CN101524195A - Multifunctional safety shoes with oil resistance, insulation, acid and alkali resistance and high temperature resistance - Google Patents
Multifunctional safety shoes with oil resistance, insulation, acid and alkali resistance and high temperature resistance Download PDFInfo
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- CN101524195A CN101524195A CN200910030815A CN200910030815A CN101524195A CN 101524195 A CN101524195 A CN 101524195A CN 200910030815 A CN200910030815 A CN 200910030815A CN 200910030815 A CN200910030815 A CN 200910030815A CN 101524195 A CN101524195 A CN 101524195A
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Abstract
The invention discloses a pair of multifunctional safety shoes with oil resistance, insulation, acid and alkali resistance and high temperature resistance. A sole is made from the following raw materials by weight percent: 17.5-52.5 percent of oil-resistant glue, 7.5-22.5 percent of natural gum, 10-30 percent of carbon soot, 5-15 percent of pottery clay, 5-15 percent of barium sulfate, 0.7-2.1 percent of stearic acid, 2.5-7.5 percent of dibutyl ester, 0.25-0.75 percent of accelerant M, 0.25-0.75 percent of accelerant DM, 0.5-1.5 percent of sulfur, 0.1-0.3 percent of TMTP and 0.7-2.1 percent of Vaseline. The multifunctional safety shoes have the advantages of oil resistance, insulation, acid and alkali resistance and high temperature resistance property.
Description
Technical field
The present invention relates to a kind of multifunctional safety shoes, particularly, the present invention relates to a kind of oil resistant, insulation, acid and alkali-resistance, high temperature resistant multifunctional safety shoes.
Background technology
Known owing to its sole lacks flexibility, and weight is bigger with the made various footwear of making through general sulfidization molding technology of rubber soles, quite feels uncomfortable when therefore wearing.Publication number is the production technology that has proposed a kind of rubber pange moulding sole in the application for a patent for invention prospectus of CN1071115A.Wherein mention the hole-forming material and the wear-resistant material that adopt two kinds of different formulations,, can make the sole of a kind of brisk, softness and good springiness, to make leather shoes comfortable and easy to wear, cloth shoes etc. through 130 ℃ of-170 ℃ of high temperature 3-7 minute sulfidization moldings.But prescription of enumerating from this patent specification and foam process are as can be seen, this technology only is fit to make common rubber soles, this sole does not possess high grease resistance, high-wearing feature and anlistatig performance, can not satisfy the on-the-spot requirement in shoes for labour protection, particularly machine shop, construction site and oil field with footwear.In addition, because its curing temperature is too high, the time is too short, add in sulfidation, raw stock is not applied any pressure, must cause foaming effect bad, can't form the generation of situations such as continuous foamed and easy deformation, make product quality low and unstable.
Publication number is to have proposed a kind of one-time formed dual-density rubber sole in the application for a patent for invention prospectus of CN1323689A, height resists oil, high abrasion and anlistatig material is made bottom and special expanded material is made surface layer by having, through 110-120 ℃, under 60-70 kilogram pressure, vulcanized 7-10 minute and be molten into one and form.This rubber soles has high anti-oil, wear-resisting and antistatic property, and light weight, softness, full of elasticity, dress are as snug as a bug in a rug.Except that being suitable as the playshoes dress, also be particularly suitable as the shoes for labour protection in construction site, machine shop and building site, oil field.Yet the sole of this footwear is a kind of dual density soles, complicated process of preparation, and do not possess the performance of acid and alkali-resistance and insulation.
Summary of the invention
In order to overcome the above-mentioned defective that exists in the prior art.The invention provides a kind of oil resistant, insulation, acid and alkali-resistance, high temperature resistant multifunctional safety shoes, its sole raw material consists of:
Oil resistant glue 17.5-52.5 weight %,
Natural gum 7.5-22.5 weight %,
Carbon black 10-30 weight %,
Potter's clay 5-15 weight %,
Barium sulfate 5-15 weight %,
Stearic acid 0.7-2.1 weight %,
Dibutyl ester 2.5-7.5 weight %,
Captax 0.25-0.75 weight %,
Altax 0.25-0.75 weight %,
Sulphur 0.5-1.5 weight %,
TMTP 0.1-0.3 weight %,
Vaseline 0.7-2.1 weight %.
