CN107200886B - Anti-skid wearable boots with spats function - Google Patents
Anti-skid wearable boots with spats function Download PDFInfo
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- CN107200886B CN107200886B CN201710379646.9A CN201710379646A CN107200886B CN 107200886 B CN107200886 B CN 107200886B CN 201710379646 A CN201710379646 A CN 201710379646A CN 107200886 B CN107200886 B CN 107200886B
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- skid wearable
- layer
- ankle
- thermal insulation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/10—Footwear characterised by the material made of rubber
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/12—Soles with several layers of different materials
- A43B13/122—Soles with several layers of different materials characterised by the outsole or external layer
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
- A43B13/22—Soles made slip-preventing or wear-resisting, e.g. by impregnation or spreading a wear-resisting layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The present invention discloses a kind of anti-skid wearable boots with spats function, including sole and boot upper and the leg of a boot, sole includes the air cushion layer being bonded as one with concave-convex inserted type, upper thermal insulation layer, honeycomb aluminum antipricking layer and lower thermal insulation layer and outer bottom, and the outer bottom includes natural rubber, butadiene-styrene rubber, butadiene rubber, tetramethylthiuram disulfide, high abrasion carbon black, Universal carbon black, dibutyl phthalate, organic zinc, softening agent, dimethylaniline, cobalt naphthenate, N- phenyl-a- naphthylamines, two sulphur of dibenzamidodiphenyl, stearic acid；Arch portion, articulationes metatarsophalangeae and heel part are corresponded on air cushion layer is provided with damping plastics piece, correspond at ankle in boot upper medial surface to being provided with the ankle guard gasket being adapted with ankle shape between sole, ankle guard gasket from boot upper inside bottom to corresponding ankle from extend and form smooth transition surface etc.；The comfort for improving dress, plays a very good protection to foot, while having anti-skid wearable anti-puncture function.
Description
Technical field
The present invention relates to a kind of anti-skid wearable boots, in particular to a kind of anti-skid wearable boots with spats function.
Background technique
With the development of China's economic technology, the demand of energy resources is also increasing, especially the need of coal resource
The amount of asking also increasingly is improving, the also just opposite increase of the yield of coal, generally by semimechanized in existing coal mine
Mode exploits coal, the work of this just needs coal miner in coal mine long period, coal miner it is moist,
High temperature, sundries mince in more mine, and foot tends to injury, and the rubber overshoes that existing coal miner is worn, generally not
It can play the role of foot to be wounded by stabbing, injure by a crashing object and fray, the waterproof action of existing rubber overshoes is mainly by sole and vamp
Increase waterproof layer to realize, but the gas permeability of rubber overshoes entirety can be reduced by increasing excessive waterproof layer, long-time service can make foot
Discomfort, or even the disease of foot can be caused, while being easy to fall at existing rubber overshoes upper of a shoe and mince, cause the discomfort of foot, by
The longevity of service in the mine of coal miner work, the severe feature of working environment, just there is an urgent need to change existing skill for this
Art deacclimatizes worse environment.
The material of outsole outsole is usually the natural rubber or synthetic rubber and reinforcing agent etc. used.Because outsole is located at shoes
The outermost bottommost of son will play the effects of anti-skidding, wear-resisting, anticorrosive well.The advantages of natural rubber, is that it very
Softness, it is elastic and good, but it is exactly that wearability is not so good that disadvantage, which is also apparent that,.The shortcomings that making up natural rubber is just
It needs and reaches better comprehensive performance with other synthetic rubber, for example BR is added to make the wear-resisting more preferable of sole.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of anti-skid wearable boots with spats function, by improving boots
Side and sole structure, improve the comfort of dress, play a very good protection to foot, not only improve the protection of shoe sole bottom
Wearability, the also skid resistance between raising sole and sole can also play the role of preventing that anti-sole punctures.
