CN106046466A - Acid-alkali-resistant anti-aging sole material - Google Patents
Acid-alkali-resistant anti-aging sole material Download PDFInfo
- Publication number
- CN106046466A CN106046466A CN201610571906.8A CN201610571906A CN106046466A CN 106046466 A CN106046466 A CN 106046466A CN 201610571906 A CN201610571906 A CN 201610571906A CN 106046466 A CN106046466 A CN 106046466A
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- CN
- China
- Prior art keywords
- parts
- component
- acid
- alkali
- sole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides an acid-alkali-resistant anti-aging sole material. The material comprises a component A and a component B in the mass ratio of (2-4):1, wherein the component A is prepared from the following components in parts by weight: 20 to 40 parts of natural rubber, 50 to 60 parts of cis-polybutadiene, 30 to 40 parts of nitrile-butadiene rubber, 80 to 90 parts of chloroprene rubber, 15 to 19 parts of glass fibres and 10 to 16 parts of pentane; the component B is prepared from the following components in parts by weight: 15 to 36 parts of white carbon black, 16 to 26 parts of calcium-zinc salt, 9 to 15 parts of tribasic lead sulphate, 11 to 17 parts of barium sulphate, 3 to 10 parts of magnesium oxide, 7 to 11 parts of stearic acid, 9 to 14 parts of polyethylene glycol, 11 to 13 parts of a vulcanization accelerator, 3 to 5 parts of an anti-aging agent and 1 to 4 parts of a filling material. The sole material is simple in preparation process, low in cost, high in elasticity, light in weight and good in softness, and can effectively resist acid and alkali and prevent aging.
Description
Technical field
The invention belongs to daily necessities field, particularly to a kind of acid and alkali-resistance aging-resistant material for sole of shoe and preparation method thereof.
Background technology
The kind of material for sole of shoe is a lot, is generally divided into natural class material for sole of shoe and synthesis class material for sole of shoe two kinds.Natural class
Material for sole of shoe includes that natural bottom leather, bamboo and wood material etc., synthesis class material for sole of shoe include rubber, PU material, PVC synthetic resin etc..Footwear
The common characteristic of bottom material possesses wear-resisting, water-fast, good springiness, be easily suitable for foot type, sizing after be unlikely to deform etc. condition.At present
Synthesis class material for sole of shoe is a most widely used class footwear material.
Sole industry is in the period of fast development, but owing to its hydrolysis and acid-proof alkaline are poor and have impact on it
Use.Therefore, the decay resistance of research material for sole of shoe, extend the life-span of material for sole of shoe, material for sole of shoe is all had the heaviest
The meaning wanted.Additionally, under the adverse circumstances such as industrial plant, sole is also easy to aging.
Summary of the invention
Technical problem: in order to solve the defect of prior art, the invention provides a kind of acid and alkali-resistance aging-resistant sole material
Material.
Technical scheme: a kind of acid and alkali-resistance aging-resistant material for sole of shoe that the present invention provides, including mass ratio (2-4): the group of 1
Part A and component B；Wherein, described component A is made up of the component of following weight ratio: natural rubber 20-40 part, butadiene rubber 50-60
Part, nitrile rubber 30-40 part, neoprene 80-90 part, glass fibre 15～19 parts, pentane 10-16 part；Described component B by
The component of following weight portion is made: white carbon 15-36 part, calcium zinc salt 16-26 part, tribasic lead sulfate 9-15 part, barium sulfate
11-17 part, magnesium oxide 3-10 part, stearic acid 7-11 part, Polyethylene Glycol 9-14 part, sulfuration kicker 11-13 part, age resistor 3-
5 parts, inserts 1～4 parts.
As improvement, described acid and alkali-resistance aging-resistant material for sole of shoe includes the component A and component B of mass ratio 3:1；Wherein,
Described component A is made up of the component of following weight ratio: natural rubber 20-40 part, butadiene rubber 55 parts, nitrile rubber 35 parts, chlorine
Buna 85 parts, glass fibre 17 parts, pentane 13 parts；Described component B is made up of the component of following weight portion: white carbon 25
Part, calcium zinc salt 21 parts, tribasic lead sulfate 14 parts, 13 parts of barium sulfate, magnesium oxide 7 parts, stearic acid 8 parts, Polyethylene Glycol 11
Part, sulfuration kicker 12 parts, 4 parts of age resistor, inserts 3 parts.
Present invention also offers the preparation method of a kind of acid and alkali-resistance aging-resistant material for sole of shoe, comprise the following steps:
(1) each component of component A is weighed in proportion, mixes；Each component of component B is weighed in proportion, mixes；
(2) each component in component A is added in autoclave, at 60-70 DEG C, react 2-3h, be cooled to room temperature, obtain pre-polymerization
Body；
(3) by performed polymer and the component B mix homogeneously of 2/3；Add in sole casting machine batch can, be warming up to 60-70 DEG C, constant temperature 5-
10min；It is cooled to 55-60 DEG C, continuously adds the component B of remaining 1/3, constant temperature 10-20min；
(4) by step (3) product on die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, the demoulding, to obtain final product.
Beneficial effect: the material for sole of shoe preparation technology that the present invention provides is simple, with low cost, elastic good, lightweight, soft
Property is good, can effective acid and alkali-resistance aging resistance.
