CN101238920A - Special type protection work shoes with antistatic oil-resistant function - Google Patents

Special type protection work shoes with antistatic oil-resistant function Download PDF

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Publication number
CN101238920A
CN101238920A CNA2008103005548A CN200810300554A CN101238920A CN 101238920 A CN101238920 A CN 101238920A CN A2008103005548 A CNA2008103005548 A CN A2008103005548A CN 200810300554 A CN200810300554 A CN 200810300554A CN 101238920 A CN101238920 A CN 101238920A
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Prior art keywords
agent
stearic acid
zinc oxide
sponge
sulphur
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CNA2008103005548A
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CN100566614C (en
Inventor
李彦
蒋绮云
丁鹏
沈彬
冀小红
王志坚
易岳雄
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Jihua 3517 Rubber Products Co Ltd
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Jihua 3517 Rubber Products Co Ltd
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Priority to CNB2008103005548A priority Critical patent/CN100566614C/en
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Abstract

The invention relates to a shoes, especially a special protective footware with electrostatic resistant property and proof-oil property. The sole rubber is formed by material with electrostatic resistant property and proof-oil property and the insole sponge is formed by material with electrostatic resistant property, wherein the sole rubber comprises (mass ratio): 50-60 of natural glue, 10-20 of butyronitrile, 20-30 of cis-butadiene rubber, 2-3 of sulphur, 1.5-3 of accelerator, 1-2 of anti-aging agent, 2-3 of stearic acid, 4-6 of zinc oxide, 5-15 of conduct agent, 40-50 of strengthening agent, 25-35 of softener and the insole sponge comprises (mass ratio): 100 of natural glue, 2-3 of stearic acid, 1.5-3 of accelerator, 1-2 of anti-aging agent, 6-10 of stearic acid, 7-10 of zinc oxide, 3-6 of foaming agent, 50-60 of softener, 10-20 of conduct agent, 70-90 of clay. The insulation material is changed into electroconductive material by adding conducting material to conducting fibre in shoe insole lining, middle sole and outsole in foam sponge, so as to effectively release and export the static electricity on human by contacting the shoes with the ground.

