CN102715693B - Leakage-proof rain shoe - Google Patents
Leakage-proof rain shoe Download PDFInfo
- Publication number
- CN102715693B CN102715693B CN201210232987.0A CN201210232987A CN102715693B CN 102715693 B CN102715693 B CN 102715693B CN 201210232987 A CN201210232987 A CN 201210232987A CN 102715693 B CN102715693 B CN 102715693B
- Authority
- CN
- China
- Prior art keywords
- leakage
- interlayer
- rubber
- butadiene
- middle end
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011229 interlayer Substances 0.000 claims abstract description 17
- 229920001971 elastomer Polymers 0.000 claims abstract description 14
- 239000005060 rubber Substances 0.000 claims abstract description 14
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 9
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims description 9
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 9
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 8
- 238000004073 vulcanization Methods 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- 239000004568 cement Substances 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 239000010721 machine oil Substances 0.000 claims description 6
- 229920001206 natural gum Polymers 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 239000011593 sulfur Substances 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 230000029058 respiratory gaseous exchange Effects 0.000 claims description 4
- 230000000149 penetrating effect Effects 0.000 claims description 3
- 229920002943 EPDM rubber Polymers 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000002844 melting Methods 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000007704 transition Effects 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 description 6
- 230000003078 antioxidant effect Effects 0.000 description 6
- 102000007620 Pulmonary Surfactant-Associated Protein C Human genes 0.000 description 5
- 108010007125 Pulmonary Surfactant-Associated Protein C Proteins 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
Landscapes
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention relates to a rain shoe which comprises a rubber upper and a sole, wherein the rubber upper is used for accepting a foot of a user; the sole is used for fixedly connecting the rubber upper; the rain shoe is characterized in that the sole is composed of an outsole, an interlayer and an insole in turn from bottom to top; and the interlayer is spliced between the outsole and the insole. A rubber interlayer is arranged between the traditional outsole and insole; the hot-melting property of the interlayer is between those of the outsole and the insole; the interlayer has an excellent transition function in a hot-melting compound technology; the component formula of the insole is adjusted; and the wrinkling and uneven problems of the prior art are thoroughly solved.
Description
Technical field
The present invention relates to a kind of rain boots.
Background technology
Traditional rain boots kind comparatively single, structure is simple, and be usually made up of sole and telescopic upper of a shoe, the commercially available new type rubber rain boots that there is sole and be made up of the large end and the middle end, have fashion and advantage attractive in appearance.
But there is a following difficult problem in its production technology, the large end and the middle end, form different due to component, cause its hot molten characteristic difference, can produce wrinkling and uneven, have a strong impact on its sealing property in gluing procedures.
Summary of the invention
For solving above-mentioned the deficiencies in the prior art, the invention provides a kind of leakage-proof rain shoe, plastic clip layer in all one's life is set between traditional large end and the middle end, the hot molten characteristic of interlayer is between the large end and the middle end, the effect of forming a connecting link can be well played in hot melt combination process, meanwhile, the component formula at the bottom of centering adjusts, and thoroughly solves the problem that prior art is wrinkling and uneven.
Concrete technical scheme of the present invention is:
A kind of leakage-proof rain shoe, comprises
Rubber upper of a shoe, for receiving the foot of user,
Sole, for affixed described rubber upper of a shoe,
It is characterized in that described sole is made up of the large end, interlayer and the middle end from bottom to up successively, interlayer was adhered at the large end and the middle end.
Formula by weight of the described middle end is:
Natural gum 5-60
Butadiene-styrene rubber 7-84
Cis-butadiene cement 3.5-40
Sulfur 0.36-4
Diphenylguanidine 0.09-1
Captax 0.15-1.8
Altax 0.11-1.2
Vulcanization accelerator TMTD 0.015-0.2
Antioxidant SP-C 0.35-4
Zinc oxide 0.9-11
Stearic acid 0.18-2
Calcium carbonate 21-240
Diethylene glycol (DEG) 0.27-3
White carbon 2-24
Machine oil 1.25-14
Resin 0.6-7.
Further, formula is by weight at the described middle end:
Natural gum 10-30
Butadiene-styrene rubber 14-42
Cis-butadiene cement 7-20
Sulfur 0.72-2
Diphenylguanidine 0.18-0.5
Captax 0.3-0.9
Altax 0.22-0.6
Vulcanization accelerator TMTD 0.03-0.1
Antioxidant SP-C 0.7-2
Zinc oxide 1.8-5.5
Stearic acid 0.36-1
Calcium carbonate 42-120
Ethylene propylene diene rubber 10.5
Diethylene glycol (DEG) 0.55-1.5
White carbon 4-12
Machine oil 2.5-7
Resin 1.2-3.5.
Closer, formula is by weight at the middle end:
Natural gum 10-30
Butadiene-styrene rubber 14-42
Cis-butadiene cement 7-20
Sulfur 0.72-2
Diphenylguanidine 0.18-0.5
Captax 0.3-0.9
Altax 0.22-0.6
Vulcanization accelerator TMTD 0.03-0.1
Antioxidant SP-C 0.7-2
Zinc oxide 1.8-5.5
Stearic acid 0.36-1
Calcium carbonate 42-120
Diethylene glycol (DEG) 0.55-1.5
White carbon 4-12
Machine oil 2.5-7
Resin 1.2-3.5.
