CN108530831A - A kind of high performance reflective color asphalt - Google Patents
A kind of high performance reflective color asphalt Download PDFInfo
- Publication number
- CN108530831A CN108530831A CN201810290009.9A CN201810290009A CN108530831A CN 108530831 A CN108530831 A CN 108530831A CN 201810290009 A CN201810290009 A CN 201810290009A CN 108530831 A CN108530831 A CN 108530831A
- Authority
- CN
- China
- Prior art keywords
- parts
- high performance
- color asphalt
- reflective color
- petropols
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of high performance reflective color asphalts, are made of the raw material of following parts by weight：50 55 parts by weight of epoxy resin, 23 25 parts of Petropols, 38 parts of styrene butadiene styrene block copolymer, 35 40 parts of furfural extract oil, 25 parts of dioctyl phthalate, 58 parts of diatomite, 5 12 parts of inorganic pigment, 25 parts of reflectorized material.The present invention can produce the color asphalt of various colors, improve vision, can be widely used in the different places such as street, pavement and landscape road, can not only meet the needs of various places, while can also beautify the environment.The present invention realizes the color asphalt product for being prepared have excellent performance at lower cost by being formulated global design.
Description
Technical field
The present invention relates to technical field of road engineering, more particularly to a kind of high performance reflective color asphalt.
Background technology
Elasticity of the Colorful Asphalt Pavement with asphalt concrete is strong, damping strong and is easy to clean the formedness such as flushing
Can be outer, the monotonicity of plain asphalt road surface black is further improved, can be collocated with each other, coordinate with the building of surrounding, landscape, have
Apparent Landscape benefit.In addition, color asphalt increasingly obtains the organization and management effect of traffic the attention of people.Different colours
Bituminous paving, the recognition effect of driver can be improved, and the attention of driver can also be made more to concentrate, to play
Induce wagon flow, safe driving, the effect for making traffic administration intuitively change.It, can be with such as in the multiple location of Urban Road Traffic Accidents
Driver is intuitively reminded note that driving a vehicle with caution, to a certain extent than vertical traffic sign in making red or yellow road surface
And stroke markings are more preferable on track.
But the performance of existing color asphalt is still to be improved.
Invention content
In order to make up the defect of prior art, the present invention provides a kind of high performance reflective color asphalt.
The technical problems to be solved by the invention are achieved by the following technical programs：
A kind of high performance reflective color asphalt, is made of the raw material of following parts by weight：Epoxy resin 50-55 parts by weight,
23-25 parts of Petropols, 3-8 parts of Styrene-Butadiene-Styrene Block Copolymer, 35-40 parts of furfural extract oil, adjacent benzene two
2-5 parts of formic acid dioctyl ester, 5-8 parts of diatomite, 5-12 parts of inorganic pigment, 2-5 parts of reflectorized material.
Further, inorganic pigment be iron oxide red pigment, chrome green pigment, iron green pigment, titanium dioxide pigment, in chrome yellow extremely
Few one kind.
Further, the reflectorized material is aluminum plating glass microballon and perforated retroreflective glass microballoon according to weight ratio 2:3 groups
At mixture.
Further, the preparation method of the Petropols is：（1）With ethylene unit by-product pyrolysis c9 fraction in vacuum degree
, by rectification under vacuum, to intercept boiling point in 100-150 DEG C of C9 components as raw material A under the conditions of -0.085MPa；With ethylene unit
By-product pyrolysis c9 fraction or pyrolysis C 5 are existed under the conditions of vacuum degree is -0.090MPa by rectification under vacuum, interception boiling point
It is raw material B that 160-175 DEG C of fraction, which obtains dicyclopentadiene DCPD enriched compositions,；Above-mentioned raw materials A and B in mass ratio 2-6: 1 is mixed
Conjunction obtains reaction raw materials C；（2）In the reaction kettle with forced circulation, the reaction raw materials C of said ratio is put into advance, is enabled anti-
It answers material to be reacted 25-30 hours under the conditions of 180-240 DEG C, obtains polymer fluid；（3）Above-mentioned polymer fluid is entered in insulation still,
The composite antioxidant for accounting for polymer fluid mass ratio 2~5 ‰ is put into again, and keeps the temperature 10-15 hours under the conditions of 180-200 DEG C；（4）It will
It is -0.07MPa that the polymer fluid that step (3) obtains, which delivers into top vacuum degree, and the desolventizing that 90~120 DEG C of tower top temperature evaporates tower
Interior carry out solvent removal, control reflux ratio are 2；Tower top obtains solvent of the boiling point at 85-200 DEG C, and bottom of tower obtains resin liquid；（5）
Above-mentioned resin liquid is input into the extracting of row steam distillation, top vacuum degree -0.0850MPa extracts several equal molecules by stripping
Oligomer of the amount less than 400 is to get to Petropols.
