CN105968421A - Biodegradable mosquito-repelling slipper sole material - Google Patents
Biodegradable mosquito-repelling slipper sole material Download PDFInfo
- Publication number
- CN105968421A CN105968421A CN201610572061.4A CN201610572061A CN105968421A CN 105968421 A CN105968421 A CN 105968421A CN 201610572061 A CN201610572061 A CN 201610572061A CN 105968421 A CN105968421 A CN 105968421A
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- CN
- China
- Prior art keywords
- parts
- component
- agent
- mosquito
- sole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/04—Starch derivatives, e.g. crosslinked derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention provides a biodegradable mosquito-repelling slipper sole material which comprises a component A and a component B in a mass ratio (2-4):1. The component A is prepared from the following ingredients in parts by weight: 30-50 parts of modified starch, 20-30 parts of plant fiber, 10-20 parts of starch octylsuccinate, 10-20 parts of biological fully-degradable resin, 4-6 parts of biomass-base 1,4-butyldiisocyanate, 3-7 parts of nano filler, 2-4 parts of folium artemisiae argyi and 1-3 parts of citronella. The component B is prepared from the following ingredients in parts by weight: 30-40 parts of xylan, 11-19 parts of mannan, 21-25 parts of polycaprolactone, 1-5 parts of compatibilizer, 1-5 parts of coupling agent, 1-5 parts of antioxidant, 2-8 parts of calcium carbonate, 2-5 parts of stearic acid, 1-5 parts of glass fiber, 1-3 parts of crosslinking agent, 2-7 parts of foaming agent and 4-8 parts of stabilizer. The slipper sole material has the advantages of simple preparation technique, low cost, favorable elasticity, light weight and favorable flexibility, and can effectively implement biodegradability and mosquito repelling.
Description
Technical field
The invention belongs to daily necessities field, particularly to a kind of biodegradable mosquito-proof cooling slippers material for sole of shoe and system thereof
Preparation Method.
Background technology
The kind of cooling slippers material for sole of shoe is a lot, is generally divided into natural class cooling slippers material for sole of shoe and synthesis class cooling slippers footwear
Bottom material two kinds.Natural class cooling slippers material for sole of shoe includes natural bottom leather, bamboo and wood material etc., synthesizes class cooling slippers material for sole of shoe bag
Include rubber, PU material, PVC synthetic resin etc..The common characteristic of cooling slippers material for sole of shoe possesses wear-resisting, water-fast, good springiness, easily
Condition it is unlikely to deform etc. after being suitable for foot type, sizing.Synthesis class cooling slippers material for sole of shoe is most widely used class footwear at present
Material.
Main Ingredients and Appearance PVC (polrvinyl chloride), the PE of the most existing footwear material and packaging antidetonation sheet material are (poly-
Ethylene), PP (polypropylene), EVA (ethylene-vinyl acetate copolymer), rubber etc. be petrochemicals, they
All belonging to high polymer, because the degree of polymerization is relatively big, intermolecular force is strong, and macromolecular chain is difficult to fracture and decomposes, thus causes existing footwear
Material and packaging antidetonation sheet material have non-biodegradable, pollute the environment.Oil is non-renewable resources on the earth simultaneously, and this makes
Obtain petroleum product and have non-renewable, and cost is high.
In hot summer, people generally prefer that and wear the footwear that slippers, sandals etc. are the most ventilative, but foot is refrigerant in enjoyment
But can be bothered by mosquito while Tou Qi, the most also not have material for sole of shoe to possess mosquito-proof function, people can only be led to
Crossing spraying anophelifuge water and come mosquito-proof, but effect is not fine, because foot easily perspires, sweat can be substantially reduced mosquito-proof liquid medicine
Drug effect.
Summary of the invention
Technical problem: in order to solve the defect of prior art, the invention provides a kind of biodegradable mosquito-proof flip-flop
Footwear material for sole of shoe.
