CN106751299A - A kind of preparation method of anti-puncture climbing boot material for sole of shoe - Google Patents
A kind of preparation method of anti-puncture climbing boot material for sole of shoe Download PDFInfo
- Publication number
- CN106751299A CN106751299A CN201710068463.5A CN201710068463A CN106751299A CN 106751299 A CN106751299 A CN 106751299A CN 201710068463 A CN201710068463 A CN 201710068463A CN 106751299 A CN106751299 A CN 106751299A
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- CN
- China
- Prior art keywords
- parts
- component
- sole
- shoe
- climbing boot
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The preparation method of a kind of anti-puncture climbing boot material for sole of shoe that the present invention is provided, comprises the following steps：The each component of component A is weighed in proportion, is mixed；The each component of component B is weighed in proportion, is mixed；By in each component addition autoclave in 2/3 component A, reacted at 50 80 DEG C；Add during each component in 1/3 component A adds autoclave, continue to react at 50 80 DEG C；Room temperature is cooled to, performed polymer is obtained；The component B of performed polymer and 1/3 is well mixed；Add in tennis sole casting machine batch can, heat up, constant temperature；The component B for continuously adding 1/3 is well mixed, and heats up, constant temperature；Cooling, continuously adds remaining 1/3 component B, constant temperature；Coating release agent, drying, cast on tennis die for shoe-sole by step (3) product, insulation, the demoulding are obtained final product.The material for sole of shoe preparation process is simple, with low cost, good permeability, light weight, performance are good.
Description
Technical field
The invention belongs to daily necessities field, more particularly to a kind of anti-puncture climbing boot material for sole of shoe and preparation method thereof.
Background technology
The species of material for sole of shoe is a lot, is generally divided into two kinds of natural class material for sole of shoe and synthesis class material for sole of shoe.Natural class
Material for sole of shoe includes natural bottom leather, bamboo and wood material etc., and synthesis class material for sole of shoe is including rubber, PU materials, PVC synthetic resin etc..
Outdoor exercises are a motions for health, and suitable outdoor sports shoe not only needs wear-resisting, and also needs to anti-wearing
Thorn.
Some sharp articles are often had on ground when moving out of doors, if imprudence is stepped on above, can be pierced
Sole, or even bacterium infection can be caused.At present, anti-puncture footwear on the market are mostly one layer of steel plates of increase in climbing boot sole
Or other hard plates, although it is difficult to be pierced, but such footwear increased weight, and people wear can be very tired, is not suitable for family
Outer motion.
The content of the invention
Technical problem：In order to solve the defect of prior art, the invention provides a kind of anti-puncture climbing boot material for sole of shoe.
Technical scheme：A kind of anti-puncture climbing boot material for sole of shoe that the present invention is provided, including mass ratio (2-4):1 component
A and component B；Wherein, the component A by following weight than component be made：ACM 77-94 parts, Vulcanization accelerator TMTD
5-16 parts, thiurampolysulfides 1-3 parts, 14-18 parts, fast extruding furnace black 16-19 parts, paraffin 15-20 parts of N- phenyl-2-naphthylamines；
The component B is made up of the component of following weight portion：Nano zine oxide 10-18 parts, antimony oxide 17-30 parts, zinc carbonate 11-
18 parts, stearic acid 6-15 parts salicylic acid 9-17 parts, magnesia 9-12 parts, 30~40 parts of potter's clay, 5~10 parts of dibutyl ester, dioctyl ester
10~17 parts, high-phenylethylene 12-19 parts, 3~5 parts of activating agent.
Preferably, including mass ratio 3:1 component A and component B；Wherein, the component A by following weight than component
It is made：81 parts of ACM, 11 parts of Vulcanization accelerator TMTD, 2 parts of thiurampolysulfides, 17 parts of N- phenyl-2-naphthylamines, fast pressure
Go out 18 parts of furnace black, 16 parts of paraffin；The component B is made up of the component of following weight portion：16 parts of nano zine oxide, antimony oxide
21 parts, 15 parts of zinc carbonate, 8 parts of stearic acid, 12 parts of salicylic acid, 11 parts of magnesia, 34 parts of potter's clay, 7 parts of dibutyl ester, dioctyl ester 14
Part, 16 parts of high-phenylethylene, 4 parts of activating agent.
Present invention also offers a kind of preparation method of anti-puncture climbing boot material for sole of shoe, comprise the following steps：
(1) each component of component A weighed in proportion, mixed；The each component of component B is weighed in proportion, is mixed；
(2) by each component addition autoclave in 2/3 component A, at 50-80 DEG C, 0.5-1h is reacted；Add 1/3
Component A in each component add autoclave in, at 50-80 DEG C, continue react 3-4h；Room temperature is cooled to, performed polymer is obtained；
(3) the component B of performed polymer and 1/3 is well mixed；Add in climbing boot sole casting machine batch can, be warming up to 60-
70 DEG C, constant temperature 5-10min；The component B for continuously adding 1/3 is well mixed, and is warming up to 75-80 DEG C, constant temperature 10-15min；It is cooled to
55-60 DEG C, continuously add remaining 1/3 component B, constant temperature 15-20min；
(4) coating release agent, drying, cast on climbing boot die for shoe-sole by step (3) product, is incubated 10-12min, takes off
Mould, obtains final product.
Beneficial effect：Climbing boot material for sole of shoe preparation process is simple, with low cost, good permeability, matter that the present invention is provided
Amount is light, performance is good.