Description

A kind of special type protection work shoes with antistatic oil-resistant function
Technical field
The present invention relates to mankind life article's shoes, refer in particular to a kind of special type protection work shoes with antistatic oil-resistant function.
Background technology
Airport ground service, gas station and various antistatics operating area all are the special work posts with particular surroundings restriction.All there is certain greasy dirt on airport ground service, gas station and surface, staff's routine work place, various antistatics operating area, and gasoline, diesel oil etc. is again high dangerous fuel, and the entrained static of human body is worked in this environment and had sizable dangerous hidden danger.Simultaneously, existing various protection work shoes, it is functional more single, and can not satisfy the various barrier propterties of the required collection of its particular job environment is the work rubber overshoes of one comprehensively.
Summary of the invention
The objective of the invention is to be improved, a kind of have antistatic, grease proofing, anti-skidding, anti-pounding be provided at shortcoming that exists in the background technology and problem, summer heat insulation, radiate heat and ventilate, winter is warming, and resistant, comfortable special type protection work shoes.
Sole part rubber of the present invention is to be made by antistatic and grease proofing formula materials, and sponge of the interior end of footwear is to be made by the antistatic formula materials; Wherein, sole part rubber is made up of following materials in weight portion:
Natural gum 50-60, NBR 10-20, cis-butadiene cement 20-30, sulphur 2-3, promoter 1.5-3, age resistor 1-2, stearic acid 2-3, zinc oxide 4-6, conductive agent 5-15, reinforcing agent 40-50, softening agent 25-35;
Sponge is made up of following materials in weight portion at the described footwear interior end:
Natural gum 100, sulphur 2-3, promoter 1.5-3, age resistor 1-2, stearic acid 6-10, zinc oxide 7-10, blowing agent 3-6, softening agent 50-60, conductive agent 10-20, potter's clay 70-90.
Advantage of the present invention and beneficial effect:
1, static electricity resistance: the conductive materials that the present invention adds by the middle end and outer bottom in the conductive fiber in the centering base fabric, the foam sponge, insulating matter has been become the material with certain electric conductivity, can effectively human body institute static electrification have been discharged with contacting of ground by footwear and derive.
2, skid resistance: outer bottom decorative pattern of the present invention is block some supporting construction, and outstanding decorative pattern is provided with the graininess pattern of cobblestone shape, has strengthened the skidproof effect that contacts with ground; The little decorative pattern of rhombus that the middle part of the side is designed has been strengthened the skid resistance of working stand up and down.
3, grease proofness: the present invention makes this footwear that certain oil resistant, grease proofing effect be arranged by the use to sizing compound formula material therefor and additive.
4, protective: the present invention has added built-in glue packet header in paracone toe place in footwear, and its hardness has reached 90 ± 5 ° (Shao Er A), when the object that can effectively cushion constant weight falls to the injury of toe.
5, function comfortableness: the present invention on structural design, fully taken into account since working environment and the different due heat insulating functions in season, radiate heat and ventilate function and winter performance such as heat-preserving function.Its heat-proof quality realizes by the thickness that increases outer bottom bottom decorative pattern; Radiate heat and ventilate then realizes by the characteristic of group's flooring; Thermal property is then realized by increasing the warming layer and the warming interior end in the group.The wash filament yarn fabric of upper of a shoe major ingredient for handling through performance, have ventilative, do not fade, wearing well, performance such as easy cleaning.The mesh material that low waist counter is selected for use has further been strengthened heat radiation, airing function, makes it to have more applicability.
Physical and mechanical properties index of the present invention:
Figure A20081030055400041
Description of drawings
Fig. 1 is a footwear body structure schematic diagram of the present invention
Fig. 2 is Fig. 1 shoes bottom schematic view
The specific embodiment
Sole part rubber of the present invention is made up of following materials in weight portion:
Natural gum 55, NBR 15, cis-butadiene cement 25, sulphur 2.5, promoter 2, age resistor 1.5, stearic acid 2.5, zinc oxide 5, conductive agent 10, reinforcing agent 45, softening agent 30;
Sponge is made up of following materials in weight portion at the footwear interior end:
Natural gum 70, sulphur 2.5, promoter 2, age resistor 1.5, stearic acid 8, zinc oxide 9, blowing agent 4.5, softening agent 55, conductive agent 15, potter's clay 80.
Reference configuration of the present invention is: upper of a shoe is made up of footwear toe lasting 4 and counter 10, and wherein footwear toe lasting 4 is different with the material of counter 10, and counter 10 is a grid cloth, is used to breathe freely; Sole is divided into the end in the big end 8 of footwear, the footwear, and the big end 8 of footwear is that bulk is put at the bottom of the vulcanized rubber of pattern structure, is used for anti-skidding; Footwear body front portion is provided with interior toecap 5, and what be used for the toe position anti-ly pounds protection; The end, comprise middle base fabric and foam sponge layer in the described footwear, is provided with conductive fiber in the wherein middle base fabric, and the end and footwear are provided with conductive layer at big the end 8 in the foam sponge, are used to discharge the static electricity on human body.
Footwear toe lasting 4 of the present invention comprises that toe lasting encloses 7, and toe lasting encloses 7 and is located between footwear toe lasting 4 and the foxing 6, is used to increase the intensity of upper of a shoe.In comprising, described counter 10, is used for the protection of heel with lining 12 and outer with lining 11.Described counter 10 also comprises external eyes lining 3, and external eyes lining 3 is provided with eyelet 2, is used to wear and ties the shoelace.Be provided with reinforcement cloth 9 between described counter 10 and the foxing 6, be used to increase the intensity of back group and foxing.The edge of described footwear toe lasting 4 and counter 10 is equipped with along bar 1.
The present invention adopts the vamp material of following specification:
Figure A20081030055400051
Embodiment of the present invention only is the description that preferred implementation of the present invention is carried out; be not that design of the present invention and scope are limited; do not breaking away under the preceding topic of design philosophy of the present invention; engineers and technicians make technical scheme of the present invention in this area various modification and improvement; all should fall into protection scope of the present invention; the technology contents that the present invention asks for protection all is documented in claims.