Technical scheme: a kind of biodegradable mosquito-proof cooling slippers material for sole of shoe that the present invention provides, including mass ratio (2-
4): the component A and component B of 1；Wherein, described component A is made up of the component of following weight ratio: modified starch 30-50 part, plant
Fiber 20-30 part, octyl group succinic acid starch ester 10-20 part, fully bio-degradable resin 10-20 part, biomass-based 1,4-fourth two are different
Cyanate 4-6 part, Nano filling 3-7 part, Folium Artemisiae Argyi 2-4 part, Herba Cymbopogonis Citrari 1-3 part；Described component B is by the component system of following weight portion
Become: xylan 30-40 part, mannan 11-19 part, polycaprolactone 21 25 parts, bulking agent 1-5 part, coupling agent 1-5 part, anti-
Oxidant 1-5 part, calcium carbonate 2-8 part, stearic acid 2～5 parts, glass fibre 1-5 part, cross-linking agent 1-3 part, foaming agent 2-7 part, steady
Determine agent 4-8 part.
As improvement, described biodegradable mosquito-proof cooling slippers material for sole of shoe includes component A and the component of mass ratio 3:1
B；Wherein, described component A is made up of the component of following weight ratio: modified starch 40 parts, Plant fiber 25 parts, octyl group succinic acid form sediment
Powder ester 17 parts, fully bio-degradable resin 16 parts, biomass-based 1,4-fourth diisocyanate 5 parts, Nano filling 4 parts, Folium Artemisiae Argyi 3 parts,
2 parts of Herba Cymbopogonis Citrari；Described component B is made up of the component of following weight portion: xylan 34 parts, mannan 18 parts, polycaprolactone 25 parts,
Bulking agent 4 parts, coupling agent 2 parts, antioxidant 3 parts, calcium carbonate 4 parts, stearic acid 5 parts, glass fibre 4 parts, cross-linking agent 2 part,
Infusion 5 parts, stabilizer 5 parts.
Present invention also offers the preparation method of a kind of biodegradable mosquito-proof cooling slippers material for sole of shoe, including following step
Rapid:
(1) each component of component A is weighed in proportion, mixes；Each component of component B is weighed in proportion, mixes；
(2) each component in component A is added in autoclave, at 60-70 DEG C, react 2-3h, be cooled to room temperature, obtain pre-polymerization
Body；
(3) by performed polymer and the component B mix homogeneously of 2/3；Add in sole casting machine batch can, be warming up to 60-70 DEG C, constant temperature 5-
10min；It is cooled to 55-60 DEG C, continuously adds the component B of remaining 1/3, constant temperature 10-20min；
(4) by step (3) product on die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, the demoulding, to obtain final product.
Beneficial effect: cooling slippers material for sole of shoe preparation technology good, the weight simple, with low cost, elastic that the present invention provides
Gently, flexibility good, can be effective biodegradable mosquito-proof.
Detailed description of the invention
Mosquito-proof cooling slippers material for sole of shoe biodegradable to the present invention further illustrates below.
Biodegradable mosquito-proof cooling slippers material for sole of shoe, including the component A and component B of mass ratio 3:1；Wherein, described
Component A is made up of the component of following weight ratio: modified starch 40 parts, Plant fiber 25 parts, octyl group succinic acid starch ester 17 parts, life
Thing degradable resin 16 parts, biomass-based 1,4-fourth diisocyanate 5 parts, Nano filling 4 parts, Folium Artemisiae Argyi 3 parts, 2 parts of Herba Cymbopogonis Citrari；Described
Component B is made up of the component of following weight portion: xylan 34 parts, mannan 18 parts, polycaprolactone 25 parts, bulking agent 4 parts, idol
Join agent 2 parts, antioxidant 3 parts, calcium carbonate 4 parts, stearic acid 5 parts, glass fibre 4 parts, cross-linking agent 2 parts, foaming agent 5 parts, stablize
Agent 5 parts.
