CN105330908A - Composite TPR type shoe material and preparation method thereof - Google Patents
Composite TPR type shoe material and preparation method thereof Download PDFInfo
- Publication number
- CN105330908A CN105330908A CN201510777992.3A CN201510777992A CN105330908A CN 105330908 A CN105330908 A CN 105330908A CN 201510777992 A CN201510777992 A CN 201510777992A CN 105330908 A CN105330908 A CN 105330908A
- Authority
- CN
- China
- Prior art keywords
- parts
- compound
- weight
- footwear material
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a composite TPR type shoe material and a preparation method thereof. The preparation method comprises the following steps that 1, ball milling is conducted on calcium sulfate and boron nitride respectively through a ball mill for 2-4 h, the ball-to-powder weight ratio in the ball mill ranges from 15:1 to 25:1, and the calcium sulfate and the boron nitride are ball-milled for standby; 2, 6-15 parts by weight of polyisoprene, 4-10 parts by weight of butadiene rubber, 2-8 parts by weight of hydrogenated nitrile rubber, 4-10 parts by weight of polyphenylene sulfide resin, 2-4 parts by weight of triallyl isocyanurate, 2-5 parts by weight of polymethacrylamidopropyltrimonium chloride, 3-6 parts by weight of polyethylene wax, 5-10 parts by weight of polyvinylidene fluoride, 3-8 parts by weight of calcium sulfate and 2-4 parts by weight of boron nitride are taken for even mixing, internal mixing is conducted through a mixer, the internal mixing temperature ranges from 90 DEG C to 120 DEG C, and the internal mixing time ranges from 5 min to 10 min; 3, open mixing is conducted on an internally mixed mixture on an open mixing mill, granulation is conducted, and the composite TPR shoe material is obtained.
Description
Technical field
The invention belongs to footwear material field, be specifically related to a kind of compound TPR type footwear material and preparation method thereof.
Technical background
Thermoplastic elastomer (ThermoplasticRubber), it is a kind of material having rubber and thermoplastics characteristic concurrently, there is the performance of rubber can be undertaken processing and reclaiming by thermoplastics again, rubber item can be made with common plastic cement forming mill in the mode of ejection formation, extrusion moulding, blow molding.The material of sole has a lot, as TPU sole, and PVC sole, at the bottom of EVA shoe, PU sole, TPE sole.TPR sole is a kind of environment-friendly materials of novel thermoplastic rubber, has the performance of rubber and the characteristic of plastics concurrently, does not need sulfuration, and complete processing is simple, casting after heating.TPR material has adjustable physical property, easy-formation.Heavy TPR sole, footwear material weight, pliability is poor, so low price.Price decision sole quality factor, TPR sole proportion is little, and footwear material is light, good springiness, easily colouring, good permeability, intensity height etc. feature.
Summary of the invention
The technical problem solved: TPR type footwear material is in occupation of very large market in the kind of various footwear material, and TPR type footwear material is obtained for widespread use in multiple field, the object of the invention is the elongation at break of raising TPR type footwear material, elasticity and abrasive wear resistance thereof.
Technical scheme: a kind of compound TPR type footwear material, comprises the composition of following weight parts:
Preferably, described a kind of compound TPR type footwear material, comprises the composition of following weight parts:
The preparation method of described a kind of compound TPR type footwear material, step is as follows:
(1) calcium sulfate and boron nitride are separately used ball mill ball milling 2-4h, in ball mill, ratio of grinding media to material is 15:1-25:1, for subsequent use after ball milling;
(2) polyisoprene 6-15 part, cis-1,4-polybutadiene rubber 4-10 part, hydrogenated nitrile-butadiene rubber 2-8 part, polyphenylene sulfide 4-10 part, cyanacrylate 2-4 part, PMAm hydroxypropyltrimonium chloride 2-5 part, polyethylene wax 3-6 part, poly(vinylidene fluoride) 5-10 part, calcium sulfate 3-8 part, boron nitride 2-4 part is got by weight respectively, above-mentioned composition is mixed rear Banbury mixer banburying, banburying temperature is 90-120 DEG C, and the banburying time is 5-10min;
(3) again the mixture after banburying is opened refining more on a mill until, then carry out granulation, obtain compound TPR type footwear material.
