CN107236164A - A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe - Google Patents
A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe Download PDFInfo
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- CN107236164A CN107236164A CN201710630577.4A CN201710630577A CN107236164A CN 107236164 A CN107236164 A CN 107236164A CN 201710630577 A CN201710630577 A CN 201710630577A CN 107236164 A CN107236164 A CN 107236164A
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- safety shoe
- shoe
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/14—Footwear characterised by the material made of plastics
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
- A43B23/02—Uppers; Boot legs
- A43B23/0205—Uppers; Boot legs characterised by the material
- A43B23/0215—Plastics or artificial leather
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2255—Oxides; Hydroxides of metals of molybdenum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/325—Calcium, strontium or barium phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of anti-puncture anti-skid multifunctional safety shoe of the high-temperature insulation for belonging to clothes manufacturing technology field.The material for sole of shoe is made up of the raw material of following parts by weight：30 50 parts of butadiene-styrene rubber, 10 15 parts of butyl acrylate, 15 25 parts of epoxy resin, 12 parts of trifluoro Peracetic acid, 35 parts of molybdenum trioxide, 12 parts of sulphur, 25 parts of bone meal；The vamp material coats the anti-glue that pierces through of high-temperature insulation by canvas and is made.The high-temperature insulation of the present invention is anti-to pierce through anti-skid multifunctional safety shoe, and using brand-new formula, the safety shoe wearing comfort of preparation, heat-resisting ability is strong, anti-puncture ability is strong, easy to use in calamity fire fighting effort is robbed, and can prevent from burning, electric shock, good insulation preformance, service life is long.
Description
Technical field
The invention belongs to clothes manufacturing technology field, and in particular to a kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety
Footwear.
Background technology
Current safety shoe is generally made of industrial chemicals, and the pliability of footwear is not high, and safety shoe is in anti-puncture side
Face performance is not high, in engineering worksite or laboratory, and often in contact with to electricity, safety shoe insulating properties are not good, in hot environment, hold
Easily soften, ftracture, melting.
Patent 201210336177.X discloses it and is made up of the two parts bonded or acupuncture is combined：Part I is：Nothing
Spin felt and Woven cloth compounded felt shoes bottom；Part II is：Plastic anti-skid layer；Non-woven mat and Woven cloth compounded felt shoes bottom be by
Single or multiple lift non-woven mat is composited with single or multiple lift woven cloth with needle point method or Method for bonding or other methods, by using change
Learning reagent cure process makes its structure more stablize, and can effectively prevent from puncturing, and plastic anti-skid layer is that one layer is filled in silicon rubber
Fabric reaches more abrasion resistant effect.Patent 200810196326.0 discloses a kind of manufacture material of appliances for labor protection, specifically
It is a kind of material for sole of shoe of the high temperature resistant labor protection shoes used in high temperature environments.The composition and weight proportion of the material be:
Fourth is fine 38.5-40.5 parts, 7.6-8.2 parts of sulphur, 2.51-3.05 parts of altax, 11.3-13.1 parts of Vulcanization accelerator TMTD, oxidation
4.3-4.9 parts of zinc, 1.8-2.2 parts of carbon black, 4.9-5.5 parts of calcium carbonate, 7.6-8.2 parts of stearic acid, dibutylester 0.107-0.1198
4.53-5.02 parts, 8.9-9.5 parts of magnesia drop in part, 0.38-0.60 parts of zinc stearate, solid horse.Safety shoe disclosed in above-mentioned patent
Insulating properties are not good, puncture resistant ability, are only useful in common occasion wearing, are not suitable for the disaster relief, the use for the occasion such as speedily carry out rescue work.
The content of the invention
It is an object of the invention to provide a kind of anti-puncture anti-skid multifunctional safety shoe of high-temperature insulation.
A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe, including material for sole of shoe and vamp material, the sole
Material is made up of the raw material of following parts by weight：30-50 parts of butadiene-styrene rubber, 10-15 parts of butyl acrylate, epoxy resin 15-25
Part, 1-2 parts of trifluoro Peracetic acid, 3-5 parts of molybdenum trioxide, 1-2 parts of sulphur, 2-5 parts of bone meal；The vamp material is coated by canvas
The anti-glue that pierces through of high-temperature insulation is made.
