CN108997624A - A kind of sole high wear-resistant rubber material and preparation method thereof - Google Patents
A kind of sole high wear-resistant rubber material and preparation method thereof Download PDFInfo
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- CN108997624A CN108997624A CN201810916948.XA CN201810916948A CN108997624A CN 108997624 A CN108997624 A CN 108997624A CN 201810916948 A CN201810916948 A CN 201810916948A CN 108997624 A CN108997624 A CN 108997624A
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B25/042—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/16—Layered products comprising a layer of natural or synthetic rubber comprising polydienes homopolymers or poly-halodienes homopolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B2038/0052—Other operations not otherwise provided for
- B32B2038/0076—Curing, vulcanising, cross-linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
- B32B2250/248—All polymers belonging to those covered by group B32B25/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/51—Elastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/552—Fatigue strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/582—Tearability
- B32B2307/5825—Tear resistant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2319/00—Synthetic rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3009—Sulfides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of sole high wear-resistant rubber materials, belong to field of rubber materials, the raw material including following parts by weight: 30-50 parts of butadiene rubber, 120-150 parts of isoprene rubber, 70-80 parts of methyl vinyl silicone rubber, 20-34 parts of white carbon black, 10-12 parts of polysiloxanes, 5-7 parts of silicon carbide, 14-20 parts of glass fibre, 3-5 parts of molybdenum disulfide, 3-9 parts of polytetrafluoroethylene (PTFE), 5-7 parts of carbon nanotube, end containing hydrogen silicone oil 1-3 parts, 1-3 parts of side containing hydrogen silicone oil, 10-15 parts of graphene, 1-3 parts of plasticizer, 1-3 parts of vulcanizing agent, 1-3 parts of crosslinking agent.Sole of the present invention while keeping wear-resisting property, maintains the elasticity of material with high wear-resistant rubber material, and the sole of production is made mill pin phenomenon will not to occur because hardness is big.
Description
Technical field
The present invention relates to field of rubber materials, and in particular to a kind of sole high wear-resistant rubber material and preparation method thereof.
Background technique
Rubber refers to the high elastic polymer material with reversible deformation, at room temperature high resilience, in the external force of very little
Effect is lower to generate larger deformation, remove resilient after external force.Rubber belongs to entirely without styling polymer, its vitrifying
Transition temperature is low, and molecular weight is often very big, is greater than hundreds of thousands.The rubber of early stage is taken from the glue of the plants such as rubber tree, kok-saghyz
Cream, be made after processing with elasticity, insulating properties, impermeable water and air material.It is elastomeric high-molecular compound.Rubber point
For natural rubber and two kinds of synthetic rubber.Natural rubber is made of the extraction colloid post-processing from the plants such as rubber tree, kok-saghyz；
Synthetic rubber is then obtained by the aggregated reaction of various monomers.
It is that it the advantages of rubber soles material can be divided into natural rubber or asynthetic rubber, natural rubber very
Softness, elasticity is splendid, can accommodate in various movements, but it is exactly very not wear-resisting, indoor sport shoes that disadvantage, which is also apparent that,
Multi-purpose natural rubber.It is divided into abrasive rubber, environment-friendly rubber, air rubber, bala gutta, hard rubber in asynthetic rubber again
Glue adds carbon rubber.General wear-resistant rubber sole material all has excellent wear-resisting property and flexibility, but hardness is very big, wears
It is less comfort, weight is big, and some can also mill pin.
Summary of the invention
The purpose of the present invention is to provide a kind of sole high wear-resistant rubber materials, while keeping wear-resisting property,
The elasticity for maintaining material makes the sole of production mill pin phenomenon will not occur because hardness is big.
To achieve the above object, the invention provides the following technical scheme:
A kind of sole high wear-resistant rubber material, the raw material including following parts by weight: 30-50 parts of butadiene rubber, isoamyl rubber
120-150 parts of glue, 70-80 parts of methyl vinyl silicone rubber, 20-34 parts of white carbon black, 10-12 parts of polysiloxanes, silicon carbide 5-7
Part, 14-20 parts of glass fibre, 3-5 parts of molybdenum disulfide, 3-9 parts of polytetrafluoroethylene (PTFE), 5-7 parts of carbon nanotube, end containing hydrogen silicone oil 1-3
Part, 1-3 parts of side containing hydrogen silicone oil, 10-15 parts of graphene, 1-3 parts of plasticizer, 1-3 parts of vulcanizing agent, 1-3 parts of crosslinking agent.
