CN107501905A - A kind of TPE plastics and preparation method thereof - Google Patents

A kind of TPE plastics and preparation method thereof Download PDF

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Publication number
CN107501905A
CN107501905A CN201710853617.1A CN201710853617A CN107501905A CN 107501905 A CN107501905 A CN 107501905A CN 201710853617 A CN201710853617 A CN 201710853617A CN 107501905 A CN107501905 A CN 107501905A
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China
Prior art keywords
parts
preparation
tpe plastics
tpe
sebs
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Pending
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CN201710853617.1A
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Chinese (zh)
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苏安分
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Individual
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Individual
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Priority to CN201710853617.1A priority Critical patent/CN107501905A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of TPE plastics and preparation method thereof, it belongs to plastic formula technical field.It includes the composition of following parts by weight:23 35 parts of SEBS, 10 25 parts of SBS, 3 12 parts of elastomer, 30 45 parts of TPU, 20 30 parts of rubber oil, 10 25 parts of polypropylene, 0.4 0.8 parts of zinc stearate, 20 30 parts of calcium carbonate, 2.2 3.0 parts of alumina powder, 1.5 2.3 parts of magnesium stearate;The preparation method of the TPE plastics includes:SEBS, SBS, TPU and polypropylene are put into mixer, are filled with rubber oil stirring, elastomer, zinc stearate, coarse whiting, anti-wear agent and heat-resistant agent are added in mixer after abundant oil suction and stirred, then adds mixture into double screw extruder extruding pelletization.Present invention is mainly used for the preparation of TPE plastics.

Description

A kind of TPE plastics and preparation method thereof
Technical field
The invention belongs to plastic formula technical field, specifically, more particularly to a kind of TPE plastics and preparation method thereof.
Background technology
With developing rapidly for economy, the continuous improvement of enhancing and product requirement of the mankind to environmental consciousness, people are to height It is required that plastics demand it is increasing.And TPE (thermoplastic elastomer (TPE)) is a kind of high resiliency with rubber, high intensity, height time Elasticity, again have can injection molding feature material, there is asepsis environment-protecting, have excellent coloring, weatherability and temperature tolerance, add Work superior performance, it can recycle.TPE had both had the processing characteristics of thermoplastic, had the physical of vulcanization rubber again Energy.But the price of existing TPE plastics is higher, and production yield rate is relatively low, and wearability and heat resistance be not also high.
The content of the invention
It is an object of the invention to provide a kind of TPE plastics and preparation method thereof, have low manufacturing cost, function admirable, into The characteristics of product rate height, environmental protection, antistatic, and there is stronger wearability and preferable heat resistance.
To achieve the above object, the present invention uses following technical scheme:
A kind of TPE plastics, in parts by weight, including SEBS 23-35 parts, SBS 10-25 parts, elastomer 3-12 parts, TPU 30-45 parts, rubber oil 20-30 parts, polypropylene 10-25 parts, zinc stearate 0.4-0.8 parts, calcium carbonate 20-30 parts, alumina powder 2.2-3.0 part, magnesium stearate 1.5-2.3 parts.
Further, the SEBS proportions are more than rubber oil proportion.
SEBS, SBS, TPU and polypropylene, are first put into mixer by a kind of preparation method of TPE plastics as described above, Rubber oil stirring is filled with, elastomer, zinc stearate, calcium carbonate, alumina powder and magnesium stearate are added after abundant oil suction and stirred Mix in machine and stir, then add mixture into double screw extruder extruding pelletization.
Further, its hardness is 45HB.
Further, its extrusion temperature is 155 DEG C.
Compared with prior art, the beneficial effects of the invention are as follows:
TPE plastics provided by the invention are cheap, function admirable, high yield rate, environmental protection, antistatic, and with stronger Wearability and preferable heat resistance;The preparation method of TPE plastics provided by the invention is simple and efficient to handle, high yield rate.
Embodiment
Below by specific embodiment, the invention will be further described.
Embodiment 1
The present embodiment is related to a kind of TPE plastics, and it includes the composition of following parts by weight:SEBS 23-35 parts, SBS 10-25 Part, elastomer 3-12 parts, TPU30-45 parts, rubber oil 20-30 parts, polypropylene 10-25 parts, zinc stearate 0.4-0.8 parts, carbonic acid Calcium 20-30 parts, alumina powder 2.2-3.0 parts, magnesium stearate 1.5-2.3 parts;SEBS proportions are more than rubber oil proportion.
The TPE plastics that the present embodiment is related to, its specific preparation process comprise the following steps:
First SEBS, SBS, TPU and polypropylene are put into mixer, rubber oil stirring is filled with, by bullet after abundant oil suction Property body, zinc stearate, calcium carbonate, alumina powder and magnesium stearate add in mixer and stir, then add mixture into double Screw extruder extruding pelletization;Its hardness is 45HB;Its extrusion temperature is 155 DEG C.
Embodiment 2:
The present embodiment is related to a kind of TPE plastics, and it includes the composition of following parts by weight:SEBS23-30 parts, SBS10-20 Part, elastomer 3-8 parts, TPU30-38 parts, rubber oil 20-25 parts, polypropylene 10-18 parts, zinc stearate 0.4-0.6 parts, carbonic acid Calcium 20-25 parts, alumina powder 2.2-2.6 parts, magnesium stearate 1.5-1.9 parts.
The TPE plastics that the present embodiment is related to, its specific preparation process is the same as embodiment 1.
Embodiment 3:
The present embodiment is related to a kind of TPE plastics, and it includes the composition of following parts by weight:SEBS23 parts, SBS10 parts, elasticity It is 3 parts of body, TPU30 parts, 20 parts of rubber oil, 10 parts of polypropylene, 0.4 part of zinc stearate, 20 parts of calcium carbonate, 2.2 parts of alumina powder, hard 1.5 parts of fatty acid magnesium.
The TPE plastics that the present embodiment is related to, its specific preparation process is the same as embodiment 1.
Embodiment 4:
The present embodiment is related to a kind of TPE plastics, and it includes the composition of following parts by weight:SEBS35 parts, SBS25 parts, elasticity 12 parts of body, TPU45 parts, 30 parts of rubber oil, polipropene 25 part, 0.8 part of zinc stearate, 30 parts of calcium carbonate, 3.0 parts of alumina powder, 2.3 parts of magnesium stearate.
The TPE plastics that the present embodiment is related to, its specific preparation process is the same as embodiment 1.
Embodiment 5:
The present embodiment is related to a kind of TPE plastics, and it includes the composition of following parts by weight:SEBS29 parts, SBS17 parts, elasticity 7.5 parts of body, TPU37.5 parts, 25 parts of rubber oil, 17 parts of polypropylene, 0.6 part of zinc stearate, 25 parts of calcium carbonate, alumina powder 2.6 Part, 1.9 parts of magnesium stearate.
The TPE plastics that the present embodiment is related to, its specific preparation process is the same as embodiment 1.

