CN108192162A - A kind of Sports shoe sole abrasive rubber and preparation method thereof - Google Patents
A kind of Sports shoe sole abrasive rubber and preparation method thereof Download PDFInfo
- Publication number
- CN108192162A CN108192162A CN201711453911.XA CN201711453911A CN108192162A CN 108192162 A CN108192162 A CN 108192162A CN 201711453911 A CN201711453911 A CN 201711453911A CN 108192162 A CN108192162 A CN 108192162A
- Authority
- CN
- China
- Prior art keywords
- parts
- rubber
- agent
- shoe sole
- sports shoe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/002—Methods
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of Sports shoe sole abrasive rubbers, in terms of mass parts, including 0.5 1 parts of 50 80 parts of butadiene rubber, 10 30 parts of epoxy natural rubber, 5 20 parts of hydrogenated nitrile-butadiene rubber, 12 parts of homogenizing agent, 25 parts of silane coupling agent, 25 65 parts of reinforcing agent, Zinc Oxide 25,25 parts of polyethylene glycol, 0.5 2 parts of zinc stearate, 1.5 2 parts of vulcanizing agent, 1.6 2.1 parts of accelerating agent, 0.5 2 parts of tackifier, 25 parts of softening oil, 13 parts of anti-aging agent and paraffin.The present invention also provides a kind of preparation method of above-mentioned Sports shoe sole abrasive rubber simultaneously.The Sports shoe sole wear-resistant rubber sole that technical scheme of the present invention makes, the super wear resistance energy for having General Purpose Rubber sole incomparable, and with multiple performances such as good weatherability and folding qualities, the production process of preparation method is simple, is suitble to extensive use.
Description
Technical field
The present invention relates to Material Fields, and in particular to a kind of Sports shoe sole abrasive rubber and preparation method thereof.
Background technology
Sport footwear is due to its special purposes, it is desirable that its sole rubber has wear-resisting property, good folding quality and resistance to
Hou Xing.Although current Sports shoe sole abrasive rubber is with certain wear-resisting property, elastic, weather-proof there are many deficiencies
Poor performance, Sports shoe sole repeatedly spring, run during, sole is worn quickly, while the sole under more adverse circumstances
The easy aging lost its bounce of material, in addition, current Sports shoe sole with abrasive rubber shrinkage is larger, slice out-of-flatness, slice
Thickness is difficult to control, and in back segment sulfidation, because the air-tightness of material is strong, poor fluidity, shrinkage is big, exhaust it is bad etc. because
Element, defect rate is more, influences production efficiency.Therefore, existing Sports shoe sole is still treated with abrasive rubber and preparation method thereof into one
Step is improved.
Invention content
It is an object of the invention to solve the problems of the prior art, providing a kind of has super wear resistance energy, good resistance to
Sports shoe sole abrasive rubber of multiple performances such as time property and folding quality and preparation method thereof.
A kind of Sports shoe sole abrasive rubber, in terms of mass parts, including 50-80 parts of butadiene rubber, epoxy natural rubber 10-
30 parts, 5-20 parts of hydrogenated nitrile-butadiene rubber, 1-2 parts of homogenizing agent, 2-5 parts of silane coupling agent, 25-65 parts of reinforcing agent, Zinc Oxide 2-5,
It is 2-5 parts of polyethylene glycol, 0.5-2 parts of zinc stearate, 1.5-2 parts of vulcanizing agent, 1.6-2.1 parts of accelerating agent, 0.5-2 parts of tackifier, soft
0.5-1 parts of 2-5 parts of carburetion, 1-3 parts of anti-aging agent and paraffin.
Preferably, the silane coupling agent is double-[3- (triethoxysilicane) propyl]-tetrasulfide.
Preferably, the reinforcing agent is white carbon and nano oxidized aluminium mixture, and wherein white carbon is 20-50 parts, nanometer
Aluminium oxide is 5-15 parts.
Preferably, the vulcanizing agent is sulphur.
Preferably, the accelerating agent is thiazoles, thiurams and dithiocarbamates mix class accelerating agent.