Preferably, sole high wear-resistant rubber material, the raw material including following parts by weight: 30 parts of butadiene rubber, different
Penta 120 parts of rubber, 70 parts of methyl vinyl silicone rubber, 20 parts of white carbon black, 10 parts of polysiloxanes, 5 parts of silicon carbide, glass fibre 14
Part, 3 parts of molybdenum disulfide, 3 parts of polytetrafluoroethylene (PTFE), 5 parts of carbon nanotube, end 1 part of containing hydrogen silicone oil, 1 part of side containing hydrogen silicone oil, graphene 10
Part, 1 part of plasticizer, 1 part of vulcanizing agent, 1 part of crosslinking agent.
Preferably, sole high wear-resistant rubber material, the raw material including following parts by weight: 40 parts of butadiene rubber, different
Penta 135 parts of rubber, 75 parts of methyl vinyl silicone rubber, 28 parts of white carbon black, 11 parts of polysiloxanes, 6 parts of silicon carbide, glass fibre 17
Part, 4 parts of molybdenum disulfide, 6 parts of polytetrafluoroethylene (PTFE), 6 parts of carbon nanotube, end 2 parts of containing hydrogen silicone oil, 2 parts of side containing hydrogen silicone oil, graphene 13
Part, 2 parts of plasticizer, 2 parts of vulcanizing agent, 2 parts of crosslinking agent.
Preferably, sole high wear-resistant rubber material, the raw material including following parts by weight: 50 parts of butadiene rubber, different
Penta 150 parts of rubber, 80 parts of methyl vinyl silicone rubber, 34 parts of white carbon black, 12 parts of polysiloxanes, 7 parts of silicon carbide, glass fibre 20
Part, 5 parts of molybdenum disulfide, 9 parts of polytetrafluoroethylene (PTFE), 7 parts of carbon nanotube, end 3 parts of containing hydrogen silicone oil, 3 parts of side containing hydrogen silicone oil, graphene 15
Part, 3 parts of plasticizer, 3 parts of vulcanizing agent, 3 parts of crosslinking agent.
Preferably, the plasticizer is dioctyl phthalate, in dibutyl phthalate, tricresyl phosphate
It is any.
Preferably, the vulcanizing agent includes any one of t-Butylphenol formaldehyde resin, t-Octylphenol formaldehyde resin.
Preferably, the crosslinking agent is one of polymethyl siloxane, titanate coupling agent, silane coupling agent or a variety of
Mixing.
Preferably, the preparation method of sole high wear-resistant rubber material, comprising the following steps:
(1) raw material of corresponding parts by weight is weighed, it is spare；
(2) butadiene rubber of the parts by weight and the isoprene rubber of the parts by weight 10% are added in high-speed mixer,
7-10min is stirred, white carbon black, polysiloxanes, silicon carbide, glass fibre, molybdenum disulfide, parts by weight 30% are continuously added
Plasticizer, the vulcanizing agent of the parts by weight 50%, the parts by weight 50% crosslinking agent, stir 20-30min, be then transferred to
In mixer, at 120-150 DEG C, mixing 7-10min recycles calender that 1-3mm is made, obtains wearing layer；
(3) methyl vinyl silicone rubber of the parts by weight and remaining isoprene rubber are added in high-speed mixer, are stirred
15-20min is mixed, continuously adds polytetrafluoroethylene (PTFE), carbon nanotube, end containing hydrogen silicone oil, side containing hydrogen silicone oil, graphene, and its remaining
Plasticizer, vulcanizing agent, crosslinking agent, stir 30-35min, be then transferred in mixer, at 180-200 DEG C, mixing 20-
25min recycles calender that 3-10mm is made, obtains elastic layer；
(4) the mold bottom that wearing layer is put into heat pressing forming machines utilizes heat then in wearing layer upper end composite elastic layer
The molding of pressing machine press mold, mold temperature are 180-200 DEG C, and vulcanization 5-6min is high resistance to get sole under sulfide stress 20MP
Rubber milling material.