Preferred its raw material consists of:
Oil resistant glue 35 weight %,
Natural gum 15 weight %,
Carbon black 20 weight %,
Potter's clay 10 weight %,
Barium sulfate 10 weight %,
Stearic acid 1.4 weight %,
Dibutyl ester 5 weight %,
Captax 0.5 weight %,
Altax 0.5 weight %,
Sulphur 1 weight %,
TMTP 0.2 weight %,
Vaseline 1.4 weight %.
Preferred wherein said oil resistant glue is acrylonitrile-butadiene rubber.
Preferred wherein said rubber polymer is a butadiene-styrene rubber.
The present invention also provides the preparation method of this oil resistant, insulation, acid and alkali-resistance, high temperature resistant multifunctional safety shoes, it is characterized in that:
(1) above-mentioned raw material are prepared in proportion standby,
(2) with the synthetic raw stock of the mixing one-tenth of the raw material that prepare,
(3) raw stock is packed in the die for shoe-sole,
(4) impose the pressure of 60-70 kilogram with hydraulic press to film, and vulcanize under 110-120 ℃ temperature conditions, the time is 7-10 minute, makes sole,
(5) make multifunctional safety shoes according to a conventional method.
Preferred curing temperature is 115-120 ℃.
Preferred cure time is 8-9 minute.
Preferred applied pressure is the 64-68 kilogram.
The multifunctional safety shoes that the present invention makes has oil resistant, insulation, acid and alkali-resistance, resistance and high temperature resistance property.
The specific embodiment
A kind of oil resistant, insulation, acid and alkali-resistance, high temperature resistant multifunctional safety shoes, the raw material composition and the production technology of its sole are as follows:
1, raw material is composed as follows:
35 kilograms of oil resistant glue acrylonitrile-butadiene rubbers,
15 kilograms in rubber polymer butadiene-styrene rubber,
20 kilograms of carbon blacks,
10 kilograms in potter's clay,
10 kilograms in barium sulfate,
1.4 kilograms of stearic acid,
5 kilograms of dibutyl esters,
0.5 kilogram of captax,
0.5 kilogram of altax,
1 kilogram in sulphur,
0.2 kilogram of TMTP,
1.4 kilograms in vaseline.
2, production technology is as follows:
(1) above-mentioned raw materials is prepared in proportion standby,
(2) with the synthetic raw stock of the mixing one-tenth of the raw material for preparing,
(3) raw stock is packed in the die for shoe-sole,
(4) impose 66 kilograms pressure with hydraulic press to film, and vulcanize under 118 ℃ temperature conditions, the time is 9 minutes, makes sole,
(5) make multifunctional safety shoes according to a conventional method.
The product that obtains is tested, and test data is as shown in the table:
Table 1 oil resistant insulating detects data
The high temperature resistant testing result of table 2
Table 2 is continuous
Table 2 is continuous
Table 3 acid and alkali-resistance testing result
Table 3 is continuous
Table 3 is continuous
Table 3 is continuous
Claims (8)
1. an oil resistant, insulation, acid and alkali-resistance, high temperature resistant multifunctional safety shoes, its sole raw material consists of:
Oil resistant glue 17.5-52.5 weight %,
Natural gum 7.5-22.5 weight %,
Carbon black 10-30 weight %,
Potter's clay 5-15 weight %,
Barium sulfate 5-15 weight %,
Stearic acid 0.7-2.1 weight %,
Dibutyl ester 2.5-7.5 weight %,
Captax 0.25-0.75 weight %,
Altax 0.25-0.75 weight %,
Sulphur 0.5-1.5 weight %,
TMTP 0.1-0.3 weight %,
Vaseline 0.7-2.1 weight %.
2. an oil resistant, insulation, acid and alkali-resistance, high temperature resistant multifunctional safety shoes, its sole raw material consists of:
Oil resistant glue 35 weight %,
Natural gum 15 weight %,
Carbon black 20 weight %,
Potter's clay 10 weight %,
Barium sulfate 10 weight %,
Stearic acid 1.4 weight %,
Dibutyl ester 5 weight %,
Captax 0.5 weight %,
Altax 0.5 weight %,
Sulphur 1 weight %,
TMTP 0.2 weight %,
Vaseline 1.4 weight %.
