CN108192162B - A kind of Sports shoe sole abrasive rubber and preparation method thereof - Google Patents
A kind of Sports shoe sole abrasive rubber and preparation method thereof Download PDFInfo
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- CN108192162B CN108192162B CN201711453911.XA CN201711453911A CN108192162B CN 108192162 B CN108192162 B CN 108192162B CN 201711453911 A CN201711453911 A CN 201711453911A CN 108192162 B CN108192162 B CN 108192162B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/002—Methods
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of Sports shoe sole abrasive rubbers, in terms of mass parts, including 50-80 parts of butadiene rubber, 10-30 parts of epoxy natural rubber, 5-20 parts of hydrogenated nitrile-butadiene rubber, 1-2 parts of homogenizing agent, 2-5 parts of silane coupling agent, 25-65 parts of reinforcing agent, Zinc Oxide 2-5,2-5 parts of polyethylene glycol, 0.5-2 parts of zinc stearate, 1.5-2 parts of vulcanizing agent, 1.6-2.1 parts of promotor, 0.5-2 parts of tackifier, 2-5 parts of softening oil, 1-3 parts of anti-aging agent and 0.5-1 parts of paraffin.The present invention also provides a kind of preparation method of above-mentioned Sports shoe sole abrasive rubber simultaneously.The Sports shoe sole wear-resistant rubber sole of technical solution of the present invention production with the incomparable super wear resistance energy of General Purpose Rubber sole, and has the multiple performances such as good weatherability and folding quality, and the production process of preparation method is simple, is suitble to be widely applied.
Description
Technical field
The present invention relates to Material Fields, and in particular to a kind of Sports shoe sole abrasive rubber and preparation method thereof.
Background technique
Sport footwear is due to its special purposes, it is desirable that its sole rubber has wear-resisting property, good folding quality and resistance to
Hou Xing.Although current Sports shoe sole abrasive rubber has certain wear-resisting property, elastic, weather-proof there are many deficiencies
Performance is poor, Sports shoe sole repeatedly spring, run during, sole is worn quickly, while the sole under more adverse circumstances
Material is easy aging lost its bounce, in addition, current Sports shoe sole is larger with abrasive rubber shrinkage, slice out-of-flatness, slice
Thickness is not easy to control, and in back segment sulfidation, because the air-tightness of material is strong, poor fluidity, shrinkage is big, be vented it is bad etc. because
Element, defect rate is more, influences production efficiency.Therefore, existing Sports shoe sole abrasive rubber and preparation method thereof is still into one
Step is improved.
Summary of the invention
It is an object of the invention to solve the problems of the prior art, providing a kind of has super wear resistance energy, good resistance to
Sports shoe sole abrasive rubber of multiple performances such as time property and folding quality and preparation method thereof.
A kind of Sports shoe sole abrasive rubber, in terms of mass parts, including 50-80 parts of butadiene rubber, epoxy natural rubber 10-
30 parts, 5-20 parts of hydrogenated nitrile-butadiene rubber, 1-2 parts of homogenizing agent, 2-5 parts of silane coupling agent, 25-65 parts of reinforcing agent, Zinc Oxide 2-5,
It is 2-5 parts of polyethylene glycol, 0.5-2 parts of zinc stearate, 1.5-2 parts of vulcanizing agent, 1.6-2.1 parts of promotor, 0.5-2 parts of tackifier, soft
2-5 parts of carburetion, 1-3 parts of anti-aging agent and 0.5-1 parts of paraffin.
Preferably, the silane coupling agent is double-[3- (triethoxysilicane) propyl]-tetrasulfide.
Preferably, the reinforcing agent is white carbon black and nano oxidized aluminium mixture, and wherein white carbon black is 20-50 parts, nanometer
Aluminium oxide is 5-15 parts.
Preferably, the vulcanizing agent is sulphur.
Preferably, the promotor is that thiazoles, thiurams and dithiocarbamates mix class promotor.
Preferably, the tackifier are aqueous tackifier resin.
Preferably, the softening oil is paraffinic base rubber softening oil.
Preferably, the anti-aging agent is di-tert-butyl p-cresol.
