in the reflecting layer 2 Structure;The introducing in the reflecting layer of the present invention does not change glass other positions and structure, reflection layer number and width and cell piece grid line And battery strings quantity is related, that is, reflects the product that layer number is equal to cell piece grid line number and battery strings quantity.
In the present invention, AR antireflection layers 1 are constituted using gadolinium oxide;1 thickness of AR antireflection layers is 100-150 nanometers; 1 preparation method of AR antireflection layers includes following method:N types using organic chemical vapor deposition method in glass body are spread Deposited oxide gadolinium antireflection layer on layer, and made annealing treatment, form silica between antireflection layer and N type diffusion layers Buffer layer completes the preparation of AR antireflection layers.The present invention AR antireflection layer defect concentrations are low, high refractive index, thermal stability Well, energy gap is big, ensure that anti-reflective effect.
In the present invention, reflecting layer 2 includes dielectric stack, Ni layers of centre, the reflecting layer Ag and metal laminated, the medium Lamination includes alternately stacked silicon dioxide layer and titanium pentoxide layer, wherein the bottom of the dielectric stack is silica Layer;Described intermediate Ni layers, it is incorporated into dielectric stack surface;The reflecting layer Ag are incorporated into the intermediate Ni layer surfaces; It is described metal laminated, including alternately stacked Ni layers and Ag layers, wherein the metal laminated top layer is Ni layers.This Alternately stacked silicon dioxide layer and titanium pentoxide layer are invented, there is better reflecting effect compared to general dielectric layer; Using ultra-thin intermediate Ni layers, the bond properties that reflectivity substantially increases the reflecting layer Ag and dielectric stack again is neither reduced, Falling off for the reflecting layer Ag is avoided, reflecting layer of the invention has higher reflectivity and higher stability.
The production method of the present invention includes the following steps:
A, photovoltaic glass is embedded to several reflections with matte catoptric arrangement in advance in glass manufacturing stage by certain mode Layer;
B, the reflecting layer of embedment is in any position in addition to glass outer surface, meanwhile, relative to cell piece, the reflecting layer position with Battery grid line position consistency.
As shown in Fig. 3, the distribution situation of reflecting layer in glass is related with battery strings quantity and cell piece grid line quantity, Fig. 3 is cell piece grid line 5, distribution situation when battery strings quantity 4 is gone here and there.
In the present invention, the light-receiving surface in reflecting layer has certain matte catoptric arrangement, the matte catoptric arrangement, be conducive into It is mapped to the light in reflecting layer, cell piece surface is entered after secondary or multiple reflections, the present invention provides a kind of photovoltaic glass, The reflecting layer that inside has rises to the ray density up to photovoltaic module internal cell piece, to the output power of photovoltaic module Being promoted has positive effect.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (5)

1. a kind of photovoltaic glass, it is characterised in that:Including AR antireflection layers(1)The reflecting layer and(2), the AR antireflection layers(1) It is arranged in glass body(3)Upper surface, the reflecting layer(2)It is arranged in glass body(3)Inside, the reflecting layer(2)Using Reflecting layer with matte catoptric arrangement, the reflecting layer(2)Light-receiving surface have certain matte catoptric arrangement.
2. a kind of photovoltaic glass according to claim 1, it is characterised in that:The AR antireflection layers(1)Using gadolinium oxide It constitutes;The AR antireflection layers(1)Thickness is 100-150 nanometers.
3. a kind of photovoltaic glass according to claim 2, it is characterised in that:The AR antireflection layers(1)Preparation method packet Include following method:Using the deposited oxide gadolinium antireflective on the N type diffusion layers of glass body of organic chemical vapor deposition method Layer, and made annealing treatment, silica buffer layer is formed between antireflection layer and N type diffusion layers, completes AR antireflectives The preparation of layer.
4. a kind of photovoltaic glass described in accordance with the claim 3, it is characterised in that:The reflecting layer(2)Including dielectric stack, Ni layers intermediate, reflecting layer Ag and metal laminated, the dielectric stack include alternately stacked silicon dioxide layer and five oxidations three Titanium layer, wherein the bottom of the dielectric stack is silicon dioxide layer;Described intermediate Ni layers, it is incorporated into dielectric stack surface; The reflecting layer Ag are incorporated into the intermediate Ni layer surfaces;It is described metal laminated, including alternately stacked Ni layers and Ag Layer, wherein the metal laminated top layer is Ni layers.
5. realizing a kind of production method of photovoltaic glass described in claim 1, it is characterised in that:Its production method includes following Step:
A, photovoltaic glass is embedded to several reflections with matte catoptric arrangement in advance in glass manufacturing stage by certain mode Layer;
B, the reflecting layer of embedment is in any position in addition to glass outer surface, meanwhile, relative to cell piece, the reflecting layer position with Battery grid line position consistency.
CN201810279834.9A 2018-04-01 2018-04-01 A kind of photovoltaic glass Pending CN108538932A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810279834.9A CN108538932A (en) 2018-04-01 2018-04-01 A kind of photovoltaic glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810279834.9A CN108538932A (en) 2018-04-01 2018-04-01 A kind of photovoltaic glass