Claims (2)

1. special type protection work shoes with antistatic oil-resistant function, it is characterized in that: sole part rubber is to be made by antistatic and grease proofing formula materials, sponge is to be made by the antistatic formula materials at the end in the footwear; Wherein, sole part rubber is made up of following materials in weight portion:
Natural gum 50-60, NBR 10-20, cis-butadiene cement 20-30, sulphur 2-3, promoter 1.5-3, age resistor 1-2, stearic acid 2-3, zinc oxide 4-6, conductive agent 5-15, reinforcing agent 40-50, softening agent 25-35;
Sponge is made up of following materials in weight portion at the described footwear interior end:
Natural gum 100, sulphur 2-3, promoter 1.5-3, age resistor 1-2, stearic acid 6-10, zinc oxide 7-10, blowing agent 3-6, softening agent 50-60, conductive agent 10-20, potter's clay 70-90.
2. a kind of special type protection work shoes according to claim 1 with antistatic oil-resistant function, sole part rubber is made up of following materials in weight portion:
Natural gum 55, NBR 15, cis-butadiene cement 25, sulphur 2.5, promoter 2, age resistor 1.5, stearic acid 2.5, zinc oxide 5, conductive agent 10, reinforcing agent 45, softening agent 30;
Sponge is made up of following materials in weight portion at the footwear interior end:
Natural gum 70, sulphur 2.5, promoter 2, age resistor 1.5, stearic acid 8, zinc oxide 9, blowing agent 4.5, softening agent 55, conductive agent 15, potter's clay 80.
CNB2008103005548A 2008-03-13 2008-03-13 A kind of special type protection work shoes with antistatic oil-resistant function Expired - Fee Related CN100566614C (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102417634A (en) * 2011-11-25 2012-04-18 芜湖风雪橡胶有限公司 Antistatic sole rubber material
CN102488348A (en) * 2011-12-09 2012-06-13 际华三五一七橡胶制品有限公司 Rubber shoes with oilproof and antiskid functions
CN102532621A (en) * 2010-12-24 2012-07-04 福建省莆田市华丰鞋业有限公司 Light modified rubber foaming undersole material prescription and processing technology
CN102898699A (en) * 2012-09-29 2013-01-30 广东智达行新材料有限公司 Conducting rubber for sole and preparation method thereof
CN103156330A (en) * 2011-12-09 2013-06-19 际华三五一七橡胶制品有限公司 Jie Fang rubber shoes with grease proofing function
CN103275364A (en) * 2013-06-18 2013-09-04 际华三五三七制鞋有限责任公司 Anti-static bacteriostatic disulfide sponge sizing material, and preparation method and application thereof
CN103275363A (en) * 2013-06-18 2013-09-04 际华三五三七制鞋有限责任公司 Anti-static flavorless disulfide sponge sizing material, and preparation method and application thereof
CN103289140A (en) * 2013-06-18 2013-09-11 际华三五三七制鞋有限责任公司 Anti-static dithio sponge rubber material as well as preparation method and application thereof
CN103289141A (en) * 2013-06-18 2013-09-11 际华三五三七制鞋有限责任公司 Anti-static odorless odor-resistant dithio sponge rubber material as well as preparation method and application thereof
CN103300532A (en) * 2013-06-18 2013-09-18 际华三五三七制鞋有限责任公司 Environment-friendly type nonmetallic anti-piercing and antistatic heat-vulcanized rubber shoes and preparation method thereof
CN104448418A (en) * 2014-11-28 2015-03-25 刘中华 Shoe glue for steel toed shoe, steel toed shoe and preparation method thereof
CN107200886A (en) * 2017-05-25 2017-09-26 际华三五三九制鞋有限公司 Anti-skid wearable boots with spats function
CN108752652A (en) * 2018-05-24 2018-11-06 际华三五七橡胶制品有限公司 Caliga rubber outsole is made in a kind of lightweight
CN108864498A (en) * 2018-05-24 2018-11-23 际华三五七橡胶制品有限公司 A kind of lightweight dual density operation shoes sole and preparation method thereof
CN110922653A (en) * 2019-11-25 2020-03-27 安徽华信安全设备有限公司 Puncture-proof antistatic safety shoe
CN111838862A (en) * 2020-06-30 2020-10-30 国家电网有限公司 Conductive shielding shoe and preparation method thereof