Preferably, the preparation method of described a kind of compound TPR type footwear material, in described step (1), in ball mill, ratio of grinding media to material is 20:1.
Preferably, the preparation method of described a kind of compound TPR type footwear material, in described step (1), Ball-milling Time is 3h.
Preferably, the preparation method of described a kind of compound TPR type footwear material, in described step (2), banburying temperature is 110 DEG C.
Preferably, the preparation method of described a kind of compound TPR type footwear material, in described step (2), the banburying time is 7min.
Beneficial effect: add in compound TPR type footwear material of the present invention polyphenylene sulfide, cyanacrylate, PMAm hydroxypropyltrimonium chloride, poly(vinylidene fluoride) to improving the elongation at break of original elastomeric material, elastic contribution is remarkable, the boron nitride added in addition also acts on significantly to the abrasive wear resistance improving TPR type footwear material, the comprehensive characteristic improving the TPR type footwear material of preparation.
Specific embodiment
Below in conjunction with specific embodiment, the present invention is further described.
Embodiment 1
(1) calcium sulfate and boron nitride are separately used ball mill ball milling 4h, in ball mill, ratio of grinding media to material is 25:1, for subsequent use after ball milling;
(2) polyisoprene 15 parts, cis-1,4-polybutadiene rubber 4 parts, hydrogenated nitrile-butadiene rubber 8 parts, polyphenylene sulfide 10 parts, cyanacrylate 2 parts, PMAm hydroxypropyltrimonium chloride 2 parts, polyethylene wax 6 parts, poly(vinylidene fluoride) 5 parts, 8 parts, calcium sulfate, boron nitride 4 parts is got by weight respectively, above-mentioned composition is mixed rear Banbury mixer banburying, banburying temperature is 120 DEG C, and the banburying time is 5min;
(3) again the mixture after banburying is opened refining more on a mill until, then carry out granulation, obtain compound TPR type footwear material.
Embodiment 2
(1) calcium sulfate and boron nitride are separately used ball mill ball milling 2h, in ball mill, ratio of grinding media to material is 15:1, for subsequent use after ball milling;
(2) polyisoprene 6 parts, cis-1,4-polybutadiene rubber 4 parts, hydrogenated nitrile-butadiene rubber 2 parts, polyphenylene sulfide 4 parts, cyanacrylate 4 parts, PMAm hydroxypropyltrimonium chloride 5 parts, polyethylene wax 3 parts, poly(vinylidene fluoride) 10 parts, 3 parts, calcium sulfate, boron nitride 2 parts is got by weight respectively, above-mentioned composition is mixed rear Banbury mixer banburying, banburying temperature is 90 DEG C, and the banburying time is 10min;
(3) again the mixture after banburying is opened refining more on a mill until, then carry out granulation, obtain compound TPR type footwear material.
Embodiment 3
(1) calcium sulfate and boron nitride are separately used ball mill ball milling 4h, in ball mill, ratio of grinding media to material is 25:1, for subsequent use after ball milling;
(2) polyisoprene 8 parts, cis-1,4-polybutadiene rubber 9 parts, hydrogenated nitrile-butadiene rubber 3 parts, polyphenylene sulfide 9 parts, cyanacrylate 4 parts, PMAm hydroxypropyltrimonium chloride 3 parts, polyethylene wax 4 parts, poly(vinylidene fluoride) 6 parts, 7 parts, calcium sulfate, boron nitride 3 parts is got by weight respectively, above-mentioned composition is mixed rear Banbury mixer banburying, banburying temperature is 120 DEG C, and the banburying time is 5min;
(3) again the mixture after banburying is opened refining more on a mill until, then carry out granulation, obtain compound TPR type footwear material.