Present invention simultaneously provides a kind of preparation methods of Sports shoe sole abrasive rubber, comprising the following steps:
1) following component is weighed by mass parts: 50-80 parts of butadiene rubber, 10-30 parts of epoxy natural rubber, hydrogenated butyronitrile rubber
5-20 parts of glue, 1-2 parts of homogenizing agent, 2-5 parts of silane coupling agent, 25-65 parts of reinforcing agent, Zinc Oxide 2-5,2-5 parts of polyethylene glycol, firmly
0.5-2 parts of resin acid zinc, 0.5-2 parts of tackifier, 2-5 parts of softening oil, 1-3 parts of anti-aging agent, 0.5-1 parts of paraffin；
2) all the components weighed in step 1) will be kneaded, the time of mixing is 7-9 minutes, and temperature is
120-140℃；
3) mixture obtained in step 2) is taken out and is cooled down；
4) following component is weighed by mass parts: 1.5-2 parts and promotor 1.6-2.1 parts of vulcanizing agent；
5) material after cooling in all the components weighed in step 4) and step 3) is kneaded, the time of mixing
It is 3-5 minutes, temperature is 50-70 DEG C
To reach above-mentioned purpose, the present invention adopts the following technical scheme:
Compared with the existing technology, the beneficial effect of acquirement is technical solutions according to the invention:
For the present invention using butadiene rubber as main material, butadiene rubber is the second largest synthesis rubber for being only second to butadiene-styrene rubber
Glue, compared with natural rubber and butadiene-styrene rubber, its cold resistance, wearability and elasticity are especially excellent after vulcanization, generate heat under dynamic load
It is few, there is good wear-resisting property to have good wear-resisting property to make product also；It is natural with hydrogenated nitrile-butadiene rubber and epoxy
Rubber is auxiliary material, and hydrogenated nitrile-butadiene rubber is to carry out a kind of HI SA highly saturated elasticity obtained from special hydrotreating to nitrile rubber
Body, with good oil resistance, and its HI SA highly saturated structure assigns its good heat resistance, and excellent chemically-resistant is rotten
Corrosion energy, excellent ozone resistance, higher incompressible permanent deformation performance；Hydrogenated nitrile-butadiene rubber also has high-strength simultaneously
Degree, high tear energy, the features such as wear-resisting property is excellent make product have super antiskid property and good wearability；Epoxidation is natural
Rubber is that the partial double bond by epoxidation reaction modified natural rubber, on rubber molecular chain is oxidized rear preparation, epoxy
The polarity of rubber macromolecule increases after changing, intermolecular force enhancing, therefore epoxy natural rubber is made both to have remained with natural rubber
The basic structure and performance characteristics of glue, and many unique performances are produced, mainly have: excellent air-tightness, excellent oil resistant
Property, compatibility, anti-slippery, low rolling resistance and the good adhesive property between other materials etc..
To improve the comprehensive performances such as butadiene rubber processability and tear resistance, the present invention by butadiene rubber with good
The epoxy natural rubber and hydrogenated nitrile-butadiene rubber of good comprehensive performance are used in combination, to improve the overall performance of rubber aniseed itself.
Specifically, wherein the tackifier being added, include aqueous tackifier lotion, aqueous tackifier resin, aqueous tackifier powder, thickening
Rosin resin, modified rosin resin etc., this case preferably use aqueous tackifier resin, can make butadiene rubber, epoxy natural rubber and
The respective decomposition of hydrogenated nitrile-butadiene rubber is more abundant, it is easier to be stirred evenly, be mixed.
The flexible resistance of rubber can be improved as reinforcing agent for white carbon black and nano aluminium oxide that product of the present invention uses, make
Have it is good deflect fatigue performance, nano aluminium oxide has biggish specific surface area and high activity high absorption capacity, receives
The addition of rice aluminium oxide can be contacted with rubber macromolecule generates strong physical crosslinking effect, forms firm cross-bond, so that
Cross-linked network more improves to increase the wear-resisting property of rubber；But for reinforcing agent in process easily conglomeration, point
Dissipate bad phenomenon, the present invention using environment-friendly type coupling agent it is double-[3- (triethoxysilicane) propyl]-tetrasulfide to white carbon black into
Row is modified, and uses softening oil simultaneously, makes reinforcing agent and powder compounding agent complete wetting, dispersion, to reach optimum efficiency.
It specifically, can be on sizing material surface using having excellent antioxygen, ozone resisting anti-aging agent and paraffin in product of the present invention
One layer of cured film is formed, the infiltration of ozone can be prevented, reaching well has protective action；And the vulcanizing agent being added is sulphur, activity
Agent is polyethylene glycol and Zinc Oxide, stearic acid, has activated entire vulcanizing system, improves the crosslink density of vulcanizate simultaneously
The heat aging property for improving vulcanizate improves the fatigue life of vulcanizate, and dynamic property is good.Add by thiazoles,
The mixed accelerators of thiurams, dithiocarbamates can shorten vulcanization time, reduce curing temperature, reduce vulcanization
The dosage of agent and the physical mechanical property for improving rubber, more can make its sulfidation more preferable.