Further, preparation method includes the following steps：Furfural extract oil is heated to 160-180 DEG C, then adds stone
Oleoresin, epoxy resin, Styrene-Butadiene-Styrene Block Copolymer stirring, then 120-140 DEG C is cooled to, then add
Dioctyl phthalate is stirred with diatomite, finally adds inorganic pigment and reflectorized material is stirred for can be obtained product.
The present invention has the advantages that：
The present invention can produce the color asphalt of various colors, improve vision, can be widely used in street, pavement and
The different places such as landscape road can not only meet the needs of various places, while can also beautify the environment.
The present invention realizes the color asphalt production for being prepared have excellent performance at lower cost by being formulated global design
Product.
Specific implementation mode
With reference to embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention,
It is not limitation of the invention.
Embodiment 1
A kind of high performance reflective color asphalt, is made of the raw material of following parts by weight：52 parts by weight of epoxy resin, oil
24 parts of resin, 5 parts of Styrene-Butadiene-Styrene Block Copolymer, 38 parts of furfural extract oil, dioctyl phthalate 3
Part, 6 parts of diatomite, 8 parts of inorganic pigment, 3 parts of reflectorized material.
Wherein, inorganic pigment is iron oxide red pigment；The reflectorized material is aluminum plating glass microballon and perforated retroreflective glass microballoon
According to weight ratio 2:The mixture of 3 compositions.
Preparation method includes the following steps：Furfural extract oil is heated to 160-180 DEG C, then add Petropols,
Epoxy resin, Styrene-Butadiene-Styrene Block Copolymer stirring, then 120-140 DEG C is cooled to, then add adjacent benzene two
Formic acid dioctyl ester is stirred with diatomite, finally adds inorganic pigment and reflectorized material is stirred for can be obtained product.
Embodiment 2
A kind of high performance reflective color asphalt, is made of the raw material of following parts by weight：50 parts by weight of epoxy resin, oil
23 parts of resin, 3 parts of Styrene-Butadiene-Styrene Block Copolymer, 35 parts of furfural extract oil, dioctyl phthalate 2
Part, 5 parts of diatomite, 5 parts of inorganic pigment, 2 parts of reflectorized material.
Wherein, inorganic pigment is iron green pigment；The reflectorized material is aluminum plating glass microballon and perforated retroreflective glass microballoon
According to weight ratio 2:The mixture of 3 compositions.
Preparation method includes the following steps：Furfural extract oil is heated to 160-180 DEG C, then add Petropols,
Epoxy resin, Styrene-Butadiene-Styrene Block Copolymer stirring, then 120-140 DEG C is cooled to, then add adjacent benzene two
Formic acid dioctyl ester is stirred with diatomite, finally adds inorganic pigment and reflectorized material is stirred for can be obtained product.
Embodiment 3
A kind of high performance reflective color asphalt, is made of the raw material of following parts by weight：55 parts by weight of epoxy resin, oil
25 parts of resin, 8 parts of Styrene-Butadiene-Styrene Block Copolymer, 40 parts of furfural extract oil, dioctyl phthalate 5
Part, 8 parts of diatomite, 12 parts of inorganic pigment, 5 parts of reflectorized material.
Wherein, inorganic pigment is titanium dioxide pigment；The reflectorized material is aluminum plating glass microballon and perforated retroreflective glass microballoon
According to weight ratio 2:The mixture of 3 compositions.
Preparation method includes the following steps：Furfural extract oil is heated to 160-180 DEG C, then add Petropols,
Epoxy resin, Styrene-Butadiene-Styrene Block Copolymer stirring, then 120-140 DEG C is cooled to, then add adjacent benzene two
Formic acid dioctyl ester is stirred with diatomite, finally adds inorganic pigment and reflectorized material is stirred for can be obtained product.
Embodiments of the present invention above described embodiment only expresses, the description thereof is more specific and detailed, but can not
Therefore it is interpreted as the limitation to the scope of the claims of the present invention, as long as skill obtained in the form of equivalent substitutions or equivalent transformations
Art scheme should all be fallen within the scope and spirit of the invention.