Embodiment 4
(1) calcium sulfate and boron nitride are separately used ball mill ball milling 2h, in ball mill, ratio of grinding media to material is 15:1, for subsequent use after ball milling;
(2) polyisoprene 12 parts, cis-1,4-polybutadiene rubber 5 parts, hydrogenated nitrile-butadiene rubber 7 parts, polyphenylene sulfide 6 parts, cyanacrylate 3 parts, PMAm hydroxypropyltrimonium chloride 4 parts, polyethylene wax 5 parts, poly(vinylidene fluoride) 9 parts, 4 parts, calcium sulfate, boron nitride 4 parts is got by weight respectively, above-mentioned composition is mixed rear Banbury mixer banburying, banburying temperature is 90 DEG C, and the banburying time is 10min;
(3) again the mixture after banburying is opened refining more on a mill until, then carry out granulation, obtain compound TPR type footwear material.
Embodiment 5
(1) calcium sulfate and boron nitride are separately used ball mill ball milling 3h, in ball mill, ratio of grinding media to material is 20:1, for subsequent use after ball milling;
(2) polyisoprene 10 parts, cis-1,4-polybutadiene rubber 7 parts, hydrogenated nitrile-butadiene rubber 5 parts, polyphenylene sulfide 8 parts, cyanacrylate 3 parts, PMAm hydroxypropyltrimonium chloride 4 parts, polyethylene wax 4 parts, poly(vinylidene fluoride) 8 parts, 5 parts, calcium sulfate, boron nitride 3 parts is got by weight respectively, above-mentioned composition is mixed rear Banbury mixer banburying, banburying temperature is 110 DEG C, and the banburying time is 7min;
(3) again the mixture after banburying is opened refining more on a mill until, then carry out granulation, obtain compound TPR type footwear material.
Comparative example 1
(1) calcium sulfate and boron nitride are separately used ball mill ball milling 4h, in ball mill, ratio of grinding media to material is 25:1, for subsequent use after ball milling;
(2) polyisoprene 15 parts, cis-1,4-polybutadiene rubber 4 parts, hydrogenated nitrile-butadiene rubber 8 parts, PMAm hydroxypropyltrimonium chloride 2 parts, polyethylene wax 6 parts, poly(vinylidene fluoride) 5 parts, 8 parts, calcium sulfate, boron nitride 4 parts is got by weight respectively, above-mentioned composition is mixed rear Banbury mixer banburying, banburying temperature is 120 DEG C, and the banburying time is 5min;
(3) again the mixture after banburying is opened refining more on a mill until, then carry out granulation, obtain compound TPR type footwear material.
Comparative example 2
(1) calcium sulfate and boron nitride are separately used ball mill ball milling 4h, in ball mill, ratio of grinding media to material is 25:1, for subsequent use after ball milling;
(2) polyisoprene 15 parts, cis-1,4-polybutadiene rubber 4 parts, hydrogenated nitrile-butadiene rubber 8 parts, polyphenylene sulfide 10 parts, cyanacrylate 2 parts, polyethylene wax 6 parts, 8 parts, calcium sulfate, boron nitride 4 parts is got by weight respectively, above-mentioned composition is mixed rear Banbury mixer banburying, banburying temperature is 120 DEG C, and the banburying time is 5min;
(3) again the mixture after banburying is opened refining more on a mill until, then carry out granulation, obtain compound TPR type footwear material.
