CN107312319A - A kind of polyurethane rubber anti-skid safety footwear - Google Patents
A kind of polyurethane rubber anti-skid safety footwear Download PDFInfo
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- CN107312319A CN107312319A CN201710631598.8A CN201710631598A CN107312319A CN 107312319 A CN107312319 A CN 107312319A CN 201710631598 A CN201710631598 A CN 201710631598A CN 107312319 A CN107312319 A CN 107312319A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
- A43B13/22—Soles made slip-preventing or wear-resisting, e.g. by impregnation or spreading a wear-resisting layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D107/00—Coating compositions based on natural rubber
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0006—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using woven fabrics
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/12—Permeability or impermeability properties
- D06N2209/126—Permeability to liquids, absorption
- D06N2209/128—Non-permeable
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- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
- D06N2211/106—Footwear
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- Health & Medical Sciences (AREA)
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- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of polyurethane rubber anti-skid safety footwear for belonging to clothes manufacturing technology field.The material for sole of shoe is made up of the raw material of following parts by weight：20 50 parts of polyurethane, 20 30 parts of butyl rubber, 10 15 parts of epoxy resin, 38 parts of string, 25 parts of clay, 12 parts of sulphur, 13 parts of CNT；The vamp material is made up of the canvas coating anti-frozen glue of waterproof.The polyurethane rubber anti-skid safety footwear of the present invention, using brand-new formula, the safety shoe wearing comfort of preparation, waterproof antifreeze ability is strong, and the sole surface being made is coarse, big in ice-sports frictional force, it is not easy to fall down, service life is long, is adapted to old man and children's ice-sports wearing.
Description
Technical field
The invention belongs to clothes manufacturing technology field, and in particular to a kind of polyurethane rubber anti-skid safety footwear.
Background technology
Current safety shoe is generally made of industrial chemicals, and the pliability of footwear is not high, due to being plastic products, surface
It is smooth, the phenomenon of skidding occurs in ice-sports, and non-watertight, it is not freeze proof, to the people in ice-sports, especially
Child, brings larger potential safety hazard.
Patent 201210355961.5 discloses a kind of anti-aging Water-resistant sole material, and the material for sole of shoe is by following heavy
The raw material of amount part proportioning is made：120-130 parts of natural rubber, 70-75 parts of thermoplastic styrene butadiene rubber, 23-30 parts of diethylene glycol,
17-20 parts of 20-24 parts of hexanedioic acid dibutyl ester, 6-8 parts of dipropylene glycol, 5-8 parts of potassium carbonate, 3-6 parts of sulphur and naphthenic oil.
Patent 201610571998.X discloses a kind of rain boots material for sole of shoe of water-proof skid-proof, including mass ratio (2-4):1 component A
With component B；Wherein, the component A by following weight than component be made：80-100 parts of natural rubber, butadiene rubber 30-40
Part, 10-20 parts of nitrile rubber, 80-94 parts of neoprene, hydroxylating polypropylene 66~72, polyolefin elastomer 16~22, glass
Glass fiber 15~19, bridging agent 4~6, bridge formation auxiliary agent 1~3,10-16 parts of pentane；The component B by following parts by weight component
It is made：20-33 parts of white carbon, 23-26 parts of calcium zinc salt, 9-15 parts of tribasic lead sulfate, 11-17 parts of plasticizer DOP, olive oil
25-36 parts, 3-10 parts of magnesia, 7-11 parts of stearic acid, 9-14 parts of polyethylene glycol, 11-13 parts of hexanedioic acid dibutyl ester, age resistor
3-5 parts, 1-3 parts of activating agent, 1~4 part of inserts, 2~3 parts of activating agent, 1~4 part of foaming agent.Above-mentioned safety shoe compares light
It is sliding, put on and be not suitable in ice-sports.
The content of the invention
It is an object of the invention to provide a kind of polyurethane rubber anti-skid safety footwear.
A kind of polyurethane rubber anti-skid safety footwear, including material for sole of shoe and vamp material, the material for sole of shoe by weighing as follows
The raw material of amount number is made：20-50 parts of polyurethane, 20-30 parts of butyl rubber, 10-15 parts of epoxy resin, string 3-8
Part, 2-5 parts of clay, 1-2 parts of sulphur, 1-3 parts of CNT；The vamp material is made up of the canvas coating anti-frozen glue of waterproof.
The string is selected from sisal fiber, monkey grass, castor-oil plant fiber, hemp, abaca fibre, elm bark
One or more in fiber.
The amount of the anti-frozen glue coating of waterproof is the 3-8% of canvas quality, is made up of the component of following parts by weight：My god
Right 20-35 parts of rubber, 3-7 parts of curing agent, 1-5 parts of triethanolamine, 3-5 parts of white carbon, 5-8 parts of paraformaldehyde, 2- acetylaminos
3-6 parts of methyl phenyl ethers anisole, 1,2- 1-3 parts of dihydroxy -1- diphenylphosphino ethanes.
Formaldehyde condensation products of the curing agent selected from sulfonated acetone, methyl diphenylene diisocyanate, polyacrylamide,
One or more in flyash calcium chloride, gypsum, calcium silicates, NPE.
The preparation method of above-mentioned polyurethane rubber anti-skid safety footwear, is made as follows：
(1) according to parts by weight, 20-50 parts of polyurethane, 20-30 parts of butyl rubber, 10-15 parts of epoxy resin, plant are taken
3-8 parts of fiber, 2-5 parts of clay, 1-2 parts of sulphur, 1-3 parts of CNT, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 80-90 kilograms of pressure to film using hydraulic press, and
Vulcanized under 100-115 DEG C of temperature conditionss, cure time 8-12 minutes, sole is made；
(3) coating accounts for the canvas quality 3-8% anti-frozen glue of waterproof on canvas, dries or dries, using sewing, glue
Viscous, sole is combined, safety shoe is made by the method for cutting with vamp.
Beneficial effects of the present invention：The polyurethane rubber anti-skid safety footwear of the present invention, using brand-new formula, preparation
Safety shoe wearing comfort, waterproof antifreeze ability is strong, and the sole surface being made is coarse, big in ice-sports frictional force, it is not easy to fall
, service life is long, is adapted to old man and children's ice-sports wearing.
Embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
A kind of polyurethane rubber anti-skid safety footwear, including material for sole of shoe and vamp material, the material for sole of shoe by weighing as follows
The raw material of amount number is made：35 parts of polyurethane, 25 parts of butyl rubber, 12 parts of epoxy resin, 6 parts of sisal fiber, 3 parts of clay, sulphur
1.5 parts of sulphur, 2 parts of CNT；The vamp material is made up of the canvas coating anti-frozen glue of waterproof.The anti-frozen glue coating of waterproof
Amount be canvas quality 6%, be made up of the component of following parts by weight：30 parts of natural rubber, diphenylmethane diisocyanate
5 parts of ester, 3 parts of triethanolamine, 4 parts of white carbon, 6 parts of paraformaldehyde, 5 parts of 2- acetyl-anisidines, 1,2- dihydroxy -1- benzene
2 parts of base ethane.
The preparation method of above-mentioned polyurethane rubber anti-skid safety footwear, is made as follows：
(1) according to parts by weight, 35 parts of polyurethane is taken, 25 parts of butyl rubber, 12 parts of epoxy resin, 6 parts of sisal fiber,
3 parts of clay, 1.5 parts of sulphur, 2 parts of CNT, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 85 kilograms of pressure to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the anti-frozen glue of waterproof of canvas quality 6% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, and safety shoe is made.
Embodiment 2
A kind of polyurethane rubber anti-skid safety footwear, including material for sole of shoe and vamp material, the material for sole of shoe by weighing as follows
The raw material of amount number is made：20 parts of polyurethane, 20 parts of butyl rubber, 10 parts of epoxy resin, 3 parts of monkey grass, 2 parts of clay, sulphur
1 part of sulphur, 1 part of CNT；The vamp material is made up of the canvas coating anti-frozen glue of waterproof.The anti-frozen glue coating of waterproof
Measure as the 3% of canvas quality, be made up of the component of following parts by weight：20 parts of natural rubber, 2 parts of polyacrylamide, flyash
1 part of calcium chloride, 1 part of triethanolamine, 3 parts of white carbon, 5 parts of paraformaldehyde, 3 parts of 2- acetyl-anisidines, 1,2- dihydroxy-
1 part of 1- diphenylphosphino ethanes.
The preparation method of above-mentioned polyurethane rubber anti-skid safety footwear, is made as follows：
(1) according to parts by weight, 20 parts of polyurethane is taken, 20 parts of butyl rubber, 10 parts of epoxy resin, 3 parts of monkey grass,
2 parts of clay, 1 part of sulphur, 1 part of CNT, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 80 kilograms of pressure to film using hydraulic press, and 100
Vulcanized under DEG C temperature conditionss, cure time 8 minutes, sole is made；
(3) coating accounts for the anti-frozen glue of waterproof of canvas quality 3% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, and safety shoe is made.
Embodiment 3
A kind of polyurethane rubber anti-skid safety footwear, including material for sole of shoe and vamp material, the material for sole of shoe by weighing as follows
The raw material of amount number is made：50 parts of polyurethane, 30 parts of butyl rubber, 15 parts of epoxy resin, 8 parts of elm bast, 5 parts of clay,
2 parts of sulphur, 3 parts of CNT；The vamp material is made up of the canvas coating anti-frozen glue of waterproof.The anti-frozen glue coating of waterproof
Amount be canvas quality 8%, be made up of the component of following parts by weight：35 parts of natural rubber, NPE 7
Part, 5 parts of triethanolamine, 5 parts of white carbon, 8 parts of paraformaldehyde, 6 parts of 2- acetyl-anisidines, 1,2- dihydroxy -1- phenyl second
3 parts of alkane.
The preparation method of above-mentioned polyurethane rubber anti-skid safety footwear, is made as follows：
(1) according to parts by weight, 50 parts of polyurethane, 30 parts of butyl rubber, 15 parts of epoxy resin, elm bast 8 are taken
Part, 5 parts of clay, 2 parts of sulphur, 3 parts of CNT, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 90 kilograms of pressure to film using hydraulic press, and 115
Vulcanized under DEG C temperature conditionss, cure time 12 minutes, sole is made；
(3) coating accounts for the anti-frozen glue of waterproof of canvas quality 8% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, and safety shoe is made.
Embodiment 4
A kind of polyurethane rubber anti-skid safety footwear, including material for sole of shoe and vamp material, the material for sole of shoe by weighing as follows
The raw material of amount number is made：35 parts of polyurethane, 25 parts of butyl rubber, 12 parts of epoxy resin, 6 parts of sisal fiber, 3 parts of clay, sulphur
1.5 parts of sulphur, 2 parts of CNT, 2 parts of giant clam powder；The vamp material is made up of the canvas coating anti-frozen glue of waterproof.It is described anti-
The amount of the anti-frozen glue coating of water is the 6% of canvas quality, is made up of the component of following parts by weight：30 parts of natural rubber, diphenyl
5 parts of methane diisocyanate, 3 parts of triethanolamine, 4 parts of white carbon, 6 parts of paraformaldehyde, 5 parts of 2- acetyl-anisidines, 1,2-
2 parts of dihydroxy -1- diphenylphosphino ethanes.
The preparation method of above-mentioned polyurethane rubber anti-skid safety footwear, is made as follows：
(1) according to parts by weight, 35 parts of polyurethane is taken, 25 parts of butyl rubber, 12 parts of epoxy resin, 6 parts of sisal fiber,
3 parts of clay, 1.5 parts of sulphur, 2 parts of CNT, 2 parts of giant clam powder, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 85 kilograms of pressure to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the anti-frozen glue of waterproof of canvas quality 6% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, and safety shoe is made.
Embodiment 5
A kind of polyurethane rubber anti-skid safety footwear, including material for sole of shoe and vamp material, the material for sole of shoe by weighing as follows
The raw material of amount number is made：35 parts of polyurethane, 25 parts of butyl rubber, 12 parts of epoxy resin, 6 parts of sisal fiber, 3 parts of clay, sulphur
1.5 parts of sulphur, 2 parts of CNT；The vamp material is made up of the canvas coating anti-frozen glue of waterproof.The anti-frozen glue coating of waterproof
Amount be canvas quality 6%, be made up of the component of following parts by weight：30 parts of natural rubber, diphenylmethane diisocyanate
5 parts of ester, 3 parts of triethanolamine, 4 parts of white carbon, 6 parts of paraformaldehyde, 5 parts of 2- acetyl-anisidines, 1,2- dihydroxy -1- benzene
2 parts of base ethane, 2 parts of 3- amino -2,6- difluorophenyl acetic acids methyl esters.
The preparation method of above-mentioned polyurethane rubber anti-skid safety footwear, is made as follows：
(1) according to parts by weight, 35 parts of polyurethane is taken, 25 parts of butyl rubber, 12 parts of epoxy resin, 6 parts of sisal fiber,
3 parts of clay, 1.5 parts of sulphur, 2 parts of CNT, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 85 kilograms of pressure to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the anti-frozen glue of waterproof of canvas quality 6% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, and safety shoe is made.
Comparative example 1
A kind of polyurethane rubber anti-skid safety footwear, including material for sole of shoe and vamp material, the material for sole of shoe by weighing as follows
The raw material of amount number is made：35 parts of polyurethane, 25 parts of butyl rubber, 12 parts of epoxy resin, 6 parts of sisal fiber, 1.5 parts of sulphur,
2 parts of CNT；The vamp material is made up of the canvas coating anti-frozen glue of waterproof.The amount of the anti-frozen glue coating of waterproof is sail
The 6% of cloth quality, is made up of the component of following parts by weight：30 parts of natural rubber, 5 parts of methyl diphenylene diisocyanate, three
3 parts of monoethanolamine, 4 parts of white carbon, 6 parts of paraformaldehyde, 5 parts of 2- acetyl-anisidines, 1,2- dihydroxy -1- diphenylphosphino ethanes 2
Part.
The preparation method of above-mentioned polyurethane rubber anti-skid safety footwear, is made as follows：
(1) according to parts by weight, 35 parts of polyurethane is taken, 25 parts of butyl rubber, 12 parts of epoxy resin, 6 parts of sisal fiber,
3 parts of clay, 1.5 parts of sulphur, 2 parts of CNT, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 85 kilograms of pressure to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the anti-frozen glue of waterproof of canvas quality 6% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, and safety shoe is made.
Comparative example 2
A kind of polyurethane rubber anti-skid safety footwear, including material for sole of shoe and vamp material, the material for sole of shoe by weighing as follows
The raw material of amount number is made：35 parts of polyurethane, 25 parts of butyl rubber, 12 parts of epoxy resin, 6 parts of sisal fiber, 3 parts of clay, sulphur
1.5 parts of sulphur, 2 parts of CNT；The vamp material is made up of the canvas coating anti-frozen glue of waterproof.The anti-frozen glue coating of waterproof
Amount be canvas quality 6%, be made up of the component of following parts by weight：30 parts of natural rubber, diphenylmethane diisocyanate
5 parts of ester, 3 parts of triethanolamine, 4 parts of white carbon, 6 parts of paraformaldehyde, 1,2- 2 parts of dihydroxy -1- diphenylphosphino ethanes.
The preparation method of above-mentioned polyurethane rubber anti-skid safety footwear, is made as follows：
(1) according to parts by weight, 35 parts of polyurethane is taken, 25 parts of butyl rubber, 12 parts of epoxy resin, 6 parts of sisal fiber,
3 parts of clay, 1.5 parts of sulphur, 2 parts of CNT, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 85 kilograms of pressure to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the anti-frozen glue of waterproof of canvas quality 6% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, and safety shoe is made.
Comparative example 3
A kind of polyurethane rubber anti-skid safety footwear, including material for sole of shoe and vamp material, the material for sole of shoe by weighing as follows
The raw material of amount number is made：35 parts of polyurethane, 25 parts of butyl rubber, 12 parts of epoxy resin, 6 parts of sisal fiber, 3 parts of clay, sulphur
1.5 parts of sulphur, 2 parts of CNT；The vamp material is made up of the canvas coating anti-frozen glue of waterproof.The anti-frozen glue coating of waterproof
Amount be canvas quality 6%, be made up of the component of following parts by weight：30 parts of natural rubber, diphenylmethane diisocyanate
5 parts of ester, 3 parts of triethanolamine, 4 parts of white carbon, 6 parts of paraformaldehyde, 5 parts of 2- acetyl-anisidines.
The preparation method of above-mentioned polyurethane rubber anti-skid safety footwear, is made as follows：
(1) according to parts by weight, 35 parts of polyurethane is taken, 25 parts of butyl rubber, 12 parts of epoxy resin, 6 parts of sisal fiber,
3 parts of clay, 1.5 parts of sulphur, 2 parts of CNT, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 85 kilograms of pressure to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the anti-frozen glue of waterproof of canvas quality 6% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, and safety shoe is made.
Embodiment 1-5 and comparative example 1-3 product sole water on-slip testing result is detected, data are as shown in table 1：
Table 1
As can be seen from Table 1, required for the shoe soles slip stopping of comparative example 1 power is maximum, compared with Example 1, other conditions phase
Together, clay is only added less, it was demonstrated that clay has the function of promoting sole structure combinations thing anti-skidding；The shoe soles slip stopping institute of embodiment 4
The power needed is smaller than embodiment 1, and compared with Example 1, other conditions are identical, is only to add giant clam powder more, it was demonstrated that
Giant clam powder has the function of promoting sole structure combinations thing anti-skidding.
Store 20 days under the conditions of -20 DEG C of low temperature, then normal temperature storage one day again, detection sole tearing strength and vamp
Breaking strength, data are as shown in table 2：
Table 2
As can be seen from Table 2, the sole tearing strength of embodiment 4 is higher than embodiment 1, compared with Example 1, other
Part is identical, is only to add giant clam powder more, illustrates that giant clam powder has the effect for promoting sole structure combinations thing freeze proof.Implement
The vamp breaking strength of example 5 is above embodiment 1, and compared with Example 1, other conditions are identical, is only to add 3- ammonia more
2 parts of base -2,6- difluorophenyl acetic acid methyl esters, illustrates that 2 parts of 3- amino -2,6- difluorophenyl acetic acids methyl esters can keep out the cold to vamp
The harm brought, strengthens its cold tolerance；The vamp breaking strength of comparative example 3 is above embodiment 1, compared with Example 1, its
His condition is identical, and 1,2- dihydroxy -1- diphenylphosphino ethanes are only added less, illustrates that 1,2- dihydroxy -1- diphenylphosphino ethanes can
Keep out the cold the harm come to shoe wear, strengthens its cold tolerance.
Claims (5)
1. a kind of polyurethane rubber anti-skid safety footwear, including material for sole of shoe and vamp material, it is characterised in that the material for sole of shoe
It is made up of the raw material of following parts by weight：20-50 parts of polyurethane, 20-30 parts of butyl rubber, 10-15 parts of epoxy resin, plant is fine
3-8 parts of dimension, 2-5 parts of clay, 1-2 parts of sulphur, 1-3 parts of CNT；The vamp material coats the anti-frozen glue system of waterproof by canvas
Into.
2. polyurethane rubber anti-skid safety footwear according to claim 1, it is characterised in that it is fine that the string is selected from sisal hemp
One or more in dimension, monkey grass, castor-oil plant fiber, hemp, abaca fibre, elm bast.
3. polyurethane rubber anti-skid safety footwear according to claim 1, it is characterised in that the amount of the anti-frozen glue coating of waterproof
For the 3-8% of canvas quality, it is made up of the component of following parts by weight：20-35 parts of natural rubber, 3-7 parts of curing agent, three ethanol
1-5 parts of amine, 3-5 parts of white carbon, 5-8 parts of paraformaldehyde, 3-6 parts of 2- acetyl-anisidines, 1,2- dihydroxy -1- diphenylphosphino ethanes
1-3 parts.
4. polyurethane rubber anti-skid safety footwear according to claim 3, it is characterised in that the curing agent is selected from sulfonated acetone
Formaldehyde condensation products, methyl diphenylene diisocyanate, polyacrylamide, flyash calcium chloride, gypsum, calcium silicates, nonyl phenol
One or more in APEO.
5. the preparation method of polyurethane rubber anti-skid safety footwear described in claim 1, it is characterised in that make as follows
Into：
(1) according to parts by weight, 20-50 parts of polyurethane, 20-30 parts of butyl rubber, 10-15 parts of epoxy resin, string are taken
3-8 parts, 2-5 parts of clay, 1-2 parts of sulphur, 1-3 parts of CNT, mixing synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes 80-90 kilograms of pressure to film using hydraulic press, and in 100-
Vulcanized under 115 DEG C of temperature conditionss, cure time 8-12 minutes, sole is made；
(3) coating accounts for the canvas quality 3-8% anti-frozen glue of waterproof on canvas, dries or dries, gluing using sewing, cuts out
The method cut, sole is combined with vamp, and safety shoe is made.
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| CN201710631598.8A CN107312319A (en) | 2017-07-28 | 2017-07-28 | A kind of polyurethane rubber anti-skid safety footwear |
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| CN201710631598.8A CN107312319A (en) | 2017-07-28 | 2017-07-28 | A kind of polyurethane rubber anti-skid safety footwear |
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| CN201710631598.8A Pending CN107312319A (en) | 2017-07-28 | 2017-07-28 | A kind of polyurethane rubber anti-skid safety footwear |
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| CN109288200A (en) * | 2018-10-18 | 2019-02-01 | 浙江靓颖实业有限公司 | A kind of women's shoes with protection composition |
| CN110144111A (en) * | 2019-04-15 | 2019-08-20 | 泉州邦尼生物科技有限公司 | A kind of lightweight adds numb polyurethane shoe-sole and preparation method thereof |
| CN110204865A (en) * | 2019-06-13 | 2019-09-06 | 钱立英 | A kind of rain-proof shoe sheath material and shoe cover becoming function with temperature |
| CN110922744A (en) * | 2019-11-25 | 2020-03-27 | 安徽华信安全设备有限公司 | Corrosion-resistant anti-skidding safety shoe |
| CN114292515A (en) * | 2022-01-12 | 2022-04-08 | 安徽冠泓塑业有限公司 | High-wear-resistance and high-strength protective boot and preparation method thereof |
| CN115162015A (en) * | 2022-07-26 | 2022-10-11 | 安踏（中国）有限公司 | Treating agent for nylon or Teflon vamp and processing method of vamp |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109288200A (en) * | 2018-10-18 | 2019-02-01 | 浙江靓颖实业有限公司 | A kind of women's shoes with protection composition |
| CN110144111A (en) * | 2019-04-15 | 2019-08-20 | 泉州邦尼生物科技有限公司 | A kind of lightweight adds numb polyurethane shoe-sole and preparation method thereof |
| CN110204865A (en) * | 2019-06-13 | 2019-09-06 | 钱立英 | A kind of rain-proof shoe sheath material and shoe cover becoming function with temperature |
| CN110922744A (en) * | 2019-11-25 | 2020-03-27 | 安徽华信安全设备有限公司 | Corrosion-resistant anti-skidding safety shoe |
| CN114292515A (en) * | 2022-01-12 | 2022-04-08 | 安徽冠泓塑业有限公司 | High-wear-resistance and high-strength protective boot and preparation method thereof |
| CN115162015A (en) * | 2022-07-26 | 2022-10-11 | 安踏（中国）有限公司 | Treating agent for nylon or Teflon vamp and processing method of vamp |
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