Preferably, the tackifier are aqueous tackifier resin.
Preferably, the softening oil is paraffinic base rubber softening oil.
Preferably, the anti-aging agent is di-tert-butyl p-cresol.
Present invention simultaneously provides a kind of preparation methods of Sports shoe sole abrasive rubber, include the following steps：
1) following component is weighed by mass parts：50-80 parts of butadiene rubber, 10-30 parts of epoxy natural rubber, hydrogenated butyronitrile rubber
5-20 parts of glue, 1-2 parts of homogenizing agent, 2-5 parts of silane coupling agent, 25-65 parts, Zinc Oxide 2-5 of reinforcing agent, 2-5 parts of polyethylene glycol, firmly
0.5-2 parts of resin acid zinc, 0.5-2 parts of tackifier, 2-5 parts of softening oil, 1-3 parts of anti-aging agent, 0.5-1 parts of paraffin；
2) all the components weighed in step 1) will be kneaded, the time of mixing is 7-9 minutes, and temperature is
120-140℃；
3) mixture obtained in step 2) is taken out and cooled down；
4) following component is weighed by mass parts：1.6-2.1 parts of 1.5-2 parts of vulcanizing agent and accelerating agent；
5) material after cooling in all the components and step 3) that have been weighed in step 4) is kneaded, the time of mixing
It it is 3-5 minutes, temperature is 50-70 DEG C
To reach above-mentioned purpose, the present invention adopts the following technical scheme that：
Technical solutions according to the invention are relative to the prior art, the advantageous effect of acquirement：
For the present invention using butadiene rubber as main material, butadiene rubber is the second largest synthesis rubber for being only second to butadiene-styrene rubber
Glue, compared with natural rubber and butadiene-styrene rubber, its cold resistance, wearability and elasticity are especially excellent after vulcanization, generate heat under dynamic load
It is few, with good wear-resisting property so as to make product also with good wear-resisting property；It is natural with hydrogenated nitrile-butadiene rubber and epoxy
Rubber is auxiliary material, and hydrogenated nitrile-butadiene rubber is a kind of HI SA highly saturated elasticity obtained from carrying out special hydrotreating to nitrile rubber
Body, with good oil resistance, and its HI SA highly saturated structure assigns its good heat resistance, and excellent chemically-resistant is rotten
Corrosion energy, excellent ozone resistance, higher incompressible permanent deformation performance；Hydrogenated nitrile-butadiene rubber also has high-strength simultaneously
Degree, high tear energy, the features such as wear-resisting property is excellent, make product have super antiskid property and good wearability；Epoxidation is natural
Rubber be by epoxidation reaction modified natural rubber, what the partial double bond on rubber molecular chain was prepared after being aoxidized, epoxy
The polarity increase of rubber macromolecule, intermolecular force enhancing after changing, therefore epoxy natural rubber is made both to have remained with natural rubber
The basic structure and performance characteristics of glue, and many unique performances are produced, mainly have：Excellent air-tightness, excellent oil resistant
Property, compatibility, anti-slippery, low rolling resistance and the good adhesive property between other materials etc..
To improve the comprehensive performances such as butadiene rubber processability and tear resistance, the present invention is good with having by butadiene rubber
The epoxy natural rubber and hydrogenated nitrile-butadiene rubber of good comprehensive performance are used in combination, so as to improve the overall performance of rubber aniseed in itself.
Specifically, wherein the tackifier added in, include aqueous tackifier lotion, aqueous tackifier resin, aqueous tackifier powder, thickening
Rosin resin, modified rosin resin etc., this case preferably using aqueous tackifier resin, can make butadiene rubber, epoxy natural rubber and
The respective decomposition of hydrogenated nitrile-butadiene rubber is more abundant, it is easier to be stirred evenly, mixed.
