CN110922653A - Puncture-proof antistatic safety shoe - Google Patents
Puncture-proof antistatic safety shoe Download PDFInfo
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- CN110922653A CN110922653A CN201911161639.7A CN201911161639A CN110922653A CN 110922653 A CN110922653 A CN 110922653A CN 201911161639 A CN201911161639 A CN 201911161639A CN 110922653 A CN110922653 A CN 110922653A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an anti-puncture antistatic safety shoe, which comprises a sole material and a vamp material; the sole material comprises: 40-45 parts of butadiene rubber; 10-12 parts of fluorinated phosphazene rubber; 5-8 parts of cyclohexanone; 8-12 parts of a plasticizer; 2-4 parts of a stabilizer; 3-6 parts of o-tolyl diguanidine; 2-4 parts of boron nitride; 5-7 parts of polyimide fibers; 0.4-0.8 part of a vulcanization accelerator; 0.5-1 part of antistatic agent. The anti-puncture antistatic safety shoe has excellent vamp toughness, enhances the anti-puncture capability of the shoe, and has the performance of promoting the sole and the vamp to keep antistatic.
Description
Technical Field
The invention relates to the technical field of safety shoes, in particular to an anti-puncture antistatic safety shoe.
Background
The safety shoes prepared by the vulcanized rubber process have certain insulating function and good toughness, but are easy to generate static electricity, and in addition, the safety shoes are easy to become brittle and hard after being used for a long time at a low temperature, become uncomfortable when worn, have poor puncture resistance, are only suitable for being worn in common occasions, and are not suitable for being used in occasions such as disaster relief, emergency rescue and the like.
Disclosure of Invention
In view of the above disadvantages, the present invention is directed to provide a puncture-resistant and antistatic safety shoe and a method for manufacturing the same, which has the advantages of puncture resistance and antistatic property.
The technical scheme of the invention is summarized as follows:
a puncture-resistant, antistatic safety shoe, wherein the safety shoe comprises a sole material and an upper material; the sole material comprises:
preferably, the anti-puncture antistatic safety shoe comprises 60-70 wt% of dioctyl adipate and 30-40 wt% of epoxidized soybean oil.
Preferably, the puncture-proof antistatic safety shoe comprises 45-50 wt% of zinc palmitate, 20-25 wt% of tert-butyl hydroquinone and 20-30 wt% of glycerol triacetate.
Preferably, the anti-puncture antistatic safety shoe comprises 30-32 wt% of stannous octoate, 26-28 wt% of zinc tetramethylthiourea isooctanoate and 40-44 wt% of N-cyclohexyl-2-benzothiazole sulfonamide.
Preferably, the anti-puncture antistatic safety shoe is characterized in that the antistatic agent is one of palm alcohol polyoxyethylene ether, nonylphenol polyoxyethylene ether and sodium isethionate.
Preferably, the anti-puncture antistatic safety shoe further comprises 1-4 parts by weight of cesium oxide.
Preferably, the anti-puncture antistatic safety shoe is characterized in that the upper material is made of canvas coated with anti-puncture glue, the coating amount of the anti-puncture glue is 25-30% of the mass of the canvas, and the anti-puncture glue comprises the following components in parts by weight:
preferably, the anti-puncture antistatic safety shoe further comprises 3-5 parts of polydimethylsiloxane.
Preferably, the anti-puncture antistatic safety shoe further comprises 0.5-1 part of 6-hydroxy-5, 12-naphthonaphthoquinone.
The invention has the beneficial effects that:
(1) the anti-puncture antistatic safety shoe has excellent vamp toughness, enhances the anti-puncture capability of the shoe, and has the performance of promoting the sole and the vamp to keep antistatic.
(2) The sole of the safety shoe of the invention mainly comprises butadiene rubber; the fluorinated phosphazene rubber is resistant to high temperature, oil and chemical corrosion and has antistatic performance; o-tolyl diguanidine can raise sulfurizing efficiency and cross-link with phosphonitrile fluoride rubber to raise antistatic performance and cross-linking strength; boron nitride can improve the anti-aging, anti-corrosion and anti-static properties of the sole; the polyimide fiber can improve the wearing comfort performance of the sole, and has good safety and long service life.
Detailed Description
The present invention is further described in detail below with reference to examples so that those skilled in the art can practice the invention with reference to the description.
