CN108530867A - A kind of biodegradable mosquito-proof disposable slippers bi-component material for sole of shoe - Google Patents
A kind of biodegradable mosquito-proof disposable slippers bi-component material for sole of shoe Download PDFInfo
- Publication number
- CN108530867A CN108530867A CN201710119418.8A CN201710119418A CN108530867A CN 108530867 A CN108530867 A CN 108530867A CN 201710119418 A CN201710119418 A CN 201710119418A CN 108530867 A CN108530867 A CN 108530867A
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- CN
- China
- Prior art keywords
- parts
- component
- sole
- shoe
- super
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
- C08L71/03—Polyepihalohydrins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of biodegradable mosquito-proof disposable slippers bi-component material for sole of shoe provided by the invention, including mass ratio (2.1 2.9):1 component A and component B；Wherein, the component A is made of the component of following weight ratio：21.5 23.6 parts of nitrile rubber, 21.5 23.6 parts of phenol formaldehyde resin, 5 10 parts of dioctyl phthalate, 11.5 17.6 parts of pine tar, 11.5 17.6 parts of polydimethyl siloxane fluid, 11.6 16.9 parts of 2 naphthylamines of N phenyl；The component B is made of the components of following parts：21.5 23.6 parts of Chloropropylene epoxide homopolymer, 11.6 16.9 parts of auxiliary stabilizer, 11.6 16.9 parts of lubricant, 11.6 16.9 parts of aliphatic polysulfide, separates 11.5 17.6 parts of diacid dibenzyl ester, 11.6 16.9 parts of super Super-conductive carbon, 1~3 part of light magnesium oxide at 11.5 17.6 parts of red mud.Bi-component material for sole of shoe preparation process is simple, of low cost, good permeability, elasticity is good, light-weight, flexibility is good, can be effectively mosquito-proof and biodegradable, is applicable to disposable slippers sole.
Description
Technical field
The invention belongs to daily necessities field, more particularly to a kind of biodegradable mosquito-proof disposable slippers bi-component sole
Material and preparation method thereof.
Background technology
There are many type of bi-component material for sole of shoe, are generally divided into natural class bi-component material for sole of shoe and synthesis class bi-component shoes
Two kinds of bottom material.Natural class bi-component material for sole of shoe includes natural bottom leather, bamboo and wood material etc., synthesizes class bi-component material for sole of shoe packet
Include rubber, PU materials, Chloropropylene epoxide homopolymer synthetic resin etc..The common characteristic of bi-component material for sole of shoe has wear-resisting, water-fast, bullet
Property it is good, be easy to be unlikely to deform after suitable foot type, sizing etc. condition.Synthesis class bi-component material for sole of shoe is most widely used at present
A kind of footwear material.
Currently on the market existing footwear material and be packed for antidetonation sheet material main ingredient Chloropropylene epoxide homopolymer (polyvinyl chloride),
PE (polyethylene), nitrile rubber (polypropylene), EVA (ethene-vinyl acetate copolymer), rubber etc. are petrochemicals,
They belong to high polymer, and because the degree of polymerization is larger, intermolecular force is strong, and macromolecular chain is difficult to be broken decomposition, so as to cause having
Footwear material and be packed for antidetonation sheet material have non-biodegradable, pollute the environment.Oil is non-renewable resources on the earth simultaneously,
It is non-renewable and of high cost that this so that petroleum product has.Meanwhile summer is easy using step by bite by mosquitos, because
This also needs to mosquito-proof.
Invention content
Technical problem：In order to solve the defects of prior art, the present invention provides a kind of biodegradable mosquito-proof primary
Property slippers bi-component material for sole of shoe.
Technical solution：A kind of biodegradable mosquito-proof disposable slippers bi-component material for sole of shoe provided by the invention, packet
Include mass ratio (2.1-2.9):1 component A and component B；Wherein, the component A is made of the component of following weight ratio：Butyronitrile rubber
21.5-23.6 parts of glue, 21.5-23.6 parts of phenol formaldehyde resin, 5-10 parts of dioctyl phthalate, pine tar 11.5-17.6
Part, 11.5-17.6 parts of polydimethyl siloxane fluid, 11.6-16.9 parts of N- phenyl-2-naphthylamines；The component B by following parts by weight group
Part is made：21.5-23.6 parts of Chloropropylene epoxide homopolymer, 11.5-17.6 parts of red mud, 11.6-16.9 parts of auxiliary stabilizer, lubricant
11.6-16.9 parts, 11.6-16.9 parts of aliphatic polysulfide, separate 11.5-17.6 parts of diacid dibenzyl ester, super Super-conductive carbon
11.6-16.9 1~3 part of part, light magnesium oxide.
As an improvement, the biodegradable mosquito-proof disposable slippers bi-component material for sole of shoe includes mass ratio 3:1
Component A and component B；Wherein, the component A is made of the component of following weight ratio：25 parts of nitrile rubber, phenol formaldehyde resin 25
Part, 7 parts of dioctyl phthalate, 15 parts of pine tar, 15 parts of polydimethyl siloxane fluid, 2 parts of N- phenyl-2-naphthylamines；The component B
It is made of the components of following parts：25 parts of Chloropropylene epoxide homopolymer, 15 parts of red mud, 2 parts of auxiliary stabilizer, 2 parts of lubricant, fat
2 parts of race's polysulfide separates 15 parts of diacid dibenzyl ester, 2 parts of super Super-conductive carbon, 2 parts of light magnesium oxide.
