CN104448418B - A kind of ferrum head footwear footwear glue, ferrum head footwear and preparation method thereof - Google Patents
A kind of ferrum head footwear footwear glue, ferrum head footwear and preparation method thereof Download PDFInfo
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- CN104448418B CN104448418B CN201410715651.9A CN201410715651A CN104448418B CN 104448418 B CN104448418 B CN 104448418B CN 201410715651 A CN201410715651 A CN 201410715651A CN 104448418 B CN104448418 B CN 104448418B
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- reinforcement members
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- adhesive
- rubber
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 72
- 239000003292 glue Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims description 8
- 239000000463 material Substances 0.000 claims abstract description 32
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 26
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000013040 rubber vulcanization Methods 0.000 claims abstract description 23
- 238000004513 sizing Methods 0.000 claims abstract description 22
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 14
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000011787 zinc oxide Substances 0.000 claims abstract description 13
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 12
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 12
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000008117 stearic acid Substances 0.000 claims abstract description 12
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 11
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 11
- 239000001993 wax Substances 0.000 claims abstract description 8
- 230000002787 reinforcement Effects 0.000 claims description 87
- 239000000853 adhesive Substances 0.000 claims description 56
- 230000001070 adhesive effect Effects 0.000 claims description 56
- 210000003423 ankle Anatomy 0.000 claims description 36
- 229910000831 Steel Inorganic materials 0.000 claims description 32
- 239000010959 steel Substances 0.000 claims description 32
- 229920001971 elastomer Polymers 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 24
- 239000005060 rubber Substances 0.000 claims description 24
- 210000003371 toe Anatomy 0.000 claims description 21
- 229910052717 sulfur Inorganic materials 0.000 claims description 14
- 239000011593 sulfur Substances 0.000 claims description 14
- 238000005516 engineering process Methods 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- 238000004140 cleaning Methods 0.000 claims description 12
- 239000004033 plastic Substances 0.000 claims description 9
- 229920003023 plastic Polymers 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 238000003825 pressing Methods 0.000 claims description 5
- NEHDRDVHPTWWFG-UHFFFAOYSA-N Dioctyl hexanedioate Chemical compound CCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCC NEHDRDVHPTWWFG-UHFFFAOYSA-N 0.000 claims description 4
- 241000143437 Aciculosporium take Species 0.000 claims description 3
- 241000196324 Embryophyta Species 0.000 claims description 3
- 241001122315 Polites Species 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 210000004744 fore-foot Anatomy 0.000 claims description 3
- 239000012943 hotmelt Substances 0.000 claims description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 3
- 235000014593 oils and fats Nutrition 0.000 claims description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims 8
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims 3
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims 2
- 230000002265 prevention Effects 0.000 abstract description 4
- -1 Ethanedioic acid dioctyl ester Chemical class 0.000 abstract 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Natural products OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 9
- PEJVLWCOQVHCAF-UHFFFAOYSA-N dioctyl oxalate Chemical compound CCCCCCCCOC(=O)C(=O)OCCCCCCCC PEJVLWCOQVHCAF-UHFFFAOYSA-N 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 244000147058 Derris elliptica Species 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/14—Footwear characterised by the material made of plastics
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43D—MACHINES, TOOLS, EQUIPMENT OR METHODS FOR MANUFACTURING OR REPAIRING FOOTWEAR
- A43D25/00—Devices for gluing shoe parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D35/00—Producing footwear
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
nullThe invention discloses a kind of sizing material，This sizing material is made up of following component by weight: 17 18 parts of glue of mark、Butadiene rubber 13 14 parts、Butyronitrile 13 14 parts、White carbon 13 14 parts、Activated Calcium carbonate 26 27 parts、Petropols 23 parts、DEOTACK RS tackifier 12 parts、Ethanedioic acid dioctyl ester 45 parts、1 1.2 parts of age resistor、0.05 0.1 parts of snow defence wax、Microwax 0.05 0.1 parts、Stearic acid 0.3 0.4 parts、Polyethylene Glycol 1 1.5 parts、Zinc oxide 2 2.3 parts、Rubber vulcanization accelerant MBT S (DM) 0.5 0.6 parts、Rubber vulcanization accelerant MBT (M) 0.2 0.3 parts、TS 80 accelerator 0.04 0.05 parts、0.8 0.9 parts of insoluble sulfur powder.Also providing for a kind of ferrum head footwear utilizing this sizing material to make, its collision prevention pierces through effective, and service life is long.