Comparative example 3
(1) by calcium sulfate ball mill ball milling 4h, in ball mill, ratio of grinding media to material is 25:1, for subsequent use after ball milling;
(2) polyisoprene 15 parts, cis-1,4-polybutadiene rubber 4 parts, hydrogenated nitrile-butadiene rubber 8 parts, polyphenylene sulfide 10 parts, cyanacrylate 2 parts, PMAm hydroxypropyltrimonium chloride 2 parts, polyethylene wax 6 parts, poly(vinylidene fluoride) 5 parts, 8 parts, calcium sulfate is got by weight respectively, above-mentioned composition is mixed rear Banbury mixer banburying, banburying temperature is 120 DEG C, and the banburying time is 5min;
(3) again the mixture after banburying is opened refining more on a mill until, then carry out granulation, obtain compound TPR type footwear material.
The Akron wear volume of the above-mentioned footwear material of preparation, elongation at break, Young's modulus are as follows:
Claims (7)
1. a compound TPR type footwear material, is characterized in that, described compound TPR type footwear material comprises the composition of following weight parts:
2. a kind of compound TPR type footwear material according to claim 1, is characterized in that, described compound TPR type footwear material comprises the composition of following weight parts:
3. the preparation method of a kind of compound TPR type footwear material according to claim 1, it is characterized in that, described preparation method's step is as follows:
(1) calcium sulfate and boron nitride are separately used ball mill ball milling 2-4h, in ball mill, ratio of grinding media to material is 15:1-25:1, for subsequent use after ball milling;
(2) polyisoprene 6-15 part, cis-1,4-polybutadiene rubber 4-10 part, hydrogenated nitrile-butadiene rubber 2-8 part, polyphenylene sulfide 4-10 part, cyanacrylate 2-4 part, PMAm hydroxypropyltrimonium chloride 2-5 part, polyethylene wax 3-6 part, poly(vinylidene fluoride) 5-10 part, calcium sulfate 3-8 part, boron nitride 2-4 part is got by weight respectively, above-mentioned composition is mixed rear Banbury mixer banburying, banburying temperature is 90-120 DEG C, and the banburying time is 5-10min;
(3) again the mixture after banburying is opened refining more on a mill until, then carry out granulation, obtain compound TPR type footwear material.
4. the preparation method of a kind of compound TPR type footwear material according to claim 3, is characterized in that, in described step (1), in ball mill, ratio of grinding media to material is 20:1.
5. the preparation method of a kind of compound TPR type footwear material according to claim 3, is characterized in that, in described step (1), Ball-milling Time is 3h.
6. the preparation method of a kind of compound TPR type footwear material according to claim 3, is characterized in that, in described step (2), banburying temperature is 110 DEG C.
7. the preparation method of a kind of compound TPR type footwear material according to claim 3, is characterized in that, in described step (2), the banburying time is 7min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510777992.3A CN105330908A (en) | 2015-11-13 | 2015-11-13 | Composite TPR type shoe material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510777992.3A CN105330908A (en) | 2015-11-13 | 2015-11-13 | Composite TPR type shoe material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105330908A true CN105330908A (en) | 2016-02-17 |
Family
ID=55281688
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510777992.3A Pending CN105330908A (en) | 2015-11-13 | 2015-11-13 | Composite TPR type shoe material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105330908A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108192162A (en) * | 2017-12-28 | 2018-06-22 | 安踏（中国）有限公司 | A kind of Sports shoe sole abrasive rubber and preparation method thereof |
| CN109082062A (en) * | 2018-06-29 | 2018-12-25 | 扬州朗劲塑胶实业有限公司 | A kind of production of TPR sole foxing and color spray technique |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735495A (en) * | 2009-12-21 | 2010-06-16 | 泰亚鞋业股份有限公司 | Formula of sole of high oil resistant rubber sneakers and manufacturing method of soles |