Publications (1)

Publication Number Publication Date
CN108538932A true CN108538932A (en) 2018-09-14

Family

ID=63482160

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810279834.9A Pending CN108538932A (en) 2018-04-01 2018-04-01 A kind of photovoltaic glass

Country Status (1)

Country Link
CN (1) CN108538932A (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1751005A (en) * 2003-02-19 2006-03-22 默克专利股份有限公司 Evaporation material for the production of average refractive optical layers
CN201336312Y (en) * 2009-01-26 2009-10-28 河南华美新材料科技有限公司 Double-sided anti-reflection film solar energy photovoltaic glass
CN103441175A (en) * 2013-08-13 2013-12-11 苏州盛康光伏科技有限公司 Crystalline silicon photovoltaic module
WO2013182352A2 (en) * 2012-06-05 2013-12-12 Robert Bosch Gmbh Solar module and method for the production thereof
CN203466206U (en) * 2013-08-13 2014-03-05 苏州盛康光伏科技有限公司 Crystalline silicon photovoltaic assembly
CN103746008A (en) * 2014-01-23 2014-04-23 通用光伏能源(烟台)有限公司 Antireflection layer for solar cell and preparing process of antireflection layer
EP2876694A1 (en) * 2013-11-20 2015-05-27 Samsung SDI Co., Ltd. Solar cell
CN207097836U (en) * 2017-07-06 2018-03-13 泰州隆基乐叶光伏科技有限公司 A kind of anti-PID photovoltaic glass

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1751005A (en) * 2003-02-19 2006-03-22 默克专利股份有限公司 Evaporation material for the production of average refractive optical layers
CN201336312Y (en) * 2009-01-26 2009-10-28 河南华美新材料科技有限公司 Double-sided anti-reflection film solar energy photovoltaic glass
WO2013182352A2 (en) * 2012-06-05 2013-12-12 Robert Bosch Gmbh Solar module and method for the production thereof
CN103441175A (en) * 2013-08-13 2013-12-11 苏州盛康光伏科技有限公司 Crystalline silicon photovoltaic module
CN203466206U (en) * 2013-08-13 2014-03-05 苏州盛康光伏科技有限公司 Crystalline silicon photovoltaic assembly
EP2876694A1 (en) * 2013-11-20 2015-05-27 Samsung SDI Co., Ltd. Solar cell
CN103746008A (en) * 2014-01-23 2014-04-23 通用光伏能源(烟台)有限公司 Antireflection layer for solar cell and preparing process of antireflection layer
CN207097836U (en) * 2017-07-06 2018-03-13 泰州隆基乐叶光伏科技有限公司 A kind of anti-PID photovoltaic glass

Similar Documents

Publication Publication Date Title
CN102544174B (en) Solar cell assembly for increasing light energy utilization ratio
WO2009116578A1 (en) Solar cell
TW201025637A (en) Solar cell
TW201021229A (en) Solar cell having reflective structure
JP2003142709A (en) Laminated solar battery and method for manufacturing the same
CN208548372U (en) A kind of double-junction solar battery
CN110061136A (en) A kind of back-contact perovskite solar cell and preparation method thereof
CN213601878U (en) Solar cell and photovoltaic module
CN205211772U (en) High resistant photovoltaic module that waits
CN204538038U (en) Promote the solar components of the efficiency of light energy utilization
CN108538932A (en) A kind of photovoltaic glass
CN102938430B (en) Comprise the silica-based many knot stacked solar cell, cascade solar cells of flexible substrate and the manufacture method thereof in intermediate layer
CN203071106U (en) Backplane and photovoltaic assembly
CN206259361U (en) A kind of back electrode structure of silicon-based film solar cells
CN105405910A (en) Heterojunction solar cell, preparation method thereof and solar cell module
CN111370580A (en) Solar cell with hole transport layer
CN202004002U (en) Laminated antireflection film for monocrystal silicon solar cell
CN109065732A (en) A kind of perovskite battery and its glass cover-plate having both wide spectrum dimmer reflecting and ultraviolet filtering function
CN209434211U (en) A kind of two-sided double-glass solar energy assembly
US20120017982A1 (en) Thin Film Silicon Solar Cell and Manufacturing Method Thereof
CN103000705A (en) Crystalline silicon solar cell antireflection film
CN106653902A (en) Solar battery assembly
TWI470814B (en) Solar cell
CN101764171A (en) Solar energy battery with reflection structure
CN211879397U (en) High-light conversion efficiency and high-heat-dissipation high-power dual-glass assembly

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180914

RJ01 Rejection of invention patent application after publication