Claims (5)
1. a kind of high performance reflective color asphalt, is made of the raw material of following parts by weight：Epoxy resin 50-55 weight
Part, 23-25 parts of Petropols, 3-8 parts of Styrene-Butadiene-Styrene Block Copolymer, 35-40 parts of furfural extract oil, adjacent benzene
2-5 parts of diformazan dioctyl phthalate, 5-8 parts of diatomite, 5-12 parts of inorganic pigment, 2-5 parts of reflectorized material.
2. high performance reflective color asphalt as described in claim 1, which is characterized in that inorganic pigment is iron oxide red pigment, chromium
At least one of green pigment, iron green pigment, titanium dioxide pigment, chrome yellow.
3. high performance reflective color asphalt as described in claim 1, which is characterized in that the reflectorized material is aluminum plating glass
Microballon and perforated retroreflective glass microballoon are according to weight ratio 2:The mixture of 3 compositions.
4. high performance reflective color asphalt as described in claim 1, which is characterized in that the preparation method of the Petropols
For：（1）Boiling point is intercepted by rectification under vacuum under the conditions of vacuum degree is -0.085MPa with ethylene unit by-product pyrolysis c9 fraction
In 100-150 DEG C of C9 components as raw material A；Be in vacuum degree with ethylene unit by-product pyrolysis c9 fraction or pyrolysis C 5-
Dicyclopentadiene DCPD enriched compositions are obtained in 160-175 DEG C of fraction by rectification under vacuum, interception boiling point under the conditions of 0.090MPa
For raw material B；Above-mentioned raw materials A and B in mass ratio 2-6: 1 is mixed to get reaction raw materials C；（2）In the reaction with forced circulation
In kettle, the reaction raw materials C of said ratio is put into advance, enables reaction mass be reacted 25-30 hours under the conditions of 180-240 DEG C, obtains
To polymer fluid；（3）Above-mentioned polymer fluid is entered in insulation still, then puts into the composite antioxidant for accounting for polymer fluid mass ratio 2~5 ‰,
And keep the temperature 10-15 hours under the conditions of 180-200 DEG C；（4）The polymer fluid that step (3) obtains is delivered into top vacuum degree
For -0.07MPa, the desolventizing that 90~120 DEG C of tower top temperature, which evaporates, carries out solvent removal in tower, control reflux ratio is 2；Tower top obtains
Solvent of the boiling point at 85-200 DEG C, bottom of tower obtains resin liquid；（5）Above-mentioned resin liquid is input into the extracting of row steam distillation, tower top
Vacuum degree -0.0850MPa extracts oligomer of the number-average molecular weight less than 400 to get to Petropols by stripping.
5. high performance reflective color asphalt as described in claim 1, which is characterized in that preparation method includes following step
Suddenly：Furfural extract oil is heated to 160-180 DEG C, then adds Petropols, epoxy resin, s-B-S
Block copolymer stirs, then cools to 120-140 DEG C, then adds dioctyl phthalate and is stirred with diatomite, is finally added
Inorganic pigment and reflectorized material is added to be stirred for can be obtained product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810290009.9A CN108530831A (en) | 2018-03-30 | 2018-03-30 | A kind of high performance reflective color asphalt |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810290009.9A CN108530831A (en) | 2018-03-30 | 2018-03-30 | A kind of high performance reflective color asphalt |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108530831A true CN108530831A (en) | 2018-09-14 |
Family
ID=63482147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810290009.9A Pending CN108530831A (en) | 2018-03-30 | 2018-03-30 | A kind of high performance reflective color asphalt |
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| Country | Link |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101619122A (en) * | 2009-07-29 | 2010-01-06 | 宁波职业技术学院 | Method for preparing m-pentadiene modified DCPD petroleum resin |
| CN107759141A (en) * | 2017-11-23 | 2018-03-06 | 北京国创通畅路桥养护有限公司 | Color asphalt concrete and preparation method thereof |
-
2018
- 2018-03-30 CN CN201810290009.9A patent/CN108530831A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101619122A (en) * | 2009-07-29 | 2010-01-06 | 宁波职业技术学院 | Method for preparing m-pentadiene modified DCPD petroleum resin |
| CN107759141A (en) * | 2017-11-23 | 2018-03-06 | 北京国创通畅路桥养护有限公司 | Color asphalt concrete and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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Application publication date: 20180914 |