The invention provides an anti-puncture antistatic safety shoe, which comprises a sole material and a vamp material; the sole material comprises:
the butadiene rubber has the advantages of high elasticity, good wear resistance, good cold resistance, low heat generation, good bending resistance and good dynamic performance; the fluorinated phosphazene rubber is resistant to high temperature, oil and chemical corrosion and has antistatic performance; o-tolyl diguanidine can raise sulfurizing efficiency and cross-link with phosphonitrile fluoride rubber to raise antistatic performance and cross-linking strength; boron nitride can improve the anti-aging, anti-corrosion and anti-static properties of the sole; the polyimide fiber can improve the wearing comfort performance of the sole, and has good safety and long service life.
In another embodiment of the present disclosure, the plasticizer includes 60 to 70 wt% dioctyl adipate and 30 to 40 wt% epoxidized soybean oil. The plasticizer weakens the secondary bond between resin molecules, increases the mobility of the resin molecular bond, reduces the crystallinity of the resin molecules, increases the plasticity of the resin molecules, enhances the flexibility and is easy to process.
As another embodiment of the present invention, the stabilizer comprises 45-50 wt% of zinc palmitate, 20-25 wt% of tert-butylhydroquinone and 20-30 wt% of glyceryl triacetate. The light stability and heat stability of the composite are improved by adding zinc palmitate, tert-butyl hydroquinone and glycerol triacetate.
As another embodiment of the present invention, the vulcanization accelerator comprises 30-32 wt% of stannous octoate, 26-28 wt% of zinc tetramethylthiourea isooctanoate, and 40-44 wt% of N-cyclohexyl-2-benzothiazole sulfonamide. The vulcanization accelerator can shorten the vulcanization time, reduce the vulcanization temperature, reduce the consumption of vulcanizing agent and improve the physical and mechanical properties of rubber, and the preferable vulcanization accelerator in the scheme is stannous octoate, zinc tetramethyl thiourea isooctanoate and N-cyclohexyl-2-benzothiazole sulfonamide.
As another embodiment of the present disclosure, the antistatic agent is one of palmityl alcohol polyoxyethylene ether, nonylphenol polyoxyethylene ether, and sodium isethionate. The antistatic property of the safety shoe is improved by adding the antistatic agent, and the preferred antistatic agent in the scheme is palm alcohol polyoxyethylene ether, nonylphenol polyoxyethylene ether and sodium isethionate.
As another embodiment of the present disclosure, the composition further comprises 1 to 4 parts by weight of cesium oxide. The puncture resistance of the sole is improved by adding cesium oxide.
As another embodiment of the scheme, the shoe upper material is made of canvas coated with anti-puncture glue, the coating amount of the anti-puncture glue is 25-30% of the mass of the canvas, and the anti-puncture glue comprises the following components in parts by weight:
the methyl vinyl silicone rubber has high and low temperature resistance, electrical insulation performance, aging resistance, surface non-adhesiveness and hydrophobic performance; the maleimide modified organic silicon resin improves the softness and the anti-puncture performance of the vamp material; the poly-1-butene has chemical resistance, aging resistance and electrical insulation; the diaminocyclohexane is resistant to high and low temperatures and can work for a long time at the temperature of-50-250 ℃, and the carnauba wax improves the softness of the vamp and improves the anti-puncture performance；Phthalic anhydride is used as a curing agent to improve the curing performance of the puncture-proof glue.
As another embodiment of the present invention, the silicone composition further comprises 3 to 5 parts of polydimethylsiloxane. The polydimethylsiloxane has good electrical insulation, weather resistance and hydrophobicity and has high puncture resistance.
As another embodiment of the present application, the composition further comprises 0.5-1 part of 6-hydroxy-5, 12-naphthonaphthoquinone. The 6-hydroxy-5, 12-naphthonaphthoquinone has excellent anti-aging performance, and the service life of the vamp material is prolonged.
The preparation method of the puncture-proof antistatic safety shoe comprises the following steps:
(1) mixing butadiene rubber, phosphonitrile fluoride rubber, cyclohexanone, a plasticizer, a stabilizer, o-tolyl diguanidine, boron nitride, polyimide fiber, a vulcanization accelerator, an antistatic agent and cesium oxide according to parts by weight to synthesize a film stock;
(2) placing the raw rubber sheet into a sole mold, applying pressure of 100 plus 110 kilograms to the rubber sheet by adopting an oil press, and vulcanizing at the temperature of 110 plus 120 ℃ for 10-15 minutes to prepare a sole;
(3) coating anti-puncture glue accounting for 20-30% of the canvas mass on the canvas, drying or sun drying, and combining the sole and the vamp by adopting sewing, gluing and cutting methods to manufacture the safety shoe.
