CN108517124A - A kind of reflective color asphalt - Google Patents
A kind of reflective color asphalt Download PDFInfo
- Publication number
- CN108517124A CN108517124A CN201810291995.XA CN201810291995A CN108517124A CN 108517124 A CN108517124 A CN 108517124A CN 201810291995 A CN201810291995 A CN 201810291995A CN 108517124 A CN108517124 A CN 108517124A
- Authority
- CN
- China
- Prior art keywords
- parts
- color asphalt
- petropols
- reflective color
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F240/00—Copolymers of hydrocarbons and mineral oils, e.g. petroleum resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08L57/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2251—Oxides; Hydroxides of metals of chromium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of reflective color asphalts, are made of the raw material of following parts by weight：30 38 parts of Petropols, 15 20 parts of aromatic naphtha, 5 10 parts of rubber oil, 5 10 parts of SBR modifying agent, 10 20 parts of inorganic pigment, 25 parts of reflectorized material.The present invention can produce the color asphalt of various colors, improve vision, can be widely used in the different places such as street, pavement and landscape road, can not only meet the needs of various places, while can also beautify the environment.The present invention realizes the color asphalt product for being prepared have excellent performance at lower cost by being formulated global design.
Description
Technical field
The present invention relates to technical field of road engineering, more particularly to a kind of reflective color asphalt.
Background technology
Elasticity of the Colorful Asphalt Pavement with asphalt concrete is strong, damping strong and is easy to clean the formedness such as flushing
Can be outer, the monotonicity of plain asphalt road surface black is further improved, can be collocated with each other, coordinate with the building of surrounding, landscape, have
Apparent Landscape benefit.In addition, color asphalt increasingly obtains the organization and management effect of traffic the attention of people.Different colours
Bituminous paving, the recognition effect of driver can be improved, and the attention of driver can also be made more to concentrate, to play
Induce wagon flow, safe driving, the effect for making traffic administration intuitively change.It, can be with such as in the multiple location of Urban Road Traffic Accidents
Driver is intuitively reminded note that driving a vehicle with caution, to a certain extent than vertical traffic sign in making red or yellow road surface
And stroke markings are more preferable on track.
But the performance of existing color asphalt is still to be improved.
Invention content
In order to make up the defect of prior art, the present invention provides a kind of reflective color asphalt.
The technical problems to be solved by the invention are achieved by the following technical programs：
A kind of reflective color asphalt, is made of the raw material of following parts by weight：30-38 parts of Petropols, aromatic naphtha 15-20
Part, 5-10 parts of rubber oil, 5-10 parts of SBR modifying agent, 10-20 parts of inorganic pigment, 2-5 parts of reflectorized material.
Further, machine pigment be iron oxide red pigment, chrome green pigment, iron green pigment, titanium dioxide pigment, in chrome yellow at least
It is a kind of.
Further, the reflectorized material is aluminum plating glass microballon and perforated retroreflective glass microballoon according to weight ratio 2:3 groups
At mixture.
Further, the preparation method of the Petropols is：（1）With ethylene unit by-product pyrolysis c9 fraction in vacuum degree
, by rectification under vacuum, to intercept boiling point in 100-150 DEG C of C9 components as raw material A under the conditions of -0.085MPa；With ethylene unit
By-product pyrolysis c9 fraction or pyrolysis C 5 are existed under the conditions of vacuum degree is -0.090MPa by rectification under vacuum, interception boiling point
It is raw material B that 160-175 DEG C of fraction, which obtains dicyclopentadiene DCPD enriched compositions,；Above-mentioned raw materials A and B in mass ratio 2-6: 1 is mixed
Conjunction obtains reaction raw materials C；（2）In the reaction kettle with forced circulation, the reaction raw materials C of said ratio is put into advance, is enabled anti-
It answers material to be reacted 25-30 hours under the conditions of 180-240 DEG C, obtains polymer fluid；（3）Above-mentioned polymer fluid is entered in insulation still,
The composite antioxidant for accounting for polymer fluid mass ratio 2~5 ‰ is put into again, and keeps the temperature 10-15 hours under the conditions of 180-200 DEG C；（4）It will
It is -0.07MPa that the polymer fluid that step (3) obtains, which delivers into top vacuum degree, and the desolventizing that 90~120 DEG C of tower top temperature evaporates tower
Interior carry out solvent removal, control reflux ratio are 2；Tower top obtains solvent of the boiling point at 85-200 DEG C, and bottom of tower obtains resin liquid；（5）
Above-mentioned resin liquid is input into the extracting of row steam distillation, top vacuum degree -0.0850MPa extracts several equal molecules by stripping
Oligomer of the amount less than 400 is to get to Petropols.
