CN108530762A - 一种抗菌防臭棉拖鞋双组分鞋底材料 - Google Patents

一种抗菌防臭棉拖鞋双组分鞋底材料 Download PDF

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CN108530762A
CN108530762A CN201710119400.8A CN201710119400A CN108530762A CN 108530762 A CN108530762 A CN 108530762A CN 201710119400 A CN201710119400 A CN 201710119400A CN 108530762 A CN108530762 A CN 108530762A
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parts
component
sole
shoe
cotton baboosh
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葛胜超
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East Asia Nanjing Product Of Rubber And Plastic Co Ltd
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East Asia Nanjing Product Of Rubber And Plastic Co Ltd
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    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/02—Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04—Plastics, rubber or vulcanised fibre
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/246—Intercrosslinking of at least two polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04—Polysiloxanes
    • C08J2383/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2445/00—Characterised by the use of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Derivatives of such polymers
    • C08J2445/02—Characterised by the use of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Derivatives of such polymers of coumarone-indene polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明提供的一种抗菌防臭棉拖鞋双组分鞋底材料，包括质量比(5.6‑5.9):1的组份A和组份B；其中，所述组份A由以下重量比的组份制成：氟橡胶21.9‑27.8份、二叔丁基过氧化物21.9‑27.8份、癸二酸二辛酯3.2‑5.6份、固体古马隆树脂11.6‑18.9份、聚二甲基硅油11.6‑18.9份、N‑苯基‑N'‑基对苯二胺1.1‑2.6份；所述组份B由以下重量份的组份制成：三元乙丙橡胶21.9‑27.8份、赤泥11.6‑18.9份、辅助稳定剂1.1‑2.6份、润滑剂1.1‑2.6份、脂肪族多硫化物1.1‑2.6份、壬二酸二辛酯11.6‑18.9份、新工艺高耐磨碳黑1.1‑2.6份、氢氧化钙1～3份。该双组分鞋底材料制备工艺简单、成本低廉、透气性好、弹性佳，可适用于棉拖鞋鞋底。