White carbon and nano aluminium oxide that product of the present invention uses can improve the flexible resistance of rubber as reinforcing agent, make
Have it is good deflect fatigue performance, nano aluminium oxide has larger specific surface area and high activity high absorption capacity, receives
The addition of rice aluminium oxide can be contacted with rubber macromolecule generates strong physical crosslinking effect, forms firm cross-bond so that
Cross-linked network more improves to increase the wear-resisting property of rubber；But for reinforcing agent in process easily conglomeration, point
Dissipate the phenomenon that bad, the present invention using environment-friendly type coupling agent it is double-[3- (triethoxysilicane) propyl]-tetrasulfide to white carbon into
Row is modified, and makes reinforcing agent and powder compounding agent complete wetting, dispersion, using softening oil to reach optimum efficiency simultaneously.
Specifically, being used in product of the present invention has excellent antioxygen, ozone resisting anti-aging agent and paraffin, can be on sizing material surface
One layer of cured film is formed, the infiltration of ozone can be prevented, reaching well has protective action；And the vulcanizing agent added in is sulphur, activity
Agent is polyethylene glycol and Zinc Oxide, stearic acid, has activated entire vulcanizing system, improves the crosslink density of vulcanizate simultaneously
The heat aging property of vulcanizate is improved, improves the fatigue life of vulcanizate, dynamic property is good.Add by thiazoles,
The mixed accelerators of thiurams, dithiocarbamates can shorten vulcanization time, reduce curing temperature, reduce vulcanization
The dosage of agent and the physical mechanical property for improving rubber, can more make its sulfidation more preferable.
It is incomparable with General Purpose Rubber sole with the Sports shoe sole wear-resistant rubber sole that this technical solution makes
Super wear resistance energy, and with multiple performances such as good weatherability and folding qualities.
Accordingly the present invention also provides a kind of preparation method of Sports shoe sole abrasive rubber, the Sports shoe sole is with wear-resisting
The production process of rubber is simple, and only need to various composition be packed into kneading machine in order is kneaded, and the time is short, and operating condition is fitted
Preferably, the operation cycle is short, and obtained rubber has the incomparable super wear resistance energy of General Purpose Rubber sole, and with good resistance to
The multiple performances such as time property and folding quality, are suitable for extensive use.
Specific embodiment
In order to make technical problems, technical solutions and advantages to be solved clearer, clear, tie below
Embodiment is closed, the present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only explaining
The present invention is not intended to limit the present invention.
The present invention provides a kind of Sports shoe sole abrasive rubber, in terms of mass parts, including 50-80 parts of butadiene rubber, epoxy
10-30 parts of natural rubber, 5-20 parts of hydrogenated nitrile-butadiene rubber, 1-2 parts of homogenizing agent, 2-5 parts of silane coupling agent, white carbon 20-50
Part, promotes 5-15 parts of nano aluminium oxide, Zinc Oxide 2-5,2-5 parts of polyethylene glycol, 0.5-2 parts of zinc stearate, 1.5-2 parts of sulphur
0.5-1 parts of 1.6-2.1 parts of agent, 0.5-2 parts of aqueous tackifier resin, 2-5 parts of softening oil, 1-3 parts of anti-aging agent and paraffin.
Wherein, silane coupling agent is double-[3- (triethoxysilicane) propyl]-tetrasulfide.Accelerating agent is thiazoles, Qiu Lan
Nurse class and dithiocarbamates mixing class accelerating agent.Softening oil is paraffinic base rubber softening oil.Anti-aging agent is two tertiary fourths
Base paracresol tackifier are aqueous tackifier resin.
Present invention simultaneously provides a kind of preparation methods of Sports shoe sole abrasive rubber, include the following steps：
1) following component is weighed by mass parts：50-80 parts of butadiene rubber, 10-30 parts of epoxy natural rubber, hydrogenated butyronitrile rubber
5-20 parts of glue, 1-2 parts of homogenizing agent, 2-5 parts of silane coupling agent, 20-50 parts of white carbon, 5-15 parts of nano aluminium oxide, Zinc Oxide 2-
5,2-5 parts of polyethylene glycol, 0.5-2 parts of zinc stearate, 0.5-2 parts of aqueous tackifier resin, 2-5 parts of softening oil, 1-3 parts of anti-aging agent,
0.5-1 parts of paraffin；
2) will all the components that weighed in step 1) be poured into mixer to be kneaded, the time of mixing is 7-9 minutes,
Temperature is 120-140 DEG C；
3) mixture that will be obtained in step 2), discharging, slice, cooling；
4) following component is weighed by mass parts：1.6-2.1 parts of 1.5-2 parts of sulphur and accelerating agent；
5) heat, then all the components with having been weighed in step 4) will be beaten on material input material preparing table after cooling in step 3)
It is kneaded, the time of mixing is 3-5 minutes, and temperature is 50-70 DEG C, then slice is got product through sulfidization molding.
