CN105968442A - Preparation method of waterproof and anti-skidding sole material for rain shoes - Google Patents
Preparation method of waterproof and anti-skidding sole material for rain shoes Download PDFInfo
- Publication number
- CN105968442A CN105968442A CN201610572000.8A CN201610572000A CN105968442A CN 105968442 A CN105968442 A CN 105968442A CN 201610572000 A CN201610572000 A CN 201610572000A CN 105968442 A CN105968442 A CN 105968442A
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- CN
- China
- Prior art keywords
- parts
- component
- agent
- sole
- shoe
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a preparation method of a waterproof and anti-skidding sole material for rain shoes. The waterproof and anti-skidding sole material is prepared from a component A and a component B, and the mass ratio of the component A to the component B is equal to (2-4): 1, wherein the component A is prepared from the following components in parts by weight: 80-100 parts of natural rubber, 30-40 parts of butadiene rubber, 10-20 parts of nitrile-butadiene rubber, 80-94 parts of chloroprene rubber, 66-72 parts of hydroxylated polypropylene, 16-22 parts of polyolefin elastomer, 15-19 parts of glass fiber, 4-6 parts of a bridging agent, 1-3 parts of a bridging assistant agent and 10-16 parts of pentane; and the component B is prepared from the following components in parts by weight: 20-33 parts of white carbon black, 23-26 parts of calcium-zinc salt, 9-15 parts of tribasic lead sulfate, 11-17 parts of a plasticizer DOP, 25-36 parts of olive oil, 3-10 parts of magnesium oxide, 7-11 parts of stearic acid, 9-14 parts of polyethylene glycol, 11-13 parts of dioctyl adipate, 3-5 parts of an anti-aging agent, 1-3 parts of an active agent, 1-4 parts of filler, 2-3 parts of another active agent and 1-4 parts of a foaming agent. The sole material is simple in preparation technology, low in cost and good in air permeability and elasticity, thus being suitable for soles of sports shoes.
Description
Technical field
The invention belongs to daily necessities field, particularly to the rain boots material for sole of shoe and preparation method thereof of a kind of water-proof skid-proof.
Background technology
The kind of material for sole of shoe is a lot, is generally divided into natural class material for sole of shoe and synthesis class material for sole of shoe two kinds.Natural class material for sole of shoe includes that natural bottom leather, bamboo and wood material etc., synthesis class material for sole of shoe include rubber, PU material, PVC synthetic resin etc..The common characteristic of material for sole of shoe possesses wear-resisting, water-fast, good springiness, be easily suitable for foot type, sizing after be unlikely to deform etc. condition.Synthesis class material for sole of shoe is a most widely used class footwear material at present.
Material for sole of shoe is mostly synthetic rubber the most on the market, uses wide and cheap.In order to adapt to different operating environment, so can be further improved performance in synthetic rubber, wherein waterproof footwear is for excess surface water or the operation that dabbles, has miner's waterproof footwear, an Aquatic product special purpose shoes etc., and existing rubber soles is not water proofing property bad.Additionally, existing rubber overshoes shoe soles slip stopping effect is poor, the ground having water or oil is easily fallen down.
Summary of the invention
Technical problem:In order to solve the defect of prior art, the invention provides the rain boots material for sole of shoe of a kind of water-proof skid-proof.
Technical scheme:The rain boots material for sole of shoe of a kind of water-proof skid-proof that the present invention provides, including mass ratio (2-4): the component A and component B of 1；Wherein, described component A is made up of the component of following weight ratio: natural rubber 80-100 part, butadiene rubber 30-40 part, nitrile rubber 10-20 part, neoprene 80-94 part, hydroxylating polypropylene 66～72, polyolefin elastomer 16～22 parts, glass fibre 15～19 parts, bridging agent 4～6 parts, bridge formation auxiliary agent 1～3 parts, pentane 10-16 part；Described component B is made up of the component of following weight portion: white carbon 20-33 part, calcium zinc salt 23-26 part, tribasic lead sulfate 9-15 part, plasticizer DOP 11-17 part, olive oil 25-36 part, magnesium oxide 3-10 part, stearic acid 7-11 part, Polyethylene Glycol 9-14 part, adipic acid dibutyl ester 11-13 part, age resistor 3-5 part, activating agent 1-3 part, inserts 1～4 parts, activating agent 2～3 parts, foaming agent 1～4 parts.