The bone meal is selected from chick bone powder, lamb bone meal, bovine bone powder, Os Sus domestica powder, duck bone meal, one kind in horse bone meal or it is a kind of with
On.
The amount of the anti-puncture glue coating of high-temperature insulation is the 5-10% of canvas quality, by the component of following parts by weight
Composition：25-35 parts of epoxy resin, 3-6 parts of curing agent, 1-2 parts of carbomer, 10-15 parts of latex, 5-10 parts of cellulose, Isosorbide-5-Nitrae, 5,
3-8 parts of 8- tetrachloroanthraquinones, 1-2 parts of 2- allyl methacrylates.
The curing agent is selected from the formaldehyde condensation products of sulfonated acetone, methyl diphenylene diisocyanate, polyacrylamide, powder
One or more in coal ash calcium chloride, gypsum, calcium silicates, NPE.
The anti-preparation method for piercing through anti-skid multifunctional safety shoe of above-mentioned high-temperature insulation, is made as follows：
(1) according to parts by weight, 30-50 parts of butadiene-styrene rubber is taken, 10-15 parts of butyl acrylate, 15-25 parts of epoxy resin,
1-2 parts of trifluoro Peracetic acid, 3-5 parts of molybdenum trioxide, 1-2 parts of sulphur, 2-5 parts of bone meal, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 80-90 kilograms of pressure to film using hydraulic press, and
Vulcanized under 100-115 DEG C of temperature conditionss, cure time 8-12 minutes, sole is made；
(3) coating accounts for the canvas quality 5-10% anti-puncture glue of high-temperature insulation on canvas, dries or dries, and uses
Sole is combined, safety shoe is made by sewing, gluing, the method for cutting with vamp.
Beneficial effects of the present invention：The high-temperature insulation of the present invention is anti-to pierce through anti-skid multifunctional safety shoe, using brand-new
Formula, the safety shoe wearing comfort of preparation, heat-resisting ability is strong, and anti-puncture ability is strong, easy to use in calamity fire fighting effort is robbed,
It can prevent from burning, electric shock, good insulation preformance, service life is long.
Embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe, including material for sole of shoe and vamp material, the sole
Material is made up of the raw material of following parts by weight：40 parts of butadiene-styrene rubber, 12 parts of butyl acrylate, 20 parts of epoxy resin, trifluoro mistake
1.5 parts of fluoroacetic acid, 4 parts of molybdenum trioxide, 1.5 parts of sulphur, 3 parts of chick bone powder；The vamp material coats high-temperature insulation by canvas
Anti- puncture glue is made.The anti-amount for piercing through glue coating of the high-temperature insulation is the 8% of canvas quality, by the group of following parts by weight
It is grouped into：30 parts of epoxy resin, 4 parts of the formaldehyde condensation products of sulfonated acetone, 1.5 parts of carbomer, 12 parts of latex, 8 parts of cellulose, 1,
4,5,8- 6 parts of tetrachloroanthraquinones, 1.5 parts of 2- allyl methacrylates.
The anti-preparation method for piercing through anti-skid multifunctional safety shoe of above-mentioned high-temperature insulation, is made as follows：
(1) according to parts by weight, 40 parts of butadiene-styrene rubber, 12 parts of butyl acrylate, 20 parts of epoxy resin, trifluoro peroxide second are taken
1.5 parts of acid, 4 parts of molybdenum trioxide, 1.5 parts of sulphur, 3 parts of chick bone powder, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 85 kilograms of pressure to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the anti-puncture glue of high-temperature insulation of canvas quality 8% on canvas, dries or dries, using seam
Thread, sole is combined, safety shoe is made by gluing, the method for cutting with vamp.
Embodiment 2
A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe, including material for sole of shoe and vamp material, the sole
Material is made up of the raw material of following parts by weight：30 parts of butadiene-styrene rubber, 10 parts of butyl acrylate, 15 parts of epoxy resin, trifluoro mistake
1 part of fluoroacetic acid, 3 parts of molybdenum trioxide, 1 part of sulphur, 2 parts of bovine bone powder；It is anti-stab that the vamp material coats high-temperature insulation by canvas
Glue is worn to be made.The anti-amount for piercing through glue coating of the high-temperature insulation is the 5% of canvas quality, by the component group of following parts by weight
Into：25 parts of epoxy resin, 3 parts of methyl diphenylene diisocyanate, 1 part of carbomer, 10 parts of latex, 5 parts of cellulose, Isosorbide-5-Nitrae, 5,8-
3 parts of tetrachloroanthraquinone, 1 part of 2- allyl methacrylates.