Description
Technical field
The present invention relates to footwear manufacturing technology field, be specifically related to a kind of ferrum head footwear footwear glue, ferrum head
Footwear and preparation method thereof.
Background technology
Society labour protection oneself become the problem that each labourer is concerned about conscientiously, thus, each side
Labor protection facilities are also corresponding a lot, and a kind of is exactly one of them for protecting the ferrum head footwear of the personal safety of labourer.
Especially it is engaged in building, lumbers, weld, carry and the industry such as machinery, manufacture, metallurgy, harbour
It is engaged in personnel, the most often mentions the weights such as the metal that foreign object or run into falls and injure instep, toe by a crashing object
Situation, therefore the quality of ferrum head footwear is particularly important.Ferrum head footwear of the prior art are due to its footwear glue material
The material problem such as proportioning and processing technology, it is impossible to meet labourer to ferrum head footwear light mass and thin wall, mechanical strength the most again
Stable demand.
Summary of the invention
In order to overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of ferrum head footwear sizing material, this glue
Material can be effectively improved the collision prevention penetration performance of ferrum head footwear.
Another object of the present invention is to provide a kind of ferrum head footwear, there is excellent collision prevention and pierce through effect,
Light mass and thin wall, mechanical strength is the most stable, and service life is long.
A further object of the present invention is to provide the preparation method of a kind of ferrum head footwear, uses the ferrum head footwear of the present invention
A kind of ferrum head footwear with superperformance prepared by sizing material.
For solving the problems referred to above, the technical solution adopted in the present invention is as follows:
A kind of ferrum head footwear sizing material, it is prepared from by following component based on following weight portion: mark glue 17-18
Part, butadiene rubber 13-14 part, butyronitrile 13-14 part, white carbon 13-14 part, activated Calcium carbonate 26-27 part,
Petropols 2-3 part, DEOTACK RS tackifier 1-2 part, ethanedioic acid dioctyl ester 4-5 part, age resistor
1-1.2 part, snow defence wax 0.05-0.1 part, microwax 0.05-0.1 part, stearic acid 0.3-0.4 part, Polyethylene Glycol
1-1.5 part, zinc oxide 2-2.3 part, rubber vulcanization accelerant MBT S (DM) 0.5-0.6 part, the vulcanization of rubber
Accelerant MBT (M) 0.2-0.3 part, TS-80 accelerator 0.04-0.05 part, insoluble sulfur powder 0.8-0.9
Part.
As preferably, described ferrum head footwear sizing material is prepared from by following component by weight: mark glue 17.9485
Part, butadiene rubber 13.4614 parts, butyronitrile 13.4614 parts, white carbon 13.4614 parts, activated Calcium carbonate 26.9277
Part, Petropols 2.2436 parts, DEOTACK RS tackifier 1.1218 parts, ethanedioic acid dioctyl ester 4.4871
Part, 1.1218 parts of age resistor, 0.0561 part of snow defence wax, microwax 0.0561 part, stearic acid 0.3590 part,
Polyethylene Glycol 1.3461 parts, zinc oxide 2.2436 parts, rubber vulcanization accelerant MBT S (DM) 0.5833
Part, rubber vulcanization accelerant MBT (M) 0.2244 part, TS-80 accelerator 0.0494 part, insoluble sulfur
0.8526 part of sulphur powder.