As improvement, the rain boots material for sole of shoe of described water-proof skid-proof includes the component A and component B of mass ratio 3:1；Wherein, described component A is made up of the component of following weight ratio: natural rubber
90 parts, butadiene rubber 35 parts, nitrile rubber 15 parts, neoprene 86 parts, hydroxylating polypropylene 69 parts, polyolefin elastomer 19 parts, glass fibre 17 parts, bridging agent 5 parts, bridge formation auxiliary agent 2 parts, pentane 13 parts；Described component B is made up of the component of following weight portion: white carbon 27 parts, calcium zinc salt 24 parts, tribasic lead sulfate 11 parts, plasticizer DOP 15 parts, 29 parts of olive oil, magnesium oxide 8 parts, stearic acid 9 parts, Polyethylene Glycol 11 parts, adipic acid dibutyl ester 12 parts, 4 parts of age resistor, activating agent 2 parts, inserts 3 parts, activating agent 2 parts, foaming agent 3 parts.
Present invention also offers the preparation method of the rain boots material for sole of shoe of a kind of water-proof skid-proof, comprise the following steps:
(1) each component of component A is weighed in proportion, mixes；Each component of component B is weighed in proportion, mixes；
(2) each component in component A is added in autoclave, at 60-70 DEG C, react 2-3h, be cooled to room temperature, obtain performed polymer；
(3) by performed polymer and the component B mix homogeneously of 2/3；Add in sole casting machine batch can, be warming up to 60-70 DEG C, constant temperature 5-10min；It is cooled to 55-60 DEG C, continuously adds the component B of remaining 1/3, constant temperature 10-20min；
(4) by step (3) product on die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, the demoulding, to obtain final product.
Beneficial effect:The present invention provide material for sole of shoe preparation technology is simple, with low cost, good permeability, elasticity is good, lightweight, flexibility is good, can effective deodorant, be applicable to athletic shoe sole.
Detailed description of the invention
Below the rain boots material for sole of shoe of water-proof skid-proof of the present invention is further illustrated.
The rain boots material for sole of shoe of water-proof skid-proof, including the component A and component B of mass ratio 3:1；Wherein, described component A is made up of the component of following weight ratio: natural rubber
90 parts, butadiene rubber 35 parts, nitrile rubber 15 parts, neoprene 86 parts, hydroxylating polypropylene 69 parts, polyolefin elastomer 19 parts, glass fibre 17 parts, bridging agent 5 parts, bridge formation auxiliary agent 2 parts, pentane 13 parts；Described component B is made up of the component of following weight portion: white carbon 27 parts, calcium zinc salt 24 parts, tribasic lead sulfate 11 parts, plasticizer DOP 15 parts, 29 parts of olive oil, magnesium oxide 8 parts, stearic acid 9 parts, Polyethylene Glycol 11 parts, adipic acid dibutyl ester 12 parts, 4 parts of age resistor, activating agent 2 parts, inserts 3 parts, activating agent 2 parts, foaming agent 3 parts.
Its preparation method, comprises the following steps:
(1) each component of component A is weighed in proportion, mixes；Each component of component B is weighed in proportion, mixes；
(2) each component in component A is added in autoclave, at 60-70 DEG C, react 2-3h, be cooled to room temperature, obtain performed polymer；
(3) by performed polymer and the component B mix homogeneously of 2/3；Add in sole casting machine batch can, be warming up to 60-70 DEG C, constant temperature 5-10min；It is cooled to 55-60 DEG C, continuously adds the component B of remaining 1/3, constant temperature 10-20min；
(4) by step (3) product on die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, the demoulding, to obtain final product.