Compared with prior art, the beneficial effects of the present invention are:
(1) present invention is compound using wearing layer and elastic layer, and wearing layer, Ke Yibao is arranged in the one end directly touched the ground
The service life for demonstrate,proving shoes makes sole have excellent wearability, in wearing layer upper end composite elastic layer, it is ensured that the elasticity of sole,
Will not make user because shoes are too hard and mill pin, increase comfort level；Secondly because wearing layer and elastic layer are using rubber system
At being not in wearing layer and the phenomenon that elastic layer is directly detached from so degrees of fusion is high.
(2) present invention is by butadiene rubber, isoprene rubber, white carbon black, polysiloxanes, silicon carbide, glass fibre, curing
Molybdenum, plasticizer, vulcanizing agent, crosslinking agent form wearing layer, and wherein butadiene rubber, isoprene rubber all have excellent wear-resisting property,
The tear-proof and heat-resisting anti-aging property of wearing layer, polysiloxanes, silicon carbide, glass fibre, curing can be enhanced in white carbon black
Molybdenum can significantly improve the wear-resisting property of wearing layer.
(3) isoprene rubber, methyl vinyl silicone rubber, polytetrafluoroethylene (PTFE), carbon nanotube, end containing hydrogen silicone oil, side Silicon Containing Hydrogen
Oil, graphene, plasticizer, vulcanizing agent, crosslinking agent constitute elastic layer, and wherein isoprene rubber and methyl ethylene silicon rubber itself have
There is excellent elasticity；Graphene has good toughness and lubricant effect, and the elasticity of rubber can be improved；The machine of polytetrafluoroethylene (PTFE)
Tool property is softer, has low-down surface energy, and ageing-resistant, degree of lubrication is high, can prevent sole mill pin；It generally holds hydrogeneous
Silicone oil, side containing hydrogen silicone oil are applied in rubber product as bridging agent, and the present invention is by adjusting its proportion, as softening agent
It uses, reduces the hardness of elastic layer；Carbon nanotube elasticity modulus is high, greatly improves the elasticity of elastic layer.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general
Logical technical staff every other embodiment obtained without making creative work belongs to what the present invention protected
Range.
Embodiment 1
A kind of sole high wear-resistant rubber material described in the present embodiment, the raw material including following parts by weight: along fourth rubber
30 parts of glue, 120 parts of isoprene rubber, 70 parts of methyl vinyl silicone rubber, 20 parts of white carbon black, 10 parts of polysiloxanes, 5 parts of silicon carbide,
14 parts of glass fibre, 3 parts of molybdenum disulfide, 3 parts of polytetrafluoroethylene (PTFE), 5 parts of carbon nanotube, end 1 part of containing hydrogen silicone oil, side containing hydrogen silicone oil 1
Part, 10 parts of graphene, 1 part of plasticizer, 1 part of vulcanizing agent, 1 part of crosslinking agent.
The plasticizer is dioctyl phthalate；The vulcanizing agent includes t-Butylphenol formaldehyde resin；The friendship
Join agent polymethyl siloxane.
The preparation method of sole high wear-resistant rubber material, comprising the following steps:
(1) raw material of corresponding parts by weight is weighed, it is spare；
(2) butadiene rubber of the parts by weight and the isoprene rubber of the parts by weight 10% are added in high-speed mixer,
7min is stirred, the increasing of white carbon black, polysiloxanes, silicon carbide, glass fibre, molybdenum disulfide, the parts by weight 30% is continuously added
Mould agent, the vulcanizing agent of the parts by weight 50%, the parts by weight 50% crosslinking agent, stir 20min, be then transferred to mixer
Interior, at 120 DEG C, mixing 7min recycles calender that 1mm is made, obtains wearing layer；
(3) methyl vinyl silicone rubber of the parts by weight and remaining isoprene rubber are added in high-speed mixer, are stirred
15min is mixed, polytetrafluoroethylene (PTFE), carbon nanotube, end containing hydrogen silicone oil, side containing hydrogen silicone oil, graphene and its remaining increasing are continuously added
Agent, vulcanizing agent, crosslinking agent are moulded, 30min is stirred, is then transferred in mixer, at 180 DEG C, mixing 20min recycles pressure
Prolong machine and 3mm is made, obtains elastic layer；
(4) the mold bottom that wearing layer is put into heat pressing forming machines utilizes heat then in wearing layer upper end composite elastic layer
The molding of pressing machine press mold, mold temperature are 180 DEG C, vulcanize 5min under sulfide stress 20MP to get sole high wear-resistant rubber
Material.