In the present invention, preferred scheme be described mark glue be trophy factory of rubber head office of rubber industry group of Vietnam
The mark glue produced, described butadiene rubber is the suitable fourth that Maoming Petrochemical branch company of middle petrochemical industry limited company produces
Rubber, described butyronitrile is the butyronitrile that Shandong Ju Ding Chemical Co., Ltd. produces, and described white carbon is Fujian Province three
The white carbon that bright positive element Chemical Co., Ltd. produces, described activated Calcium carbonate is that Heng great chemical plant, Yangshan produces
Activated Calcium carbonate, described Petropols are the oil tree that Nan Yang, Jiangsu Jingjiang City chemical industry goods and materials company limited produces
Fat, described DEOTACK RS tackifier is that Nan Yang, Jiangsu Jingjiang City chemical industry goods and materials company limited produces
DEOTACK RS tackifier, described adipic acid dioctyl ester is two that Shandong Lan Fan Chemical Co., Ltd. produces
Dioctyl phthalate, described age resistor is the age resistor that Shanghai rubber chemicals Co., Ltd., Factory produces, described microwax
The microwax produced for Lian Zheng rubber and plastic Science and Technology Ltd. of Foshan City, described stearic acid is that the polite oils and fats of Indonesia is public
The stearic acid that department produces, described Polyethylene Glycol is the Polyethylene Glycol that Jilin Chemical Industrial Co. Ltd. produces,
Described zinc oxide is the zinc oxide that Liuzhou Zhong Sexin product Co., Ltd produces, described thiofide
MBTS (DM) is the rubber vulcanization accelerant MBT S (DM) that Shenyang new oceangoing voyage Chemical Co., Ltd. produces,
Described rubber vulcanization accelerant MBT (M) is that the vulcanization of rubber that Shenyang new oceangoing voyage Chemical Co., Ltd. produces promotees
Entering agent MBT (M), described TS-80 accelerator is the TS-80 that Lian Zheng rubber and plastic Science and Technology Ltd. of Foshan City produces
Accelerator, described insoluble sulfur powder is the insoluble sulfur that Lian Zheng rubber and plastic Science and Technology Ltd. of Foshan City produces
Powder.
A kind of ferrum head footwear, these ferrum head footwear are prepared from by above-mentioned ferrum head footwear sizing material.
The preparation method of a kind of ferrum head footwear, is injected in mould after above-mentioned ferrum head footwear sizing material hot melt, respectively
It is fabricated to footwear body, toe-cap press strip large stretch of, rear, backsight, rear enclosure, sole reinforcement members, successively according to as follows
Step is carried out:
A. take ankle socks and the shoe last matched with ankle socks, shoe last is inserted in ankle socks, then in shoe last end
Ankle socks is fixed；The clamp identical with footwear height degree is utilized to finish at least two and footwear height degree phase on ankle socks
Height point before and after Tong, then finishes the connecting line between height point according to height point；
B. take ferrum head U-shaped reinforcement members, and brush adhesive in ferrum head U-shaped reinforcement members, then will
Ferrum head U-shaped reinforcement members is placed in 2 points 30 seconds in the baking oven of 60-65 DEG C, then by ferrum head U-shaped reinforcement members
It is attached at the forefoot at the bottom of ankle socks；
C. take steel toes and steel toes reinforcement members, then steel toes reinforcement members is cleaned, then by ladle
Head and steel toes reinforcement members utilize adhesive to fit together；Then by the steel toes fit together and steel
Packet header reinforcement members utilizes adhesive to be attached at the toe in ankle socks face；
D. take ferrum head D-shaped reinforcement members, then utilize adhesive that ferrum head D-shaped reinforcement members is attached to ladle
The lower section of head；
E. one layer of adhesive of uniform coating on ankle socks, is subsequently placed in 2 points 30 seconds in the baking oven of 60-65 DEG C,
Take the end and sole reinforcement members in steel, then utilize adhesive that the end in steel and sole reinforcement members are fitted in one
Rise, then one layer of adhesive of even spread in sole reinforcement members, the end in steel and sole reinforcement members are pasted
In ankle socks bottom surface, then with the pressure pressing 3-4 second of 15-20kg；
F. in steel, it is coated with one layer of adhesive at the end uniformly, sticks iron core；
G. second layer sole reinforcement members is taken, one layer of adhesive of even spread in second layer sole reinforcement members,
Second layer sole reinforcement members is attached on iron core, then carries out wheel load process；
H. take front press strip, then front press strip is carried out, then front press strip adhesive is attached to footwear body big
Sheet is corresponding to, on the position of instep, then carrying out wheel load process；
I. instep reinforcement members and foxing reiforcer component are taken, then to instep reinforcement members and foxing reiforcer component
It is carried out, then utilizes adhesive to be attached to respectively on ankle socks instep reinforcement members and foxing reiforcer component
At instep and at rear heel, then carry out wheel load process；
J. in each reinforcement members being attached on ankle socks and exposed ankle socks surface is coated with one layer of adhesive uniformly,
It is subsequently placed in 2 points 30 seconds in the baking oven of 60-65 DEG C, then the footwear body sheet through over cleaning is utilized adhesive
It is attached to footwear body position；Toe-cap sheet through over cleaning then utilize adhesive be attached to footwear body sheet corresponding to footwear
On the position of head, then carry out wheel load process；
K. take backsight, then backsight is soaked 1-2 minute in formaldehyde, be then placed in backsight tenderizing machine drying
Soft, then the back spread adhesive through over cleaning is fit together with backsight, be subsequently placed in 60-65 DEG C
2 points 30 seconds in baking oven, the rear enclosure then fit together and backsight are fitted at the rear heel of footwear body, then
Carry out wheel load process；
L. take the big end and third layer sole reinforcement members, then the big end and third layer sole reinforcement members are carried out
Cleaning treatment, fits together the big end and third layer sole reinforcement members followed by adhesive, then exists
Third layer sole reinforcement members surface is coated with three adhesives uniformly, will fit together between coating every time
The big end and reinforcement members of the big end be placed in 2 points 30 seconds in the baking oven of 60-65 DEG C, then utilize adhesive by
Three layers of sole reinforcement members fit together with second layer sole reinforcement members, carry out the most successively upper and lower press,
Wheel load processes；
The most then, footwear carrying out sulfur adding treatment, the temperature of described sulfur adding treatment is 110 DEG C, described in add at sulfur
The time of reason is 80 minutes, then carries out delasting, cutting, bound edge process, it is thus achieved that ferrum head footwear.
