CN103497377A - Shoe sole rubber composition - Google Patents
Shoe sole rubber composition Download PDFInfo
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- CN103497377A CN103497377A CN201310473835.4A CN201310473835A CN103497377A CN 103497377 A CN103497377 A CN 103497377A CN 201310473835 A CN201310473835 A CN 201310473835A CN 103497377 A CN103497377 A CN 103497377A
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Abstract
The invention discloses a rubber composition. The rubber composition comprises the following components in parts by weight: 5-10 parts of fluorosilicone rubber, 10-20 parts of acrylonitrile-butadiene rubber, 15-30 parts of styrene-butadiene rubber, 10-20 parts of isoprene rubber, 10-20 parts of white carbon black, 2-5 parts of calcium sulfate, 5-10 parts of stearic acid, 1-3 parts of sulfur, 1-3 parts of a vulcanization accelerator, 2-3 parts of zinc oxide and 1-2 parts of an anti-aging agent. Shoe soles prepared form the shoe sole rubber composition provided by the invention have abrasion resistance and good elasticity.
Description
Technical field
The present invention relates to a kind of rubber combination, relate in particular to a kind of rubber combination for sole.
Background technology
Sole, be the important part in footwear material field, and the major function of sole is to protect foot, anti-skidding, and damping guarantees the comfortable of user's foot, reduces the occurrence probability of sport injury.The material of sole is in the majority with rubber-sole, at the bottom of General Purpose Rubber, and thermoplastic shaping, minute natural rubber and regenerated rubber.
Rubber soles requires to have that wear resistance is good, anti-skidding, flexible, easy fracture not, and pliability is better, expandability good, contraction is stable, hardness is good, the characteristics of good bandability, waterproof, good springiness.
The known made various footwear of rubber soles with making through general sulfidization molding technique, because its sole lacks flexibility, and weight is larger, quite feels uncomfortable while therefore wearing.
CN1071115A has proposed a kind of production technique of rubber pange sole formed.Wherein mention the hole-forming material and the wear-resistant material that adopt two kinds of different ingredients, through 130 ℃ of-170 ℃ of high temperature 3-7 minute sulfidization moldings, can make the sole of a kind of brisk, softness and good springiness, to make leather shoes comfortable and easy to wear, cloth shoes etc.
CN1323689A has proposed a kind of one-time formed dual-density rubber sole, by having, high resistance oil, high abrasion and anlistatig material are made bottom and special foam material is made surface layer, through 110-120 ℃, under 60-70 kilogram pressure, vulcanize 7-10 minute and be molten into one and form.
But the elasticity of the rubber soles of prior art still can not meet the especially demand of sport footwear of footwear, therefore there is a need in the field to provide a kind of wear resistance good, good springiness the rubber combination for sole.
Summary of the invention
For the deficiencies in the prior art, one of purpose of the present invention is to provide a kind of rubber combination, comprises by weight following component:
Trifluoropropyl siloxane 5~10
Paracril 10~20
Styrene-butadiene rubber(SBR) 15~30
Synthetic polyisoprene 10~20
White carbon black 10~20
Calcium sulfate 2~5
Stearic acid 5~10
Sulphur 1~3
Vulcanization accelerator 1~3
Zinc oxide 2~3
Anti-aging agent 1~2.
Preferably, described composition comprises following component by weight:
Trifluoropropyl siloxane 5~8
Paracril 10~26
Styrene-butadiene rubber(SBR) 15~25
Synthetic polyisoprene 10~16
White carbon black 10~15
Calcium sulfate 2~5
Stearic acid 5~8
Sulphur 1~3
Vulcanization accelerator 1~3
Zinc oxide 2~3
Anti-aging agent 1~2.
Preferably, described anti-aging agent is anti-aging agent RD, antioxidant MB or anti-aging agent two 264.
Preferably, described vulcanization accelerator is DTDM or PDM.
Preferably, described composition comprises following component by weight:
Trifluoropropyl siloxane 5~10
Paracril 10~20
Styrene-butadiene rubber(SBR) 15~30
Synthetic polyisoprene 10~20
White carbon black 10~20
Calcium sulfate 2~5
Stearic acid 5~10
Sulphur 1~3
Accelerator D TDM 1~3
Zinc oxide 2~3
Anti-aging agent RD 1~2.
Preferably, described composition comprises following component by weight:
Trifluoropropyl siloxane 5~8
Paracril 10~26
Styrene-butadiene rubber(SBR) 15~25
Synthetic polyisoprene 10~16
White carbon black 10~15
Calcium sulfate 2~5
Stearic acid 5~8
Sulphur 1~3
Accelerator D TDM 1~3
Zinc oxide 2~3
Anti-aging agent RD 1~2.