Specific examples and comparative examples are listed below:
example 1:
a puncture-proof antistatic safety shoe comprises a sole material and a vamp material; the sole material comprises:
the plasticizer comprises 60 wt% of dioctyl adipate, 40 wt% of epoxidized soybean oil; the stabilizer comprises 45 wt% of zinc palmitate, 25 wt% of tert-butyl hydroquinone and 30 wt% of glycerol triacetate; 30 wt% of stannous octoate, 26 wt% of zinc tetramethylthiourea isooctanoate and 44 wt% of N-cyclohexyl-2-benzothiazole sulfonamide serving as vulcanization accelerators; the antistatic agent is palm alcohol polyoxyethylene ether;
the shoe upper material is made of canvas coated with anti-puncture glue, the coating amount of the anti-puncture glue is 25% of the weight of the canvas, and the anti-puncture glue comprises the following components in parts by weight:
example 2:
a puncture-proof antistatic safety shoe comprises a sole material and a vamp material; the sole material comprises:
the plasticizer comprises 65 wt% of dioctyl adipate, 35 wt% of epoxidized soybean oil; the stabilizer comprises 48 wt% of zinc palmitate, 23 wt% of tert-butyl hydroquinone and 29 wt% of glycerol triacetate; 31 wt% of stannous octoate, 27 wt% of zinc tetramethylthiourea isooctanoate and 42 wt% of N-cyclohexyl-2-benzothiazole sulfonamide serving as a vulcanization accelerator; the antistatic agent is nonylphenol polyoxyethylene ether; the shoe upper material is made of canvas coated with puncture-proof glue, the coating amount of the puncture-proof glue is 28% of the weight of the canvas, and the puncture-proof glue comprises the following components in parts by weight:
example 3:
a puncture-proof antistatic safety shoe comprises a sole material and a vamp material; the sole material comprises:
the plasticizer comprises 70 wt% of dioctyl adipate, 30 wt% of epoxidized soybean oil; the stabilizer comprises 50 wt% of zinc palmitate, 25 wt% of tert-butyl hydroquinone and 25 wt% of glycerol triacetate; 32 wt% of stannous octoate, 28 wt% of zinc tetramethylthiourea isooctanoate and 40 wt% of N-cyclohexyl-2-benzothiazole sulfonamide serving as vulcanization accelerators; the antistatic agent is hydroxyethyl sodium sulfonate
The shoe upper material is made of canvas coated with puncture-proof glue, the coating amount of the puncture-proof glue is 30% of the mass of the canvas, and the puncture-proof glue comprises the following components in parts by weight:
comparative example 1:
a puncture-proof antistatic safety shoe comprises a sole material and a vamp material; the sole material comprises:
the plasticizer comprises 60 wt% of dioctyl adipate, 40 wt% of epoxidized soybean oil; the stabilizer comprises 45 wt% of zinc palmitate, 25 wt% of tert-butyl hydroquinone and 30 wt% of glycerol triacetate; 30 wt% of stannous octoate, 26 wt% of zinc tetramethylthiourea isooctanoate and 44 wt% of N-cyclohexyl-2-benzothiazole sulfonamide serving as vulcanization accelerators; the antistatic agent is palm alcohol polyoxyethylene ether;
the shoe upper material is made of canvas coated with anti-puncture glue, the coating amount of the anti-puncture glue is 25% of the weight of the canvas, and the anti-puncture glue comprises the following components in parts by weight:
comparative example 2:
a puncture-proof antistatic safety shoe comprises a sole material and a vamp material; the sole material comprises:
the plasticizer comprises 60 wt% of dioctyl adipate, 40 wt% of epoxidized soybean oil; the stabilizer comprises 45 wt% of zinc palmitate, 25 wt% of tert-butyl hydroquinone and 30 wt% of glycerol triacetate; 30 wt% of stannous octoate, 26 wt% of zinc tetramethylthiourea isooctanoate and 44 wt% of N-cyclohexyl-2-benzothiazole sulfonamide serving as vulcanization accelerators; the antistatic agent is palm alcohol polyoxyethylene ether;
the shoe upper material is made of canvas coated with anti-puncture glue, the coating amount of the anti-puncture glue is 25% of the weight of the canvas, and the anti-puncture glue comprises the following components in parts by weight:
comparative example 3:
a puncture-proof antistatic safety shoe comprises a sole material and a vamp material; the sole material comprises:
the plasticizer comprises 65 wt% of dioctyl adipate, 35 wt% of epoxidized soybean oil; the stabilizer comprises 48 wt% of zinc palmitate, 23 wt% of tert-butyl hydroquinone and 29 wt% of glycerol triacetate; 31 wt% of stannous octoate, 27 wt% of zinc tetramethylthiourea isooctanoate and 42 wt% of N-cyclohexyl-2-benzothiazole sulfonamide serving as a vulcanization accelerator; the shoe upper material is made of canvas coated with puncture-proof glue, the coating amount of the puncture-proof glue is 28% of the weight of the canvas, and the puncture-proof glue comprises the following components in parts by weight:
comparative example 4:
a puncture-proof antistatic safety shoe comprises a sole material and a vamp material; the sole material comprises:
the plasticizer comprises 65 wt% of dioctyl adipate, 35 wt% of epoxidized soybean oil; the stabilizer comprises 48 wt% of zinc palmitate, 23 wt% of tert-butyl hydroquinone and 29 wt% of glycerol triacetate; 31 wt% of stannous octoate, 27 wt% of zinc tetramethylthiourea isooctanoate and 42 wt% of N-cyclohexyl-2-benzothiazole sulfonamide serving as a vulcanization accelerator; the antistatic agent is nonylphenol polyoxyethylene ether; the shoe upper material is made of canvas coated with puncture-proof glue, the coating amount of the puncture-proof glue is 28% of the weight of the canvas, and the puncture-proof glue comprises the following components in parts by weight:
comparative example 5:
a puncture-proof antistatic safety shoe comprises a sole material and a vamp material; the sole material comprises:
the plasticizer comprises 70 wt% of dioctyl adipate, 30 wt% of epoxidized soybean oil; the stabilizer comprises 50 wt% of zinc palmitate, 25 wt% of tert-butyl hydroquinone and 25 wt% of glycerol triacetate; 32 wt% of stannous octoate, 28 wt% of zinc tetramethylthiourea isooctanoate and 40 wt% of N-cyclohexyl-2-benzothiazole sulfonamide serving as vulcanization accelerators; the antistatic agent is hydroxyethyl sodium sulfonate
The shoe upper material is made of canvas coated with puncture-proof glue, the coating amount of the puncture-proof glue is 30% of the mass of the canvas, and the puncture-proof glue comprises the following components in parts by weight:
comparative example 6:
a puncture-proof antistatic safety shoe comprises a sole material and a vamp material; the sole material comprises:
the plasticizer comprises 70 wt% of dioctyl adipate, 30 wt% of epoxidized soybean oil; the stabilizer comprises 50 wt% of zinc palmitate, 25 wt% of tert-butyl hydroquinone and 25 wt% of glycerol triacetate; 32 wt% of stannous octoate, 28 wt% of zinc tetramethylthiourea isooctanoate and 40 wt% of N-cyclohexyl-2-benzothiazole sulfonamide serving as vulcanization accelerators; the antistatic agent is hydroxyethyl sodium sulfonate
The shoe upper material is made of canvas coated with puncture-proof glue, the coating amount of the puncture-proof glue is 30% of the mass of the canvas, and the puncture-proof glue comprises the following components in parts by weight:
the antistatic properties of the soles and the uppers of the products of examples 1 to 3 and comparative examples 1 to 6 were tested using the standard provisions GB12011 to 20004.2.1 (passing at a temperature of 20 ℃, a relative humidity of 60%, a working test voltage of 6kV, a duration of 1min, and a leakage current of less than 1.8), the data being shown in Table 1: the tearing strength of the soles and the vamps (more than 60N/mm is qualified) is tested by adopting standard terms GB12011-20003.3, the puncture-proof performance of the soles and the vamps of the products of examples 1-3 and comparative examples 1-6 is tested, and the data are shown in Table 1:
TABLE 1
As can be seen from Table 1, the soles of examples 1-3 have excellent vamp toughness, enhance the puncture resistance, and promote the soles and the vamps to keep antistatic performance.
While embodiments of the invention have been disclosed above, it is not limited to the applications listed in the description and the embodiments, which are fully applicable in all kinds of fields of application of the invention, and further modifications may readily be effected by those skilled in the art, so that the invention is not limited to the specific details without departing from the general concept defined by the claims and the scope of equivalents.
Claims (9)
1. A puncture-resistant antistatic safety shoe is characterized in that the safety shoe comprises a sole material and a vamp material; the sole material comprises:
2. the puncture-resistant antistatic safety shoe according to claim 1, wherein the plasticizer comprises 60 to 70 wt% dioctyl adipate, 30 to 40 wt% epoxidized soybean oil.