Also include between described l, m step that step n. takes two pieces trade mark patch, then utilize adhesive respectively will
Two pieces trade mark patch fits together with rear enclosure, footwear body sheet, then utilizes cross press to carry out pressing process.
Step p is also included: the ferrum head footwear of acquisition utilize gasoline be cleaned processing after described m step,
It is then placed in shoe pad, is then coated with one layer of waterproofing agent uniformly on ferrum head footwear surface.
Compared to existing technology, the beneficial effects of the present invention is:
Ferrum head footwear sizing material of the present invention is by selecting conjunction between the component of uniqueness, each component in current material
The proportioning of reason so that footwear glue has good wear-resisting, ageing resistace and oil resistant soda acid performance；Use this
The ferrum head footwear wear-resisting antiskid that bright described ferrum head footwear sizing material makes, oil resistant soda acid, there is excellent collision prevention
While penetration performance, have again that light mass and thin wall, mechanical strength be big, the advantage of good stability, service life
Long, it is possible to adapt to different working environments.
Below in conjunction with detailed description of the invention, the present invention is described in further detail.
Detailed description of the invention
Enforcement 1:
A kind of ferrum head footwear sizing material, it is prepared from by following component by weight: 17.9485 parts of glue of mark,
Butadiene rubber 13.4614 parts, butyronitrile 13.4614 parts, white carbon 13.4614 parts, activated Calcium carbonate 26.9277
Part, Petropols 2.2436 parts, DEOTACK RS tackifier 1.1218 parts, ethanedioic acid dioctyl ester 4.4871
Part, 1.1218 parts of age resistor, 0.0561 part of snow defence wax, microwax 0.0561 part, stearic acid 0.3590 part,
Polyethylene Glycol 1.3461 parts, zinc oxide 2.2436 parts, rubber vulcanization accelerant MBT S (DM) 0.5833
Part, rubber vulcanization accelerant MBT (M) 0.2244 part, TS-80 accelerator 0.0494 part, insoluble sulfur
0.8526 part of sulphur powder.
Enforcement 2:
A kind of ferrum head footwear sizing material, it is prepared from by following component by weight: mark 17 parts of glue, along fourth
Rubber 13 parts, butyronitrile 13 parts, white carbon 13 parts, activated Calcium carbonate 26 parts, Petropols 2 parts, DEOTACK
RS tackifier 1 part, ethanedioic acid dioctyl ester 4 parts, 1 part of age resistor, 0.05 part of snow defence wax, microwax 0.05
Part, stearic acid 0.3 part, Polyethylene Glycol 1 part, zinc oxide 2 parts, rubber vulcanization accelerant MBT S (DM)
0.5 part, rubber vulcanization accelerant MBT (M) 0.2 part, TS-80 accelerator 0.04 part, insoluble sulfur
0.8 part of powder.
Enforcement 3:
A kind of ferrum head footwear sizing material, it is prepared from by following component by weight: mark 18 parts of glue, along fourth
Rubber 14 parts, butyronitrile 14 parts, white carbon 14 parts, activated Calcium carbonate 27 parts, Petropols 3 parts, DEOTACK
RS tackifier 2 parts, ethanedioic acid dioctyl ester 5 parts, 1.2 parts of age resistor, 0.1 part of snow defence wax, microwax 0.1
Part, stearic acid 0.4 part, Polyethylene Glycol 1.5 parts, zinc oxide 2.3 parts, rubber vulcanization accelerant MBT S (DM)
0.6 part, rubber vulcanization accelerant MBT (M) 0.3 part, TS-80 accelerator 0.05 part, insoluble sulfur
0.9 part of powder.