The composite middle end that the present invention uses, the ozone resistance of shoes, anti-light photograph and ultraviolet performance can be increased, the environment for use of various complexity can be adapted to, there is good versatility and service life.
Be provided with a doublet cord for ventilating in the middle part of the bottom surface of described interlayer, this doublet cord extends to heel part from heelpiece portion always, after penetrating medium bottom shoes heel, connects with rubber upper heel portion line of breathing freely.Overlapping being designed with of two-wire is beneficial to breathing freely in heat seal process, easily discharges the air of footwear inside in order to avoid sole produces bubble.
The bonding leakproof flap in described rubber upper of a shoe cylinder portion, flap both sides are provided with the welt for bandage.By the strap configurations of similar Martin's boots, play the effect of laminating foot, there is feature elegant in appearance simultaneously.
Under the english abbreviation concrete meaning related to herein enters:
Diphenylguanidine: accelerator D, CAS No:102-06-7, molecular formula C13H13N3.
Captax: accelerator M, molecular formula: C7H5NS2, CAS NO:149-30-4.
Altax: 2,2'-dibenzothiazoledisulfde, CAS No:120-78-5, molecular formula: C14H8N2S4.
Vulcanization accelerator TMTD: AATIRAM, molecular formula: C6H12N2S4, CAS No:137-26-8.
Antioxidant SP-C:Antioxidant SP-C, is made up of styrenated phenol and mineral filler, is a kind of not staining antioxidant used in natural and synthetic rubber articles, has and do not separate out and good dispersion.
Accompanying drawing explanation
Fig. 1 is rain boots structural representation of the present invention.
Fig. 2 is rain boots part-structure schematic diagram of the present invention.
Fig. 3 is footwear sole construction schematic diagram of the present invention.
Wherein, the large end 1, the middle end 2, upper of a shoe 3, suture 4, flap 5, welt 6, ornamental strip 7, lace hole 8, ventilative line 9, carries band 10, interlayer 11, doublet cord 12.
Detailed description of the invention
Below in conjunction with accompanying drawing, the utility model is further described.
As shown in Figure 1-Figure 3, rain boots form primarily of sole and upper of a shoe 3, and sole as shown in Figure 3, is made up of the large end 1, the middle end 2 and interlayer 11, and interlayer 11 is as interlayer adhesion and greatly at the end 1 and the middle end 2.Be provided with a doublet cord 12 for ventilating in the middle part of the bottom surface of interlayer 11, this doublet cord 12 extends to heel part from heelpiece portion always, after penetrating heel part of the middle end 2, connects with rubber upper of a shoe 3 rear heel line 9 of breathing freely.
The shoulder at the middle end 2 can arrange suture 4, with Martin's boots unlike, this suture 4 only plays decoration function.
Upper of a shoe 3 comprises a leakproof flap 5, and the both sides of flap 5 are provided with the welt 6 of lace hole 8, and the downside of welt 6 can be provided with for beautifying and the ornamental strip 7 of reinforcement effect.
Claims (5)
1. a leakage-proof rain shoe, comprises
Rubber upper of a shoe, for receiving the foot of user,
Sole, for affixed described rubber upper of a shoe,
It is characterized in that described sole is made up of the large end, interlayer and the middle end from bottom to up successively, interlayer is adhered at the large end and the middle end;
Be provided with a doublet cord for ventilating in the middle part of the bottom surface of described interlayer, this doublet cord extends to heel part from heelpiece portion always, after penetrating medium bottom shoes heel, connects with rubber upper heel portion line of breathing freely.
2. leakage-proof rain shoe according to claim 1, is characterized in that formula by weight of the described middle end is:
Natural gum 5-60
Butadiene-styrene rubber 7-84
Cis-butadiene cement 3.5-40
Sulfur 0.36-4
Diphenylguanidine 0.09-1
Captax 0.15-1.8
Altax 0.11-1.2
Vulcanization accelerator TMTD 0.015-0.2
Promoter SP-c 0.35-4
Zinc oxide 0.9-11
Stearic acid 0.18-2
Calcium carbonate 21-240
Diethylene glycol (DEG) 0.27-3
White carbon 2-24
Machine oil 1.25-14
Resin 0.6-7.
3. leakage-proof rain shoe according to claim 1, is characterized in that formula by weight of the described middle end is:
Natural gum 10-30
Butadiene-styrene rubber 14-42
Cis-butadiene cement 7-20
Sulfur 0.72-2
Diphenylguanidine 0.18-0.5
Captax 0.3-0.9
Altax 0.22-0.6
Vulcanization accelerator TMTD 0.03-0.1
Promoter SP-c 0.7-2
Zinc oxide 1.8-5.5
Stearic acid 0.36-1
Calcium carbonate 42-120
Ethylene propylene diene rubber 10.5
Diethylene glycol (DEG) 0.55-1.5
White carbon 4-12
Machine oil 2.5-7
Resin 1.2-3.5.