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102532621A (en) * 2010-12-24 2012-07-04 福建省莆田市华丰鞋业有限公司 Light modified rubber foaming undersole material prescription and processing technology
CN102417634A (en) * 2011-11-25 2012-04-18 芜湖风雪橡胶有限公司 Antistatic sole rubber material
CN102488348A (en) * 2011-12-09 2012-06-13 际华三五一七橡胶制品有限公司 Rubber shoes with oilproof and antiskid functions
CN103156330A (en) * 2011-12-09 2013-06-19 际华三五一七橡胶制品有限公司 Jie Fang rubber shoes with grease proofing function
CN102898699A (en) * 2012-09-29 2013-01-30 广东智达行新材料有限公司 Conducting rubber for sole and preparation method thereof
CN103275363A (en) * 2013-06-18 2013-09-04 际华三五三七制鞋有限责任公司 Anti-static flavorless disulfide sponge sizing material, and preparation method and application thereof
CN103289140B (en) * 2013-06-18 2016-04-13 际华三五三七制鞋有限责任公司 Anti-electrostatic two sulphur sponge sizing material and preparation method thereof and application
CN103289140A (en) * 2013-06-18 2013-09-11 际华三五三七制鞋有限责任公司 Anti-static dithio sponge rubber material as well as preparation method and application thereof
CN103289141A (en) * 2013-06-18 2013-09-11 际华三五三七制鞋有限责任公司 Anti-static odorless odor-resistant dithio sponge rubber material as well as preparation method and application thereof
CN103300532A (en) * 2013-06-18 2013-09-18 际华三五三七制鞋有限责任公司 Environment-friendly type nonmetallic anti-piercing and antistatic heat-vulcanized rubber shoes and preparation method thereof
CN103275364A (en) * 2013-06-18 2013-09-04 际华三五三七制鞋有限责任公司 Anti-static bacteriostatic disulfide sponge sizing material, and preparation method and application thereof
CN103275363B (en) * 2013-06-18 2015-10-28 际华三五三七制鞋有限责任公司 Tasteless two sulphur sponge sizing materials of anti-electrostatic and preparation method thereof and application
CN103289141B (en) * 2013-06-18 2015-11-11 际华三五三七制鞋有限责任公司 Anti-electrostatic tasteless deodorization two sulphur sponge sizing material and preparation method thereof and application
CN103275364B (en) * 2013-06-18 2016-04-13 际华三五三七制鞋有限责任公司 Anti-static bacteriostatic two sulphur sponge sizing material and preparation method thereof and application
CN104448418A (en) * 2014-11-28 2015-03-25 刘中华 Shoe glue for steel toed shoe, steel toed shoe and preparation method thereof
CN104448418B (en) * 2014-11-28 2016-08-24 刘中华 A kind of ferrum head footwear footwear glue, ferrum head footwear and preparation method thereof
CN107200886A (en) * 2017-05-25 2017-09-26 际华三五三九制鞋有限公司 Anti-skid wearable boots with spats function
CN108752652A (en) * 2018-05-24 2018-11-06 际华三五七橡胶制品有限公司 Caliga rubber outsole is made in a kind of lightweight
CN108864498A (en) * 2018-05-24 2018-11-23 际华三五七橡胶制品有限公司 A kind of lightweight dual density operation shoes sole and preparation method thereof
CN110922653A (en) * 2019-11-25 2020-03-27 安徽华信安全设备有限公司 Puncture-proof antistatic safety shoe
CN111838862A (en) * 2020-06-30 2020-10-30 国家电网有限公司 Conductive shielding shoe and preparation method thereof
CN111838862B (en) * 2020-06-30 2021-09-07 国家电网有限公司 Conductive shielding shoe and preparation method thereof

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