CN106750638A - A kind of anti-skidding rain boots material for sole of shoe - Google Patents
A kind of anti-skidding rain boots material for sole of shoe Download PDFInfo
- Publication number
- CN106750638A CN106750638A CN201710068462.0A CN201710068462A CN106750638A CN 106750638 A CN106750638 A CN 106750638A CN 201710068462 A CN201710068462 A CN 201710068462A CN 106750638 A CN106750638 A CN 106750638A
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- sole
- shoe
- rain boots
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
A kind of anti-skidding rain boots material for sole of shoe that the present invention is provided, including mass ratio (1.0 2.5):1 component A and component B；Wherein, the component A by following weight than component be made：77 94 parts of butadiene-vinylpyridine rubber, 4 12 parts of TM monex TM, 13 parts of 2 benzothiazole sulfenamide of N cyclohexyl, 16 19 parts of 1 naphthylamines of N phenyl, 11 14 parts of EPC easy processing channel black, 15 20 parts of vaseline；The component B is made up of the component of following weight portion：10 18 parts of nano zine oxide, 17 30 parts of antimony oxide, 11 18 parts of zinc carbonate, 6 15 parts of stearic acid, 9 17 parts of salicylic acid, 9 12 parts of magnesia, 30~40 parts of potter's clay, 5~10 parts of dibutyl ester, 10~17 parts of dioctyl ester, 12 19 parts of high-phenylethylene, 3~5 parts of activating agent.The rain boots material for sole of shoe preparation process is simple, with low cost, good permeability, light weight, performance are good.
Description
Technical field
The invention belongs to daily necessities field, more particularly to a kind of anti-skidding rain boots material for sole of shoe and preparation method thereof.
Background technology
The species of material for sole of shoe is a lot, is generally divided into two kinds of natural class material for sole of shoe and synthesis class material for sole of shoe.Natural class
Material for sole of shoe includes natural bottom leather, bamboo and wood material etc., and synthesis class material for sole of shoe is including rubber, PU materials, PVC synthetic resin etc..
Rain boots material for sole of shoe is mostly synthetic rubber on the market at present, using wide and cheap.In order to adapt to different works
Make environment, so performance can be further improved in synthetic rubber, and existing draining the oil property of rubber rain shoes sole is poor, while on-slip is imitated
It is really poor, easily fallen down on the ground for having water or oil.
The content of the invention
Technical problem：In order to solve the defect of prior art, the invention provides a kind of anti-skidding rain boots material for sole of shoe.
Technical scheme：A kind of anti-skidding rain boots material for sole of shoe that the present invention is provided, including mass ratio (1.0-2.5):1 component
A and component B；Wherein, the component A by following weight than component be made：Butadiene-vinylpyridine rubber 77-94 parts, TM monex TM 4-12
Part, N cyclohexyl 2 benzothiazole sulfenamide 1-3 parts, 16-19 parts of N- phenyl-1-naphthylamines, EPC easy processing channel black 11-14 parts, all scholars
Woods 15-20 parts；The component B is made up of the component of following weight portion：Nano zine oxide 10-18 parts, antimony oxide 17-30
Part, zinc carbonate 11-18 parts, stearic acid 6-15 parts salicylic acid 9-17 parts, magnesia 9-12 parts, 30~40 parts of potter's clay, dibutyl ester 5~
10 parts, 10~17 parts of dioctyl ester, high-phenylethylene 12-19 parts, 3~5 parts of activating agent.
As improvement, including mass ratio 1.2:1 component A and component B；Wherein, the component A by following weight than group
Part is made：83 parts of butadiene-vinylpyridine rubber, 8 parts of TM monex TM, 2 parts of N cyclohexyl 2 benzothiazole sulfenamide, N- phenyl -1- naphthalenes
17 parts of amine, 13 parts of EPC easy processing channel black, 17 parts of vaseline；The component B is made up of the component of following weight portion：Nano zine oxide 16
Part, 21 parts of antimony oxide, 15 parts of zinc carbonate, 8 parts of stearic acid, 12 parts of salicylic acid, 11 parts of magnesia, 34 parts of potter's clay, dibutyl ester 7
Part, 14 parts of dioctyl ester, 16 parts of high-phenylethylene, 4 parts of activating agent.
Present invention also offers a kind of preparation method of anti-skidding rain boots material for sole of shoe, comprise the following steps：
(1) each component of component A weighed in proportion, mixed；The each component of component B is weighed in proportion, is mixed；
(2) by each component addition autoclave in 2/3 component A, at 50-80 DEG C, 0.5-1h is reacted；Add 1/3
Component A in each component add autoclave in, at 50-80 DEG C, continue react 3-4h；Room temperature is cooled to, performed polymer is obtained；
(3) the component B of performed polymer and 1/3 is well mixed；Add in rain boots sole casting machine batch can, be warming up to 60-70
DEG C, constant temperature 5-10min；The component B for continuously adding 1/3 is well mixed, and is warming up to 75-80 DEG C, constant temperature 10-15min；It is cooled to
55-60 DEG C, continuously add remaining 1/3 component B, constant temperature 15-20min；
(4) coating release agent, drying, cast on rain boots die for shoe-sole by step (3) product, insulation 10-12min, the demoulding,
Obtain final product.