The anti-preparation method for piercing through anti-skid multifunctional safety shoe of above-mentioned high-temperature insulation, is made as follows：
(1) according to parts by weight, 30 parts of butadiene-styrene rubber, 10 parts of butyl acrylate, 15 parts of epoxy resin, trifluoro peroxide second are taken
1 part of acid, 3 parts of molybdenum trioxide, 1 part of sulphur, 2 parts of bovine bone powder, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 80 kilograms of pressure to film using hydraulic press, and 100
Vulcanized under DEG C temperature conditionss, cure time 8 minutes, sole is made；
(3) coating accounts for the anti-puncture glue of high-temperature insulation of canvas quality 5% on canvas, dries or dries, using seam
Thread, sole is combined, safety shoe is made by gluing, the method for cutting with vamp.
Embodiment 3
A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe, including material for sole of shoe and vamp material, the sole
Material is made up of the raw material of following parts by weight：50 parts of butadiene-styrene rubber, 15 parts of butyl acrylate, 25 parts of epoxy resin, trifluoro mistake
2 parts of fluoroacetic acid, 5 parts of molybdenum trioxide, 2 parts of sulphur, 5 parts of Os Sus domestica powder；It is anti-stab that the vamp material coats high-temperature insulation by canvas
Glue is worn to be made.The anti-amount for piercing through glue coating of the high-temperature insulation is the 10% of canvas quality, by the component of following parts by weight
Composition：35 parts of epoxy resin, 2 parts of polyacrylamide, 2 parts of flyash calcium chloride, 2 parts of gypsum, 2 parts of carbomer, 15 parts of latex is fine
10 parts of dimension element, Isosorbide-5-Nitrae, 5,8- 8 parts of tetrachloroanthraquinones, 2 parts of 2- allyl methacrylates.
The anti-preparation method for piercing through anti-skid multifunctional safety shoe of above-mentioned high-temperature insulation, is made as follows：
(1) according to parts by weight, 50 parts of butadiene-styrene rubber, 15 parts of butyl acrylate, 25 parts of epoxy resin, trifluoro peroxide second are taken
2 parts of acid, 5 parts of molybdenum trioxide, 2 parts of sulphur, 5 parts of Os Sus domestica powder, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 90 kilograms of pressure to film using hydraulic press, and 115
Vulcanized under DEG C temperature conditionss, cure time 12 minutes, sole is made；
(3) coating accounts for the anti-puncture glue of high-temperature insulation of canvas quality 10% on canvas, dries or dries, using seam
Thread, sole is combined, safety shoe is made by gluing, the method for cutting with vamp.
Embodiment 4
A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe, including material for sole of shoe and vamp material, the sole
Material is made up of the raw material of following parts by weight：40 parts of butadiene-styrene rubber, 12 parts of butyl acrylate, 20 parts of epoxy resin, trifluoro mistake
1.5 parts of fluoroacetic acid, 4 parts of molybdenum trioxide, 1.5 parts of sulphur, 3 parts of chick bone powder, 1 part of acrocarp tongue extract；The acrocarp tongue extract
Extracting method be：Acrocarp tongue blade is dried, clayed into power, plus 5 times of weight water refluxing extraction 3 times, merging filtrate is evaporated
It is made；The vamp material coats the anti-glue that pierces through of high-temperature insulation by canvas and is made.The high-temperature insulation is anti-to pierce through glue coating
Amount be canvas quality 8%, be made up of the component of following parts by weight：30 parts of epoxy resin, the formaldehyde condensation of sulfonated acetone
4 parts of thing, 1.5 parts of carbomer, 12 parts of latex, 8 parts of cellulose, Isosorbide-5-Nitrae, 5,8- 6 parts of tetrachloroanthraquinones, 2- allyl methacrylates
1.5 part.