3. claim 1 or 2 described multifunctional safety shoes, wherein said oil resistant glue is acrylonitrile-butadiene rubber.
4. claim 1 or 2 described multifunctional safety shoes, wherein said rubber polymer is a butadiene-styrene rubber.
5. method for preparing each described oil resistant of claim 1-4, insulation, acid and alkali-resistance, high temperature resistant multifunctional safety shoes is characterized in that:
(1) above-mentioned raw material are prepared in proportion standby,
(2) with the synthetic raw stock of the mixing one-tenth of the raw material that prepare,
(3) raw stock is packed in the die for shoe-sole,
(4) impose the pressure of 60-70 kilogram with hydraulic press to film, and vulcanize under 110-120 ℃ temperature conditions, the time is 7-10 minute, makes sole,
(5) make multifunctional safety shoes according to a conventional method.
6. the described method of claim 5, wherein curing temperature is 115-120 ℃.
7. the described method of claim 5, wherein cure time is 8-9 minute.
8. the described method of claim 5, wherein applied pressure is the 64-68 kilogram.
Priority Applications (1)
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CN200910030815A CN101524195A (en) | 2009-04-16 | 2009-04-16 | Multifunctional safety shoes with oil resistance, insulation, acid and alkali resistance and high temperature resistance |
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CN200910030815A CN101524195A (en) | 2009-04-16 | 2009-04-16 | Multifunctional safety shoes with oil resistance, insulation, acid and alkali resistance and high temperature resistance |
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CN101524195A true CN101524195A (en) | 2009-09-09 |
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CN200910030815A Pending CN101524195A (en) | 2009-04-16 | 2009-04-16 | Multifunctional safety shoes with oil resistance, insulation, acid and alkali resistance and high temperature resistance |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101864099A (en) * | 2010-06-09 | 2010-10-20 | 尤建义 | Preparation technology of high-insulation natural rubber material |
CN102398373A (en) * | 2010-09-08 | 2012-04-04 | 吴声鸿 | Manufacture method for safety boots |
CN102850713A (en) * | 2012-09-24 | 2013-01-02 | 吴江市信许塑料鞋用配套有限公司 | Preparation method of high-temperature resistant insulating sole material |
CN106589479A (en) * | 2016-12-06 | 2017-04-26 | 界首市华阳鞋业有限公司 | Antistatic, high-voltage-proof and anticorrosive shoe sole composition |
CN107236164A (en) * | 2017-07-28 | 2017-10-10 | 扬州多力鞋服有限公司 | A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe |
CN114209122A (en) * | 2021-12-07 | 2022-03-22 | 上海安瑞达实业有限公司 | Preparation process of acid-base-resistant and high-temperature-resistant rubber sole and safety shoe |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1323689A (en) * | 2001-06-18 | 2001-11-28 | 卓辉雄 | Double-density rubber shoe sole and its single-forming production process |
-
2009
- 2009-04-16 CN CN200910030815A patent/CN101524195A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1323689A (en) * | 2001-06-18 | 2001-11-28 | 卓辉雄 | Double-density rubber shoe sole and its single-forming production process |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101864099A (en) * | 2010-06-09 | 2010-10-20 | 尤建义 | Preparation technology of high-insulation natural rubber material |
CN102398373A (en) * | 2010-09-08 | 2012-04-04 | 吴声鸿 | Manufacture method for safety boots |
CN102850713A (en) * | 2012-09-24 | 2013-01-02 | 吴江市信许塑料鞋用配套有限公司 | Preparation method of high-temperature resistant insulating sole material |
CN106589479A (en) * | 2016-12-06 | 2017-04-26 | 界首市华阳鞋业有限公司 | Antistatic, high-voltage-proof and anticorrosive shoe sole composition |
CN107236164A (en) * | 2017-07-28 | 2017-10-10 | 扬州多力鞋服有限公司 | A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe |
CN107236164B (en) * | 2017-07-28 | 2018-12-18 | 扬州多力鞋服有限公司 | A kind of anti-puncture anti-skid multifunctional safety shoe of high-temperature insulation |
CN114209122A (en) * | 2021-12-07 | 2022-03-22 | 上海安瑞达实业有限公司 | Preparation process of acid-base-resistant and high-temperature-resistant rubber sole and safety shoe |
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Application publication date: 20090909 |