Anti-skid wearable boots with spats function of the invention, including sole and boot upper and the leg of a boot, the sole is from upper
Successively include under the air cushion layer being bonded as one with concave-convex inserted type, upper thermal insulation layer, honeycomb aluminum antipricking layer and under it is heat-insulated
Layer and outer bottom, the outer bottom include following raw material by weight：
5-10 parts of natural rubber, 80-90 parts of butadiene-styrene rubber, butadiene rubber 80-90 points, tetramethylthiuram disulfide 20-
30 parts, 20-30 parts of high abrasion carbon black, 10-15 parts of Universal carbon black, 10-20 parts of dibutyl phthalate, 15-25 parts of organic zinc,
6-16 parts of softening agent, 6-9 parts of dimethylaniline, 6-9 parts of cobalt naphthenate, 5-10 parts of N- phenyl-a- naphthylamines, dibenzamido two
14-18 parts, 6-10 parts of stearic acid of two sulphur of phenyl；
Arch portion, articulationes metatarsophalangeae and heel part are corresponded on the air cushion layer and is provided with damping plastics piece, in the boots
Side medial surface correspond at ankle to being provided with the ankle guard gasket adaptable with ankle shape between sole, and the ankle guard gasket is from boots
Side inside bottom is to extension at corresponding ankle and forms smooth transition surface, and the outer bottom bottom surface is provided with anti-skid wearable surface layer,
The anti-skid wearable surface layer by several antiskid particles, the setting of corresponding forefoot middle line four rectangular projections of different sizes,
Along the symmetrically arranged semilune lug boss of rectangular projection and the " u "-shaped lug boss for being set to corresponding heel setting；
Further, the outer bottom includes following raw material by weight：
8 parts of natural rubber, 85 parts of butadiene-styrene rubber, butadiene rubber 85 divide, 25 parts of tetramethylthiuram disulfide, high wear-resistant carbon
Black 25 parts, 12 parts of Universal carbon black, 15 parts of dibutyl phthalate, 20 parts of organic zinc, 12 parts of softening agent, 7 parts of dimethylaniline,
7 parts of cobalt naphthenate, 8 parts of N- phenyl-a- naphthylamines, 16 parts, 8 parts of stearic acid of two sulphur of dibenzamidodiphenyl；
Further, the softening agent is obtained by following manner：
Further, the air cushion layer bottom surface is provided with the slot for accommodating damping plastics piece；
Further, the air cushion layer is formed by several layers cloth cementation laminated；
Further, the upper thermal insulation layer and lower thermal insulation layer are glass fiber material；
Further, the thickness of the upper thermal insulation layer and lower thermal insulation layer is 1-1.5cm；
Further, the boot upper leading inside is provided with is pounded as glass fibre and protection the anti-of toes made of resin compounded
Packet header.
Beneficial effects of the present invention：Anti-skid wearable boots with spats function of the invention, by improving boot upper and sole
Construction, improves the comfort of dress, plays a very good protection to foot, not only improves the protection wearability of shoe sole bottom,
The skid resistance between sole and sole is also improved, can also play the role of preventing that anti-sole punctures.In addition, changing to boots outer bottom
Into natural rubber, butadiene-styrene rubber and the glued use of butadiene rubber three, synergistic effect learn from other's strong points to offset one's weaknesses, give full play to wearability, elasticity
The characteristics of good and good moldability, and under the collaboration of other auxiliary agents, overcome butadiene-styrene rubber tortoise as caused by the influence of benzene lateral group
Fragility, overcome butadiene rubber due to strand it is submissive caused by sticky bad, poor in processability, tear resistance, being folded without breaking and anti-skidding
Property bad disadvantage by three glue modified synergics promote the raising of the anti-skid wearable and anti-puncture function of boots outer bottom, and lead to
It crosses high abrasion carbon black and Universal carbon black and with playing the role of reinforcement and filling, and is cooperateed with organic zinc, make reinforcement and processability
Can be suitable for, it is ensured that suitable hardness and tearing toughness because when carbon black is more than certain magnitude, can only play filling effect and
Reinforcing effect cannot be played, viscosity is enhanced by dibutyl phthalate and improves the cold tolerance of rubber, passes through hexichol first
The collaboration of acylamino- Diphenyl disulfide, stearic acid and organic zinc improves processing performance, shortens process time.