With the Sports shoe sole wear-resistant rubber sole that this technical solution makes, have General Purpose Rubber sole incomparable
Super wear resistance energy, and there are the multiple performances such as good weatherability and folding quality.
Accordingly the present invention also provides a kind of preparation method of Sports shoe sole abrasive rubber, the Sports shoe sole is with wear-resisting
The production process of rubber is simple, only various composition need to be packed into kneading machine in order and is kneaded, and the time is short, and operating condition is suitable
Preferably, the operation cycle is short, the super wear resistance energy that obtained rubber has General Purpose Rubber sole incomparable, and has good resistance to
The multiple performances such as time property and folding quality, are suitable for being widely applied.
Specific embodiment
In order to be clearer and more clear technical problems, technical solutions and advantages to be solved, tie below
Embodiment is closed, the present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only to explain
The present invention is not intended to limit the present invention.
The present invention provides a kind of Sports shoe sole abrasive rubber, in terms of mass parts, including 50-80 parts of butadiene rubber, epoxy
10-30 parts of natural rubber, 5-20 parts of hydrogenated nitrile-butadiene rubber, 1-2 parts of homogenizing agent, 2-5 parts of silane coupling agent, white carbon black 20-50
Part, promotes 5-15 parts of nano aluminium oxide, Zinc Oxide 2-5,2-5 parts of polyethylene glycol, 0.5-2 parts of zinc stearate, 1.5-2 parts of sulphur
1.6-2.1 parts of agent, 0.5-2 parts of aqueous tackifier resin, 2-5 parts of softening oil, 1-3 parts of anti-aging agent and 0.5-1 parts of paraffin.
Wherein, silane coupling agent is double-[3- (triethoxysilicane) propyl]-tetrasulfide.Promotor is thiazoles, Qiu Lan
Nurse class and dithiocarbamates mix class promotor.Softening oil is paraffinic base rubber softening oil.Anti-aging agent is two tertiary fourths
Base paracresol tackifier are aqueous tackifier resin.
Present invention simultaneously provides a kind of preparation methods of Sports shoe sole abrasive rubber, comprising the following steps:
1) following component is weighed by mass parts: 50-80 parts of butadiene rubber, 10-30 parts of epoxy natural rubber, hydrogenated butyronitrile rubber
5-20 parts of glue, 1-2 parts of homogenizing agent, 2-5 parts of silane coupling agent, 20-50 parts of white carbon black, 5-15 parts of nano aluminium oxide, Zinc Oxide 2-
5,2-5 parts of polyethylene glycol, 0.5-2 parts of zinc stearate, 0.5-2 parts of aqueous tackifier resin, 2-5 parts of softening oil, 1-3 parts of anti-aging agent,
0.5-1 parts of paraffin；
2) all the components weighed in step 1) mixer will be poured into be kneaded, the time of mixing is 7-9 minutes,
Temperature is 120-140 DEG C；
3) by mixture obtained in step 2), discharging, slice, cooling；
4) following component is weighed by mass parts: 1.5-2 parts and promotor 1.6-2.1 parts of sulphur；
5) material after cooling in step 3) is put on material preparing table and beats heat, then with all the components weighed in step 4)
It is kneaded, the time of mixing is 3-5 minutes, and temperature is 50-70 DEG C, then slice is got product through sulfidization molding.
According to above Sports shoe sole abrasive rubber and preparation method thereof, Sports shoe sole abrasive rubber of the invention can
Different formula combinations is selected, to meet the requirement of different product, following examples show a variety of different Sports shoe sole use
The formula combination and its preparation process of abrasive rubber.
Table 1: Sports shoe sole is with wearable rubber formulation (part)
Wherein, silane coupling agent is double-[3- (triethoxysilicane) propyl]-tetrasulfide, and softening oil is paraffinic base rubber
Softening oil, anti-aging agent are di-tert-butyl p-cresol.
Wherein, in embodiment 1, the mixing time in step 2) is 9 minutes, and temperature is 120-140 DEG C；In step 5)
Mixing time is 3 minutes, and temperature is 50-70 DEG C；
In embodiment 2, the mixing time in step 2) is 7 minutes, and temperature is 120-140 DEG C；When mixing in step 5)
Between be 5 minutes, temperature be 50-70 DEG C；
In embodiment 3, the mixing time in step 2) is 8 minutes, and temperature is 120-140 DEG C；When mixing in step 5)
Between be 4 minutes, temperature be 50-70 DEG C.
By Sports shoe sole abrasive rubber obtained by above-described embodiment 1,2 and 3, carry out performance detection, at the same with it is existing
The performance of product compares, as a result such as the following table 2.