Embodiment 2
A kind of sole high wear-resistant rubber material described in the present embodiment, the raw material including following parts by weight: along fourth rubber
40 parts of glue, 135 parts of isoprene rubber, 75 parts of methyl vinyl silicone rubber, 28 parts of white carbon black, 11 parts of polysiloxanes, 6 parts of silicon carbide,
17 parts of glass fibre, 4 parts of molybdenum disulfide, 6 parts of polytetrafluoroethylene (PTFE), 6 parts of carbon nanotube, end 2 parts of containing hydrogen silicone oil, side containing hydrogen silicone oil 2
Part, 13 parts of graphene, 2 parts of plasticizer, 2 parts of vulcanizing agent, 2 parts of crosslinking agent.
The plasticizer is dibutyl phthalate；The vulcanizing agent includes t-Octylphenol formaldehyde resin；The friendship
Connection agent is titanate coupling agent.
The preparation method of sole high wear-resistant rubber material, comprising the following steps:
(1) raw material of corresponding parts by weight is weighed, it is spare；
(2) butadiene rubber of the parts by weight and the isoprene rubber of the parts by weight 10% are added in high-speed mixer,
8min is stirred, the increasing of white carbon black, polysiloxanes, silicon carbide, glass fibre, molybdenum disulfide, the parts by weight 30% is continuously added
Mould agent, the vulcanizing agent of the parts by weight 50%, the parts by weight 50% crosslinking agent, stir 25min, be then transferred to mixer
Interior, at 135 DEG C, mixing 8min recycles calender that 2mm is made, obtains wearing layer；
(3) methyl vinyl silicone rubber of the parts by weight and remaining isoprene rubber are added in high-speed mixer, are stirred
17min is mixed, polytetrafluoroethylene (PTFE), carbon nanotube, end containing hydrogen silicone oil, side containing hydrogen silicone oil, graphene and its remaining increasing are continuously added
Agent, vulcanizing agent, crosslinking agent are moulded, 33min is stirred, is then transferred in mixer, at 190 DEG C, mixing 23min recycles pressure
Prolong machine and 7mm is made, obtains elastic layer；
(4) the mold bottom that wearing layer is put into heat pressing forming machines utilizes heat then in wearing layer upper end composite elastic layer
The molding of pressing machine press mold, mold temperature are 190 DEG C, vulcanize 5min under sulfide stress 20MP to get sole high wear-resistant rubber
Material.
Embodiment 3
A kind of sole high wear-resistant rubber material described in the present embodiment, the raw material including following parts by weight: along fourth rubber
50 parts of glue, 150 parts of isoprene rubber, 80 parts of methyl vinyl silicone rubber, 34 parts of white carbon black, 12 parts of polysiloxanes, 7 parts of silicon carbide,
20 parts of glass fibre, 5 parts of molybdenum disulfide, 9 parts of polytetrafluoroethylene (PTFE), 7 parts of carbon nanotube, end 3 parts of containing hydrogen silicone oil, side containing hydrogen silicone oil 3
Part, 15 parts of graphene, 3 parts of plasticizer, 3 parts of vulcanizing agent, 3 parts of crosslinking agent.
The plasticizer is tricresyl phosphate；The vulcanizing agent includes t-Octylphenol formaldehyde resin；The silane is even
Join agent.
The preparation method of sole high wear-resistant rubber material, comprising the following steps:
(1) raw material of corresponding parts by weight is weighed, it is spare；
(2) butadiene rubber of the parts by weight and the isoprene rubber of the parts by weight 10% are added in high-speed mixer,
10min is stirred, the increasing of white carbon black, polysiloxanes, silicon carbide, glass fibre, molybdenum disulfide, the parts by weight 30% is continuously added
Mould agent, the vulcanizing agent of the parts by weight 50%, the parts by weight 50% crosslinking agent, stir 30min, be then transferred to mixer
Interior, at 150 DEG C, mixing 10min recycles calender that 3mm is made, obtains wearing layer；
(3) methyl vinyl silicone rubber of the parts by weight and remaining isoprene rubber are added in high-speed mixer, are stirred
20min is mixed, polytetrafluoroethylene (PTFE), carbon nanotube, end containing hydrogen silicone oil, side containing hydrogen silicone oil, graphene and its remaining increasing are continuously added
Agent, vulcanizing agent, crosslinking agent are moulded, 35min is stirred, is then transferred in mixer, at 200 DEG C, mixing 25min recycles pressure
Prolong machine and 10mm is made, obtains elastic layer；
(4) the mold bottom that wearing layer is put into heat pressing forming machines utilizes heat then in wearing layer upper end composite elastic layer
The molding of pressing machine press mold, mold temperature are 200 DEG C, vulcanize 6min under sulfide stress 20MP to get sole high wear-resistant rubber
Material.