According to above Sports shoe sole abrasive rubber and preparation method thereof, Sports shoe sole abrasive rubber of the invention can
Different formula combinations is selected, to meet the requirement of different product, following examples show a variety of different Sports shoe sole use
The formula combination and its preparation process of abrasive rubber.
Table 1：Sports shoe sole is with wearable rubber formulation (part)
Wherein, silane coupling agent is double-[3- (triethoxysilicane) propyl]-tetrasulfide, and softening oil is paraffinic base rubber
Softening oil, anti-aging agent are di-tert-butyl p-cresol.
Wherein, in embodiment 1, the mixing time in step 2) is 9 minutes, and temperature is 120-140 DEG C；In step 5)
Mixing time is 3 minutes, and temperature is 50-70 DEG C；
In embodiment 2, the mixing time in step 2) is 7 minutes, and temperature is 120-140 DEG C；During mixing in step 5)
Between for 5 minutes, temperature is 50-70 DEG C；
In embodiment 3, the mixing time in step 2) is 8 minutes, and temperature is 120-140 DEG C；During mixing in step 5)
Between for 4 minutes, temperature is 50-70 DEG C.
By the Sports shoe sole abrasive rubber obtained by above-described embodiment 1,2 and 3, carry out performance detection, at the same with it is existing
The performance of product is compared, as a result such as the following table 2.
Table 2：The performance of embodiment 1-3 and existing Sports shoe sole abrasive rubber
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Hardness (Shao Er A) | 67 | 68 | 67 |
| Tensile strength (MPa) | 17 | 18 | 17 |
| Elongation at break (%) | 737 | 745 | 742 |
| Right-angle tearing (N/cm) | 72 | 69 | 70 |
| DIN(mm3) | 33 | 31 | 35 |
| Density (g/cm3) | 1.13 | 1.14 | 1.13 |
| Folding quality (mm) | 5.1 | 5.2 | 5.2 |
| Anti-hydrolytic performance | Meet | Meet | Meet |
Note：2 data of table are the data obtained by national standard test method.
By data in table 2 it is found that Sports shoe sole abrasive rubber of the present invention, perfection solve the behaviour of existing wearable rubber formulation
Make performance：It is easy to operate, as planarization of the material in slice is good, shrinkage is small and can improve vulcanization of rubber exhaust well
Performance etc. so as to the product quality and the production efficiency that improve, reduces production cost；In terms of physical property, wear-resisting property side
Face is more prominent, and can it is firm well it is weather-proof can and folding quality (be less than 5.2mm) also much smaller than existing product, meet country
Related physical performance standard.
For the present invention using butadiene rubber as main material, butadiene rubber is the second largest synthesis rubber for being only second to butadiene-styrene rubber
Glue, compared with natural rubber and butadiene-styrene rubber, its cold resistance, wearability and elasticity are especially excellent after vulcanization, generate heat under dynamic load
It is few, with good wear-resisting property so as to make its product with good wear-resisting property；It is natural with hydrogenated nitrile-butadiene rubber and epoxy
Rubber is auxiliary material, and hydrogenated nitrile-butadiene rubber is a kind of HI SA highly saturated elasticity obtained from carrying out special hydrotreating to nitrile rubber
Body assigns its good heat resistance, excellent chemically-resistant with good oil resistance and its HI SA highly saturated structure
Corrosive nature, excellent ozone resistance, higher incompressible permanent deformation performance；Hydrogenated nitrile-butadiene rubber also has high-strength simultaneously
Degree, high tear energy, the features such as wear-resisting property is excellent, make product have super antiskid property and good wearability；Epoxidation is natural
Rubber be by epoxidation reaction modified natural rubber, what the partial double bond on rubber molecular chain was prepared after being aoxidized, epoxy
The polarity increase of rubber macromolecule, intermolecular force enhancing after changing, therefore epoxy natural rubber is made both to have remained with natural rubber
The basic structure and performance characteristics of glue, and many unique performances are produced, mainly have：Excellent air-tightness, excellent oil resistant
Property, compatibility, anti-slippery, low rolling resistance and the good adhesive property between other materials etc..