Table 2: the performance of embodiment 1-3 and existing Sports shoe sole abrasive rubber
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Hardness (Shao Er A) | 67 | 68 | 67 |
| Tensile strength (MPa) | 17 | 18 | 17 |
| Elongation at break (%) | 737 | 745 | 742 |
| Right-angle tearing (N/cm) | 72 | 69 | 70 |
| DIN(mm3) | 33 | 31 | 35 |
| Density (g/cm3) | 1.13 | 1.14 | 1.13 |
| Folding quality (mm) | 5.1 | 5.2 | 5.2 |
| Anti-hydrolytic performance | Meet | Meet | Meet |
Note: 2 data of table are the data obtained by national standard test method.
By data in table 2 it is found that Sports shoe sole abrasive rubber of the present invention, is solved perfectly the behaviour of existing wearable rubber formulation
Make performance: it is easy to operate, as planarization of the material in slice is good, shrinkage is small and can improve vulcanization of rubber exhaust well
Performance etc., so that the product quality and the production efficiency that improve, reduce production cost；In terms of physical property, wear-resisting property side
Face is more prominent, and can it is firm well it is weather-proof can and folding quality (be less than 5.2mm) also much smaller than existing product, meet country
Related physical performance standard.
For the present invention using butadiene rubber as main material, butadiene rubber is the second largest synthesis rubber for being only second to butadiene-styrene rubber
Glue, compared with natural rubber and butadiene-styrene rubber, its cold resistance, wearability and elasticity are especially excellent after vulcanization, generate heat under dynamic load
It is few, make its product that there is good wear-resisting property with good wear-resisting property；It is natural with hydrogenated nitrile-butadiene rubber and epoxy
Rubber is auxiliary material, and hydrogenated nitrile-butadiene rubber is to carry out a kind of HI SA highly saturated elasticity obtained from special hydrotreating to nitrile rubber
Body, with good oil resistance and its HI SA highly saturated structure assigns its good heat resistance, excellent chemically-resistant
Corrosive nature, excellent ozone resistance, higher incompressible permanent deformation performance；Hydrogenated nitrile-butadiene rubber also has high-strength simultaneously
Degree, high tear energy, the features such as wear-resisting property is excellent make product have super antiskid property and good wearability；Epoxidation is natural
Rubber is that the partial double bond by epoxidation reaction modified natural rubber, on rubber molecular chain is oxidized rear preparation, epoxy
The polarity of rubber macromolecule increases after changing, intermolecular force enhancing, therefore epoxy natural rubber is made both to have remained with natural rubber
The basic structure and performance characteristics of glue, and many unique performances are produced, mainly have: excellent air-tightness, excellent oil resistant
Property, compatibility, anti-slippery, low rolling resistance and the good adhesive property between other materials etc..
To improve the comprehensive performances such as butadiene rubber processability and tear resistance, the present invention by butadiene rubber with good
The epoxy natural rubber and hydrogenated nitrile-butadiene rubber of good comprehensive performance are used in combination, to improve the overall performance of rubber aniseed itself.
Specifically, wherein the tackifier being added, include aqueous tackifier lotion, aqueous tackifier resin, aqueous tackifier powder, thickening
Rosin resin, modified rosin resin etc., this case preferably use aqueous tackifier resin, can make butadiene rubber, epoxy natural rubber and
The respective decomposition of hydrogenated nitrile-butadiene rubber is more abundant, it is easier to be stirred evenly, be mixed.
The flexible resistance of rubber can be improved as reinforcing agent for white carbon black and nano aluminium oxide that product of the present invention uses, make
Have it is good deflect fatigue performance, nano aluminium oxide has biggish specific surface area and high activity high absorption capacity, receives
The addition of rice aluminium oxide can be contacted with rubber macromolecule generates strong physical crosslinking effect, forms firm cross-bond, so that
Cross-linked network more improves to increase the wear-resisting property of rubber；But for reinforcing agent in process easily conglomeration, point
Dissipate bad phenomenon, the present invention using environment-friendly type coupling agent it is double-[3- (triethoxysilicane) propyl]-tetrasulfide to white carbon black into
Row is modified, and uses softening oil simultaneously, makes reinforcing agent and powder compounding agent complete wetting, dispersion, to reach optimum efficiency.