Detailed description of the invention
The invention will be further described with reference to the accompanying drawings and examples：
Fig. 1 is the structural diagram of the present invention；
Fig. 2 is the structural schematic diagram of air cushion layer in the present invention；
Fig. 3 is the structural schematic diagram at China and foreign countries bottom of the present invention.
Specific embodiment
Fig. 1 is the structural diagram of the present invention, as shown in the figure：Anti-skid wearable boots with spats function of the invention, packet
Sole 1 and boot upper 2 and the leg of a boot 3 are included, the sole 1 successively includes the air cushion being bonded as one with concave-convex inserted type from top to bottom
Layer 11, upper thermal insulation layer 12, honeycomb aluminum antipricking layer 13 and lower thermal insulation layer 14 and outer bottom 15, it is corresponding on the air cushion layer 11
Arch portion, articulationes metatarsophalangeae and heel part are provided with damping plastics piece 16, correspond at ankle in 2 medial surface of boot upper to sole
It is provided with the ankle guard gasket 21 being adapted with ankle shape between 1, the ankle guard gasket 21 is from 2 inside bottom of boot upper to corresponding foot
Extend at ankle and form smooth transition surface, 15 bottom surface of outer bottom is provided with anti-skid wearable surface layer, the anti-skid wearable surface layer
By several antiskid particles 17, four rectangular projections 18 of different sizes of corresponding forefoot middle line setting, along rectangular projection
18 symmetrically arranged semilune lug bosses 19 and be set to corresponding heel setting " U " shape lug boss 10；Sole passes through concave-convex embedding
The mode for closing bonding enhances the connective stability of each layer structure, improves firmness, avoids delamination, while playing degassing function,
It by thermal insulation layer, prevents foot from overheating, by the damping plastics piece 16 of setting, plays the role of alleviating impact force, ankle guard gasket
21 pairs of ankles are supported and protect.The special construction on anti-skid wearable surface layer designs, and enhances the wearability of sole, plays very well
Antiskid function, can be realized comprehensive skid-proof function.
In the present embodiment, 11 bottom surface of air cushion layer is provided with the slot for accommodating damping plastics piece 16；Slot is easy to implement
The shock-absorbing function of damping plastics piece 16, while ventilative effect is played again.
In the present embodiment, the air cushion layer 11 is formed by several layers cloth cementation laminated；Formation can store moisture and suction
The countless cabooses of attached a large amount of salts etc., more preferable than the effect of sponge, because sponge is too soft, and multilayer cloth has centainly
Hardness also has certain anti-puncture function, is combined with the honeycomb aluminum antipricking layer 13 in above structure, and enhancing sole is whole
Anti- puncture effect, while meeting the requirement of comfort again.
In the present embodiment, the upper thermal insulation layer 12 and lower thermal insulation layer 14 are glass fiber material；It can prevent foot from overheating,
Comfort is further increased, foot health is conducive to.
In the present embodiment, the thickness of the upper thermal insulation layer 12 and lower thermal insulation layer 14 is 1-1.5cm；The setting of thickness
Ensure heat insulation, in turn, ensures that certain comfort.
In the present embodiment, 2 leading inside of boot upper, which is provided with, protects toes as made of glass fibre and resin compounded
Anti- pound packet header 22；It is anti-compared with the light one third weight of steel toes to pound impact force >=200J.
Embodiment one
Outer bottom includes following raw material by weight：
5 parts of natural rubber, 80 parts of butadiene-styrene rubber, 80 parts of butadiene rubber, 20 parts of tetramethylthiuram disulfide, high wear-resistant carbon
Black 20 parts, 10 parts of Universal carbon black, 10 parts of dibutyl phthalate, 15 parts of organic zinc, 6 parts of softening agent, 6 parts of dimethylaniline,
6 parts of cobalt naphthenate, 5 parts of N- phenyl-a- naphthylamines, 14 parts, 6 parts of stearic acid of two sulphur of dibenzamidodiphenyl.