To improve the comprehensive performances such as butadiene rubber processability and tear resistance, the present invention is good with having by butadiene rubber
The epoxy natural rubber and hydrogenated nitrile-butadiene rubber of good comprehensive performance are used in combination, so as to improve the overall performance of rubber aniseed in itself.
Specifically, wherein the tackifier added in, include aqueous tackifier lotion, aqueous tackifier resin, aqueous tackifier powder, thickening
Rosin resin, modified rosin resin etc., this case preferably using aqueous tackifier resin, can make butadiene rubber, epoxy natural rubber and
The respective decomposition of hydrogenated nitrile-butadiene rubber is more abundant, it is easier to be stirred evenly, mixed.
White carbon and nano aluminium oxide that product of the present invention uses can improve the flexible resistance of rubber as reinforcing agent, make
Have it is good deflect fatigue performance, nano aluminium oxide has larger specific surface area and high activity high absorption capacity, receives
The addition of rice aluminium oxide can be contacted with rubber macromolecule generates strong physical crosslinking effect, forms firm cross-bond so that
Cross-linked network more improves to increase the wear-resisting property of rubber；But for reinforcing agent in process easily conglomeration, point
Dissipate the phenomenon that bad, the present invention using environment-friendly type coupling agent it is double-[3- (triethoxysilicane) propyl]-tetrasulfide to white carbon into
Row is modified, and makes reinforcing agent and powder compounding agent complete wetting, dispersion, using softening oil to reach optimum efficiency simultaneously.
Specifically, being used in product of the present invention has excellent antioxygen, ozone resisting anti-aging agent and paraffin, can be on sizing material surface
One layer of cured film is formed, the infiltration of ozone can be prevented, reaching well has protective action；And the vulcanizing agent added in is sulphur, activity
Agent is polyethylene glycol and Zinc Oxide, stearic acid, has activated entire vulcanizing system, improves the crosslink density of vulcanizate simultaneously
The heat aging property of vulcanizate is improved, improves the fatigue life of vulcanizate, dynamic property is good.Add by thiazoles,
The mixed accelerators of thiurams, dithiocarbamates can shorten vulcanization time, reduce curing temperature, reduce vulcanization
The dosage of agent and the physical mechanical property for improving rubber, can more make its sulfidation more preferable.
It is incomparable with General Purpose Rubber sole with the Sports shoe sole wear-resistant rubber sole that this technical solution makes
Super wear resistance energy, and with multiple performances such as good weatherability and folding qualities.
The preparation method of the present invention, the production process of the Sports shoe sole abrasive rubber is simple, need to only press various composition
Sequence is packed into kneading machine and is kneaded, and the time is short, and operating condition is suitable, and the operation cycle is short, and obtained rubber has General Purpose Rubber
The incomparable super wear resistance energy of sole, and with multiple performances such as good weatherability and folding qualities, be suitable for extensively
Using.
Description above describe the preferred embodiment of the present invention, it is to be understood that the present invention is not limited to above-mentioned implementation
Example, and the exclusion to other embodiment should not be regarded as.By the enlightenment of the present invention, those skilled in the art combine known or existing
The change that technology, knowledge are carried out also should be regarded as in protection scope of the present invention.