It specifically, can be on sizing material surface using having excellent antioxygen, ozone resisting anti-aging agent and paraffin in product of the present invention
One layer of cured film is formed, the infiltration of ozone can be prevented, reaching well has protective action；And the vulcanizing agent being added is sulphur, activity
Agent is polyethylene glycol and Zinc Oxide, stearic acid, has activated entire vulcanizing system, improves the crosslink density of vulcanizate simultaneously
The heat aging property for improving vulcanizate improves the fatigue life of vulcanizate, and dynamic property is good.Add by thiazoles,
The mixed accelerators of thiurams, dithiocarbamates can shorten vulcanization time, reduce curing temperature, reduce vulcanization
The dosage of agent and the physical mechanical property for improving rubber, more can make its sulfidation more preferable.
With the Sports shoe sole wear-resistant rubber sole that this technical solution makes, have General Purpose Rubber sole incomparable
Super wear resistance energy, and there are the multiple performances such as good weatherability and folding quality.
The production process of preparation method of the invention, the Sports shoe sole abrasive rubber is simple, need to only press various composition
Sequence is packed into kneading machine and is kneaded, and the time is short, and operating condition is suitable for that the operation cycle is short, and obtained rubber has General Purpose Rubber
The incomparable super wear resistance energy of sole, and there are the multiple performances such as good weatherability and folding quality, it is suitable for extensively
Using.
Description above describe the preferred embodiment of the present invention, it is to be understood that the present invention is not limited to above-mentioned implementation
Example, and excluding other embodiments should not be regarded as.Enlightenment through the invention, those skilled in the art combine known or existing
The change that technology, knowledge are carried out also should be regarded as in protection scope of the present invention.
Claims (8)
1. a kind of Sports shoe sole abrasive rubber, it is characterised in that: in terms of mass parts, including 50-80 parts of butadiene rubber, epoxy day
Right 10-30 parts of rubber, 5-20 parts of hydrogenated nitrile-butadiene rubber, 1-2 parts of homogenizing agent, 2-5 parts of silane coupling agent, 25-65 parts of reinforcing agent, zinc
Oxygen powder 2-5,2-5 parts of polyethylene glycol, 0.5-2 parts of zinc stearate, 1.5-2 parts of vulcanizing agent, 1.6-2.1 parts of promotor, tackifier
0.5-2 parts, 2-5 parts of softening oil, 1-3 parts of anti-aging agent and 0.5-1 parts of paraffin.
2. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that: the silane coupling agent be it is double-
[3- (triethoxysilicane) propyl]-tetrasulfide.
3. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that: the reinforcing agent be white carbon black and
Nano oxidized aluminium mixture, wherein white carbon black is 20-50 parts, and nano aluminium oxide is 5-15 parts.
4. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that: the vulcanizing agent is sulphur.
5. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that: the promotor be thiazoles,
Thiurams and dithiocarbamates mix class promotor.
6. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that: the tackifier are aqueous tackifier
Resin.
7. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that: the softening oil is paraffinic base rubber
Gum softening oil.
8. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that: the anti-aging agent is di-t-butyl
Paracresol.
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| CN201711453911.XA CN108192162B (en) | 2017-12-28 | 2017-12-28 | A kind of Sports shoe sole abrasive rubber and preparation method thereof |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108851336A (en) * | 2018-06-29 | 2018-11-23 | 广州华腾云谷科技有限公司 | Antiskid sole |
| CN109083523A (en) * | 2018-09-25 | 2018-12-25 | 江苏三乔智能科技有限公司 | Door and window support rod |
| CN111533967B (en) * | 2020-06-16 | 2022-05-17 | 广东石油化工学院 | Rubber sole and preparation method thereof |
| CN113717446A (en) * | 2020-12-08 | 2021-11-30 | 佛山市大唐新新橡塑有限公司 | Temperature-variable rubber |
| CN112679871B (en) * | 2020-12-25 | 2023-06-06 | 安踏（中国）有限公司 | Composite rubber, preparation method thereof and sole material |
| CN117362772A (en) * | 2023-11-06 | 2024-01-09 | 浙江天台祥和实业股份有限公司 | High-wear-resistance rubber material and preparation method thereof |
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| CN102061017B (en) * | 2010-12-06 | 2012-10-10 | 安踏（中国）有限公司 | Rubber for sneaker sole and preparation method thereof |
| JP5882685B2 (en) * | 2011-11-10 | 2016-03-09 | 弘進ゴム株式会社 | Oil and slip resistant sole |
| CN104277274B (en) * | 2014-08-07 | 2016-07-20 | 福建登泰科技有限公司 | A kind of oil-proof anti-skid rubber soles and preparation method thereof |
| CN105330908A (en) * | 2015-11-13 | 2016-02-17 | 吴江市风尚鞋厂 | Composite TPR type shoe material and preparation method thereof |
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