Detailed description of the invention
Below acid and alkali-resistance aging-resistant material for sole of shoe of the present invention is further illustrated.
Acid and alkali-resistance aging-resistant material for sole of shoe, including the component A and component B of mass ratio 3:1；Wherein, described component A by with
The component of lower weight ratio is made: natural rubber 20-40 part, butadiene rubber 55 parts, nitrile rubber 35 parts, neoprene 85 parts, glass
Glass fiber 17 parts, pentane 13 parts；Described component B is made up of the component of following weight portion: white carbon 25 parts, calcium zinc salt 21 parts,
Tribasic lead sulfate 14 parts, 13 parts of barium sulfate, magnesium oxide 7 parts, stearic acid 8 parts, Polyethylene Glycol 11 parts, sulfuration kicker 12
Part, 4 parts of age resistor, inserts 3 parts.
Its preparation method, comprises the following steps:
(1) each component of component A is weighed in proportion, mixes；Each component of component B is weighed in proportion, mixes；
(2) each component in component A is added in autoclave, at 60-70 DEG C, react 2-3h, be cooled to room temperature, obtain pre-polymerization
Body；
(3) by performed polymer and the component B mix homogeneously of 2/3；Add in sole casting machine batch can, be warming up to 60-70 DEG C, constant temperature 5-
10min；It is cooled to 55-60 DEG C, continuously adds the component B of remaining 1/3, constant temperature 10-20min；
(4) by step (3) product on die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, the demoulding, to obtain final product.
Claims (2)
1. an acid and alkali-resistance aging-resistant material for sole of shoe, it is characterised in that: include mass ratio (2-4): the component A and component B of 1；
Wherein, described component A is made up of the component of following weight ratio: described component A is made up of the component of following weight ratio: natural rubber
20-40 part, butadiene rubber 50-60 part, nitrile rubber 30-40 part, neoprene 80-90 part, glass fibre 15～19 parts, penta
Alkane 10-16 part；Described component B is made up of the component of following weight portion: white carbon 15-36 part, calcium zinc salt 16-26 part, three alkali
Formula lead sulfate 9-15 part, barium sulfate 11-17 part, magnesium oxide 3-10 part, stearic acid 7-11 part, Polyethylene Glycol 9-14 part, sulfuration
Kicker 11-13 part, age resistor 3-5 part, inserts 1～4 parts.
A kind of acid and alkali-resistance aging-resistant material for sole of shoe the most according to claim 1, it is characterised in that: include mass ratio 3:1
Component A and component B；Wherein, described component A is made up of the component of following weight ratio: natural rubber 20-40 part, butadiene rubber
55 parts, nitrile rubber 35 parts, neoprene 85 parts, glass fibre 17 parts, pentane 13 parts；Described component B is by following weight portion
Component is made: white carbon 25 parts, calcium zinc salt 21 parts, tribasic lead sulfate 14 parts, 13 parts of barium sulfate, magnesium oxide 7 parts, tristearin
Acid 8 parts, Polyethylene Glycol 11 parts, sulfuration kicker 12 parts, 4 parts of age resistor, inserts 3 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610571906.8A CN106046466A (en) | 2016-07-20 | 2016-07-20 | Acid-alkali-resistant anti-aging sole material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610571906.8A CN106046466A (en) | 2016-07-20 | 2016-07-20 | Acid-alkali-resistant anti-aging sole material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106046466A true CN106046466A (en) | 2016-10-26 |
Family
ID=57188279
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610571906.8A Pending CN106046466A (en) | 2016-07-20 | 2016-07-20 | Acid-alkali-resistant anti-aging sole material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106046466A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107474341A (en) * | 2017-08-18 | 2017-12-15 | 晋江市池店镇娇鹏贸易有限公司 | A kind of formula for making the anti-aging heat-insulated sole of acid and alkali-resistance |
| CN107641225A (en) * | 2017-08-18 | 2018-01-30 | 西北矿冶研究院 | Sole material made of acid-leaching modified white ash |
| CN108440810A (en) * | 2018-03-20 | 2018-08-24 | 唐旭 | A kind of damping vibration combination object and the shoes using the damping vibration combination object |
| CN109294017A (en) * | 2018-10-29 | 2019-02-01 | 南京航空航天大学溧水仿生产业研究院有限公司 | A kind of wear-resisting acid and alkali-resistance rubber material |
-
2016
- 2016-07-20 CN CN201610571906.8A patent/CN106046466A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107474341A (en) * | 2017-08-18 | 2017-12-15 | 晋江市池店镇娇鹏贸易有限公司 | A kind of formula for making the anti-aging heat-insulated sole of acid and alkali-resistance |
| CN107641225A (en) * | 2017-08-18 | 2018-01-30 | 西北矿冶研究院 | Sole material made of acid-leaching modified white ash |
| CN108440810A (en) * | 2018-03-20 | 2018-08-24 | 唐旭 | A kind of damping vibration combination object and the shoes using the damping vibration combination object |
| CN109294017A (en) * | 2018-10-29 | 2019-02-01 | 南京航空航天大学溧水仿生产业研究院有限公司 | A kind of wear-resisting acid and alkali-resistance rubber material |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161026 |