Claims (9)
1. a kind of Sports shoe sole abrasive rubber, it is characterised in that：In terms of mass parts, including 50-80 parts of butadiene rubber, epoxy day
10-30 parts of T PNR, 5-20 parts of hydrogenated nitrile-butadiene rubber, 1-2 parts of homogenizing agent, 2-5 parts of silane coupling agent, 25-65 parts of reinforcing agent, zinc
Oxygen powder 2-5,2-5 parts of polyethylene glycol, 0.5-2 parts of zinc stearate, 1.5-2 parts of vulcanizing agent, 1.6-2.1 parts of accelerating agent, tackifier
0.5-1 parts of 0.5-2 parts, 2-5 parts of softening oil, 1-3 parts of anti-aging agent and paraffin.
2. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that：The silane coupling agent for it is double-
[3- (triethoxysilicane) propyl]-tetrasulfide.
3. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that：The reinforcing agent for white carbon and
Nano oxidized aluminium mixture, wherein white carbon are 20-50 parts, and nano aluminium oxide is 5-15 parts.
4. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that：The vulcanizing agent is sulphur.
5. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that：The accelerating agent for thiazoles,
Thiurams and dithiocarbamates mixing class accelerating agent.
6. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that：The tackifier are aqueous tackifier
Resin.
7. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that：The softening oil is paraffinic base rubber
Gum softening oil.
8. a kind of Sports shoe sole abrasive rubber as described in claim 1, it is characterised in that：The anti-aging agent is di-t-butyl
Paracresol.
9. a kind of preparation method of Sports shoe sole abrasive rubber, it is characterised in that：Include the following steps：
1) following component is weighed by mass parts：50-80 parts of butadiene rubber, 10-30 parts of epoxy natural rubber, hydrogenated nitrile-butadiene rubber 5-
20 parts, 1-2 parts of homogenizing agent, 2-5 parts of silane coupling agent, 25-65 parts, Zinc Oxide 2-5 of reinforcing agent, 2-5 parts of polyethylene glycol, stearic acid
0.5-2 parts of zinc, 0.5-2 parts of tackifier, 2-5 parts of softening oil, 1-3 parts of anti-aging agent, 0.5-1 parts of paraffin；
2) all the components weighed in step 1) will be kneaded, the time of mixing is 7-9 minutes, temperature 120-140
℃；
3) mixture obtained in step 2) is taken out and cooled down；
4) following component is weighed by mass parts：1.6-2.1 parts of 1.5-2 parts of vulcanizing agent and accelerating agent；5) it will be weighed in step 4)
All the components and step 3) in material after cooling be kneaded, time of mixing is 3-5 minute, and temperature is 50-70 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711453911.XA CN108192162B (en) | 2017-12-28 | 2017-12-28 | A kind of Sports shoe sole abrasive rubber and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711453911.XA CN108192162B (en) | 2017-12-28 | 2017-12-28 | A kind of Sports shoe sole abrasive rubber and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108192162A true CN108192162A (en) | 2018-06-22 |
| CN108192162B CN108192162B (en) | 2019-11-01 |
Family
ID=62584870
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711453911.XA Active CN108192162B (en) | 2017-12-28 | 2017-12-28 | A kind of Sports shoe sole abrasive rubber and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108192162B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108851336A (en) * | 2018-06-29 | 2018-11-23 | 广州华腾云谷科技有限公司 | Antiskid sole |
| CN110094126A (en) * | 2018-09-25 | 2019-08-06 | 江苏三乔智能科技有限公司 | Door and window support rod |
| CN111533967A (en) * | 2020-06-16 | 2020-08-14 | 广东石油化工学院 | Rubber sole and preparation method thereof |
| CN112679871A (en) * | 2020-12-25 | 2021-04-20 | 安踏（中国）有限公司 | Composite rubber, preparation method thereof and sole material |
| CN113717446A (en) * | 2020-12-08 | 2021-11-30 | 佛山市大唐新新橡塑有限公司 | Temperature-variable rubber |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102061017A (en) * | 2010-12-06 | 2011-05-18 | 安踏（中国）有限公司 | Rubber for sneaker sole and preparation method thereof |
