CN107641225A - Sole material made of acid-leaching modified white ash - Google Patents
Sole material made of acid-leaching modified white ash Download PDFInfo
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- CN107641225A CN107641225A CN201710712764.7A CN201710712764A CN107641225A CN 107641225 A CN107641225 A CN 107641225A CN 201710712764 A CN201710712764 A CN 201710712764A CN 107641225 A CN107641225 A CN 107641225A
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- parts
- modified
- sole
- cigarette ash
- acidleach
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- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a sole material made of acid-leaching modified white ash, belongs to the technical field of sole manufacturing, and aims to solve the problems that resources are wasted due to the fact that white ash resources are difficult to recycle, and main components of the existing sole material harm health of operators and pollute the environment in the production process. The sole material comprises the following raw materials: natural rubber, chloroprene rubber, acid-leaching modified white ash tailings, a plasticizer and olive oil. The invention adopts the acidized modified white ash composite lead salt and the acidized modified white ash composite basic lead phosphite as the stabilizer, the additive and the filler, thereby realizing the comprehensive utilization of the white ash resources; the sole material disclosed by the invention is simple in raw material components, has the characteristics of insulation, puncture prevention, static electricity prevention, cold protection, heat insulation, good waterproofness and elasticity and the like, and is suitable for industrial production.
Description
Technical field
The invention belongs to sole fabrication technology field, and in particular to a kind of sole material that white cigarette ash making is modified with acidleach
Material.
Background technology
In process of production, human foot may be by mechanical wounding, high temperature injury, injury from low temperature, electricity injury, vibration
Injury, chemicals injury etc..From suitable safety shoe, it is ensured that foot is safe and can increase the comfortableness of human body.Peace
Full protection sole typically by with preferable energy absorption, human body walking can be buffered when brain vibrations and wear-resisting rubber,
The material such as rubber and plastic or thermoplastic is made.Material for sole of shoe is mostly to use wide and cheap synthesis rubber on the market at present
Glue, and some existing rubber soles are not that water proofing property is bad, are exactly elastic bad, easy to wear.Chinese patent CN102875856A
A kind of Elastic waterproof sole material is disclosed, overcomes the problems such as water proofing property is bad existing for prior art, but invent and use three
Basic lead sulphate is as stabilizer.And the production of lead sulfate tribasic needs to make raw material, production cost mistake with lead oxide, lead button etc.
It is high.And during production and application, unavoidable dust from flying sucks human body, easily causes lead poisoning, health is damaged,
Also pollute the environment simultaneously.
White cigarette ash is in the fusion process of copper smelting by pyrometallurgy, ash-laden gas caused by sulfonium and blowing two benches is being made, through excess enthalpy
After heat boiler, roto-clone, induced-draft fan and cottrell, what is obtained contains the white of a variety of valuable metals such as a large amount of copper, zinc, lead
Color cigarette ash.The cigarette ash is rich in there is a variety of valuable metals such as copper, lead, zinc, arsenic, bismuth, antimony, indium, for this rich in valuable metal
Flue dust, current most of method of comprehensive utilization leach the soluble metals such as copper and the zinc in white cigarette ash with water logging and dilute sulfuric acid, then
Leachate and leached mud are handled respectively using different methods.But due to being influenceed by raw material, process, process conditions, copper
Cigarette ash complicated component caused by melting, thing phase composition fluctuation is big, it is difficult to have unified processing method, particularly leaching valuable metal
Tailings in still contain soluble metal and poisonous and hazardous heavy non-ferrous metal element, directly discharge can cause environmental pollution, only
Environmental protection can be had a great influence as danger wastes stockpiling disposal.
The content of the invention
It is an object of the invention to provide a kind of material for sole of shoe that white cigarette ash making is modified with acidleach, to solve white cigarette lime-ash money
Source is difficult to recycling and causes the wasting of resources, and the main component of existing material for sole of shoe endangers operating personnel and is good in process of production
The problem of health, pollution environment.
In order to achieve the above object, the technical solution adopted by the present invention is：
A kind of material for sole of shoe that white cigarette ash making is modified with acidleach, is made up of the raw material of following weight：Natural rubber
120-130 parts, neoprene 88-98 parts, acidleach are modified white cigarette ash tailings 42-64 parts, plasticizer 3-6 parts and olive oil 17-18
Part.
In order to further realize the present invention, the material for sole of shoe of white cigarette ash making is modified by following weight with acidleach
Raw material is made：125 parts of natural rubber, 92 parts of neoprene, acidleach are modified 18 parts of 54 parts of white cigarette ash, 5 parts of plasticizer and olive oil.
In order to further realize the present invention, plasticizer DOP.
In order to further realize the present invention, acidleach is modified white cigarette ash tailings as stabilizer, is to be by Copper making white cigarette ash
The acidified and modified co-precipitation compound stabilizer being process of raw material, its active ingredient be tribasic lead sulfate, lead silicate, its
His basic metal sulfate, amorphous silicic acid and silicate.
Having the beneficial effect that compared to prior art of the invention：
The present invention is using acidified modified white cigarette ash complex lead salt and the compound alkali lead phosphite of acidified modified white cigarette ash as stable
Agent, auxiliary agent and filler, realize the comprehensive utilization of white cigarette cinder resource.
The grey material for sole of shoe made as composite thermal stabilizer of white cigarette is modified by the use of acidleach in the present invention, raw material components are simple,
Have the characteristics that insulation, anti-puncture, antistatic, cold-proof, heat-insulated, water proofing property and elasticity are good, suitable for industrialized production.