Further, preparation method includes the following steps：（1）Aromatic naphtha is added according to the parts by weight, is heated to
Under the conditions of 165-190 DEG C, the stirring melting of SBR modifying agent is added, Petropols, rubber oil are added after being completely dissolved, is eventually adding
Inorganic pigment and reflectorized material, are uniformly mixed.
The present invention has the advantages that：
The present invention can produce the color asphalt of various colors, improve vision, can be widely used in street, pavement and
The different places such as landscape road can not only meet the needs of various places, while can also beautify the environment.
The present invention realizes the color asphalt production for being prepared have excellent performance at lower cost by being formulated global design
Product.
Specific implementation mode
With reference to embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention,
It is not limitation of the invention.
Embodiment 1
A kind of reflective color asphalt, is made of the raw material of following parts by weight：34 parts of Petropols, 18 parts of aromatic naphtha, rubber
8 parts of oil, 8 parts of SBR modifying agent, 15 parts of inorganic pigment, 3 parts of reflectorized material.
Wherein, machine pigment is iron oxide red pigment；The reflectorized material is that aluminum plating glass microballon and perforated retroreflective glass microballoon are pressed
According to weight ratio 2:The mixture of 3 compositions.
Preparation method includes the following steps：（1）Aromatic naphtha is added according to the parts by weight, is heated to 165-190 DEG C
Under the conditions of, be added SBR modifying agent stirring melting, after being completely dissolved be added Petropols, rubber oil, be eventually adding inorganic pigment and
Reflectorized material is uniformly mixed.
Embodiment 2
A kind of reflective color asphalt, is made of the raw material of following parts by weight：30 parts of Petropols, 15 parts of aromatic naphtha, rubber
5 parts of oil, 5 parts of SBR modifying agent, 10 parts of inorganic pigment, 2 parts of reflectorized material.
Wherein, machine pigment is iron green pigment；The reflectorized material is that aluminum plating glass microballon and perforated retroreflective glass microballoon are pressed
According to weight ratio 2:The mixture of 3 compositions.
Preparation method includes the following steps：（1）Aromatic naphtha is added according to the parts by weight, is heated to 165-190 DEG C
Under the conditions of, be added SBR modifying agent stirring melting, after being completely dissolved be added Petropols, rubber oil, be eventually adding inorganic pigment and
Reflectorized material is uniformly mixed.
Embodiment 3
A kind of reflective color asphalt, is made of the raw material of following parts by weight：38 parts of Petropols, 20 parts of aromatic naphtha, rubber
10 parts of oil, 10 parts of SBR modifying agent, 20 parts of inorganic pigment, 5 parts of reflectorized material.
Wherein, machine pigment is chrome yellow；The reflectorized material is that aluminum plating glass microballon and perforated retroreflective glass microballoon are pressed
According to weight ratio 2:The mixture of 3 compositions.
Preparation method includes the following steps：（1）Aromatic naphtha is added according to the parts by weight, is heated to 165-190 DEG C
Under the conditions of, be added SBR modifying agent stirring melting, after being completely dissolved be added Petropols, rubber oil, be eventually adding inorganic pigment and
Reflectorized material is uniformly mixed.
Embodiments of the present invention above described embodiment only expresses, the description thereof is more specific and detailed, but can not
Therefore it is interpreted as the limitation to the scope of the claims of the present invention, as long as skill obtained in the form of equivalent substitutions or equivalent transformations
Art scheme should all be fallen within the scope and spirit of the invention.
Claims (5)
1. a kind of reflective color asphalt, is made of the raw material of following parts by weight：30-38 parts of Petropols, aromatic naphtha 15-20
Part, 5-10 parts of rubber oil, 5-10 parts of SBR modifying agent, 10-20 parts of inorganic pigment, 2-5 parts of reflectorized material.
