CN108530776A - A kind of preparation method of the high ultralight basketball shoes bi-component material for sole of shoe of rebound - Google Patents

A kind of preparation method of the high ultralight basketball shoes bi-component material for sole of shoe of rebound Download PDF

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Publication number
CN108530776A
CN108530776A CN201710119390.8A CN201710119390A CN108530776A CN 108530776 A CN108530776 A CN 108530776A CN 201710119390 A CN201710119390 A CN 201710119390A CN 108530776 A CN108530776 A CN 108530776A
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CN
China
Prior art keywords
parts
component
sole
shoe
ultralight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710119390.8A
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Chinese (zh)
Inventor
葛胜超
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East Asia Nanjing Product Of Rubber And Plastic Co Ltd
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East Asia Nanjing Product Of Rubber And Plastic Co Ltd
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Application filed by East Asia Nanjing Product Of Rubber And Plastic Co Ltd filed Critical East Asia Nanjing Product Of Rubber And Plastic Co Ltd
Priority to CN201710119390.8A priority Critical patent/CN108530776A/en
Publication of CN108530776A publication Critical patent/CN108530776A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04Plastics, rubber or vulcanised fibre
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/32Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur
    • C08L23/34Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur by chlorosulfonation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of preparation method of high ultralight basketball shoes bi-component material for sole of shoe of rebound provided by the invention, including mass ratio (6.9 7.5):1 component A and component B;Wherein, the component A is made of the component of following weight ratio:36.8 41.4 parts of chlorosulfonated polyethylene, 36.8 41.4 parts of toluene di-isocyanate(TDI), 3.3 6.8 parts of plasticizer, 11.6 15.8 parts of paraffin-base petroleum, 11.6 15.8 parts of polydimethyl siloxane fluid, N, 1.5 1.8 parts of N ' diphenyl-para-phenylene diamines;The component B is made of the components of following parts:36.8 41.4 parts of methyl oxirane rubber, 11.6 15.8 parts of red mud, 1.5 1.8 parts of auxiliary stabilizer, 1.5 1.8 parts of lubricant, 1.5 1.8 parts of Sulfur, 11.6 15.8 parts of repefral, 1.5 1.8 parts of conductive carbon black, 1~3 part of basic lead silicate.Bi-component material for sole of shoe preparation process is simple, of low cost, good permeability, elasticity is good, light-weight, flexibility is good, is applicable to basketball shoes sole.