The present invention also provides a kind of preparation method of biodegradable mosquito-proof disposable slippers bi-component material for sole of shoe,
Include the following steps：
(1) each component of component A is weighed in proportion, mixing；The each component of component B is weighed in proportion, mixing；
(2) each component in component A is added in autoclave, at 60-70 DEG C, reacts 2-3h, be cooled to room temperature, obtain pre-
Aggressiveness；
(3) the component B of performed polymer and 2/3 is uniformly mixed；It is added in sole casting machine batch can, is warming up to 60-70 DEG C, perseverance
Warm 5-10min；It is cooled to 55-60 DEG C, continuously adds remaining 1/3 component B, constant temperature 11.5-17.6min；
(4) by step (3) product coating release agent, drying, cast on die for shoe-sole, 10-12min is kept the temperature, is demoulded, i.e.,
.
Advantageous effect：Bi-component material for sole of shoe preparation process provided by the invention is simple, of low cost, good permeability, bullet
Property it is good, light-weight, flexibility is good, can effectively it is mosquito-proof and biodegradable, be applicable to disposable slippers sole.
Specific implementation mode
The mosquito-proof disposable slippers bi-component material for sole of shoe biodegradable to the present invention further illustrates below.
Biodegradable mosquito-proof disposable slippers bi-component material for sole of shoe, including mass ratio 1:2 component A and component B；
Wherein, the component A is made of the component of following weight ratio：25 parts of nitrile rubber, 25 parts of phenol formaldehyde resin, phthalic acid
7 parts of dioctyl ester, 15 parts of pine tar, 15 parts of polydimethyl siloxane fluid, 2 parts of N- phenyl-2-naphthylamines；The component B is by following parts by weight
Component be made：25 parts of Chloropropylene epoxide homopolymer, 15 parts of red mud, 2 parts of auxiliary stabilizer, 2 parts of lubricant, aliphatic polysulfide 2
Part separates 15 parts of diacid dibenzyl ester, 2 parts of super Super-conductive carbon, 2 parts of light magnesium oxide.
Preparation method includes the following steps：
(1) each component of component A is weighed in proportion, mixing；The each component of component B is weighed in proportion, mixing；
(2) each component in component A is added in autoclave, at 60-70 DEG C, reacts 2-3h, be cooled to room temperature, obtain pre-
Aggressiveness；
(3) the component B of performed polymer and 2/3 is uniformly mixed；It is added in sole casting machine batch can, is warming up to 60-70 DEG C, perseverance
Warm 5-10min；It is cooled to 55-60 DEG C, continuously adds remaining 1/3 component B, constant temperature 11.5-17.6min；
(4) by step (3) product coating release agent, drying, cast on die for shoe-sole, 10-12min is kept the temperature, is demoulded, i.e.,
.
Claims (2)
1. a kind of biodegradable mosquito-proof disposable slippers bi-component material for sole of shoe, it is characterised in that：Including mass ratio (2.1-
2.9):1 component A and component B；Wherein, the component A is made of the component of following weight ratio：Nitrile rubber 21.5-23.6
Part, 21.5-23.6 parts of phenol formaldehyde resin, 5-10 parts of dioctyl phthalate, 11.5-17.6 parts of pine tar, poly dimethyl
11.5-17.6 parts of silicone oil, 11.6-16.9 parts of N- phenyl-2-naphthylamines；The component B is made of the components of following parts：Homopolymerization
21.5-23.6 parts of epichlorohydrin rubber, 11.5-17.6 parts of red mud, 11.6-16.9 parts of auxiliary stabilizer, 11.6-16.9 parts of lubricant,
11.6-16.9 parts of aliphatic polysulfide separates 11.5-17.6 parts of diacid dibenzyl ester, is Super-conductive carbon 11.6-16.9 parts super, is light
1~3 part of matter magnesia.
2. a kind of biodegradable mosquito-proof disposable slippers bi-component material for sole of shoe according to claim 1, feature
It is：Including mass ratio 3:1 component A and component B；Wherein, the component A is made of the component of following weight ratio：Butyronitrile rubber
25 parts of glue, 25 parts of phenol formaldehyde resin, 7 parts of dioctyl phthalate, 15 parts of pine tar, 15 parts of polydimethyl siloxane fluid, N- benzene
2 parts of base -2- naphthylamines；The component B is made of the components of following parts：25 parts of Chloropropylene epoxide homopolymer, 15 parts of red mud, auxiliary are steady
Determine 2 parts of agent, 2 parts of lubricant, 2 parts of aliphatic polysulfide, separate 15 parts of diacid dibenzyl ester, 2 parts of super Super-conductive carbon, lightweight oxidation
2 parts of magnesium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710119418.8A CN108530867A (en) | 2017-03-02 | 2017-03-02 | A kind of biodegradable mosquito-proof disposable slippers bi-component material for sole of shoe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710119418.8A CN108530867A (en) | 2017-03-02 | 2017-03-02 | A kind of biodegradable mosquito-proof disposable slippers bi-component material for sole of shoe |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108530867A true CN108530867A (en) | 2018-09-14 |
Family
ID=63488894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710119418.8A Pending CN108530867A (en) | 2017-03-02 | 2017-03-02 | A kind of biodegradable mosquito-proof disposable slippers bi-component material for sole of shoe |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108530867A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111777844A (en) * | 2020-07-21 | 2020-10-16 | 贵州大学 | Biodegradable polyester polymer/red mud composite material with high filling and low cost and controllable biodegradation and preparation method thereof |
-
2017
- 2017-03-02 CN CN201710119418.8A patent/CN108530867A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111777844A (en) * | 2020-07-21 | 2020-10-16 | 贵州大学 | Biodegradable polyester polymer/red mud composite material with high filling and low cost and controllable biodegradation and preparation method thereof |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180914 |