Its preparation method, comprises the following steps:
(1) each component of component A is weighed in proportion, mixes；Each component of component B is weighed in proportion, mixes；
(2) each component in component A is added in autoclave, at 60-70 DEG C, react 2-3h, be cooled to room temperature, obtain pre-polymerization
Body；
(3) by performed polymer and the component B mix homogeneously of 2/3；Add in sole casting machine batch can, be warming up to 60-70 DEG C, constant temperature 5-
10min；It is cooled to 55-60 DEG C, continuously adds the component B of remaining 1/3, constant temperature 10-20min；
(4) by step (3) product on die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, the demoulding, to obtain final product.
Claims (2)
1. a biodegradable mosquito-proof cooling slippers material for sole of shoe, it is characterised in that: include mass ratio (2-4): the component A of 1
With component B；Wherein, described component A is made up of the component of following weight ratio: modified starch 30-50 part, Plant fiber's 20-30 part,
Octyl group succinic acid starch ester 10-20 part, fully bio-degradable resin 10-20 part, biomass-based 1,4-fourth diisocyanate 4-6 part,
Nano filling 3-7 part, Folium Artemisiae Argyi 2-4 part, Herba Cymbopogonis Citrari 1-3 part；Described component B is made up of the component of following weight portion: xylan 30-40
Part, mannan 11-19 part, polycaprolactone 21 25 parts, bulking agent 1-5 part, coupling agent 1-5 part, antioxidant 1-5 part, carbon
Acid calcium 2-8 part, stearic acid 2～5 parts, glass fibre 1-5 part, cross-linking agent 1-3 part, foaming agent 2-7 part, stabilizer 4-8 part.
A kind of biodegradable mosquito-proof cooling slippers material for sole of shoe the most according to claim 1, it is characterised in that: wherein,
Described component A is made up of the component of following weight ratio: modified starch 40 parts, Plant fiber 25 parts, octyl group succinic acid starch ester 17
Part, fully bio-degradable resin 16 parts, biomass-based 1,4-fourth diisocyanate 5 parts, Nano filling 4 parts, Folium Artemisiae Argyi 3 parts, Herba Cymbopogonis Citrari 2
Part；Described component B is made up of the component of following weight portion: xylan 34 parts, mannan 18 parts, polycaprolactone 25 parts, increase-volume
Agent 4 parts, coupling agent 2 parts, antioxidant 3 parts, calcium carbonate 4 parts, stearic acid 5 parts, glass fibre 4 parts, cross-linking agent 2 parts, foaming agent 5
Part, stabilizer 5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610572061.4A CN105968421A (en) | 2016-07-20 | 2016-07-20 | Biodegradable mosquito-repelling slipper sole material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610572061.4A CN105968421A (en) | 2016-07-20 | 2016-07-20 | Biodegradable mosquito-repelling slipper sole material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105968421A true CN105968421A (en) | 2016-09-28 |
Family
ID=56951828
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610572061.4A Pending CN105968421A (en) | 2016-07-20 | 2016-07-20 | Biodegradable mosquito-repelling slipper sole material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105968421A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107090171A (en) * | 2017-06-02 | 2017-08-25 | 安徽爱舍家居制品有限公司 | A kind of preparation method of the mosquito-proof cooling slippers of soft |
| WO2018058542A1 (en) * | 2016-09-30 | 2018-04-05 | 张爱丽 | Environmentally-friendly plastic material and manufacturing method thereof |
-
2016
- 2016-07-20 CN CN201610572061.4A patent/CN105968421A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018058542A1 (en) * | 2016-09-30 | 2018-04-05 | 张爱丽 | Environmentally-friendly plastic material and manufacturing method thereof |
| CN107090171A (en) * | 2017-06-02 | 2017-08-25 | 安徽爱舍家居制品有限公司 | A kind of preparation method of the mosquito-proof cooling slippers of soft |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160928 |