In above-described embodiment 1-3, described mark glue is that trophy factory of rubber head office of rubber industry group of Vietnam produces
Mark glue, described butadiene rubber is the butadiene rubber that Maoming Petrochemical branch company of middle petrochemical industry limited company produces,
Described butyronitrile is the butyronitrile that Shandong Ju Ding Chemical Co., Ltd. produces, and described white carbon is Sanming City, Fujian Province positive element
The white carbon that Chemical Co., Ltd. produces, described activated Calcium carbonate is the activated carbon that Heng great chemical plant, Yangshan produces
Acid calcium, described Petropols are the Petropols that Nan Yang, Jiangsu Jingjiang City chemical industry goods and materials company limited produces, institute
Stating DEOTACK RS tackifier is the DEOTACK that Nan Yang, Jiangsu Jingjiang City chemical industry goods and materials company limited produces
RS tackifier, described adipic acid dioctyl ester is the adipic acid dioctyl ester that Shandong Lan Fan Chemical Co., Ltd. produces,
Described age resistor is the age resistor that Shanghai rubber chemicals Co., Ltd., Factory produces, and described microwax is Foshan City's connection
The microwax that positive rubber and plastic Science and Technology Ltd. produces, described stearic acid is the hard of polite oils and fats company of Indonesia production
Fat acid, described Polyethylene Glycol is the Polyethylene Glycol that Jilin Chemical Industrial Co. Ltd. produces, described oxidation
Zinc is the zinc oxide that Liuzhou Zhong Sexin product Co., Ltd produces, described rubber vulcanization accelerant MBT S
(DM) be Shenyang new oceangoing voyage Chemical Co., Ltd. produce rubber vulcanization accelerant MBT S (DM), described
Rubber vulcanization accelerant MBT (M) is the thiofide that Shenyang new oceangoing voyage Chemical Co., Ltd. produces
MBT (M), described TS-80 accelerator is that the TS-80 that Lian Zheng rubber and plastic Science and Technology Ltd. of Foshan City produces promotees
Entering agent, described insoluble sulfur powder is the insoluble sulfur powder that Lian Zheng rubber and plastic Science and Technology Ltd. of Foshan City produces.
Embodiment 4:
A kind of ferrum head footwear, its manufacture method is to be injected in mould after above-mentioned ferrum head footwear sizing material hot melt, point
It is not fabricated to footwear body, toe-cap press strip large stretch of, rear, backsight, rear enclosure, sole reinforcement members, successively according to such as
Lower step is carried out:
A. take ankle socks and the shoe last matched with ankle socks, shoe last is inserted in ankle socks, then in shoe last end
Ankle socks is fixed；Utilize the clamp identical with footwear height degree finish on ankle socks two identical with footwear height degree
Anterior and posterior height point, then finishes the connecting line between height point according to height point；
B. take ferrum head U-shaped reinforcement members, and brush adhesive in ferrum head U-shaped reinforcement members, then will
Ferrum head U-shaped reinforcement members is placed in 2 points 30 seconds in the baking oven of 60-65 DEG C, then by ferrum head U-shaped reinforcement members
It is attached at the forefoot at the bottom of ankle socks；
C. take steel toes and steel toes reinforcement members, then steel toes reinforcement members is cleaned, then by ladle
Head and steel toes reinforcement members utilize adhesive to fit together；Then by the steel toes fit together and steel
Packet header reinforcement members utilizes adhesive to be attached at the toe in ankle socks face；
D. take ferrum head D-shaped reinforcement members, then utilize adhesive that ferrum head D-shaped reinforcement members is attached to ladle
The lower section of head；
E. one layer of adhesive of uniform coating on ankle socks, is subsequently placed in 2 points 30 seconds in the baking oven of 60-65 DEG C,
Take the end and sole reinforcement members in steel, then utilize adhesive that the end in steel and sole reinforcement members are fitted in one
Rise, then one layer of adhesive of even spread in sole reinforcement members, the end in steel and sole reinforcement members are pasted
In ankle socks bottom surface, then with the pressure pressing 3-4 second of 15-20kg；
F. in steel, it is coated with one layer of adhesive at the end uniformly, sticks iron core；
G. second layer sole reinforcement members is taken, one layer of adhesive of even spread in second layer sole reinforcement members,
Second layer sole reinforcement members is attached on iron core, then carries out wheel load process；
H. take front press strip, then front press strip is carried out, then front press strip adhesive is attached to footwear body big
Sheet is corresponding to, on the position of instep, then carrying out wheel load process；
