CN110628099A - Formula and preparation method of shoe sole anti-slip material - Google Patents
Formula and preparation method of shoe sole anti-slip material Download PDFInfo
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- CN110628099A CN110628099A CN201910862486.2A CN201910862486A CN110628099A CN 110628099 A CN110628099 A CN 110628099A CN 201910862486 A CN201910862486 A CN 201910862486A CN 110628099 A CN110628099 A CN 110628099A
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- Prior art keywords
- rubber
- oil
- slip
- mixing
- medicament
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/168—Zinc halides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a formula of a sole anti-slip material, which is characterized in that: the material comprises the following materials by mass: imported nitrile rubber 240: 25-35 kg, 2.8-4 kg of non-slip oil, 3-4 kg of transparent zinc chloride, 3-3 kg of active agent PEG2, 0.5-0.8 kg of rubber agent DM, 0.2-0.3 kg of rubber agent D, 9-11 kg of oil DOP, 8.5-11 kg of white smoke, 8-10 kg of brominated butyl, 10-12 kg of butyl butylbenzene, TS: 0.3-0.4 kg and an anti-aging agent OH-5: 0.3-0.5 kg. The invention also provides a preparation method of the formula of the sole anti-slip material. The sole made of the sole anti-slip material formula provided by the invention has higher anti-slip and wear-resistant properties and better dry and wet anti-slip properties.
Description
Technical Field
The invention relates to a formula of a sole anti-slip material. The invention also relates to a preparation method of the formula of the sole anti-slip material.
Background
The traditional sole mainly depends on sole patterns, but the research on the anti-slip material is relatively deficient, so that the traditional anti-slip sole has poor anti-slip performance on ice and water-stained roads.
Disclosure of Invention
The invention aims to solve the technical problem of providing a formula of a shoe sole anti-slip material with better anti-slip performance. The technical problem to be solved by the invention also comprises providing a preparation method of the formula of the anti-slip material for the shoe sole.
Therefore, the formula of the anti-slip material for the sole provided by the invention is characterized in that: the material comprises the following materials by mass: imported nitrile rubber 240: 25-35 kg, 2.8-4 kg of non-slip oil, 3-4 kg of transparent zinc chloride, 3-3 kg of active agent PEG2, 0.5-0.8 kg of rubber agent DM, 0.2-0.3 kg of rubber agent D, 9-11 kg of oil DOP, 8.5-11 kg of white smoke, 8-10 kg of brominated butyl, 10-12 kg of butyl butylbenzene, TS: 0.3-0.4 kg and an anti-aging agent OH-5: 0.3-0.5 kg.
The invention also provides a preparation method of the formula of the anti-slip material for the soles, which comprises the following steps:
step 1: putting the nitrile rubber into an internal mixer for internal mixing, and mixing at the internal mixing temperature of 120 ℃;
step 2: placing the banburied nitrile rubber into an open mill for thin-passing plastication until molecular chains of the rubber are opened, and placing the rubber at normal temperature for 24 hours to be used as main rubber;
and step 3: adding the lubricating oil, the oil DOP, the transparent zinc chloride, the butyl bromide and the solution-based butylbenzene into the main rubber, and mixing at 90-110 ℃ for 3-5 minutes;
and 4, step 4: adding an anti-aging agent OH, white smoke and an active agent PEG, mixing at 90-120 ℃, discharging after mixing for 2-5 minutes, and cooling for 24 hours to be used as mixing base rubber for later use;
and 5: adding TS, rubber medicament DM and rubber medicament D into the base rubber according to the parts, uniformly mixing on an open mill, and then discharging, cooling and blanking into semi-finished blanks with the size of a product;
step 6: and putting the semi-finished blank into a mold of a mold pressing vulcanizing machine for vulcanizing to obtain a finished product.
The invention has the technical effects that: detection shows that the Akron wear value of the slip-resistant sheet prepared by the sole slip-resistant material formula is 0.22 cm/1.61 km, detection shows that the dry type slip-resistant coefficient of the whole shoe is 1.62 and the wet type slip-resistant coefficient is 1.03 according to the shoe detection standard, and the slip-resistant performance is greatly improved.
Detailed Description
The present invention is described in further detail below, wherein the specific examples are described for the purpose of illustration only and are not to be construed as limiting the invention.
The invention discloses a formula of a sole anti-slip material, which comprises the following materials by mass: imported nitrile butadiene rubber (imported from japan or germany) 240: 25-35 kg, 2.8-4 kg of non-slip oil, 3-4 kg of transparent zinc chloride, 3-3 kg of active agent PEG2, 0.5-0.8 kg of rubber agent DM, 0.2-0.3 kg of rubber agent D, 9-11 kg of oil DOP, 8.5-11 kg of white smoke, 8-10 kg of brominated butyl, 10-12 kg of butyl butylbenzene, TS: 0.3-0.4 kg and an anti-aging agent OH-5: 0.3-0.5 kg.
Example 1: the sole anti-slip material comprises the following components in percentage by mass: imported nitrile rubber 240: 30 kg, 3.5 kg of anti-skid oil, 3.2 kg of transparent zinc chloride, 2.6 kg of active agent PEG, 0.7 kg of rubber medicament DM, 0.2 kg of rubber medicament D, 10 kg of oil DOP, 10 kg of white smoke, 9 kg of butyl bromide, 11 kg of butyl butylbenzene and TS: 0.35 kg and an anti-aging agent OH-5: 0.4 kg.
Example 2: the weight ratio is as follows: imported nitrile rubber 240: 28 kg, 3 kg of non-slip oil, 3.5 kg of transparent zinc chloride, 3 kg of active agent PEG, 0.6 kg of rubber medicament DM, 0.28 kg of rubber medicament D, 9.5 kg of oil DOP, 9 kg of white smoke, 8.5 kg of butyl bromide, 10 kg of butyl butylbenzene and TS: 0.4 kg and an anti-aging agent OH-5: 0.45 kg.
Example 3: the weight ratio is as follows: imported nitrile rubber 240: 32 kg, 3.8 kg of anti-slip oil, 3.2 kg of transparent zinc chloride, 2.6 kg of active agent PEG, 0.8 kg of rubber medicament DM, 0.22 kg of rubber medicament D, 10.8 kg of oil DOP, 10.6 kg of white smoke, 9.5 kg of butyl bromide, 11.5 kg of butyl butylbenzene, TS: 0.38 kg and an anti-aging agent OH-5: 0.45 kg.
The preparation method of the formula of the anti-slip material for the shoe soles provided by the invention comprises the following steps of:
step 1: putting the nitrile rubber into an internal mixer for internal mixing, and mixing at the internal mixing temperature of 120 ℃;
step 2: placing the banburied nitrile rubber into an open mill for thin-passing plastication until molecular chains of the rubber are opened, and placing the rubber at normal temperature for 24 hours to be used as main rubber;
and step 3: adding the lubricating oil, the oil DOP, the transparent zinc chloride, the butyl bromide and the solution-based butylbenzene into the main rubber, and mixing at 90-110 ℃ for 3-5 minutes;
and 4, step 4: adding an anti-aging agent OH, white smoke and an active agent PEG, mixing at 90-120 ℃, discharging after mixing for 2-5 minutes, and cooling for 24 hours to be used as mixing base rubber for later use;
and 5: adding TS, rubber medicament DM and rubber medicament D into the base rubber according to the parts, uniformly mixing on an open mill, and then discharging, cooling and blanking into semi-finished blanks with the size of a product;
step 6: and putting the semi-finished blank into a mold of a mold pressing vulcanizing machine for vulcanizing to obtain a finished product.
In order to further enhance the wear resistance of the anti-slip part and simultaneously avoid the wear resistance from being improved and simultaneously reduce the anti-slip performance, short carbon fibers are added in the step 3, and the adding amount of the short carbon fibers is 1-3 kg. The amount of short carbon fibers added is generally 1.2 kg.
Claims (7)
1. A formula of a shoe sole anti-slip material is characterized in that: the material comprises the following materials by mass: imported nitrile butadiene rubber (japan or germany) 240: 25-35 kg, 2.8-4 kg of non-slip oil, 3-4 kg of transparent zinc chloride, 3-3 kg of active agent PEG2, 0.5-0.8 kg of rubber agent DM, 0.2-0.3 kg of rubber agent D, 9-11 kg of oil DOP, 8.5-11 kg of white smoke, 8-10 kg of brominated butyl, 10-12 kg of butyl butylbenzene, TS: 0.3-0.4 kg and an anti-aging agent OH-5: 0.3-0.5 kg.
2. The formulation of the anti-slip material for shoe soles according to claim 1, wherein: the weight ratio is as follows: imported nitrile rubber 240: 30 kg, 3.5 kg of anti-skid oil, 3.2 kg of transparent zinc chloride, 2.6 kg of active agent PEG, 0.7 kg of rubber medicament DM, 0.2 kg of rubber medicament D, 10 kg of oil DOP, 10 kg of white smoke, 9 kg of butyl bromide, 11 kg of butyl butylbenzene and TS: 0.35 kg and an anti-aging agent OH-5: 0.4 kg.
3. The formulation of the anti-slip material for shoe soles according to claim 1, wherein: the weight ratio is as follows: imported nitrile rubber 240: 28 kg, 3 kg of non-slip oil, 3.5 kg of transparent zinc chloride, 3 kg of active agent PEG, 0.6 kg of rubber medicament DM, 0.28 kg of rubber medicament D, 9.5 kg of oil DOP, 9 kg of white smoke, 8.5 kg of butyl bromide, 10 kg of butyl butylbenzene and TS: 0.4 kg and an anti-aging agent OH-5: 0.45 kg.
4. The formulation of the anti-slip material for shoe soles according to claim 1, wherein: the weight ratio is as follows: imported nitrile rubber 240: 32 kg, 3.8 kg of anti-slip oil, 3.2 kg of transparent zinc chloride, 2.6 kg of active agent PEG, 0.8 kg of rubber medicament DM, 0.22 kg of rubber medicament D, 10.8 kg of oil DOP, 10.6 kg of white smoke, 9.5 kg of butyl bromide, 11.5 kg of butyl butylbenzene, TS: 0.38 kg and an anti-aging agent OH-5: 0.45 kg.
5. A method for preparing the formula of the anti-slip material for the shoe soles as claimed in claim 1, 2, 3 or 4 is characterized by comprising the following steps:
step 1: putting the nitrile rubber into an internal mixer for internal mixing, and mixing at the internal mixing temperature of 120 ℃;
step 2: placing the banburied nitrile rubber into an open mill for thin-passing plastication until molecular chains of the rubber are opened, and placing the rubber at normal temperature for 24 hours to be used as main rubber;
and step 3: adding the lubricating oil, the oil DOP, the transparent zinc chloride, the butyl bromide and the solution-based butylbenzene into the main rubber, and mixing at 90-110 ℃ for 3-5 minutes;
and 4, step 4: adding an anti-aging agent OH, white smoke and an active agent PEG, mixing at 90-120 ℃, discharging after mixing for 2-5 minutes, and cooling for 24 hours to be used as mixing base rubber for later use;
and 5: adding TS, rubber medicament DM and rubber medicament D into the base rubber according to the parts, uniformly mixing on an open mill, and then discharging, cooling and blanking into semi-finished blanks with the size of a product;
step 6: and putting the semi-finished blank into a mold of a mold pressing vulcanizing machine for vulcanizing to obtain a finished product.
6. The method for preparing the anti-slip material for soles according to claim 5, wherein the short carbon fibers are added in the step 3, and the addition amount of the short carbon fibers is 1-3 kg.
7. The method for preparing the anti-slip material for soles according to claim 6, wherein the amount of the short carbon fiber added is 1.2 kg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910862486.2A CN110628099A (en) | 2019-09-12 | 2019-09-12 | Formula and preparation method of shoe sole anti-slip material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910862486.2A CN110628099A (en) | 2019-09-12 | 2019-09-12 | Formula and preparation method of shoe sole anti-slip material |
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| CN110628099A true CN110628099A (en) | 2019-12-31 |
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| CN201910862486.2A Pending CN110628099A (en) | 2019-09-12 | 2019-09-12 | Formula and preparation method of shoe sole anti-slip material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4215578A4 (en) * | 2020-10-23 | 2023-10-25 | ASICS Corporation | Anti-slip member for wearable article or sports article, wearable article, and sports article |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0342245A (en) * | 1989-07-10 | 1991-02-22 | Sanshin Kosan Kk | Viscoelastic elastomer composite material and preparation thereof |
| CN101899176A (en) * | 2010-08-20 | 2010-12-01 | 温州市海滨秀龙鞋材有限公司 | Material for sole |
| CN106750655A (en) * | 2016-12-23 | 2017-05-31 | 福建省惠安县万事达鞋塑有限公司 | A kind of anti-slip rubber sole |
| CN106905625A (en) * | 2017-03-01 | 2017-06-30 | 成都鑫丰业鞋业有限公司 | A kind of Antiskid sole and preparation method thereof |
| CN108384076A (en) * | 2018-02-08 | 2018-08-10 | 浙江中瑞橡胶高分子材料股份有限公司 | A kind of big-sole formula and preparation method thereof with high oil-resisting antistatic high slip preventing function |
| CN109851873A (en) * | 2019-01-27 | 2019-06-07 | 浙江奥康鞋业股份有限公司 | A kind of formula and its production technology of grease formula on-slip material |
| CN109957157A (en) * | 2019-04-02 | 2019-07-02 | 晋江市鑫铭鞋材科技有限公司 | The formula and its technique of a kind of oil ground Anti-skidding rubber sole |
-
2019
- 2019-09-12 CN CN201910862486.2A patent/CN110628099A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0342245A (en) * | 1989-07-10 | 1991-02-22 | Sanshin Kosan Kk | Viscoelastic elastomer composite material and preparation thereof |
| CN101899176A (en) * | 2010-08-20 | 2010-12-01 | 温州市海滨秀龙鞋材有限公司 | Material for sole |
| CN106750655A (en) * | 2016-12-23 | 2017-05-31 | 福建省惠安县万事达鞋塑有限公司 | A kind of anti-slip rubber sole |
| CN106905625A (en) * | 2017-03-01 | 2017-06-30 | 成都鑫丰业鞋业有限公司 | A kind of Antiskid sole and preparation method thereof |
| CN108384076A (en) * | 2018-02-08 | 2018-08-10 | 浙江中瑞橡胶高分子材料股份有限公司 | A kind of big-sole formula and preparation method thereof with high oil-resisting antistatic high slip preventing function |
| CN109851873A (en) * | 2019-01-27 | 2019-06-07 | 浙江奥康鞋业股份有限公司 | A kind of formula and its production technology of grease formula on-slip material |
| CN109957157A (en) * | 2019-04-02 | 2019-07-02 | 晋江市鑫铭鞋材科技有限公司 | The formula and its technique of a kind of oil ground Anti-skidding rubber sole |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4215578A4 (en) * | 2020-10-23 | 2023-10-25 | ASICS Corporation | Anti-slip member for wearable article or sports article, wearable article, and sports article |
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Application publication date: 20191231 |
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