Description

A kind of preparation method of the high ultralight basketball shoes bi-component material for sole of shoe of rebound
Technical field
The invention belongs to daily necessities field, more particularly to the ultralight basketball shoes bi-component material for sole of shoe of a kind of high rebound and its system Preparation Method.
Background technology
There are many type of bi-component material for sole of shoe, are generally divided into natural class bi-component material for sole of shoe and synthesis class bi-component shoes Two kinds of bottom material.Natural class bi-component material for sole of shoe includes natural bottom leather, bamboo and wood material etc., synthesizes class bi-component material for sole of shoe packet Include rubber, PU materials, methyl oxirane rubbery synthetic resin etc..The common characteristic of bi-component material for sole of shoe has wear-resisting, resistance to Water, elasticity are good, be easy suitable foot type, sizing after be unlikely to deform etc. condition.Synthesis class bi-component material for sole of shoe is application at present Widest one kind footwear material.
Basketball movement needs have extraordinary spring, and the spring of sportsman is in addition to the related and basket with itself constitution The elasticity of sneakers is also related.Basketball is more for deodorization and aeroelastic requirements higher due to the use of person's basketball.In addition, suitable basketball Shoes also need to merrily and lightheartedly mitigate the burden of sportsman.
Invention content
Technical problem:In order to solve the defects of prior art, the present invention provides a kind of high double groups of the ultralight basketball shoes of rebound Divide material for sole of shoe.
Technical solution:A kind of high ultralight basketball shoes bi-component material for sole of shoe of rebound provided by the invention, including mass ratio (6.9-7.5):1 component A and component B;Wherein, the component A is made of the component of following weight ratio:Chlorosulfonated polyethylene 36.8-41.4 parts, 36.8-41.4 parts of toluene di-isocyanate(TDI), 3.3-6.8 parts of plasticizer, 11.6-15.8 parts of paraffin-base petroleum, 11.6-15.8 parts of polydimethyl siloxane fluid, N, 1.5-1.8 parts of N '-diphenyl-para-phenylene diamines;The component B is by following parts by weight Component is made:36.8-41.4 parts of methyl oxirane rubber, 11.6-15.8 parts of red mud, 1.5-1.8 parts of auxiliary stabilizer, lubrication 1.5-1.8 parts of agent, 1.5-1.8 parts of Sulfur, 11.6-15.8 parts of repefral, 1.5-1.8 parts of conductive carbon black, alkali formula 1~3 part of lead silicate.
As an improvement, the high ultralight basketball shoes bi-component material for sole of shoe of rebound includes mass ratio 3:1 component A and component B;Wherein, the component A is made of the component of following weight ratio:25 parts of chlorosulfonated polyethylene, increases 25 parts of toluene di-isocyanate(TDI) Mould 7 parts of agent, 15 parts of paraffin-base petroleum, 15 parts of polydimethyl siloxane fluid, N, 2 parts of N '-diphenyl-para-phenylene diamines;The component B by with The component of lower parts by weight is made:25 parts of methyl oxirane rubber, 15 parts of red mud, 2 parts of auxiliary stabilizer, 2 parts of lubricant, Sulfur 2 parts, 15 parts of repefral, 2 parts of conductive carbon black, 2 parts of basic lead silicate.
The present invention also provides a kind of preparation methods of the high ultralight basketball shoes bi-component material for sole of shoe of rebound, including following step Suddenly:
(1) each component of component A is weighed in proportion, mixing;The each component of component B is weighed in proportion, mixing;
(2) each component in component A is added in autoclave, at 60-70 DEG C, reacts 2-3h, be cooled to room temperature, obtain pre- Aggressiveness;
(3) the component B of performed polymer and 2/3 is uniformly mixed;It is added in sole casting machine batch can, is warming up to 60-70 DEG C, perseverance Warm 3.3-6.8min;It is cooled to 55-60 DEG C, continuously adds remaining 1/3 component B, constant temperature 11.6-15.8min;
(4) by step (3) product coating release agent, drying, cast on die for shoe-sole, 10-12min is kept the temperature, is demoulded, i.e., .
Advantageous effect:Bi-component material for sole of shoe preparation process provided by the invention is simple, of low cost, good permeability, bullet Property is good, light-weight, flexibility is good, is applicable to basketball shoes sole.
Specific implementation mode
The high ultralight basketball shoes bi-component material for sole of shoe of rebound of the invention is further illustrated below.
Height springs back ultralight basketball shoes bi-component material for sole of shoe, including mass ratio 1:2 component A and component B;Wherein, described Component A is made of the component of following weight ratio:25 parts of chlorosulfonated polyethylene, 25 parts of toluene di-isocyanate(TDI), 7 parts of plasticizer, stone 15 parts of paraffin-base oil, 15 parts of polydimethyl siloxane fluid, N, 2 parts of N '-diphenyl-para-phenylene diamines;The component B is by following parts by weight Component is made:25 parts of methyl oxirane rubber, 15 parts of red mud, 2 parts of auxiliary stabilizer, 2 parts of lubricant, 2 parts of Sulfur, adjacent benzene two 15 parts of formic acid dimethyl ester, 2 parts of conductive carbon black, 2 parts of basic lead silicate.
Preparation method includes the following steps:
(1) each component of component A is weighed in proportion, mixing;The each component of component B is weighed in proportion, mixing;
(2) each component in component A is added in autoclave, at 60-70 DEG C, reacts 2-3h, be cooled to room temperature, obtain pre- Aggressiveness;
(3) the component B of performed polymer and 2/3 is uniformly mixed;It is added in sole casting machine batch can, is warming up to 60-70 DEG C, perseverance Warm 3.3-6.8min;It is cooled to 55-60 DEG C, continuously adds remaining 1/3 component B, constant temperature 11.6-15.8min;
(4) by step (3) product coating release agent, drying, cast on die for shoe-sole, 10-12min is kept the temperature, is demoulded, i.e., .