Comparative example 1
It is in place of comparative example 1 and the difference of embodiment 2: without containing end containing hydrogen silicone oil.
Comparative example 2
It is in place of comparative example 1 and the difference of embodiment 2: without containing side containing hydrogen silicone oil.
Comparative example 3
It is in place of comparative example 1 and the difference of embodiment 2: without containing end containing hydrogen silicone oil, side containing hydrogen silicone oil.
In order to verify the performance of resulting materials of the present invention, embodiment 1-3 and comparative example 1-3 resulting materials are measured,
Acquired results are as follows:
1 performance measurement result table of table
Above content is only to structure of the invention example and explanation, affiliated those skilled in the art couple
Described specific embodiment does various modifications or additions or is substituted in a similar manner, without departing from the present invention
Structure or beyond the scope defined by this claim, be within the scope of protection of the invention.
Claims (8)
1. a kind of sole high wear-resistant rubber material, which is characterized in that the raw material including following parts by weight: butadiene rubber 30-50
Part, 120-150 parts of isoprene rubber, 70-80 parts of methyl vinyl silicone rubber, 20-34 parts of white carbon black, 10-12 parts of polysiloxanes, carbon
5-7 parts of SiClx, 14-20 parts of glass fibre, 3-5 parts of molybdenum disulfide, 3-9 parts of polytetrafluoroethylene (PTFE), 5-7 parts of carbon nanotube, end are hydrogeneous
1-3 parts of silicone oil, 1-3 parts of side containing hydrogen silicone oil, 10-15 parts of graphene, 1-3 parts of plasticizer, 1-3 parts of vulcanizing agent, 1-3 parts of crosslinking agent.
2. a kind of sole high wear-resistant rubber material according to claim 1, which is characterized in that including following parts by weight
Raw material: 30 parts of butadiene rubber, 120 parts of isoprene rubber, 70 parts of methyl vinyl silicone rubber, 20 parts of white carbon black, 10 parts of polysiloxanes,
5 parts of silicon carbide, 14 parts of glass fibre, 3 parts of molybdenum disulfide, 3 parts of polytetrafluoroethylene (PTFE), 5 parts of carbon nanotube, end 1 part of containing hydrogen silicone oil, side
1 part of containing hydrogen silicone oil, 10 parts of graphene, 1 part of plasticizer, 1 part of vulcanizing agent, 1 part of crosslinking agent.
3. a kind of sole high wear-resistant rubber material according to claim 1, which is characterized in that including following parts by weight
Raw material: 40 parts of butadiene rubber, 135 parts of isoprene rubber, 75 parts of methyl vinyl silicone rubber, 28 parts of white carbon black, 11 parts of polysiloxanes,
6 parts of silicon carbide, 17 parts of glass fibre, 4 parts of molybdenum disulfide, 6 parts of polytetrafluoroethylene (PTFE), 6 parts of carbon nanotube, end 2 parts of containing hydrogen silicone oil, side
2 parts of containing hydrogen silicone oil, 13 parts of graphene, 2 parts of plasticizer, 2 parts of vulcanizing agent, 2 parts of crosslinking agent.
4. a kind of sole high wear-resistant rubber material according to claim 1, which is characterized in that including following parts by weight
Raw material: 50 parts of butadiene rubber, 150 parts of isoprene rubber, 80 parts of methyl vinyl silicone rubber, 34 parts of white carbon black, 12 parts of polysiloxanes,
7 parts of silicon carbide, 20 parts of glass fibre, 5 parts of molybdenum disulfide, 9 parts of polytetrafluoroethylene (PTFE), 7 parts of carbon nanotube, end 3 parts of containing hydrogen silicone oil, side
3 parts of containing hydrogen silicone oil, 15 parts of graphene, 3 parts of plasticizer, 3 parts of vulcanizing agent, 3 parts of crosslinking agent.
5. a kind of sole high wear-resistant rubber material according to claim 1, it is characterised in that: the plasticizer is adjacent benzene
Any one of diformazan dioctyl phthalate, dibutyl phthalate, tricresyl phosphate.