The anti-preparation method for piercing through anti-skid multifunctional safety shoe of above-mentioned high-temperature insulation, is made as follows：
(1) according to parts by weight, 40 parts of butadiene-styrene rubber, 12 parts of butyl acrylate, 20 parts of epoxy resin, trifluoro peroxide second are taken
1.5 parts of acid, 4 parts of molybdenum trioxide, 1.5 parts of sulphur, 3 parts of chick bone powder, 1 part of acrocarp tongue extract, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 85 kilograms of pressure to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the anti-puncture glue of high-temperature insulation of canvas quality 8% on canvas, dries or dries, using seam
Thread, sole is combined, safety shoe is made by gluing, the method for cutting with vamp.
Embodiment 5
A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe, including material for sole of shoe and vamp material, the sole
Material is made up of the raw material of following parts by weight：40 parts of butadiene-styrene rubber, 12 parts of butyl acrylate, 20 parts of epoxy resin, trifluoro mistake
1.5 parts of fluoroacetic acid, 4 parts of molybdenum trioxide, 1.5 parts of sulphur, 3 parts of chick bone powder；The vamp material coats high-temperature insulation by canvas
Anti- puncture glue is made.The anti-amount for piercing through glue coating of the high-temperature insulation is the 8% of canvas quality, by the group of following parts by weight
It is grouped into：30 parts of epoxy resin, 4 parts of the formaldehyde condensation products of sulfonated acetone, 1.5 parts of carbomer, 12 parts of latex, 8 parts of cellulose, 1,
4,5,8- 6 parts of tetrachloroanthraquinones, 1.5 parts of 2- allyl methacrylates, 1 part of thymolphthalein monophosphate di-ammonium salts.
The anti-preparation method for piercing through anti-skid multifunctional safety shoe of above-mentioned high-temperature insulation, is made as follows：
(1) according to parts by weight, 40 parts of butadiene-styrene rubber, 12 parts of butyl acrylate, 20 parts of epoxy resin, trifluoro peroxide second are taken
1.5 parts of acid, 4 parts of molybdenum trioxide, 1.5 parts of sulphur, 3 parts of chick bone powder, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 85 kilograms of pressure to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the anti-puncture glue of high-temperature insulation of canvas quality 8% on canvas, dries or dries, using seam
Thread, sole is combined, safety shoe is made by gluing, the method for cutting with vamp.
Comparative example 1
A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe, including material for sole of shoe and vamp material, the sole
Material is made up of the raw material of following parts by weight：40 parts of butadiene-styrene rubber, 12 parts of butyl acrylate, 20 parts of epoxy resin, trifluoro mistake
1.5 parts of fluoroacetic acid, 4 parts of molybdenum trioxide, 1.5 parts of sulphur；The vamp material coats the anti-puncture glue system of high-temperature insulation by canvas
Into.The anti-amount for piercing through glue coating of the high-temperature insulation is the 8% of canvas quality, is made up of the component of following parts by weight：Ring
30 parts of oxygen tree fat, 4 parts of the formaldehyde condensation products of sulfonated acetone, 1.5 parts of carbomer, 12 parts of latex, 8 parts of cellulose, Isosorbide-5-Nitrae, 5,8- tetra-
6 parts of chloroanthraquinone, 1.5 parts of 2- allyl methacrylates.
The anti-preparation method for piercing through anti-skid multifunctional safety shoe of above-mentioned high-temperature insulation, is made as follows：
(1) according to parts by weight, 40 parts of butadiene-styrene rubber, 12 parts of butyl acrylate, 20 parts of epoxy resin, trifluoro peroxide second are taken
1.5 parts of acid, 4 parts of molybdenum trioxide, 1.5 parts of sulphur, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 85 kilograms of pressure to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the anti-puncture glue of high-temperature insulation of canvas quality 8% on canvas, dries or dries, using seam
Thread, sole is combined, safety shoe is made by gluing, the method for cutting with vamp.