3. The puncture-resistant antistatic safety shoe as claimed in claim 1, wherein the stabilizer comprises 45-50 wt% of zinc palmitate, 20-25 wt% of tert-butylhydroquinone and 20-30 wt% of glyceryl triacetate.
4. The anti-puncture antistatic safety shoe according to claim 1, wherein the vulcanization accelerator comprises 30 to 32 wt% of stannous octoate, 26 to 28 wt% of zinc tetramethylthiourea isooctanoate, and 40 to 44 wt% of N-cyclohexyl-2-benzothiazolesulfenamide.
5. The anti-pierce antistatic safety shoe according to claim 1, wherein the antistatic agent is one of palm alcohol polyoxyethylene ether, nonylphenol polyoxyethylene ether, and sodium isethionate.
6. The puncture-resistant antistatic safety shoe as claimed in claim 1, further comprising 1 to 4 parts by weight of cesium oxide.
7. The anti-puncture antistatic safety shoe as claimed in claim 1, wherein the upper material is made of canvas coated with anti-puncture glue, the coating amount of the anti-puncture glue is 25-30% of the mass of the canvas, and the anti-puncture glue comprises the following components in parts by weight:
8. the anti-puncture and anti-static safety shoe according to claim 7, further comprising 3 to 5 parts of polydimethylsiloxane.
9. The puncture-resistant antistatic safety shoe as claimed in claim 7, further comprising 0.5 to 1 part of 6-hydroxy-5, 12-naphthonaphthonaphthoquinone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911161639.7A CN110922653A (en) | 2019-11-25 | 2019-11-25 | Puncture-proof antistatic safety shoe |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911161639.7A CN110922653A (en) | 2019-11-25 | 2019-11-25 | Puncture-proof antistatic safety shoe |
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| CN110922653A true CN110922653A (en) | 2020-03-27 |
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| CN201911161639.7A Pending CN110922653A (en) | 2019-11-25 | 2019-11-25 | Puncture-proof antistatic safety shoe |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112932010A (en) * | 2021-03-03 | 2021-06-11 | 温州美联美鞋业有限公司 | Women's shoes with anti-cracking vamps and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005008650A (en) * | 2003-04-22 | 2005-01-13 | Tokuyama Corp | Filler for clear rubber |
| JP2006063183A (en) * | 2004-08-26 | 2006-03-09 | Jsr Corp | Thermoplastic polymer composition |
| CN101238920A (en) * | 2008-03-13 | 2008-08-13 | 际华三五一七橡胶制品有限公司 | Special type protection work shoes with antistatic oil-resistant function |
| CN103829452A (en) * | 2014-03-17 | 2014-06-04 | 德州市鑫华润聚氨酯鞋材股份有限公司 | Antistatic combined shoe sole and manufacturing method thereof |
| CN107236164A (en) * | 2017-07-28 | 2017-10-10 | 扬州多力鞋服有限公司 | A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe |
| CN107383467A (en) * | 2017-07-28 | 2017-11-24 | 扬州健步鞋业有限公司 | One kind is anti-to pound acid and alkali-resistance anti-skid multifunctional safety shoe |
-
2019
- 2019-11-25 CN CN201911161639.7A patent/CN110922653A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005008650A (en) * | 2003-04-22 | 2005-01-13 | Tokuyama Corp | Filler for clear rubber |
| JP2006063183A (en) * | 2004-08-26 | 2006-03-09 | Jsr Corp | Thermoplastic polymer composition |
| CN101238920A (en) * | 2008-03-13 | 2008-08-13 | 际华三五一七橡胶制品有限公司 | Special type protection work shoes with antistatic oil-resistant function |
| CN103829452A (en) * | 2014-03-17 | 2014-06-04 | 德州市鑫华润聚氨酯鞋材股份有限公司 | Antistatic combined shoe sole and manufacturing method thereof |
| CN107236164A (en) * | 2017-07-28 | 2017-10-10 | 扬州多力鞋服有限公司 | A kind of high-temperature insulation is anti-to pierce through anti-skid multifunctional safety shoe |
| CN107383467A (en) * | 2017-07-28 | 2017-11-24 | 扬州健步鞋业有限公司 | One kind is anti-to pound acid and alkali-resistance anti-skid multifunctional safety shoe |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112932010A (en) * | 2021-03-03 | 2021-06-11 | 温州美联美鞋业有限公司 | Women's shoes with anti-cracking vamps and preparation method thereof |
| CN112932010B (en) * | 2021-03-03 | 2022-04-22 | 温州美联美鞋业有限公司 | Women's shoes with anti-cracking vamps and preparation method thereof |
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Application publication date: 20200327 |