6. a kind of sole high wear-resistant rubber material according to claim 1, it is characterised in that: the vulcanizing agent includes uncle
Any one of butylphenol formaldehyde resin, t-Octylphenol formaldehyde resin.
7. a kind of sole high wear-resistant rubber material according to claim 1, it is characterised in that: the crosslinking agent is poly- first
One of radical siloxane, titanate coupling agent, silane coupling agent or a variety of mixing.
8. the sole according to claim 1-7 preparation method of high wear-resistant rubber material, which is characterized in that packet
Include following steps:
(1) raw material of corresponding parts by weight is weighed, it is spare；
(2) butadiene rubber of the parts by weight and the isoprene rubber of the parts by weight 10% are added in high-speed mixer, stirring
7-10min continuously adds the plasticising of white carbon black, polysiloxanes, silicon carbide, glass fibre, molybdenum disulfide, the parts by weight 30%
Agent, the vulcanizing agent of the parts by weight 50%, the parts by weight 50% crosslinking agent, stir 20-30min, be then transferred to mixing
In machine, at 120-150 DEG C, mixing 7-10min recycles calender that 1-3mm is made, obtains wearing layer；
(3) methyl vinyl silicone rubber of the parts by weight and remaining isoprene rubber are added in high-speed mixer, stir 15-
20min continuously adds polytetrafluoroethylene (PTFE), carbon nanotube, end containing hydrogen silicone oil, side containing hydrogen silicone oil, graphene and its remaining plasticising
Agent, vulcanizing agent, crosslinking agent stir 30-35min, are then transferred in mixer, at 180-200 DEG C, mixing 20-25min,
It recycles calender that 3-10mm is made, obtains elastic layer；
(4) wearing layer is put into the mold bottom of heat pressing forming machines, then in wearing layer upper end composite elastic layer, using being hot pressed into
The molding of type machine press mold, mold temperature are 180-200 DEG C, and vulcanization 5-6min is to get sole with high abrasion rubber under sulfide stress 20MP
Glue material.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810916948.XA CN108997624A (en) | 2018-08-13 | 2018-08-13 | A kind of sole high wear-resistant rubber material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810916948.XA CN108997624A (en) | 2018-08-13 | 2018-08-13 | A kind of sole high wear-resistant rubber material and preparation method thereof |
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| CN108997624A true CN108997624A (en) | 2018-12-14 |
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| CN201810916948.XA Withdrawn CN108997624A (en) | 2018-08-13 | 2018-08-13 | A kind of sole high wear-resistant rubber material and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109897385A (en) * | 2019-03-11 | 2019-06-18 | 安踏（中国）有限公司 | A kind of vibration-damping foamed middle bottom material and preparation method thereof of width temperature range |
| CN110698737A (en) * | 2019-09-26 | 2020-01-17 | 江苏新奥碳纳米材料应用技术研究院有限公司 | Graphene-reinforced antistatic rubber composition and preparation method thereof |
| CN114957814A (en) * | 2022-06-14 | 2022-08-30 | 陈栋 | Wear-resistant rubber material for fire-fighting shoes and preparation method thereof |
| CN115028909A (en) * | 2022-06-22 | 2022-09-09 | 佛山市俊亿鞋业有限公司 | Ice surface antiskid rubber and preparation method thereof |
-
2018
- 2018-08-13 CN CN201810916948.XA patent/CN108997624A/en not_active Withdrawn
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109897385A (en) * | 2019-03-11 | 2019-06-18 | 安踏（中国）有限公司 | A kind of vibration-damping foamed middle bottom material and preparation method thereof of width temperature range |
| CN109897385B (en) * | 2019-03-11 | 2021-08-17 | 安踏（中国）有限公司 | Wide-temperature-range shock-absorption foaming insole material and preparation method thereof |
| CN110698737A (en) * | 2019-09-26 | 2020-01-17 | 江苏新奥碳纳米材料应用技术研究院有限公司 | Graphene-reinforced antistatic rubber composition and preparation method thereof |
| CN114957814A (en) * | 2022-06-14 | 2022-08-30 | 陈栋 | Wear-resistant rubber material for fire-fighting shoes and preparation method thereof |
| CN115028909A (en) * | 2022-06-22 | 2022-09-09 | 佛山市俊亿鞋业有限公司 | Ice surface antiskid rubber and preparation method thereof |
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Application publication date: 20181214 |