Embodiment
With reference to embodiment, the present invention will be further described.
Embodiment 1：
120 parts of natural rubber, 88 parts of neoprene, acidleach are modified 17 parts of 42 parts of white cigarette ash, 3 parts of plasticizer DOP and olive oil.Will
Above-mentioned composition passes through conventional mixing, banburying, begun to pratise, and then the mixture after beginning to pratise is granulated through comminutor, obtains particle, will
Particle is put into tank cooling, is then dried at room temperature for, that is, obtains material for sole of shoe.
Embodiment 2：
125 parts of natural rubber, 92 parts of neoprene, acidleach are modified 18 parts of 54 parts of white cigarette ash, 5 parts of plasticizer DOP and olive oil.Will
Above-mentioned composition passes through conventional mixing, banburying, begun to pratise, and then the mixture after beginning to pratise is granulated through comminutor, obtains particle, will
Particle is put into tank cooling, is then dried at room temperature for, that is, obtains material for sole of shoe.
Embodiment 3：
130 parts of natural rubber, 98 parts of neoprene, acidleach are modified 18 parts of 64 parts of white cigarette ash, 6 parts of plasticizer DOP and olive oil.Will
Above-mentioned composition passes through conventional mixing, banburying, begun to pratise, and then the mixture after beginning to pratise is granulated through comminutor, obtains particle, will
Particle is put into tank cooling, is then dried at room temperature for, that is, obtains material for sole of shoe.
Reference examples
According to invention CN102875856A embodiment, material for sole of shoe, natural rubber are made using the raw material of following weight
130 parts of glue, 98 parts of neoprene, 30 parts of white carbon, 16 parts of calcium zinc salt, 8 parts of tribasic lead sulfate, 6 parts of plasticizer DOP, olive
18 parts of oil.Above-mentioned composition is passed through into conventional mixing, banburying, begun to pratise, then the mixture after beginning to pratise is granulated through comminutor, obtained
To particle, particle is put into tank cooling, is then dried at room temperature for, that is, obtains material for sole of shoe.
Product test
The material for sole of shoe manufactured to embodiment 1-3 and reference examples is as a result as shown in table 1 below according to national standard performance detection.
The assay of table 1
Conclusion：Shown by the result of table 1, acidleach, which is modified white cigarette ash, to be used as composite thermal stabilizer to substitute three base lead sulfate and its
His filler is used for the manufacture of security protection material for sole of shoe, and the material for sole of shoe properties for manufacturing to obtain meet that national standard performance is examined
Survey and require.
Claims (4)
- A kind of 1. material for sole of shoe that white cigarette ash making is modified with acidleach, it is characterised in that：By the raw material system of following weight Into：Natural rubber 120-130 parts, neoprene 88-98 parts, acidleach be modified white cigarette ash tailings 42-64 parts, plasticizer 3-6 parts and Olive oil 17-18 parts.
- 2. the material for sole of shoe of white cigarette ash making is modified with acidleach as claimed in claim 1, it is characterised in that：By following parts by weight The raw material of proportioning is made：125 parts of natural rubber, 92 parts of neoprene, acidleach are modified 54 parts of white cigarette ash, 5 parts of plasticizer and olive 18 parts of oil.
- 3. the material for sole of shoe of white cigarette ash making is modified with acidleach as claimed in claim 1 or 2, it is characterised in that：The increasing Modeling agent is DOP.
- 4. the material for sole of shoe of white cigarette ash making is modified with acidleach as claimed in claim 3, it is characterised in that：The acidleach changes Property white cigarette ash tailings as stabilizer, be compound for the acidified and modified co-precipitation that is process of raw material by Copper making white cigarette ash Stabilizer, its active ingredient are tribasic lead sulfate, lead silicate, other basic metal sulfate, amorphous silicic acid and silicate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710712764.7A CN107641225A (en) | 2017-08-18 | 2017-08-18 | Sole material made of acid-leaching modified white ash |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710712764.7A CN107641225A (en) | 2017-08-18 | 2017-08-18 | Sole material made of acid-leaching modified white ash |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107641225A true CN107641225A (en) | 2018-01-30 |
Family
ID=61110803
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710712764.7A Pending CN107641225A (en) | 2017-08-18 | 2017-08-18 | Sole material made of acid-leaching modified white ash |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107641225A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101519729A (en) * | 2009-03-19 | 2009-09-02 | 金川集团有限公司 | Method for preparing tribasic lead sulfate by using ash of copper converter |
| CN102875856A (en) * | 2012-09-24 | 2013-01-16 | 吴江市信许塑料鞋用配套有限公司 | Elastic waterproof sole material |
| CN106046466A (en) * | 2016-07-20 | 2016-10-26 | 南京东亚橡塑制品有限公司 | Acid-alkali-resistant anti-aging sole material |
-
2017
- 2017-08-18 CN CN201710712764.7A patent/CN107641225A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101519729A (en) * | 2009-03-19 | 2009-09-02 | 金川集团有限公司 | Method for preparing tribasic lead sulfate by using ash of copper converter |
| CN102875856A (en) * | 2012-09-24 | 2013-01-16 | 吴江市信许塑料鞋用配套有限公司 | Elastic waterproof sole material |
| CN106046466A (en) * | 2016-07-20 | 2016-10-26 | 南京东亚橡塑制品有限公司 | Acid-alkali-resistant anti-aging sole material |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180130 |