Embodiment two
Outer bottom includes following raw material by weight：
10 parts of natural rubber, 90 parts of butadiene-styrene rubber, butadiene rubber 90 divide, 30 parts of tetramethylthiuram disulfide, high abrasion
30 parts of carbon black, 15 parts of Universal carbon black, 20 parts of dibutyl phthalate, 25 parts of organic zinc, 16 parts of softening agent, dimethylaniline 9
Part, 9 parts of cobalt naphthenate, 10 parts of N- phenyl-a- naphthylamines, 18 parts, 10 parts of stearic acid of two sulphur of dibenzamidodiphenyl.
Embodiment three
Outer bottom includes following raw material by weight：
5 parts of natural rubber, 90 parts of butadiene-styrene rubber, butadiene rubber 80 divide, 30 parts of tetramethylthiuram disulfide, high wear-resistant carbon
Black 20 parts, 15 parts of Universal carbon black, 10 parts of dibutyl phthalate, 25 parts of organic zinc, 6 parts of softening agent, 9 parts of dimethylaniline,
6 parts of cobalt naphthenate, 10 parts of N- phenyl-a- naphthylamines, 14 parts, 10 parts of stearic acid of two sulphur of dibenzamidodiphenyl.
Example IV
Outer bottom includes following raw material by weight：
10 parts of natural rubber, 80 parts of butadiene-styrene rubber, butadiene rubber 90 divide, 20 parts of tetramethylthiuram disulfide, high abrasion
30 parts of carbon black, 10 parts of Universal carbon black, 20 parts of dibutyl phthalate, 15 parts of organic zinc, 16 parts of softening agent, dimethylaniline 6
Part, 9 parts of cobalt naphthenate, 5 parts of N- phenyl-a- naphthylamines, 18 parts, 6 parts of stearic acid of two sulphur of dibenzamidodiphenyl.
Embodiment five
Outer bottom includes following raw material by weight：
6 parts of natural rubber, 80 parts of butadiene-styrene rubber, butadiene rubber 85 divide, 30 parts of tetramethylthiuram disulfide, high wear-resistant carbon
Black 25 parts, 10 parts of Universal carbon black, 18 parts of dibutyl phthalate, 15 parts of organic zinc, 16 parts of softening agent, 7 parts of dimethylaniline,
6 parts of cobalt naphthenate, 10 parts of N- phenyl-a- naphthylamines, 16 parts, 7 parts of stearic acid of two sulphur of dibenzamidodiphenyl.
Embodiment six
Outer bottom includes following raw material by weight：
8 parts of natural rubber, 85 parts of butadiene-styrene rubber, butadiene rubber 85 divide, 25 parts of tetramethylthiuram disulfide, high wear-resistant carbon
Black 25 parts, 12 parts of Universal carbon black, 15 parts of dibutyl phthalate, 20 parts of organic zinc, 12 parts of softening agent, 7 parts of dimethylaniline,
7 parts of cobalt naphthenate, 8 parts of N- phenyl-a- naphthylamines, 16 parts, 8 parts of stearic acid of two sulphur of dibenzamidodiphenyl.
In above-described embodiment, the softening agent is obtained by following manner：It is dehydrated after the heated filtering of thick tall oil, then
Add catalyst, and post curing is polymerize by oxygen, last settle and separate, reaction equation is as follows：
Table 1：Use the performance indexes of the sole of above-mentioned material:
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to compared with
Good embodiment describes the invention in detail, those skilled in the art should understand that, it can be to skill of the invention
Art scheme is modified or replaced equivalently, and without departing from the objective and range of technical solution of the present invention, should all be covered at this
In the scope of the claims of invention.