Comparative example 2
A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe, including material for sole of shoe and vamp material, the sole
Material is made up of the raw material of following parts by weight：40 parts of butadiene-styrene rubber, 12 parts of butyl acrylate, 20 parts of epoxy resin, trifluoro mistake
1.5 parts of fluoroacetic acid, 4 parts of molybdenum trioxide, 1.5 parts of sulphur, 3 parts of chick bone powder；The vamp material coats high-temperature insulation by canvas
Anti- puncture glue is made.The anti-amount for piercing through glue coating of the high-temperature insulation is the 8% of canvas quality, by the group of following parts by weight
It is grouped into：30 parts of epoxy resin, 4 parts of the formaldehyde condensation products of sulfonated acetone, 1.5 parts of carbomer, 12 parts of latex, 8 parts of cellulose, 2-
1.5 parts of allyl methacrylate.
The anti-preparation method for piercing through anti-skid multifunctional safety shoe of above-mentioned high-temperature insulation, is made as follows：
(1) according to parts by weight, 40 parts of butadiene-styrene rubber, 12 parts of butyl acrylate, 20 parts of epoxy resin, trifluoro peroxide second are taken
1.5 parts of acid, 4 parts of molybdenum trioxide, 1.5 parts of sulphur, 3 parts of chick bone powder, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 85 kilograms of pressure to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the anti-puncture glue of high-temperature insulation of canvas quality 8% on canvas, dries or dries, using seam
Thread, sole is combined, safety shoe is made by gluing, the method for cutting with vamp.
Comparative example 3
A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe, including material for sole of shoe and vamp material, the sole
Material is made up of the raw material of following parts by weight：40 parts of butadiene-styrene rubber, 12 parts of butyl acrylate, 20 parts of epoxy resin, trifluoro mistake
1.5 parts of fluoroacetic acid, 4 parts of molybdenum trioxide, 1.5 parts of sulphur, 3 parts of chick bone powder；The vamp material coats high-temperature insulation by canvas
Anti- puncture glue is made.The anti-amount for piercing through glue coating of the high-temperature insulation is the 8% of canvas quality, by the group of following parts by weight
It is grouped into：30 parts of epoxy resin, 4 parts of the formaldehyde condensation products of sulfonated acetone, 1.5 parts of carbomer, 12 parts of latex, 8 parts of cellulose, 1,
6 parts of 4,5,8- tetrachloroanthraquinones.
The anti-preparation method for piercing through anti-skid multifunctional safety shoe of above-mentioned high-temperature insulation, is made as follows：
(1) according to parts by weight, 40 parts of butadiene-styrene rubber, 12 parts of butyl acrylate, 20 parts of epoxy resin, trifluoro peroxide second are taken
1.5 parts of acid, 4 parts of molybdenum trioxide, 1.5 parts of sulphur, 3 parts of chick bone powder, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 85 kilograms of pressure to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the anti-puncture glue of high-temperature insulation of canvas quality 8% on canvas, dries or dries, using seam
Thread, sole is combined, safety shoe is made by gluing, the method for cutting with vamp.
In 300 DEG C of temperature holding 60s, whether observation sole or vamp soften, melt, situations such as cracking, and detection is real
A 1-5 and comparative example 1-3 product sole and the resistance to elevated temperatures of vamp is applied, data are as shown in table 1：
Table 1
As can be seen from Table 1, the sole of comparative example 1 has softening, melting, and compared with Example 1, other conditions are identical, only
It is to add chick bone powder less, it was demonstrated that chick bone powder, which has, promotes the resistant to elevated temperatures function of sole structure combinations thing；Comparative example 2 and the footwear of comparative example 3
There is softening in face, melts, cracking, and compared with Example 1, other conditions are identical, is only to add Isosorbide-5-Nitrae, 5,8- tetrachloros less respectively
Anthraquinone, 2- allyl methacrylates, it was demonstrated that above-mentioned substance has the resistant to elevated temperatures function of vamp.
Using standard clause GB12011-2000 4.2.1 (in 20 DEG C of temperature, relative humidity 60%, performance test voltage
6kV, duration 1min, Leakage Current are less than 1.8 to be qualified), detect embodiment 1-5 and comparative example 1-3 product sole and
The insulating properties of vamp, data are as shown in table 2：
Table 2
As can be seen from Table 2, the sole Leakage Current of comparative example 1 is not too high up to standard, compared with Example 1, other conditions phase
Together, chick bone powder is only added less, it was demonstrated that chick bone powder has the performance for promoting sole structure combinations thing to keep insulation；Vamp leakage electricity
The electric current of comparative example 2 and comparative example 3 is not too high up to standard in stream detection, and compared with Example 1, other conditions are identical, only few
Add Isosorbide-5-Nitrae, 5,8- tetrachloroanthraquinones, 2- allyl methacrylates, it was demonstrated that Isosorbide-5-Nitrae, 5,8- tetrachloroanthraquinones, 2- methacrylic acid alkene
Propyl ester has the performance for promoting vamp composition to keep insulation.