| CN102504513A (en) * | 2011-10-24 | 2012-06-20 | 日照日纳功能材料科技有限公司 | Nanometer compound heat conduction macromolecular shoe material |
| CN102660057A (en) * | 2012-05-23 | 2012-09-12 | 新疆泰安鞋业有限公司 | Formula of multi-functional rubber soles |
| CN102796292A (en) * | 2012-08-09 | 2012-11-28 | 际华三五三七制鞋有限责任公司 | High-elongation wear-resistant oil-resistant rubber sole and preparation method thereof |
-
2015
- 2015-11-13 CN CN201510777992.3A patent/CN105330908A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735495A (en) * | 2009-12-21 | 2010-06-16 | 泰亚鞋业股份有限公司 | Formula of sole of high oil resistant rubber sneakers and manufacturing method of soles |
| CN102504513A (en) * | 2011-10-24 | 2012-06-20 | 日照日纳功能材料科技有限公司 | Nanometer compound heat conduction macromolecular shoe material |
| CN102660057A (en) * | 2012-05-23 | 2012-09-12 | 新疆泰安鞋业有限公司 | Formula of multi-functional rubber soles |
| CN102796292A (en) * | 2012-08-09 | 2012-11-28 | 际华三五三七制鞋有限责任公司 | High-elongation wear-resistant oil-resistant rubber sole and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108192162A (en) * | 2017-12-28 | 2018-06-22 | 安踏（中国）有限公司 | A kind of Sports shoe sole abrasive rubber and preparation method thereof |
| CN109082062A (en) * | 2018-06-29 | 2018-12-25 | 扬州朗劲塑胶实业有限公司 | A kind of production of TPR sole foxing and color spray technique |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105860172B (en) | A kind of Wear-resistant sole material and preparation method thereof | |
| CN101955599B (en) | Formula for in situ preparing rolled high brightness shoe side rubber and preparation method thereof | |
| CN103159999A (en) | Wear-resistant sole material and preparation method thereof | |
| CN105670145B (en) | A kind of preparation method of ageing-resistant tire curing bladder | |
| CN105566730A (en) | Poly vinyl acetate modified foaming body | |
| CN103370375A (en) | Polymer composition comprising polyamide and ionomer | |
| CN105367919A (en) | Preparation method for plastic particles filling anti-aging artificial lawn | |
| CN105482351A (en) | ABS material with marble imitation decorative effect and preparation method thereof | |
| CN103159993A (en) | Oil-resistant non-skid sole material and preparation method thereof | |
| CN106317662A (en) | Ultra-light wear-resistant anti-skidding shoe sole and preparation method thereof | |
| CN102127283B (en) | Polypropylene composite used for injection moulding splicing floor and preparation method thereof | |
| CN105061877A (en) | Wear-resisting artificial turf with high stress release and preparation process of wear-resisting artificial turf | |
| CN105330908A (en) | Composite TPR type shoe material and preparation method thereof | |
| CN102924770B (en) | Mirror varnishing rubber sole and manufacturing method thereof | |
| CN107011573A (en) | A kind of foamed low density anti-aging chinampa filling plastic cement and preparation method thereof | |
| CN107501905A (en) | A kind of TPE plastics and preparation method thereof | |
| CN102604195A (en) | EVA (ethylene vinyl acetate)/PE (polyethylene)/PVC (polyvinyl chloride) composite foam material and preparation method thereof | |
| CN105602036A (en) | Acrylonitrile-butadiene rubber powder and preparation method thereof | |
| CN105086497A (en) | Granular material for manufacturing flexible, high-elastic and abrasion-proof foamed sole and production technology thereof | |
| CN106380650A (en) | Synthetic material for outsole of footwear | |
| CN110028731A (en) | A kind of sole material and preparation method thereof of shock-absorbing rebound | |
| CN102329495A (en) | Thermoplastic sole material and preparation method thereof | |
| CN105086013A (en) | No-blooming wear-resistant rubber and preparing method thereof | |
| CN107434860A (en) | A kind of anti-ozone-induced cracking rubber composition for footwear and its application | |
| CN106916348A (en) | A kind of wear-resisting high-strength degree slipper sole and its production technology and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160217 |
|
| RJ01 | Rejection of invention patent application after publication |