Claims (7)
1. a kind of anti-skid wearable boots with spats function, it is characterised in that：Including sole and boot upper and the leg of a boot, the sole
Successively include from top to bottom the air cushion layer being bonded as one with concave-convex inserted type, upper thermal insulation layer, honeycomb aluminum antipricking layer and under
Thermal insulation layer and outer bottom, the outer bottom include following raw material by weight：
5-10 parts of natural rubber, 80-90 parts of butadiene-styrene rubber, 80-90 parts of butadiene rubber, 20-30 parts of tetramethylthiuram disulfide,
20-30 parts of high abrasion carbon black, 10-15 parts of Universal carbon black, 10-20 parts of dibutyl phthalate, 15-25 parts of organic zinc, softening
6-16 parts of agent, 6-9 parts of dimethylaniline, 6-9 parts of cobalt naphthenate, 5-10 parts of N- phenyl-a- naphthylamines, dibenzamidodiphenyl
Two 14-18 parts of sulphur, 6-10 parts of stearic acid；
Arch portion, articulationes metatarsophalangeae and heel part are corresponded on the air cushion layer and is provided with damping plastics piece, in the boot upper
Side is corresponded to the ankle guard gasket being adapted with ankle shape is provided between sole at ankle, and the ankle guard gasket is out of boot upper
Side bottom is to extension at corresponding ankle and forms smooth transition surface, and the outer bottom bottom surface is provided with anti-skid wearable surface layer, described
Anti-skid wearable surface layer by several antiskid particles, four rectangular projections of different sizes of corresponding forefoot middle line setting, along square
The symmetrically arranged semilune lug boss of shape protrusion and the " u "-shaped lug boss for being set to corresponding heel setting；
The softening agent is obtained by following manner：
2. the anti-skid wearable boots according to claim 1 with spats function, it is characterised in that：The outer bottom is by weight
Including following raw material：
8 parts of natural rubber, 85 parts of butadiene-styrene rubber, 85 parts of butadiene rubber, 25 parts of tetramethylthiuram disulfide, high abrasion carbon black 25
Part, 12 parts of Universal carbon black, 15 parts of dibutyl phthalate, 20 parts of organic zinc, 12 parts of softening agent, 7 parts of dimethylaniline, cycloalkanes
7 parts of sour cobalt, 8 parts of N- phenyl-a- naphthylamines, 16 parts, 8 parts of stearic acid of two sulphur of dibenzamidodiphenyl.
3. the anti-skid wearable boots according to claim 1 with spats function, it is characterised in that：The air cushion layer bottom surface is set
It is equipped with the slot for accommodating damping plastics piece.
4. the anti-skid wearable boots according to claim 1 with spats function, it is characterised in that：The air cushion layer is by several
Layer cloth cementation laminated forms.
5. the anti-skid wearable boots according to claim 1 with spats function, it is characterised in that：The upper thermal insulation layer is under
Thermal insulation layer is glass fiber material.
6. the anti-skid wearable boots according to claim 5 with spats function, it is characterised in that：The upper thermal insulation layer is under
The thickness of thermal insulation layer is 1-1.5cm.
7. the anti-skid wearable boots according to claim 1 with spats function, it is characterised in that：The boot upper leading inside
It is provided with protection the anti-of toes as made of glass fibre and resin compounded and pounds packet header.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710379646.9A CN107200886B (en) | 2017-05-25 | 2017-05-25 | Anti-skid wearable boots with spats function |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710379646.9A CN107200886B (en) | 2017-05-25 | 2017-05-25 | Anti-skid wearable boots with spats function |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107200886A CN107200886A (en) | 2017-09-26 |
| CN107200886B true CN107200886B (en) | 2018-11-23 |
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ID=59905370
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710379646.9A Active CN107200886B (en) | 2017-05-25 | 2017-05-25 | Anti-skid wearable boots with spats function |
Country Status (1)
| Country | Link |
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| CN (1) | CN107200886B (en) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2279811Y (en) * | 1997-01-31 | 1998-04-29 | 李新海 | Work footwear with functions of anti-rammed, anti-pulunged, acid/base resistant and oil resistant |
| CN100566614C (en) * | 2008-03-13 | 2009-12-09 | 际华三五一七橡胶制品有限公司 | A kind of special type protection work shoes with antistatic oil-resistant function |
| CN201541806U (en) * | 2009-09-28 | 2010-08-11 | 芜湖华松鞋业有限公司 | Air cushion rubber boot |
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2017
- 2017-05-25 CN CN201710379646.9A patent/CN107200886B/en active Active
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| Publication number | Publication date |
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| CN107200886A (en) | 2017-09-26 |
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