Claims (5)

  1. A kind of 1. TPE plastics, it is characterised in that:In parts by weight, including SEBS 23-35 parts, SBS 10-25 parts, elastomer 3- 12 parts, TPU 30-45 parts, rubber oil 20-30 parts, polypropylene 10-25 parts, zinc stearate 0.4-0.8 parts, calcium carbonate 20-30 parts, Alumina powder 2.2-3.0 parts, magnesium stearate 1.5-2.3 parts.
  2. A kind of 2. TPE plastics according to claim 1, it is characterised in that:The SEBS proportions are more than rubber oil institute Accounting example.
  3. A kind of a kind of 3. preparation method of TPE plastics as claimed in claim 1 or 2, it is characterised in that:First by SEBS, SBS, TPU and polypropylene are put into mixer, be filled with rubber oil stirring, after abundant oil suction by elastomer, zinc stearate, calcium carbonate, Alumina powder and magnesium stearate, which are added in mixer, to stir, then adds mixture into double screw extruder extruding pelletization.
  4. A kind of 4. preparation method of TPE plastics according to claim 3, it is characterised in that:Its hardness is 45HB.
  5. A kind of 5. preparation method of TPE plastics according to claim 3, it is characterised in that:Its extrusion temperature is 155 DEG C.
CN201710853617.1A 2017-09-20 2017-09-20 A kind of TPE plastics and preparation method thereof Pending CN107501905A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710853617.1A CN107501905A (en) 2017-09-20 2017-09-20 A kind of TPE plastics and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710853617.1A CN107501905A (en) 2017-09-20 2017-09-20 A kind of TPE plastics and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107501905A true CN107501905A (en) 2017-12-22

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108175519A (en) * 2018-01-30 2018-06-19 张云华 A kind of operation C-arm rack
CN112048187A (en) * 2020-09-15 2020-12-08 张家港市民华塑胶有限公司 Anti-aging TPE (thermoplastic elastomer) granules and preparation method thereof
CN114801055A (en) * 2022-03-15 2022-07-29 祥星塑料模具(嘉兴)有限公司 Plastic shell injection molding process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104164040A (en) * 2014-08-12 2014-11-26 苏州新区枫盛塑料制品厂 TPE (thermoplastic elastomer) plastic formula
CN104371301A (en) * 2014-10-29 2015-02-25 苏州新区枫盛塑料制品厂 TPE (thermoplastic elastomer) plastic formula
CN105331090A (en) * 2015-11-24 2016-02-17 王晓伟 TPE (thermal plastic elastomer) plastic formula

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104164040A (en) * 2014-08-12 2014-11-26 苏州新区枫盛塑料制品厂 TPE (thermoplastic elastomer) plastic formula
CN104371301A (en) * 2014-10-29 2015-02-25 苏州新区枫盛塑料制品厂 TPE (thermoplastic elastomer) plastic formula
CN105331090A (en) * 2015-11-24 2016-02-17 王晓伟 TPE (thermal plastic elastomer) plastic formula

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108175519A (en) * 2018-01-30 2018-06-19 张云华 A kind of operation C-arm rack
CN112048187A (en) * 2020-09-15 2020-12-08 张家港市民华塑胶有限公司 Anti-aging TPE (thermoplastic elastomer) granules and preparation method thereof
CN114801055A (en) * 2022-03-15 2022-07-29 祥星塑料模具(嘉兴)有限公司 Plastic shell injection molding process

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Application publication date: 20171222