2. reflective color asphalt as described in claim 1, which is characterized in that the inorganic pigment is iron oxide red pigment, chrome green face
At least one of material, iron green pigment, titanium dioxide pigment, chrome yellow.
3. reflective color asphalt as described in claim 1, which is characterized in that the reflectorized material is aluminum plating glass microballon and more
Hole reflective glass beads are according to weight ratio 2:The mixture of 3 compositions.
4. reflective color asphalt as described in claim 1, which is characterized in that the preparation method of the Petropols is：（1）With
Ethylene unit by-product pyrolysis c9 fraction is by rectification under vacuum under the conditions of vacuum degree is -0.085MPa, and interception boiling point is in 100-150
DEG C C9 components as raw material A；With ethylene unit by-product pyrolysis c9 fraction or pyrolysis C 5 in vacuum degree for -0.090MPa items
Dicyclopentadiene DCPD enriched compositions are obtained as raw material B in 160-175 DEG C of fraction by rectification under vacuum, interception boiling point under part；It will
Above-mentioned raw materials A and B in mass ratio 2-6: 1 is mixed to get reaction raw materials C；（2）In the reaction kettle with forced circulation, throw in advance
The reaction raw materials C for entering said ratio enables reaction mass be reacted 25-30 hours under the conditions of 180-240 DEG C, obtains polymer fluid；（3）
Above-mentioned polymer fluid is entered in insulation still, then puts into the composite antioxidant for accounting for polymer fluid mass ratio 2~5 ‰, and at 180-200 DEG C
Under the conditions of keep the temperature 10-15 hours；（4）It is -0.07MPa, tower top that the polymer fluid that step (3) obtains, which is delivered into top vacuum degree,
The desolventizing that 90~120 DEG C of temperature, which evaporates, carries out solvent removal in tower, control reflux ratio is 2；Tower top obtains boiling point at 85-200 DEG C
Solvent, bottom of tower obtains resin liquid；（5）Above-mentioned resin liquid is input into the extracting of row steam distillation, top vacuum degree-
0.0850MPa extracts oligomer of the number-average molecular weight less than 400 to get to Petropols by stripping.
5. reflective color asphalt as described in claim 1, which is characterized in that preparation method includes the following steps：（1）According to
Aromatic naphtha is added in the parts by weight, is heated under the conditions of 165-190 DEG C, the stirring melting of SBR modifying agent is added, after being completely dissolved
Petropols, rubber oil is added, is eventually adding inorganic pigment and reflectorized material, is uniformly mixed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810291995.XA CN108517124A (en) | 2018-03-30 | 2018-03-30 | A kind of reflective color asphalt |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810291995.XA CN108517124A (en) | 2018-03-30 | 2018-03-30 | A kind of reflective color asphalt |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108517124A true CN108517124A (en) | 2018-09-11 |
Family
ID=63431165
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810291995.XA Pending CN108517124A (en) | 2018-03-30 | 2018-03-30 | A kind of reflective color asphalt |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108517124A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101619122A (en) * | 2009-07-29 | 2010-01-06 | 宁波职业技术学院 | Method for preparing m-pentadiene modified DCPD petroleum resin |
| CN106633606A (en) * | 2016-10-13 | 2017-05-10 | 上海浦东路桥建设股份有限公司 | Colored asphalt cementing material suitable for heavy traffic and preparation method thereof |
| CN106674877A (en) * | 2017-01-20 | 2017-05-17 | 河南九环保科技股份有限公司 | Normal-temperature-mixed colored asphalt and preparation method thereof |
-
2018
- 2018-03-30 CN CN201810291995.XA patent/CN108517124A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101619122A (en) * | 2009-07-29 | 2010-01-06 | 宁波职业技术学院 | Method for preparing m-pentadiene modified DCPD petroleum resin |
| CN106633606A (en) * | 2016-10-13 | 2017-05-10 | 上海浦东路桥建设股份有限公司 | Colored asphalt cementing material suitable for heavy traffic and preparation method thereof |
| CN106674877A (en) * | 2017-01-20 | 2017-05-17 | 河南九环保科技股份有限公司 | Normal-temperature-mixed colored asphalt and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180911 |
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| RJ01 | Rejection of invention patent application after publication |