Specific embodiment
Anti-puncture climbing boot material for sole of shoe of the invention is further illustrated below.
Anti-puncture climbing boot material for sole of shoe, including mass ratio 3:1 component A and component B；Wherein, the component A is by following
Weight than component be made：81 parts of ACM, 11 parts of Vulcanization accelerator TMTD, 2 parts of thiurampolysulfides, N- phenyl -2- naphthalenes
17 parts of amine, 18 parts of fast extruding furnace black, 16 parts of paraffin；The component B is made up of the component of following weight portion：Nano zine oxide 16
Part, 21 parts of antimony oxide, 15 parts of zinc carbonate, 8 parts of stearic acid, 12 parts of salicylic acid, 11 parts of magnesia, 34 parts of potter's clay, dibutyl ester 7
Part, 14 parts of dioctyl ester, 16 parts of high-phenylethylene, 4 parts of activating agent.
Its preparation method, comprises the following steps：
(1) each component of component A weighed in proportion, mixed；The each component of component B is weighed in proportion, is mixed；
(2) by each component addition autoclave in 2/3 component A, at 50-80 DEG C, 0.5-1h is reacted；Add 1/3
Component A in each component add autoclave in, at 50-80 DEG C, continue react 3-4h；Room temperature is cooled to, performed polymer is obtained；
(3) the component B of performed polymer and 1/3 is well mixed；Add in climbing boot sole casting machine batch can, be warming up to 60-
70 DEG C, constant temperature 5-10min；The component B for continuously adding 1/3 is well mixed, and is warming up to 75-80 DEG C, constant temperature 10-15min；It is cooled to
55-60 DEG C, continuously add remaining 1/3 component B, constant temperature 15-20min；
(4) coating release agent, drying, cast on climbing boot die for shoe-sole by step (3) product, is incubated 10-12min, takes off
Mould, obtains final product.
Claims (2)
1. a kind of preparation method of anti-puncture climbing boot material for sole of shoe, it is characterised in that：Comprise the following steps：
(1) each component of component A weighed in proportion, mixed；The each component of component B is weighed in proportion, is mixed；
(2) by each component addition autoclave in 2/3 component A, at 50-80 DEG C, 0.5-1h is reacted；Add 1/3 group
Divide in A in each component addition autoclave, at 50-80 DEG C, continue to react 3-4h；Room temperature is cooled to, performed polymer is obtained；
(3) the component B of performed polymer and 1/3 is well mixed；Add in climbing boot sole casting machine batch can, be warming up to 60-70 DEG C,
Constant temperature 5-10min；The component B for continuously adding 1/3 is well mixed, and is warming up to 75-80 DEG C, constant temperature 10-15min；It is cooled to 55-60
DEG C, continuously add remaining 1/3 component B, constant temperature 15-20min；
(4) coating release agent, drying, cast on climbing boot die for shoe-sole by step (3) product, insulation 10-12min, the demoulding, i.e.,
；
Wherein, the mass ratio of component A and component B is (2-4):1；Wherein, the component A by following weight than component be made：
ACM 77-94 parts, Vulcanization accelerator TMTD 5-16 parts, thiurampolysulfides 1-3 parts, 14-18 parts of N- phenyl-2-naphthylamines,
Fast extruding furnace black 16-19 parts, paraffin 15-20 parts；The component B is made up of the component of following weight portion：Nano zine oxide 10-18
Part, antimony oxide 17-30 parts, zinc carbonate 11-18 parts, stearic acid 6-15 parts salicylic acid 9-17 parts, magnesia 9-12 parts, potter's clay
30~40 parts, 5~10 parts of dibutyl ester, 10~17 parts of dioctyl ester, high-phenylethylene 12-19 parts, 3~5 parts of activating agent.
2. the preparation method of a kind of anti-puncture climbing boot material for sole of shoe according to claim 1, it is characterised in that：Including matter
Amount compares 3:1 component A and component B；Wherein, the component A by following weight than component be made：81 parts of ACM,
11 parts of Vulcanization accelerator TMTD, 2 parts of thiurampolysulfides, 17 parts of N- phenyl-2-naphthylamines, 18 parts of fast extruding furnace black, 16 parts of paraffin；Institute
Component B is stated to be made up of the component of following weight portion：16 parts of nano zine oxide, 21 parts of antimony oxide, 15 parts of zinc carbonate, stearic acid
8 parts, 12 parts of salicylic acid, 11 parts of magnesia, 34 parts of potter's clay, 7 parts of dibutyl ester, 14 parts of dioctyl ester, 16 parts of high-phenylethylene, activating agent 4
Part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710068463.5A CN106751299A (en) | 2017-02-08 | 2017-02-08 | A kind of preparation method of anti-puncture climbing boot material for sole of shoe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710068463.5A CN106751299A (en) | 2017-02-08 | 2017-02-08 | A kind of preparation method of anti-puncture climbing boot material for sole of shoe |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106751299A true CN106751299A (en) | 2017-05-31 |
Family
ID=58955340
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710068463.5A Pending CN106751299A (en) | 2017-02-08 | 2017-02-08 | A kind of preparation method of anti-puncture climbing boot material for sole of shoe |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106751299A (en) |
-
2017
- 2017-02-08 CN CN201710068463.5A patent/CN106751299A/en active Pending
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170531 |