I. instep reinforcement members and foxing reiforcer component are taken, then to instep reinforcement members and foxing reiforcer component
It is carried out, then utilizes adhesive to be attached to respectively on ankle socks instep reinforcement members and foxing reiforcer component
At instep and at rear heel, then carry out wheel load process；
J. in each reinforcement members being attached on ankle socks and exposed ankle socks surface is coated with one layer of adhesive uniformly,
It is subsequently placed in 2 points 30 seconds in the baking oven of 60-65 DEG C, then the footwear body sheet through over cleaning is utilized adhesive
It is attached to footwear body position；Toe-cap sheet through over cleaning then utilize adhesive be attached to footwear body sheet corresponding to footwear
On the position of head, then carry out wheel load process；
K. take backsight, then backsight is soaked 1-2 minute in formaldehyde, be then placed in backsight tenderizing machine drying
Soft, then the back spread adhesive through over cleaning is fit together with backsight, be subsequently placed in 60-65 DEG C
2 points 30 seconds in baking oven, the rear enclosure then fit together and backsight are fitted at the rear heel of footwear body, then
Carry out wheel load process；
L. take the big end and third layer sole reinforcement members, then the big end and third layer sole reinforcement members are carried out
Cleaning treatment, fits together the big end and third layer sole reinforcement members followed by adhesive, then exists
Third layer sole reinforcement members surface is coated with three adhesives uniformly, will fit together between coating every time
The big end and reinforcement members of the big end be placed in 2 points 30 seconds in the baking oven of 60-65 DEG C, then utilize adhesive by
Three layers of sole reinforcement members fit together with second layer sole reinforcement members, carry out the most successively upper and lower press,
Wheel load processes；
The most then, footwear carrying out sulfur adding treatment, the temperature of described sulfur adding treatment is 110 DEG C, described in add at sulfur
The time of reason is 80 minutes, then carries out delasting, cutting, bound edge process, it is thus achieved that ferrum head footwear.
Performance test
Following test is to carry out the ferrum head footwear of above-described embodiment 4 according to GB GB4014-83 and LD50-94
Test.
1. compression resistance test
Concrete method of testing is by toe-cap at 25mm ± 3mm after steel toes, and even side undercutting is cut off.It is placed in
The error of indication is on the platform of the pressure testing machine of 1%.High 35mm is put in toe-cap, diameter 22mm's
Plasticine cylinder.Then exert a force required power with the speed of 5mm/min-2mm/min, continue 1min,
Power is made to return to zero-bit again.Take out the plasticine compressed, use kind of calliper height, measure with lowest order
Value is measured value.Testing result meets regulation.
2. anti-impact force test
Concrete grammar is to will be equipped with the toe-cap of toe box and cylindric plasticine is placed under shock machine, fix by
Inspection toe-cap, promotes jump bit 23kg ± 0.2kg and impacts toe-cap to the height required then freely falling body.Take out
Plasticine kind of calliper height.Detected value meets regulation.
3. prevent piercing through test
Concrete method of testing is for No. 60 (standard type GB346-75) steel nails, and the error of indication is the pressure of 1%
On the platform of testing machine, fixing upright with plasticine, the half sole central part being placed on sole slowly pressurizes, and works as pressure
Power reaches shutdown inspection during 50kg.Testing result is that sole does not pierce through.
Above-mentioned embodiment is only the preferred embodiment of the present invention, it is impossible to limit present invention protection with this
Scope, the change of any unsubstantiality that those skilled in the art is done on the basis of the present invention and replacement
Belong to scope of the present invention.
Claims (7)
1. a ferrum head footwear sizing material, it is characterised in that: this sizing material is by following component system based on following weight portion
Standby form: mark glue 17-18 part, butadiene rubber 13-14 part, butyronitrile 13-14 part, white carbon 13-14 part,
Activated Calcium carbonate 26-27 part, Petropols 2-3 part, DEOTACK RS tackifier 1-2 part, adipic acid
Dioctyl ester 4-5 part, age resistor 1-1.2 part, snow defence wax 0.05-0.1 part, microwax 0.05-0.1 part, tristearin
Acid 0.3-0.4 part, Polyethylene Glycol 1-1.5 part, zinc oxide 2-2.3 part, rubber vulcanization accelerant MBT S 0.5-0.6
Part, rubber vulcanization accelerant MBT 0.2-0.3 part, TS-80 accelerator 0.04-0.05 part, insoluble sulfur powder
0.8-0.9 part.