Description

一种抗菌防臭棉拖鞋双组分鞋底材料
技术领域
本发明属于日用品领域，特别涉及一种抗菌防臭棉拖鞋双组分鞋底材料及其制备方法。
背景技术
双组分鞋底材料的种类很多，一般分为天然类双组分鞋底材料和合成类双组分鞋底材料两种。天然类双组分鞋底材料包括天然底革、竹、木材等，合成类双组分鞋底材料包括橡胶、PU材料、三元乙丙橡胶合成树脂等。双组分鞋底材料共通的特性具备耐磨、耐水、弹性好、容易适合脚型、定型后不易变形等等条件。目前合成类双组分鞋底材料是应用最广泛的一类鞋材。
棉拖鞋极易滋生细菌，导致不卫生，且会发出臭味。
发明内容
技术问题：为了解决现有技术的缺陷，本发明提供了一种抗菌防臭棉拖鞋双组分鞋底材料。
技术方案：本发明提供的一种抗菌防臭棉拖鞋双组分鞋底材料，包括质量比(5.6-5.9):1的组份A和组份B；其中，所述组份A由以下重量比的组份制成：氟橡胶21.9-27.8份、二叔丁基过氧化物21.9-27.8份、癸二酸二辛酯3.2-5.6份、固体古马隆树脂11.6-18.9份、聚二甲基硅油11.6-18.9份、N-苯基-N'-基对苯二胺1.1-2.6份；所述组份B由以下重量份的组份制成：三元乙丙橡胶21.9-27.8份、赤泥11.6-18.9份、辅助稳定剂1.1-2.6份、润滑剂1.1-2.6份、脂肪族多硫化物1.1-2.6份、壬二酸二辛酯11.6-18.9份、新工艺高耐磨碳黑1.1-2.6份、氢氧化钙1～3份。
作为改进，所述抗菌防臭棉拖鞋双组分鞋底材料包括质量比3:1的组份A和组份B；其中，所述组份A由以下重量比的组份制成：氟橡胶25份、二叔丁基过氧化物25份、癸二酸二辛酯7份、固体古马隆树脂15份、聚二甲基硅油15份、N-苯基-N'-基对苯二胺2份；所述组份B由以下重量份的组份制成：三元乙丙橡胶25份、赤泥15份、辅助稳定剂2份、润滑剂2份、脂肪族多硫化物2份、壬二酸二辛酯15份、新工艺高耐磨碳黑2份、氢氧化钙2份。
本发明还提供了一种抗菌防臭棉拖鞋双组分鞋底材料的制备方法，包括以下步骤：
(1)将组份A的各组分按比例称量、混匀；将组份B的各组分按比例称量、混匀；
(2)将组分A中各组分加入高压釜中，在60-70℃下，反应2-3h，冷却至室温，得到预聚体；
(3)将预聚体和2/3的组分B混合均匀；加入鞋底浇注机料罐中，升温至60-70℃，恒温3.2-5.6min；降温至55-60℃，继续加入剩余的1/3的组份B，恒温11.6-18.9min；
(4)将步骤(3)产品在鞋底模具上涂脱模剂、吹干、浇注，保温10-12min，脱模，即得。
有益效果：本发明提供的双组分鞋底材料制备工艺简单、成本低廉、透气性好、弹性佳、重量轻、柔软性好、能够有效防臭，可适用于棉拖鞋鞋底。
具体实施方式
下面对本发明抗菌防臭棉拖鞋双组分鞋底材料作出进一步说明。
抗菌防臭棉拖鞋双组分鞋底材料，包括质量比1:2的组份A和组份B；其中，所述组份A由以下重量比的组份制成：氟橡胶25份、二叔丁基过氧化物25份、癸二酸二辛酯7份、固体古马隆树脂15份、聚二甲基硅油15份、N-苯基-N'-基对苯二胺2份；所述组份B由以下重量份的组份制成：三元乙丙橡胶25份、赤泥15份、辅助稳定剂2份、润滑剂2份、脂肪族多硫化物2份、壬二酸二辛酯15份、新工艺高耐磨碳黑2份、氢氧化钙2份。
其制备方法，包括以下步骤：
(1)将组份A的各组分按比例称量、混匀；将组份B的各组分按比例称量、混匀；
(2)将组分A中各组分加入高压釜中，在60-70℃下，反应2-3h，冷却至室温，得到预聚体；
(3)将预聚体和2/3的组分B混合均匀；加入鞋底浇注机料罐中，升温至60-70℃，恒温3.2-5.6min；降温至55-60℃，继续加入剩余的1/3的组份B，恒温11.6-18.9min；
(4)将步骤(3)产品在鞋底模具上涂脱模剂、吹干、浇注，保温10-12min，脱模，即得。

Claims (2)

1.一种抗菌防臭棉拖鞋双组分鞋底材料，其特征在于：包括质量比(5.6-5.9):1的组份A和组份B；其中，所述组份A由以下重量比的组份制成：氟橡胶21.9-27.8份、二叔丁基过氧化物21.9-27.8份、癸二酸二辛酯3.2-5.6份、固体古马隆树脂11.6-18.9份、聚二甲基硅油11.6-18.9份、N-苯基-N'-基对苯二胺1.1-2.6份；所述组份B由以下重量份的组份制成：三元乙丙橡胶21.9-27.8份、赤泥11.6-18.9份、辅助稳定剂1.1-2.6份、润滑剂1.1-2.6份、脂肪族多硫化物1.1-2.6份、壬二酸二辛酯11.6-18.9份、新工艺高耐磨碳黑1.1-2.6份、氢氧化钙1～3份。
2.根据权利要求1所述的一种抗菌防臭棉拖鞋双组分鞋底材料，其特征在于：包括质量比3:1的组份A和组份B；其中，所述组份A由以下重量比的组份制成：氟橡胶25份、二叔丁基过氧化物25份、癸二酸二辛酯7份、固体古马隆树脂15份、聚二甲基硅油15份、N-苯基-N'-基对苯二胺2份；所述组份B由以下重量份的组份制成：三元乙丙橡胶25份、赤泥15份、辅助稳定剂2份、润滑剂2份、脂肪族多硫化物2份、壬二酸二辛酯15份、新工艺高耐磨碳黑2份、氢氧化钙2份。
CN201710119400.8A 2017-03-02 2017-03-02 一种抗菌防臭棉拖鞋双组分鞋底材料 Pending CN108530762A (zh)

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