Claims (2)
1. the preparation method of the rain boots material for sole of shoe of a water-proof skid-proof, it is characterised in that: comprise the following steps:
(1) each component of component A is weighed in proportion, mixes；Each component of component B is weighed in proportion, mixes；
(2) each component in component A is added in autoclave, at 60-70 DEG C, react 2-3h, be cooled to room temperature, obtain performed polymer；
(3) by performed polymer and the component B mix homogeneously of 2/3；Add in sole casting machine batch can, be warming up to 60-70 DEG C, constant temperature 5-10min；It is cooled to 55-60 DEG C, continuously adds the component B of remaining 1/3, constant temperature 10-20min；
(4) by step (3) product on die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, the demoulding, to obtain final product；
Wherein, the mass ratio of component A and component B is (2-4): 1；Described component A is made up of the component of following weight ratio: natural rubber 80-100 part, butadiene rubber 30-40 part, nitrile rubber 10-20 part, neoprene 80-94 part, hydroxylating polypropylene 66～72 parts, polyolefin elastomer 16～22 parts, glass fibre 15～19 parts, bridging agent 4～6 parts, bridge formation auxiliary agent 1～3 parts, pentane 10-16 part；Described component B is made up of the component of following weight portion: white carbon 20-33 part, calcium zinc salt 23-26 part, tribasic lead sulfate 9-15 part, plasticizer DOP 11-17 part, olive oil 25-36 part, magnesium oxide 3-10 part, stearic acid 7-11 part, Polyethylene Glycol 9-14 part, adipic acid dibutyl ester 11-13 part, age resistor 3-5 part, activating agent 1-3 part, inserts 1～4 parts, activating agent 2～3 parts, foaming agent 1～4 parts.
The preparation method of the rain boots material for sole of shoe of a kind of water-proof skid-proof the most according to claim 1, it is characterised in that: include the component A and component B of mass ratio 3:1；Wherein, described component A is made up of the component of following weight ratio: natural rubber 90 parts, butadiene rubber 35 parts, nitrile rubber 15 parts, neoprene 86 parts, hydroxylating polypropylene 69 parts, polyolefin elastomer 19 parts, glass fibre 17 parts, bridging agent 5 parts, bridge formation auxiliary agent 2 parts, pentane 13 parts；Described component B is made up of the component of following weight portion: white carbon 27 parts, calcium zinc salt 24 parts, tribasic lead sulfate 11 parts, plasticizer DOP 15 parts, 29 parts of olive oil, magnesium oxide 8 parts, stearic acid 9 parts, Polyethylene Glycol 11 parts, adipic acid dibutyl ester 12 parts, 4 parts of age resistor, activating agent 2 parts, inserts 3 parts, activating agent 2 parts, foaming agent 3 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610572000.8A CN105968442A (en) | 2016-07-20 | 2016-07-20 | Preparation method of waterproof and anti-skidding sole material for rain shoes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610572000.8A CN105968442A (en) | 2016-07-20 | 2016-07-20 | Preparation method of waterproof and anti-skidding sole material for rain shoes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105968442A true CN105968442A (en) | 2016-09-28 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610572000.8A Pending CN105968442A (en) | 2016-07-20 | 2016-07-20 | Preparation method of waterproof and anti-skidding sole material for rain shoes |
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|---|---|
| CN (1) | CN105968442A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107556564A (en) * | 2017-10-08 | 2018-01-09 | 界首市旭升塑胶制品有限公司 | A kind of production technology of the rain boots of waterproof and breathable |
| CN112280234A (en) * | 2020-10-10 | 2021-01-29 | 南京和润新材料科技有限公司 | TPR material for sole raw material and preparation method thereof |
-
2016
- 2016-07-20 CN CN201610572000.8A patent/CN105968442A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107556564A (en) * | 2017-10-08 | 2018-01-09 | 界首市旭升塑胶制品有限公司 | A kind of production technology of the rain boots of waterproof and breathable |
| CN107556564B (en) * | 2017-10-08 | 2021-03-30 | 界首市旭升塑胶制品有限公司 | Production process of waterproof and breathable rain shoes |
| CN112280234A (en) * | 2020-10-10 | 2021-01-29 | 南京和润新材料科技有限公司 | TPR material for sole raw material and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160928 |
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| WD01 | Invention patent application deemed withdrawn after publication |