A kind of ferrum head footwear sizing material the most according to claim 1, it is characterised in that: this sizing material is pressed by following
The component of weight portion meter is prepared from: mark 17.9485 parts of glue, butadiene rubber 13.4614 parts, butyronitrile 13.4614
Part, white carbon 13.4614 parts, activated Calcium carbonate 26.9277 parts, Petropols 2.2436 parts, DEOTACK
RS tackifier 1.1218 parts, dioctyl adipate 4.4871 parts, 1.1218 parts of age resistor, snow defence wax 0.0561
Part, microwax 0.0561 part, stearic acid 0.3590 part, Polyethylene Glycol 1.3461 parts, zinc oxide 2.2436
Part, rubber vulcanization accelerant MBT S 0.5833 part, rubber vulcanization accelerant MBT 0.2244 part, TS-80
Accelerator 0.0494 part, 0.8526 part of insoluble sulfur powder.
A kind of ferrum head footwear sizing material the most according to claim 1 and 2, it is characterised in that: described mark glue is
The mark glue that trophy factory of rubber head office of rubber industry group of Vietnam produces, described butadiene rubber is middle petrochemical industry share
The butadiene rubber that Maoming Petrochemical branch company of company limited produces, described butyronitrile is Shandong Ju Ding Chemical Co., Ltd.
The butyronitrile produced, described white carbon is the white carbon that Sanming City, Fujian Province positive element Chemical Co., Ltd. produces, described
Activated Calcium carbonate is the activated Calcium carbonate that Heng great chemical plant, Yangshan produces, and described Petropols are Jiangsu Jingjiang City
The Petropols that Nan Yang chemical industry goods and materials company limited produces, described DEOTACK RS tackifier is Jiangsu Jingjiang
The DEOTACK RS tackifier that Nan Yang, city chemical industry goods and materials company limited produces, described dioctyl adipate is mountain
The dioctyl adipate that Dong Lan sail Chemical Co., Ltd. produces, described age resistor is that Shanghai rubber chemicals factory is limited
The age resistor that company produces, described microwax is the microwax that Lian Zheng rubber and plastic Science and Technology Ltd. of Foshan City produces,
Described stearic acid is the stearic acid that polite oils and fats company of Indonesia produces, and described Polyethylene Glycol is Jilin chemical industry
The Polyethylene Glycol that limited company produces, described zinc oxide is that Liuzhou Zhong Sexin product Co., Ltd produces
Zinc oxide, described rubber vulcanization accelerant MBT S be Shenyang new oceangoing voyage Chemical Co., Ltd. produce rubber
Accelerator M BTS, described rubber vulcanization accelerant MBT is that Shenyang new oceangoing voyage Chemical Co., Ltd. produces
Rubber vulcanization accelerant MBT, described TS-80 accelerator is that Lian Zheng rubber and plastic Science and Technology Ltd. of Foshan City is raw
The TS-80 accelerator produced, described insoluble sulfur powder is that Lian Zheng rubber and plastic Science and Technology Ltd. of Foshan City produces
Insoluble sulfur powder.
4. ferrum head footwear, it is characterised in that: these ferrum head footwear are prepared by the sizing material weighed according to any one of 1-3
Form.
