CN103497370A - Shoe sole rubber composition - Google Patents

Shoe sole rubber composition Download PDF

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Publication number
CN103497370A
CN103497370A CN201310473551.5A CN201310473551A CN103497370A CN 103497370 A CN103497370 A CN 103497370A CN 201310473551 A CN201310473551 A CN 201310473551A CN 103497370 A CN103497370 A CN 103497370A
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CN
China
Prior art keywords
parts
rubber
aging agent
sole
vaseline
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310473551.5A
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Chinese (zh)
Inventor
黄海胜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KUNSHAN CHUNBAI PRECISION HARDWARE Co Ltd
Original Assignee
KUNSHAN CHUNBAI PRECISION HARDWARE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KUNSHAN CHUNBAI PRECISION HARDWARE Co Ltd filed Critical KUNSHAN CHUNBAI PRECISION HARDWARE Co Ltd
Priority to CN201310473551.5A priority Critical patent/CN103497370A/en
Publication of CN103497370A publication Critical patent/CN103497370A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a shoe sole rubber composition. The shoe sole rubber composition comprises the following components in parts by weight: 3-8 parts of fluorosilicone rubber, 12-25 parts of acrylonitrile-butadiene rubber, 15-30 parts of polybutadiene rubber, 10-20 parts of white carbon black, 3-8 parts of calcium carbonate, 3-8 parts of calcium sulfate, 2-5 parts of stearic acid, 1-4 parts of sulfur, 1-4 parts of a vulcanization accelerator, 2-3 parts of zinc oxide, 1-2 parts of an anti-aging agent and 1-4 parts of vaseline. Shoe soles prepared from the shoe sole rubber composition provided by the invention have abrasion resistance and good elasticity.

Description

A kind of sole rubber composition
Technical field
The present invention relates to a kind of rubber combination, relate in particular to a kind of rubber combination for sole.
Background technology
Sole, be the important part in footwear material field, and the major function of sole is to protect foot, anti-skidding, and damping guarantees the comfortable of user's foot, reduces the occurrence probability of sport injury.The material of sole is in the majority with rubber-sole, at the bottom of General Purpose Rubber, and thermoplastic shaping, minute natural rubber and regenerated rubber.
Rubber soles requires to have that wear resistance is good, anti-skidding, flexible, easy fracture not, and pliability is better, expandability good, contraction is stable, hardness is good, the characteristics of good bandability, waterproof, good springiness.
The known made various footwear of rubber soles with making through general sulfidization molding technique, because its sole lacks flexibility, and weight is larger, quite feels uncomfortable while therefore wearing.
CN1071115A has proposed a kind of production technique of rubber pange sole formed.Wherein mention the hole-forming material and the wear-resistant material that adopt two kinds of different ingredients, through 130 ℃ of-170 ℃ of high temperature 3-7 minute sulfidization moldings, can make the sole of a kind of brisk, softness and good springiness, to make leather shoes comfortable and easy to wear, cloth shoes etc.
CN1323689A has proposed a kind of one-time formed dual-density rubber sole, by having, high resistance oil, high abrasion and anlistatig material are made bottom and special foam material is made surface layer, through 110-120 ℃, under 60-70 kilogram pressure, vulcanize 7-10 minute and be molten into one and form.
But the elasticity of the rubber soles of prior art still can not meet the especially demand of sport footwear of footwear, therefore there is a need in the field to provide a kind of wear resistance good, good springiness the rubber combination for sole.
Summary of the invention
For the deficiencies in the prior art, one of purpose of the present invention is to provide a kind of sole rubber composition, and described composition comprises following component by weight:
Trifluoropropyl siloxane 3~8
Paracril 12~25
Cis-1,4-polybutadiene rubber 15~30
White carbon black 10~20
Calcium carbonate 3~8
Calcium sulfate 3~8
Stearic acid 2~5
Sulphur 1~4
Vulcanization accelerator 1~4
Zinc oxide 2~3
Anti-aging agent 1~2
Vaseline 1~4.
Preferably, described composition comprises following component by weight:
Trifluoropropyl siloxane 3~6
Paracril 15~20
Cis-1,4-polybutadiene rubber 16~27
White carbon black 10~15
Calcium carbonate 3~6
Calcium sulfate 3~6
Stearic acid 2~4
Sulphur 2~4
Vulcanization accelerator 2~4
Zinc oxide 2~3
Anti-aging agent 1~2
Vaseline 1~4.
Preferably, described anti-aging agent is anti-aging agent RD, antioxidant MB or anti-aging agent two 264.
Preferably, described vulcanization accelerator is DTDM or PDM.
As optimal technical scheme, described composition comprises following component by weight:
Trifluoropropyl siloxane 3~8
Paracril 12~25
Cis-1,4-polybutadiene rubber 15~30
White carbon black 10~20
Calcium carbonate 3~8
Calcium sulfate 3~8
Stearic acid 2~5
Sulphur 1~4
Accelerator D TDM 1~4
Zinc oxide 2~3
Anti-aging agent RD 1~2
Vaseline 1~4.
As further optimal technical scheme, described composition comprises following component by weight:
Trifluoropropyl siloxane 3~6
Paracril 15~20
Cis-1,4-polybutadiene rubber 16~27
White carbon black 10~15
Calcium carbonate 3~6
Calcium sulfate 3~6
Stearic acid 2~4
Sulphur 2~4
Accelerator D TDM 2~4
Zinc oxide 2~3
Anti-aging agent RD 1~2
Vaseline 1~4.
Two of purpose of the present invention is to provide a kind of sole, and described sole is prepared by foregoing rubber combination.
Compared with prior art, when the sole that uses sole rubber composition provided by the invention to prepare has wear resistance, also there is good elasticity.
Embodiment
For the present invention is described better, be convenient to understand technical scheme of the present invention, typical but non-limiting embodiment of the present invention is as follows:
Embodiment 1
A kind of sole rubber composition, described composition comprises following component by weight:
Trifluoropropyl siloxane 3
Paracril 25
Cis-1,4-polybutadiene rubber 15
White carbon black 20
Calcium carbonate 3
Calcium sulfate 8
Stearic acid 2
Sulphur 4
Accelerator D TDM 1
Zinc oxide 3
Anti-aging agent RD 1
Vaseline 4.
Embodiment 2
A kind of sole rubber composition, described composition comprises following component by weight:
Trifluoropropyl siloxane 8
Paracril 12
Cis-1,4-polybutadiene rubber 30
White carbon black 10
Calcium carbonate 8
Calcium sulfate 3
Stearic acid 5
Sulphur 1
Accelerator D TDM 4
Zinc oxide 2
Anti-aging agent RD 2
Vaseline 1.
Embodiment 3
A kind of sole rubber composition, described composition comprises following component by weight:
Trifluoropropyl siloxane 5
Paracril 17
Cis-1,4-polybutadiene rubber 23
White carbon black 16
Calcium carbonate 5
Calcium sulfate 5
Stearic acid 3
Sulphur 3
Accelerator D TDM 3
Zinc oxide 2.6
Anti-aging agent RD 1.4
Vaseline 2.
Should be noted that and understand, in the situation that do not break away from the desired the spirit and scope of the present invention of accompanying claim, can make to the present invention of foregoing detailed description various modifications and improvement.Therefore, the scope of claimed technical scheme is not subject to the restriction of given any specific exemplary teachings.
Applicant's statement, the present invention illustrates detailed method of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned detailed method, does not mean that the present invention must rely on above-mentioned detailed method and could implement.The person of ordinary skill in the field should understand, any improvement in the present invention, to the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, the selection of concrete mode etc., within all dropping on protection scope of the present invention and open scope.