Standard clause GB12011-2000 3.3 is used to detect that the tearing strength of sole and vamp (is more than 60N/mm to close
Lattice), embodiment 1-5 and comparative example 1-3 product sole and the penetration-resistant energy of vamp are detected, data are as shown in table 3：
Table 2
As can be seen from Table 2, the sole tearing strength of embodiment 4 is more than embodiment 1, compared with Example 1, other conditions phase
Together, it is only to add acrocarp tongue extract, it was demonstrated that acrocarp tongue extract, which has, promotes sole structure combinations thing toughness, strengthens it and resists more
Puncture ability；The vamp tearing strength of embodiment 5 is more than embodiment 1, and compared with Example 1, other conditions are identical, are only to add
Thymolphthalein monophosphate di-ammonium salts are entered, it was demonstrated that thymolphthalein monophosphate di-ammonium salts have enhancing vamp toughness, have strengthened it and anti-wear
Thorn ability.
Claims (5)
1. a kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe, including material for sole of shoe and vamp material, it is characterised in that
The material for sole of shoe is made up of the raw material of following parts by weight：30-50 parts of butadiene-styrene rubber, 10-15 parts of butyl acrylate, asphalt mixtures modified by epoxy resin
15-25 parts of fat, 1-2 parts of trifluoro Peracetic acid, 3-5 parts of molybdenum trioxide, 1-2 parts of sulphur, 2-5 parts of bone meal；The vamp material by
The anti-glue that pierces through of canvas coating high-temperature insulation is made.
2. high-temperature insulation is anti-according to claim 1 pierces through anti-skid multifunctional safety shoe, it is characterised in that the bone meal choosing
From chick bone powder, lamb bone meal, bovine bone powder, Os Sus domestica powder, duck bone meal, the one or more in horse bone meal.
3. high-temperature insulation is anti-according to claim 1 pierces through anti-skid multifunctional safety shoe, it is characterised in that the high temperature resistant
The anti-amount for piercing through glue coating of insulation is the 5-10% of canvas quality, is made up of the component of following parts by weight：Epoxy resin 25-35
Part, 3-6 parts of curing agent, 1-2 parts of carbomer, 10-15 parts of latex, 5-10 parts of cellulose, Isosorbide-5-Nitrae, 5,8- 3-8 parts of tetrachloroanthraquinones, 2-
1-2 parts of allyl methacrylate.
4. high-temperature insulation is anti-according to claim 3 pierces through anti-skid multifunctional safety shoe, it is characterised in that the curing agent
Formaldehyde condensation products selected from sulfonated acetone, methyl diphenylene diisocyanate, polyacrylamide, flyash calcium chloride, gypsum, silicon
One or more in sour calcium, NPE.