5. the preparation method of ferrum head footwear as claimed in claim 4, it is characterised in that: by claim
It is injected in mould after ferrum head footwear sizing material hot melt described in any one of 1-3, is fabricated to footwear body sheet, toe-cap respectively
Press strip large stretch of, rear, backsight, rear enclosure, sole reinforcement members, carried out the most in accordance with the following steps:
A. take ankle socks and the shoe last matched with ankle socks, shoe last is inserted in ankle socks, then in shoe last end
Ankle socks is fixed；The clamp identical with footwear height degree is utilized to finish at least two and footwear height degree phase on ankle socks
Height point before and after Tong, then finishes the connecting line between height point according to height point；
B. take ferrum head U-shaped reinforcement members, and brush adhesive in ferrum head U-shaped reinforcement members, then will
Ferrum head U-shaped reinforcement members is placed in 2 points 30 seconds in the baking oven of 60-65 DEG C, then by ferrum head U-shaped reinforcement members
It is attached at the forefoot at the bottom of ankle socks；
C. take steel toes and steel toes reinforcement members, then steel toes reinforcement members is cleaned, then by ladle
Head and steel toes reinforcement members utilize adhesive to fit together；Then by the steel toes fit together and steel
Packet header reinforcement members utilizes adhesive to be attached at the toe in ankle socks face；
D. take ferrum head D-shaped reinforcement members, then utilize adhesive that ferrum head D-shaped reinforcement members is attached to ladle
The lower section of head；
E. one layer of adhesive of uniform coating on ankle socks, is subsequently placed in 2 points 30 seconds in the baking oven of 60-65 DEG C,
Take the end and sole reinforcement members in steel, then utilize adhesive that the end in steel and sole reinforcement members are fitted in one
Rise, then one layer of adhesive of even spread in sole reinforcement members, the end in steel and sole reinforcement members are pasted
In ankle socks bottom surface, then with the pressure pressing 3-4 second of 15-20kg；
F. in steel, it is coated with one layer of adhesive at the end uniformly, sticks iron core；
G. second layer sole reinforcement members is taken, one layer of adhesive of even spread in second layer sole reinforcement members,
Second layer sole reinforcement members is attached on iron core, then carries out wheel load process；
H. take front press strip, then front press strip is carried out, then front press strip adhesive is attached to footwear body big
Sheet is corresponding to, on the position of instep, then carrying out wheel load process；
I. instep reinforcement members and foxing reiforcer component are taken, then to instep reinforcement members and foxing reiforcer component
It is carried out, then utilizes adhesive to be attached to respectively on ankle socks instep reinforcement members and foxing reiforcer component
At instep and at rear heel, then carry out wheel load process；
J. in each reinforcement members being attached on ankle socks and exposed ankle socks surface is coated with one layer of adhesive uniformly,
It is subsequently placed in 2 points 30 seconds in the baking oven of 60-65 DEG C, then the footwear body sheet through over cleaning is utilized adhesive
It is attached to footwear body position；Toe-cap sheet through over cleaning then utilize adhesive be attached to footwear body sheet corresponding to footwear
On the position of head, then carry out wheel load process；
K. take backsight, then backsight is soaked 1-2 minute in formaldehyde, be then placed in backsight tenderizing machine drying
Soft, then the back spread adhesive through over cleaning is fit together with backsight, be subsequently placed in 60-65 DEG C
2 points 30 seconds in baking oven, the rear enclosure then fit together and backsight are fitted at the rear heel of footwear body, then
Carry out wheel load process；
L. take the big end and third layer sole reinforcement members, then the big end and third layer sole reinforcement members are carried out
Cleaning treatment, fits together the big end and third layer sole reinforcement members followed by adhesive, then exists
Third layer sole reinforcement members surface is coated with three adhesives uniformly, will fit together between coating every time
The big end and reinforcement members of the big end be placed in 2 points 30 seconds in the baking oven of 60-65 DEG C, then utilize adhesive by
Three layers of sole reinforcement members fit together with second layer sole reinforcement members, carry out the most successively upper and lower press,
Wheel load processes；
The most then, footwear carrying out sulfur adding treatment, the temperature of described sulfur adding treatment is 110 DEG C, described in add at sulfur
The time of reason is 80 minutes, then carries out delasting, cutting, bound edge process, it is thus achieved that ferrum head footwear.
The preparation method of ferrum head footwear the most according to claim 5, it is characterised in that: described l, m walk
Also include between Zhou that step n. takes two pieces trade mark patch, then utilize adhesive respectively by two pieces trade mark patch with after
Set, footwear body sheet fit together, and then utilize cross press to carry out pressing process.
The preparation method of ferrum head footwear the most according to claim 5, it is characterised in that: described m step it
After also include step p: the ferrum head footwear of acquisition utilize gasoline be cleaned processing, are then placed in shoe pad.
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| CN105924707A (en) * | 2016-05-11 | 2016-09-07 | 刘中华 | Industrial shoe mucilage and industrial shoes prepared from same |
| CN105901838B (en) * | 2016-05-11 | 2019-04-02 | 刘中华 | A kind of fishing shoes and its manufacture craft |
| CN115281417B (en) * | 2022-08-25 | 2024-08-09 | 重庆强步鞋业有限公司 | Labor protection shoe sole and forming method thereof |
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