Claims (2)

1. a kind of preparation method of the high ultralight basketball shoes bi-component material for sole of shoe of rebound, it is characterised in that:Include the following steps:
(1) each component of component A is weighed in proportion, mixing;The each component of component B is weighed in proportion, mixing;
(2) each component in component A is added in autoclave, at 60-70 DEG C, reacts 2-3h, be cooled to room temperature, obtain pre-polymerization Body;
(3) the component B of performed polymer and 2/3 is uniformly mixed;It is added in sole casting machine batch can, is warming up to 60-70 DEG C, constant temperature 3.3-6.8min;It is cooled to 55-60 DEG C, continuously adds remaining 1/3 component B, constant temperature 11.6-15.8min;
(4) by step (3) product coating release agent, drying, cast on die for shoe-sole, keep the temperature 10-12min, demoulding to get;
Wherein, the component A is made of the component of following weight ratio:36.8-41.4 parts of chlorosulfonated polyethylene, toluene diisocynate 36.8-41.4 parts of ester, 3.3-6.8 parts of plasticizer, 11.6-15.8 parts of paraffin-base petroleum, 11.6-15.8 parts of polydimethyl siloxane fluid, N, N ' 1.5-1.8 parts of-diphenyl-para-phenylene diamine;The component B is made of the components of following parts:Methyl oxirane rubber 36.8-41.4 parts, 11.6-15.8 parts of red mud, 1.5-1.8 parts of auxiliary stabilizer, 1.5-1.8 parts of lubricant, Sulfur 1.5-1.8 Part, 11.6-15.8 parts of repefral, 1.5-1.8 parts of conductive carbon black, 1~3 part of basic lead silicate.
2. a kind of preparation method of high ultralight basketball shoes bi-component material for sole of shoe of rebound according to claim 1, feature It is:Including mass ratio 3:1 component A and component B;Wherein, the component A is made of the component of following weight ratio:Chlorosulfonation 25 parts of polyethylene, 25 parts of toluene di-isocyanate(TDI), 7 parts of plasticizer, 15 parts of paraffin-base petroleum, 15 parts of polydimethyl siloxane fluid, N, N '- 2 parts of diphenyl-para-phenylene diamine;The component B is made of the components of following parts:25 parts of methyl oxirane rubber, red mud 15 Part, 2 parts of auxiliary stabilizer, 2 parts of lubricant, 2 parts of Sulfur, 15 parts of repefral, 2 parts of conductive carbon black, alkali formula silicic acid 2 parts of lead.
CN201710119390.8A 2017-03-02 2017-03-02 A kind of preparation method of the high ultralight basketball shoes bi-component material for sole of shoe of rebound Pending CN108530776A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710119390.8A CN108530776A (en) 2017-03-02 2017-03-02 A kind of preparation method of the high ultralight basketball shoes bi-component material for sole of shoe of rebound

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710119390.8A CN108530776A (en) 2017-03-02 2017-03-02 A kind of preparation method of the high ultralight basketball shoes bi-component material for sole of shoe of rebound

Publications (1)

Publication Number Publication Date
CN108530776A true CN108530776A (en) 2018-09-14

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CN201710119390.8A Pending CN108530776A (en) 2017-03-02 2017-03-02 A kind of preparation method of the high ultralight basketball shoes bi-component material for sole of shoe of rebound

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Application publication date: 20180914