Beneficial effect：Rain boots material for sole of shoe preparation process is simple, with low cost, good permeability, quality that the present invention is provided
Gently, performance is good.
Specific embodiment
Anti-skidding rain boots material for sole of shoe of the invention is further illustrated below.
Anti-skidding rain boots material for sole of shoe, including mass ratio 1.2:1 component A and component B；Wherein, the component A is by following heavy
The component for measuring ratio is made：83 parts of butadiene-vinylpyridine rubber, 8 parts of TM monex TM, 2 parts of N cyclohexyl 2 benzothiazole sulfenamide, N-
17 parts of phenyl-1-naphthylamine, 13 parts of EPC easy processing channel black, 17 parts of vaseline；The component B is made up of the component of following weight portion：Nanometer
16 parts of zinc oxide, 21 parts of antimony oxide, 15 parts of zinc carbonate, 8 parts of stearic acid, 12 parts of salicylic acid, 11 parts of magnesia, potter's clay 34
Part, 7 parts of dibutyl ester, 14 parts of dioctyl ester, 16 parts of high-phenylethylene, 4 parts of activating agent.
Present invention also offers a kind of preparation method of anti-skidding rain boots material for sole of shoe, comprise the following steps：
(1) each component of component A weighed in proportion, mixed；The each component of component B is weighed in proportion, is mixed；
(2) by each component addition autoclave in 2/3 component A, at 50-80 DEG C, 0.5-1h is reacted；Add 1/3
Component A in each component add autoclave in, at 50-80 DEG C, continue react 3-4h；Room temperature is cooled to, performed polymer is obtained；
(3) the component B of performed polymer and 1/3 is well mixed；Add in rain boots sole casting machine batch can, be warming up to 60-70
DEG C, constant temperature 5-10min；The component B for continuously adding 1/3 is well mixed, and is warming up to 75-80 DEG C, constant temperature 10-15min；It is cooled to
55-60 DEG C, continuously add remaining 1/3 component B, constant temperature 15-20min；
(4) coating release agent, drying, cast on rain boots die for shoe-sole by step (3) product, insulation 10-12min, the demoulding,
Obtain final product.
Claims (2)
1. a kind of anti-skidding rain boots material for sole of shoe, it is characterised in that：Including mass ratio (1.0-2.5):1 component A and component B；Its
In, the component A by following weight than component be made：Butadiene-vinylpyridine rubber 77-94 parts, 4-12 parts of TM monex TM, N- hexamethylenes
Base -1-3 parts of 2-[4-morpholinodithio sulfenamide, 16-19 parts of N- phenyl-1-naphthylamines, EPC easy processing channel black 11-14 parts, vaseline 15-20
Part；The component B is made up of the component of following weight portion：Nano zine oxide 10-18 parts, antimony oxide 17-30 parts, zinc carbonate
11-18 parts, stearic acid 6-15 parts salicylic acid 9-17 parts, magnesia 9-12 parts, it is 30~40 parts of potter's clay, 5~10 parts of dibutyl ester, two pungent
10~17 parts of ester, high-phenylethylene 12-19 parts, 3~5 parts of activating agent.
2. a kind of anti-skidding rain boots material for sole of shoe according to claim 1, it is characterised in that：Including mass ratio 1.2:1 group
Part A and component B；Wherein, the component A by following weight than component be made：83 parts of butadiene-vinylpyridine rubber, 8 parts of TM monex TM,
2 parts of N cyclohexyl 2 benzothiazole sulfenamide, 17 parts of N- phenyl-1-naphthylamines, 13 parts of EPC easy processing channel black, 17 parts of vaseline；It is described
Component B is made up of the component of following weight portion：16 parts of nano zine oxide, 21 parts of antimony oxide, 15 parts of zinc carbonate, stearic acid 8
Part, 12 parts of salicylic acid, 11 parts of magnesia, 34 parts of potter's clay, 7 parts of dibutyl ester, 14 parts of dioctyl ester, 16 parts of high-phenylethylene, activating agent 4
Part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710068462.0A CN106750638A (en) | 2017-02-08 | 2017-02-08 | A kind of anti-skidding rain boots material for sole of shoe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710068462.0A CN106750638A (en) | 2017-02-08 | 2017-02-08 | A kind of anti-skidding rain boots material for sole of shoe |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106750638A true CN106750638A (en) | 2017-05-31 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710068462.0A Pending CN106750638A (en) | 2017-02-08 | 2017-02-08 | A kind of anti-skidding rain boots material for sole of shoe |
Country Status (1)
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| CN (1) | CN106750638A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108641137A (en) * | 2018-05-25 | 2018-10-12 | 安徽新创智能科技有限公司 | A kind of shared bicycle high abrasion tire material and preparation method |
| CN108749207A (en) * | 2018-03-28 | 2018-11-06 | 天长市蓝天复合材料有限公司 | A kind of double glazing steel grating and preparation method |
-
2017
- 2017-02-08 CN CN201710068462.0A patent/CN106750638A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108749207A (en) * | 2018-03-28 | 2018-11-06 | 天长市蓝天复合材料有限公司 | A kind of double glazing steel grating and preparation method |
| CN108641137A (en) * | 2018-05-25 | 2018-10-12 | 安徽新创智能科技有限公司 | A kind of shared bicycle high abrasion tire material and preparation method |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170531 |
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| WD01 | Invention patent application deemed withdrawn after publication |