5. the anti-preparation method for piercing through anti-skid multifunctional safety shoe of high-temperature insulation described in claim 1, it is characterised in that according to
Following method is made：
(1) according to parts by weight, 30-50 parts of butadiene-styrene rubber, 10-15 parts of butyl acrylate, 15-25 parts of epoxy resin, trifluoro are taken
1-2 parts of Peracetic acid, 3-5 parts of molybdenum trioxide, 1-2 parts of sulphur, 2-5 parts of bone meal, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 80-90 kilograms of pressure to film using hydraulic press, and in 100-
Vulcanized under 115 DEG C of temperature conditionss, cure time 8-12 minutes, sole is made；
(3) coating accounts for the canvas quality 5-10% anti-puncture glue of high-temperature insulation on canvas, dries or dries, using seam
Thread, sole is combined, safety shoe is made by gluing, the method for cutting with vamp.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108276625A (en) * | 2018-01-25 | 2018-07-13 | 温州鑫彩鸿安防科技有限公司 | A kind of high temperature resistance safety shoe and its manufacturing method |
| CN110922653A (en) * | 2019-11-25 | 2020-03-27 | 安徽华信安全设备有限公司 | Puncture-proof antistatic safety shoe |
| CN111150169A (en) * | 2020-01-07 | 2020-05-15 | 宁乡陆戈鞋业科技有限公司 | Insulation shoe for electrician and manufacturing method thereof |
| CN112137237A (en) * | 2020-09-25 | 2020-12-29 | 扬州健步鞋业有限公司 | Antiskid insulating leather shoes |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101524195A (en) * | 2009-04-16 | 2009-09-09 | 邵良林 | Multifunctional safety shoes with oil resistance, insulation, acid and alkali resistance and high temperature resistance |
| CN101569441A (en) * | 2009-04-16 | 2009-11-04 | 邵良林 | Oil-resistant, insulating, acid and alkali resistant, and high temperature resistant multifunctional safety shoe |
| CN101665594A (en) * | 2008-09-05 | 2010-03-10 | 江苏省派登鞋业有限公司 | Sole material for high temperature resistant labor protection shoes |
| CN102311588A (en) * | 2011-07-20 | 2012-01-11 | 中国皮革和制鞋工业研究院 | Lightweight, flame retardant and rubber foaming sole material and manufacturing method thereof |
| CN102894538A (en) * | 2012-09-13 | 2013-01-30 | 黄乐军 | Temperature-resistant shoe soles |
| CN105330917A (en) * | 2015-11-13 | 2016-02-17 | 吴江市风尚鞋厂 | Insulating and high-temperature-resistant sizing material for rubber shoe sole |
-
2017
- 2017-07-28 CN CN201710630577.4A patent/CN107236164B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101665594A (en) * | 2008-09-05 | 2010-03-10 | 江苏省派登鞋业有限公司 | Sole material for high temperature resistant labor protection shoes |
| CN101524195A (en) * | 2009-04-16 | 2009-09-09 | 邵良林 | Multifunctional safety shoes with oil resistance, insulation, acid and alkali resistance and high temperature resistance |
| CN101569441A (en) * | 2009-04-16 | 2009-11-04 | 邵良林 | Oil-resistant, insulating, acid and alkali resistant, and high temperature resistant multifunctional safety shoe |
| CN102311588A (en) * | 2011-07-20 | 2012-01-11 | 中国皮革和制鞋工业研究院 | Lightweight, flame retardant and rubber foaming sole material and manufacturing method thereof |
| CN102894538A (en) * | 2012-09-13 | 2013-01-30 | 黄乐军 | Temperature-resistant shoe soles |
| CN105330917A (en) * | 2015-11-13 | 2016-02-17 | 吴江市风尚鞋厂 | Insulating and high-temperature-resistant sizing material for rubber shoe sole |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108276625A (en) * | 2018-01-25 | 2018-07-13 | 温州鑫彩鸿安防科技有限公司 | A kind of high temperature resistance safety shoe and its manufacturing method |
| CN108276625B (en) * | 2018-01-25 | 2019-11-22 | 温州鑫彩鸿安防科技有限公司 | A kind of safety shoe resistant to high temperatures and its manufacturing method |
| CN110922653A (en) * | 2019-11-25 | 2020-03-27 | 安徽华信安全设备有限公司 | Puncture-proof antistatic safety shoe |
| CN111150169A (en) * | 2020-01-07 | 2020-05-15 | 宁乡陆戈鞋业科技有限公司 | Insulation shoe for electrician and manufacturing method thereof |
| CN112137237A (en) * | 2020-09-25 | 2020-12-29 | 扬州健步鞋业有限公司 | Antiskid insulating leather shoes |
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| CN107236164B (en) | 2018-12-18 |
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Effective date of registration: 20210208 Address after: 225000 Xinfu Road, Touqiao Town, Guangling District, Yangzhou City, Jiangsu Province Patentee after: YANGZHOU JIANBU SHOE INDUSTRY Co.,Ltd. Address before: 225000 Erqiao village, Touqiao Town, Yangzhou City, Jiangsu Province Patentee before: YANGZHOU DUOLI SHOES AND GARMENT Co.,Ltd. |
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