Claims (7)

1. a sole rubber composition, is characterized in that, described composition comprises following component by weight:
Trifluoropropyl siloxane 3~8
Paracril 12~25
Cis-1,4-polybutadiene rubber 15~30
White carbon black 10~20
Calcium carbonate 3~8
Calcium sulfate 3~8
Stearic acid 2~5
Sulphur 1~4
Vulcanization accelerator 1~4
Zinc oxide 2~3
Anti-aging agent 1~2
Vaseline 1~4.
2. composition as claimed in claim 1, is characterized in that, described composition comprises following component by weight:
Trifluoropropyl siloxane 3~6
Paracril 15~20
Cis-1,4-polybutadiene rubber 16~27
White carbon black 10~15
Calcium carbonate 3~6
Calcium sulfate 3~6
Stearic acid 2~4
Sulphur 2~4
Vulcanization accelerator 2~4
Zinc oxide 2~3
Anti-aging agent 1~2
Vaseline 1~4.
3. composition as claimed in claim 1 or 2, is characterized in that, described anti-aging agent is anti-aging agent RD, antioxidant MB or anti-aging agent two 264.
4. composition as described as one of claim 1~3, is characterized in that, described vulcanization accelerator is DTDM or PDM.
5. composition as described as one of claim 1~4, is characterized in that, described composition comprises following component by weight:
Trifluoropropyl siloxane 3~8
Paracril 12~25
Cis-1,4-polybutadiene rubber 15~30
White carbon black 10~20
Calcium carbonate 3~8
Calcium sulfate 3~8
Stearic acid 2~5
Sulphur 1~4
Accelerator D TDM 1~4
Zinc oxide 2~3
Anti-aging agent RD 1~2
Vaseline 1~4.
6. composition as described as one of claim 1~5, is characterized in that, described composition comprises following component by weight:
Trifluoropropyl siloxane 3~6
Paracril 15~20
Cis-1,4-polybutadiene rubber 16~27
White carbon black 10~15
Calcium carbonate 3~6
Calcium sulfate 3~6
Stearic acid 2~4
Sulphur 2~4
Accelerator D TDM 2~4
Zinc oxide 2~3
Anti-aging agent RD 1~2
Vaseline 1~4.
7. a sole, is characterized in that, described sole is prepared by the described rubber combination of one of claim 1~6.
CN201310473551.5A 2013-10-11 2013-10-11 Shoe sole rubber composition Pending CN103497370A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310473551.5A CN103497370A (en) 2013-10-11 2013-10-11 Shoe sole rubber composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310473551.5A CN103497370A (en) 2013-10-11 2013-10-11 Shoe sole rubber composition

Publications (1)

Publication Number Publication Date
CN103497370A true CN103497370A (en) 2014-01-08

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Family Applications (1)

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CN201310473551.5A Pending CN103497370A (en) 2013-10-11 2013-10-11 Shoe sole rubber composition

Country Status (1)

Country Link
CN (1) CN103497370A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104292563A (en) * 2014-10-21 2015-01-21 常熟市任阳工艺鞋厂 Abrasion-resistant antibacterial sole material
CN104292533A (en) * 2014-10-21 2015-01-21 常熟市任阳工艺鞋厂 Anti-bacterial sole material
CN104311915A (en) * 2014-10-21 2015-01-28 常熟市任阳工艺鞋厂 Anti-aging and anti-bacterial sole material
CN105330912A (en) * 2015-11-13 2016-02-17 吴江市风尚鞋厂 High temperature and corrosion resisting sizing material for rubber sole and preparing technology thereof
CN105694147A (en) * 2016-03-22 2016-06-22 苏州越湖海绵复合厂 Light-reflecting shoe material suitable for night running and preparation method of light-reflecting shoe material
CN107254078A (en) * 2017-07-05 2017-10-17 泉州市华阳鞋材科技有限公司晋江分公司 A kind of lightweight rubber soles material
CN108948461A (en) * 2018-07-26 2018-12-07 合肥远科服装设计有限公司 A kind of wear-resisting sole rubber mass and preparation method thereof
CN108976517A (en) * 2018-07-26 2018-12-11 合肥远科服装设计有限公司 A kind of corrosion-and high-temp-resistant sizing material for rubber shoe sole and preparation method thereof
CN109054125A (en) * 2018-07-26 2018-12-21 合肥远科服装设计有限公司 A kind of sizing material for rubber shoe sole and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012124026A1 (en) * 2011-03-11 2012-09-20 ダイセル・エボニック株式会社 Sheet for shoe sole and shoe sole using sheet
CN102964645A (en) * 2012-11-29 2013-03-13 泰亚鞋业股份有限公司 Ice surface anti-slip rubber sports shoe soles and manufacturing method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012124026A1 (en) * 2011-03-11 2012-09-20 ダイセル・エボニック株式会社 Sheet for shoe sole and shoe sole using sheet
CN102964645A (en) * 2012-11-29 2013-03-13 泰亚鞋业股份有限公司 Ice surface anti-slip rubber sports shoe soles and manufacturing method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104292563A (en) * 2014-10-21 2015-01-21 常熟市任阳工艺鞋厂 Abrasion-resistant antibacterial sole material
CN104292533A (en) * 2014-10-21 2015-01-21 常熟市任阳工艺鞋厂 Anti-bacterial sole material
CN104311915A (en) * 2014-10-21 2015-01-28 常熟市任阳工艺鞋厂 Anti-aging and anti-bacterial sole material
CN105330912A (en) * 2015-11-13 2016-02-17 吴江市风尚鞋厂 High temperature and corrosion resisting sizing material for rubber sole and preparing technology thereof
CN105694147A (en) * 2016-03-22 2016-06-22 苏州越湖海绵复合厂 Light-reflecting shoe material suitable for night running and preparation method of light-reflecting shoe material
CN107254078A (en) * 2017-07-05 2017-10-17 泉州市华阳鞋材科技有限公司晋江分公司 A kind of lightweight rubber soles material
CN108948461A (en) * 2018-07-26 2018-12-07 合肥远科服装设计有限公司 A kind of wear-resisting sole rubber mass and preparation method thereof
CN108976517A (en) * 2018-07-26 2018-12-11 合肥远科服装设计有限公司 A kind of corrosion-and high-temp-resistant sizing material for rubber shoe sole and preparation method thereof
CN109054125A (en) * 2018-07-26 2018-12-21 合肥远科服装设计有限公司 A kind of sizing material for rubber shoe sole and preparation method thereof

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Application publication date: 20140108