Two of purpose of the present invention is to provide a kind of sole, and described sole is prepared by foregoing rubber combination.
Compared with prior art, when the sole that uses sole rubber composition provided by the invention to prepare has wear resistance, also there is good elasticity.
Embodiment
For the present invention is described better, be convenient to understand technical scheme of the present invention, typical but non-limiting embodiment of the present invention is as follows:
Embodiment 1
A kind of rubber combination, described composition comprises following component by weight:
Trifluoropropyl siloxane 5
Paracril 20
Styrene-butadiene rubber(SBR) 15
Synthetic polyisoprene 20
White carbon black 10
Calcium sulfate 5
Stearic acid 5
Sulphur 3
Accelerator D TDM 1
Zinc oxide 3
Anti-aging agent RD 1.
Embodiment 2
A kind of sole rubber composition, described composition comprises following component by weight:
Trifluoropropyl siloxane 10
Paracril 10
Styrene-butadiene rubber(SBR) 30
Synthetic polyisoprene 10
White carbon black 20
Calcium sulfate 2
Stearic acid 10
Sulphur 1
Accelerator P DM 3
Zinc oxide 2
Antioxidant MB 2.
Embodiment 3
A kind of sole rubber composition, described composition comprises following component by weight:
Trifluoropropyl siloxane 7
Paracril 15
Styrene-butadiene rubber(SBR) 28
Synthetic polyisoprene 15
White carbon black 15
Calcium sulfate 4
Stearic acid 8
Sulphur 2
Accelerator P DM 2
Zinc oxide 2.5
Anti-aging agent RD 1.3.
Should be noted that and understand, in the situation that do not break away from the desired the spirit and scope of the present invention of accompanying claim, can make to the present invention of foregoing detailed description various modifications and improvement.Therefore, the scope of claimed technical scheme is not subject to the restriction of given any specific exemplary teachings.
Applicant's statement, the present invention illustrates detailed method of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned detailed method, does not mean that the present invention must rely on above-mentioned detailed method and could implement.The person of ordinary skill in the field should understand, any improvement in the present invention, to the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, the selection of concrete mode etc., within all dropping on protection scope of the present invention and open scope.
Claims (7)
1. a rubber combination, is characterized in that, described composition comprises following component by weight:
Trifluoropropyl siloxane 5~10
Paracril 10~20
Styrene-butadiene rubber(SBR) 15~30
Synthetic polyisoprene 10~20
White carbon black 10~20
Calcium sulfate 2~5
Stearic acid 5~10
Sulphur 1~3
Vulcanization accelerator 1~3
Zinc oxide 2~3
Anti-aging agent 1~2.
2. composition as claimed in claim 1, is characterized in that, described composition comprises following component by weight:
Trifluoropropyl siloxane 5~8
Paracril 10~26
Styrene-butadiene rubber(SBR) 15~25
Synthetic polyisoprene 10~16
White carbon black 10~15
Calcium sulfate 2~5
Stearic acid 5~8
Sulphur 1~3
Vulcanization accelerator 1~3
Zinc oxide 2~3
Anti-aging agent 1~2.
3. composition as claimed in claim 1 or 2, is characterized in that, described anti-aging agent is anti-aging agent RD, antioxidant MB or anti-aging agent two 264.
4. composition as described as one of claim 1~3, is characterized in that, described vulcanization accelerator is DTDM or PDM.
5. composition as described as one of claim 1~4, is characterized in that, described composition comprises following component by weight:
Trifluoropropyl siloxane 5~10
Paracril 10~20
Styrene-butadiene rubber(SBR) 15~30
Synthetic polyisoprene 10~20
White carbon black 10~20
Calcium sulfate 2~5
Stearic acid 5~10
Sulphur 1~3
Accelerator D TDM 1~3
Zinc oxide 2~3
Anti-aging agent RD 1~2.
6. composition as described as one of claim 1~5, is characterized in that, described composition comprises following component by weight:
Trifluoropropyl siloxane 5~8
Paracril 10~26
Styrene-butadiene rubber(SBR) 15~25
Synthetic polyisoprene 10~16
White carbon black 10~15
Calcium sulfate 2~5
Stearic acid 5~8
Sulphur 1~3
Accelerator D TDM 1~3
Zinc oxide 2~3
Anti-aging agent RD 1~2.
7. a sole, is characterized in that, described sole is prepared by the described rubber combination of one of claim 1~6.
Priority Applications (1)
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CN201310473835.4A CN103497377A (en) | 2013-10-11 | 2013-10-11 | Shoe sole rubber composition |
Applications Claiming Priority (1)
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CN201310473835.4A CN103497377A (en) | 2013-10-11 | 2013-10-11 | Shoe sole rubber composition |
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CN103497377A true CN103497377A (en) | 2014-01-08 |
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CN201310473835.4A Pending CN103497377A (en) | 2013-10-11 | 2013-10-11 | Shoe sole rubber composition |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104788879A (en) * | 2015-04-09 | 2015-07-22 | 茂泰(福建)鞋材有限公司 | Electric-shock-resistant rubber sole and preparation method thereof |
CN105820383A (en) * | 2016-05-24 | 2016-08-03 | 宁波市中迪鞋业有限公司 | Composite wear-resisting shoe sole |
CN106317523A (en) * | 2016-08-31 | 2017-01-11 | 合肥邦立电子股份有限公司 | Anti-impact rubber material for wire harness shell |
CN108276625A (en) * | 2018-01-25 | 2018-07-13 | 温州鑫彩鸿安防科技有限公司 | A kind of high temperature resistance safety shoe and its manufacturing method |
CN110092956A (en) * | 2019-04-09 | 2019-08-06 | 兴化市戴窑镇永生橡胶制品厂 | A kind of antibacterial abrasive rubber and preparation method thereof |
CN110144055A (en) * | 2019-04-09 | 2019-08-20 | 兴化市戴窑镇永生橡胶制品厂 | A kind of abrasive rubber and preparation method thereof |
WO2020130952A1 (en) * | 2018-12-19 | 2020-06-25 | Trenčianska univerzita Alexandra Dubčeka v Trenčíne | Elastomer mixture and method of its preparation |
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WO2012124026A1 (en) * | 2011-03-11 | 2012-09-20 | ダイセル・エボニック株式会社 | Sheet for shoe sole and shoe sole using sheet |
CN102816358A (en) * | 2012-09-04 | 2012-12-12 | 苏州伟伦运动休闲用品有限公司 | Transparent antistatic shoe sole and production method thereof |
CN102850760A (en) * | 2012-09-24 | 2013-01-02 | 吴江市信许塑料鞋用配套有限公司 | Wear-resistant anti-static sole material |
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2013
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Patent Citations (3)
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WO2012124026A1 (en) * | 2011-03-11 | 2012-09-20 | ダイセル・エボニック株式会社 | Sheet for shoe sole and shoe sole using sheet |
CN102816358A (en) * | 2012-09-04 | 2012-12-12 | 苏州伟伦运动休闲用品有限公司 | Transparent antistatic shoe sole and production method thereof |
CN102850760A (en) * | 2012-09-24 | 2013-01-02 | 吴江市信许塑料鞋用配套有限公司 | Wear-resistant anti-static sole material |
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中国化工学会橡胶专业委员会组织编写: "《橡胶助剂手册》", 30 April 2000, 化学工业出版社 * |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104788879A (en) * | 2015-04-09 | 2015-07-22 | 茂泰(福建)鞋材有限公司 | Electric-shock-resistant rubber sole and preparation method thereof |
CN105820383A (en) * | 2016-05-24 | 2016-08-03 | 宁波市中迪鞋业有限公司 | Composite wear-resisting shoe sole |
CN105820383B (en) * | 2016-05-24 | 2018-01-02 | 宁波市中迪鞋业有限公司 | A kind of composite-material abrasive sole |
CN106317523A (en) * | 2016-08-31 | 2017-01-11 | 合肥邦立电子股份有限公司 | Anti-impact rubber material for wire harness shell |
CN108276625A (en) * | 2018-01-25 | 2018-07-13 | 温州鑫彩鸿安防科技有限公司 | A kind of high temperature resistance safety shoe and its manufacturing method |
CN108276625B (en) * | 2018-01-25 | 2019-11-22 | 温州鑫彩鸿安防科技有限公司 | A kind of safety shoe resistant to high temperatures and its manufacturing method |
WO2020130952A1 (en) * | 2018-12-19 | 2020-06-25 | Trenčianska univerzita Alexandra Dubčeka v Trenčíne | Elastomer mixture and method of its preparation |
CN110092956A (en) * | 2019-04-09 | 2019-08-06 | 兴化市戴窑镇永生橡胶制品厂 | A kind of antibacterial abrasive rubber and preparation method thereof |
CN110144055A (en) * | 2019-04-09 | 2019-08-20 | 兴化市戴窑镇永生橡胶制品厂 | A kind of abrasive rubber and preparation method thereof |
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Application publication date: 20140108 |