4. leakage-proof rain shoe according to claim 1, is characterized in that formula by weight of the described middle end is:
Natural gum 10-30
Butadiene-styrene rubber 14-42
Cis-butadiene cement 7-20
Sulfur 0.72-2
Diphenylguanidine 0.18-0.5
Captax 0.3-0.9
Altax 0.22-0.6
Vulcanization accelerator TMTD 0.03-0.1
Promoter SP-c 0.7-2
Zinc oxide 1.8-5.5
Stearic acid 0.36-1
Calcium carbonate 42-120
Diethylene glycol (DEG) 0.55-1.5
White carbon 4-12
Machine oil 2.5-7
Resin 1.2-3.5.
5. leakage-proof rain shoe according to claim 1, it is characterized in that the bonding leakproof flap in described rubber upper of a shoe cylinder portion, flap both sides are provided with the welt for bandage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210232987.0A CN102715693B (en) | 2012-07-05 | 2012-07-05 | Leakage-proof rain shoe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210232987.0A CN102715693B (en) | 2012-07-05 | 2012-07-05 | Leakage-proof rain shoe |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102715693A CN102715693A (en) | 2012-10-10 |
| CN102715693B true CN102715693B (en) | 2015-04-01 |
Family
ID=46941676
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210232987.0A Expired - Fee Related CN102715693B (en) | 2012-07-05 | 2012-07-05 | Leakage-proof rain shoe |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102715693B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105237824B (en) * | 2015-11-05 | 2017-05-03 | 常州卓源橡胶制品有限公司 | Lightweight rain boot and making method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR8603994A (en) * | 1986-08-21 | 1988-04-12 | Chiou Pyng Jang | ODOR PREVENTIVE SHOE INSOLE |
| CN1522617A (en) * | 2003-02-21 | 2004-08-25 | 杭州雅加实业有限公司 | Electricity prevention boot formula for high voltage prevention |
| CN1791338A (en) * | 2003-04-30 | 2006-06-21 | 通用电气公司 | Improved waterproof footwear construction |
| CN101117414A (en) * | 2007-06-26 | 2008-02-06 | 孙振华 | Abrasion-proof resin rubber cushion |
| CN101117027A (en) * | 2007-06-29 | 2008-02-06 | 孙振华 | Method of manufacturing plastic pad and rubber blanket |
| KR20100056052A (en) * | 2008-11-19 | 2010-05-27 | 박상용 | The insole providing a soft cusion to men's shoes |
| CN102399384A (en) * | 2011-11-25 | 2012-04-04 | 芜湖风雪橡胶有限公司 | Hard lining rubber material for shoe |
| CN202774413U (en) * | 2012-07-05 | 2013-03-13 | 杭州锦利鞋业有限公司 | Leakage-proof rain shoe |
-
2012
- 2012-07-05 CN CN201210232987.0A patent/CN102715693B/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR8603994A (en) * | 1986-08-21 | 1988-04-12 | Chiou Pyng Jang | ODOR PREVENTIVE SHOE INSOLE |
| CN1522617A (en) * | 2003-02-21 | 2004-08-25 | 杭州雅加实业有限公司 | Electricity prevention boot formula for high voltage prevention |
| CN1791338A (en) * | 2003-04-30 | 2006-06-21 | 通用电气公司 | Improved waterproof footwear construction |
| CN101117414A (en) * | 2007-06-26 | 2008-02-06 | 孙振华 | Abrasion-proof resin rubber cushion |
| CN101117027A (en) * | 2007-06-29 | 2008-02-06 | 孙振华 | Method of manufacturing plastic pad and rubber blanket |
| KR20100056052A (en) * | 2008-11-19 | 2010-05-27 | 박상용 | The insole providing a soft cusion to men's shoes |
| CN102399384A (en) * | 2011-11-25 | 2012-04-04 | 芜湖风雪橡胶有限公司 | Hard lining rubber material for shoe |
| CN202774413U (en) * | 2012-07-05 | 2013-03-13 | 杭州锦利鞋业有限公司 | Leakage-proof rain shoe |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102715693A (en) | 2012-10-10 |
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Legal Events
| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: HANGZHOU JINHU SHOES CO., LTD. Free format text: FORMER OWNER: HANGZHOU JINLI SHOES CO., LTD. Effective date: 20150216 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20150216 Address after: Banqiao Town Lingxi village of Ling'an city Hangzhou 311301 Zhejiang province No. 68 Applicant after: HANGZHOU JINHU SHOES CO., LTD. Address before: 311301, Hangzhou City, Zhejiang province Ling'an City Banqiao High Bay Village Applicant before: Hangzhou Jinli Shoes Co.,Ltd. |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170328 Address after: Banqiao Town Lingxi village of Ling'an city 311300 Hangzhou city in Zhejiang Province Patentee after: HANGZHOU LIN'AN BAISHENG SHOE INDUSTRY CO., LTD. Address before: Banqiao Town Lingxi village of Ling'an city Hangzhou 311301 Zhejiang province No. 68 Patentee before: HANGZHOU JINHU SHOES CO., LTD. |
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| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150401 Termination date: 20180705 |