| JP2013102829A (en) * | 2011-11-10 | 2013-05-30 | Kohshin Rubber Co Ltd | Oil-proof and anti-slip sole |
| CN104277274A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Oil-proof antiskid rubber sole and preparation method thereof |
| CN105330908A (en) * | 2015-11-13 | 2016-02-17 | 吴江市风尚鞋厂 | Composite TPR type shoe material and preparation method thereof |
-
2017
- 2017-12-28 CN CN201711453911.XA patent/CN108192162B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102061017A (en) * | 2010-12-06 | 2011-05-18 | 安踏（中国）有限公司 | Rubber for sneaker sole and preparation method thereof |
| JP2013102829A (en) * | 2011-11-10 | 2013-05-30 | Kohshin Rubber Co Ltd | Oil-proof and anti-slip sole |
| CN104277274A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Oil-proof antiskid rubber sole and preparation method thereof |
| CN105330908A (en) * | 2015-11-13 | 2016-02-17 | 吴江市风尚鞋厂 | Composite TPR type shoe material and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108851336A (en) * | 2018-06-29 | 2018-11-23 | 广州华腾云谷科技有限公司 | Antiskid sole |
| CN110094126A (en) * | 2018-09-25 | 2019-08-06 | 江苏三乔智能科技有限公司 | Door and window support rod |
| CN111533967A (en) * | 2020-06-16 | 2020-08-14 | 广东石油化工学院 | Rubber sole and preparation method thereof |
| CN111533967B (en) * | 2020-06-16 | 2022-05-17 | 广东石油化工学院 | Rubber sole and preparation method thereof |
| CN113717446A (en) * | 2020-12-08 | 2021-11-30 | 佛山市大唐新新橡塑有限公司 | Temperature-variable rubber |
| CN112679871A (en) * | 2020-12-25 | 2021-04-20 | 安踏（中国）有限公司 | Composite rubber, preparation method thereof and sole material |
| CN112679871B (en) * | 2020-12-25 | 2023-06-06 | 安踏（中国）有限公司 | Composite rubber, preparation method thereof and sole material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108192162B (en) | 2019-11-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108192162B (en) | A kind of Sports shoe sole abrasive rubber and preparation method thereof | |
| CN100487033C (en) | Chloroprene rubber polymer blend and its preparing method | |
| CN107383475B (en) | Lignin/nitrile rubber composite material and preparation method thereof | |
| CN101186723B (en) | Ultra-wearable rubber formulation for sports shoes sole | |
| CN105037865B (en) | A kind of modified waste rubber powder and preparation method and application | |
| CN101649073A (en) | Rubber material with damping capacity | |
| JP2006348222A (en) | Rubber composition for sidewall | |
| CN105037902A (en) | High-elastic wear-resistant EVA, preparation method and application thereof | |
| CN102604262A (en) | Rubber-plastic alloy rubber for hydraulic rubber hose and preparation method for same | |
| CN113372624B (en) | Light wear-resistant rubber foamed sole, preparation method thereof and sports shoes | |
| CN104744741A (en) | All-steel giant engineering radial tire sidewall rubber | |
| CN107652479B (en) | β type silicon carbide whisker and rubber combined tennis rubber material and preparation method thereof | |
| US20100210770A1 (en) | Elastomeric composite | |
| CN109337136A (en) | A kind of heat cure rapid shaping rubber | |
| CN113698710B (en) | Wear-resistant antibacterial shoe material and preparation method thereof | |
| CN115286862B (en) | Soft light sole material and preparation method thereof | |
| CN101633764A (en) | Rubber capable of resisting permanent deformation caused by compression and preparation method thereof | |
| CN109251382B (en) | Ageing-resistant HNBR/silicon carbon rubber composite material, preparation method thereof and obtained packer | |
| CN102134325B (en) | Method for vulcanizing nitrile elastomer | |
| CN107090130A (en) | A kind of EP rubbers composite and preparation method thereof | |
| JPH0124166B2 (en) | ||
| JPH04212844A (en) | Rubber composition for earthquakeproof laminate | |
| CN104164078A (en) | Car engine buffer block | |
| JP2006137806A (en) | Manufacturing method for rubber composition, rubber composition and pneumatic tire having sidewall consisting of the same | |
| CN107880413A (en) | Waterproof roll is blended in a kind of haloflex ethylene propylene diene rubber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |