CN108530895A - A kind of preparation method of the easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial - Google Patents

A kind of preparation method of the easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial Download PDF

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Publication number
CN108530895A
CN108530895A CN201710119468.6A CN201710119468A CN108530895A CN 108530895 A CN108530895 A CN 108530895A CN 201710119468 A CN201710119468 A CN 201710119468A CN 108530895 A CN108530895 A CN 108530895A
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CN
China
Prior art keywords
parts
component
sole
shoe
shoes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710119468.6A
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Chinese (zh)
Inventor
葛胜超
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East Asia Nanjing Product Of Rubber And Plastic Co Ltd
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East Asia Nanjing Product Of Rubber And Plastic Co Ltd
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Application filed by East Asia Nanjing Product Of Rubber And Plastic Co Ltd filed Critical East Asia Nanjing Product Of Rubber And Plastic Co Ltd
Priority to CN201710119468.6A priority Critical patent/CN108530895A/en
Publication of CN108530895A publication Critical patent/CN108530895A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04Plastics, rubber or vulcanised fibre
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

A kind of preparation method of easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial provided by the invention, including mass ratio (2 4):1 component A and component B;Wherein, the component A is made of the component of following weight ratio:19.5 19.9 parts of methyl oxirane rubber, 3,19.5 19.9 parts of 3 ' dimethyl diphenyl methane, 4,4 ' diisocyanate, 6.8 9.5 parts of dibutyl phthalate, 11.2 16.8 parts of coal tar, 11.2 16.8 parts of polydimethyl siloxane fluid, 0.5 0.8 parts of triethylene diamine;The component B is made of the components of following parts:19.5 19.9 parts of methyl silicone rubber, 11.2 16.8 parts of red mud, 0.5 0.8 parts of auxiliary stabilizer, 0.5 0.8 parts of lubricant, 0.5 0.8 parts of Sulfur, 11.2 16.8 parts of octyl epoxy stearate, 0.5 0.8 parts of fine particle thermal black, 1~3 part of zinc oxide.Bi-component material for sole of shoe preparation process is simple, of low cost, good permeability, elasticity is good, light-weight, flexibility is good, can effectively absorb moisture and antibacterial, is applicable to shoe sole of gravida shoes.

Description

A kind of preparation method of the easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial
Technical field
The invention belongs to daily necessities field, more particularly to a kind of easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial And preparation method thereof.
Background technology
There are many type of bi-component material for sole of shoe, are generally divided into natural class bi-component material for sole of shoe and synthesis class bi-component shoes Two kinds of bottom material.Natural class bi-component material for sole of shoe includes natural bottom leather, bamboo and wood material etc., synthesizes class bi-component material for sole of shoe packet Include rubber, PU materials, methyl silicone rubber synthetic resin etc..The common characteristic of bi-component material for sole of shoe has wear-resisting, water-fast, elastic It is good, be easy to be unlikely to deform after suitable foot type, sizing etc. condition.Synthesis class bi-component material for sole of shoe is most widely used at present A kind of footwear material.
Pregnant woman health is most important for family, however, pregnant woman uses conventional shoe now, encounters the rainy day When, due to surface gathered water, shoes were not often had by water so that shoes are intake, while outdoor foot on go out compared with hidrosis, can make Wearer is very uncomfortable, and also unfavorable to the health of pregnant woman.Meanwhile growth bacterium is easy after water inlet and perspiration in shoes.
Invention content
Technical problem:In order to solve the defects of prior art, the present invention provides a kind of easy pregnant woman for absorbing moisture antibacterial Shoes bi-component material for sole of shoe.
Technical solution:A kind of easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial provided by the invention, including matter Amount is than (2-4):1 component A and component B;Wherein, the component A is made of the component of following weight ratio:Methyl oxirane rubber 19.5-19.9 parts of glue, 3,3 '-dimethyl diphenyl methane -4,4 ' -19.5-19.9 parts of diisocyanate, dibutyl phthalate 6.8-9.5 parts, 11.2-16.8 parts of coal tar, 11.2-16.8 parts of polydimethyl siloxane fluid, 0.5-0.8 parts of triethylene diamine;It is described Component B is made of the components of following parts:19.5-19.9 parts of methyl silicone rubber, 11.2-16.8 parts of red mud, auxiliary stabilizer 0.5-0.8 parts, 0.5-0.8 parts of lubricant, 0.5-0.8 parts of Sulfur, 11.2-16.8 parts of octyl epoxy stearate, fine particle hot tearing 0.5-0.8 parts of method carbon black, 1~3 part of zinc oxide.
As an improvement, the easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial includes mass ratio 3:1 component A With component B;Wherein, the component A is made of the component of following weight ratio:25 parts of methyl oxirane rubber, 3,3 '-dimethyl 25 parts of 4,4 '-diisocyanate of diphenyl-methane-, 7 parts of dibutyl phthalate, 15 parts of coal tar, 15 parts of polydimethyl siloxane fluid, 2 parts of triethylene diamine;The component B is made of the components of following parts:25 parts of methyl silicone rubber, 15 parts of red mud, auxiliary are steady Determine 2 parts of agent, 2 parts of lubricant, 2 parts of Sulfur, 15 parts of octyl epoxy stearate, 2 parts of fine particle thermal black, 2 parts of zinc oxide.
The present invention also provides a kind of preparation methods of the easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial, including Following steps:
(1) each component of component A is weighed in proportion, mixing;The each component of component B is weighed in proportion, mixing;
(2) each component in component A is added in autoclave, at 60-70 DEG C, reacts 2-3h, be cooled to room temperature, obtain pre- Aggressiveness;
(3) the component B of performed polymer and 2/3 is uniformly mixed;It is added in sole casting machine batch can, is warming up to 60-70 DEG C, perseverance Warm 6.8-9.5min;It is cooled to 55-60 DEG C, continuously adds remaining 1/3 component B, constant temperature 11.2-16.8min;
(4) by step (3) product coating release agent, drying, cast on die for shoe-sole, 10-12min is kept the temperature, is demoulded, i.e., .
Advantageous effect:Bi-component material for sole of shoe preparation process provided by the invention is simple, of low cost, good permeability, bullet Property is good, light-weight, flexibility is good, can effectively absorb moisture and antibacterial, is applicable to shoe sole of gravida shoes.
Specific implementation mode
The shoes for pregnant woman bi-component material for sole of shoe of the invention for easily absorbing moisture antibacterial is further illustrated below.
Easily absorb the shoes for pregnant woman bi-component material for sole of shoe of moisture antibacterial, including mass ratio 1:2 component A and component B;Its In, the component A is made of the component of following weight ratio:25 parts of methyl oxirane rubber, 3,3 '-dimethyl diphenyl methanes- 4,4 ' -25 parts of diisocyanate, 7 parts of dibutyl phthalate, 15 parts of coal tar, 15 parts of polydimethyl siloxane fluid, triethylene two 2 parts of amine;The component B is made of the components of following parts:25 parts of methyl silicone rubber, 15 parts of red mud, 2 parts of auxiliary stabilizer, 2 parts of lubricant, 2 parts of Sulfur, 15 parts of octyl epoxy stearate, 2 parts of fine particle thermal black, 2 parts of zinc oxide.
Preparation method includes the following steps:
(1) each component of component A is weighed in proportion, mixing;The each component of component B is weighed in proportion, mixing;
(2) each component in component A is added in autoclave, at 60-70 DEG C, reacts 2-3h, be cooled to room temperature, obtain pre- Aggressiveness;
(3) the component B of performed polymer and 2/3 is uniformly mixed;It is added in sole casting machine batch can, is warming up to 60-70 DEG C, perseverance Warm 6.8-9.5min;It is cooled to 55-60 DEG C, continuously adds remaining 1/3 component B, constant temperature 11.2-16.8min;
(4) by step (3) product coating release agent, drying, cast on die for shoe-sole, 10-12min is kept the temperature, is demoulded, i.e., .

Claims (2)

1. a kind of preparation method of the easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial, it is characterised in that:Including following Step:
(1) each component of component A is weighed in proportion, mixing;The each component of component B is weighed in proportion, mixing;
(2) each component in component A is added in autoclave, at 60-70 DEG C, reacts 2-3h, be cooled to room temperature, obtain pre-polymerization Body;
(3) the component B of performed polymer and 2/3 is uniformly mixed;It is added in sole casting machine batch can, is warming up to 60-70 DEG C, constant temperature 6.8-9.5min;It is cooled to 55-60 DEG C, continuously adds remaining 1/3 component B, constant temperature 11.2-16.8min;
(4) by step (3) product coating release agent, drying, cast on die for shoe-sole, keep the temperature 10-12min, demoulding to get;Its In, the component A is made of the component of following weight ratio:19.5-19.9 parts of methyl oxirane rubber, 3,3 '-dimethyl two 19.5-19.9 parts of 4,4 '-diisocyanate of phenylmethane-, 6.8-9.5 parts of dibutyl phthalate, coal tar 11.2-16.8 Part, 11.2-16.8 parts of polydimethyl siloxane fluid, 0.5-0.8 parts of triethylene diamine;The component B by following parts by weight component system At:19.5-19.9 parts of methyl silicone rubber, 11.2-16.8 parts of red mud, 0.5-0.8 parts of auxiliary stabilizer, 0.5-0.8 parts of lubricant, 0.5-0.8 parts of Sulfur, 11.2-16.8 parts of octyl epoxy stearate, 0.5-0.8 parts of fine particle thermal black, zinc oxide 1~3 Part.
2. a kind of easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial according to claim 1, it is characterised in that:
Including mass ratio 3:1 component A and component B;Wherein, the component A is made of the component of following weight ratio:
25 parts of methyl oxirane rubber, 3,3 '-dimethyl diphenyl methane -4,4 ' -25 parts of diisocyanate, phthalic acid two 7 parts of butyl ester, 15 parts of coal tar, 15 parts of polydimethyl siloxane fluid, 2 parts of triethylene diamine;The component B by following parts by weight component It is made:25 parts of methyl silicone rubber, 15 parts of red mud, 2 parts of auxiliary stabilizer, 2 parts of lubricant, 2 parts of Sulfur, octyl epoxy stearate 15 Part, 2 parts of fine particle thermal black, 2 parts of zinc oxide.
CN201710119468.6A 2017-03-02 2017-03-02 A kind of preparation method of the easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial Pending CN108530895A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710119468.6A CN108530895A (en) 2017-03-02 2017-03-02 A kind of preparation method of the easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710119468.6A CN108530895A (en) 2017-03-02 2017-03-02 A kind of preparation method of the easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial

Publications (1)

Publication Number Publication Date
CN108530895A true CN108530895A (en) 2018-09-14

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710119468.6A Pending CN108530895A (en) 2017-03-02 2017-03-02 A kind of preparation method of the easy shoes for pregnant woman bi-component material for sole of shoe for absorbing moisture antibacterial

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CN (1) CN108530895A (en)

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Application publication date: 20180914