CN108504287A - The production method for the multicolor finish scraped can be criticized - Google Patents

The production method for the multicolor finish scraped can be criticized Download PDF

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Publication number
CN108504287A
CN108504287A CN201810248883.6A CN201810248883A CN108504287A CN 108504287 A CN108504287 A CN 108504287A CN 201810248883 A CN201810248883 A CN 201810248883A CN 108504287 A CN108504287 A CN 108504287A
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parts
added
blender
base
scraped
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CN201810248883.6A
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Inventor
尹东林
马克军
吴祖青
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Anhui Dongtai Architectural Decoration Material Co Ltd
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Anhui Dongtai Architectural Decoration Material Co Ltd
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Priority to CN201810248883.6A priority Critical patent/CN108504287A/en
Publication of CN108504287A publication Critical patent/CN108504287A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/43Thickening agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses the production methods that can criticize the multicolor finish scraped, and include the following steps:S1, polyvinyl alcohol and cellulose are added in grinder grind according to proportioning, pulverize it is last be added in blender, and water is added, stirring is all soluble in water to powder;S2, Jiang Shui, precipitated calcium carbonate, dispersant and resin are added blender and are dispersed with stirring, and add coalescents, antifoaming agent, are stood after stirring, add talcum powder, fungicide, thickener, PH conditioning agents, and base paint is made after stirring;S3, base paint obtained is taken, is mixed with pigment and acrylic acid ester emulsion and blender is added, stirs evenly obtained mill base, then the mill base stirred evenly is poured into sand mill and is ground;S4, protection sol solution is added in blender, mill base is sieved into protection sol solution using sieve, base paint is added, levelling agent is added in whipping process, be made coating, dope viscosity and adhesion made of the present invention are good, not only sprayable, can also criticize and scrape construction.

Description

The production method for the multicolor finish scraped can be criticized
Technical field
The present invention relates to technical field of coatings, more particularly to can criticize the production method for the multicolor finish scraped.
Background technology
Multicolor finish, which is mainly used in, copys stone material effect, so also known as liquid stone, is also horizon exterior coating.It is by not Compatible two phase constituents composition, wherein a phase decentralized medium is continuous phase, another phase is dispersed phase, when application, by disposable Spraying can obtain luxurious, beautiful, colorful pattern, however common coating can only use spraying, and cannot criticize and scrape, and not have It can not work in the case of flush coater.
Therefore, we have proposed can criticize the production method for the multicolor finish scraped for solving the above problems.
Invention content
The purpose of the present invention is to solve disadvantages existing in the prior art, and what is proposed can criticize the multicolor finish scraped Production method.
The production method for the multicolor finish scraped can be criticized, which is characterized in that include the following steps:
S1, the preparation for protecting sol solution:10-20 parts of polyvinyl alcohol and 1-2 parts of celluloses are added in grinder according to proportioning Grind 5-10min, be fully ground into it is powdered after powder is added in blender again, and 180-190 part water are added, stir extremely Powder is all soluble in water;
The preparation of S2, base paint:By 160-210 parts of water, 180-200 parts of precipitated calcium carbonates, 5-8 parts of dispersants and 25-28 parts of trees Blender is added in fat, is dispersed with stirring using the rotating speed of 150-200r/min, continues 3-5min, sequentially adds 2-5 parts of film forming and help Agent, 1.1-2.2 parts of antifoaming agent, using 300-350r/min rotating speed rotate 5-6min, stand 0.5-1min after, blender again 2-4.8 parts of talcum powder, 1.5-2 parts of fungicide, 1-5 parts of thickeners, 1.2-2.5 parts of PH conditioning agents are added, use 400-500r/ The rotating speed of min stirs 10-15min, and base paint is made;
The preparation of S3, mill base:100-110 parts of base paint obtained is taken, pigment and 10-13 part acrylate breast with 10-12 parts Blender is added in liquid mixing, until stirring evenly, mill base is made, then the mill base stirred evenly is poured into sand mill and is ground;
S4, colored paint are granulated:Will before protection sol solution obtained take 30-40 parts to be added in blender, using sieve by 35-45 The mill base of part is sieved into protection sol solution, adds 90-100 parts of base paint, and the rotating speed of 300-400r/min is used to run 5- 1.2-1.5 parts of levelling agents are added in whipping process, coating is made by 10min.
Preferably, the raw material of the base paint is as follows by proportion by weight:340-400 parts of water, 10-20 parts of polyvinyl alcohol, 1-2 parts of cellulose, 180-200 parts of precipitated calcium carbonate, 25-28 parts of resin, 1.2-1.5 parts of levelling agent, 10-12 parts of pigment, talcum 2-4.8 parts of powder, 2-5 parts of coalescents, 1.1-2.2 parts of antifoaming agent, 1.5-2 parts of fungicide, 1-5 parts of thickener, dispersant 5-8 Part, 1.2-2.5 parts of PH conditioning agents.
Preferably, the mesh number for screening the sieve of mill base is 500-1340 mesh.
Preferably, the coalescents are propandiol butyl ether or propylene glycol methyl ether acetate, and thickener is polyacrylamide Or hydroxyethyl cellulose, fungicide are isothiazolinone or benzoisothiazolinone, levelling agent is that polyacrylic acid or carboxymethyl are fine Dimension element, antifoaming agent are organic polyether ester or mineral oil.
Preferably, abrasive media zirconium pearl, milling time 30-35min are added in the grinder.
The beneficial effects of the invention are as follows:
1, the present invention keeps obtained coating finer and smoother, smooth, film formation time is more fast by being filtered screening to mill base Speed.
2, the present invention makes coating obtained increase vicidity, prevents from constructing by the proportioning of change thickener and talcum powder In there is sagging phenomenon, while assigning the excellent mechanical performance of coating, bin stability and film adhesive, you can spraying is applied Work can also be criticized and scrape construction.
Specific implementation mode
The present invention is made further to explain with reference to specific embodiment.
Embodiment one
S1, the preparation for protecting sol solution:10 parts of polyvinyl alcohol and 1 part of cellulose are added in grinder and are ground according to proportioning 5min, be fully ground into it is powdered after powder is added in blender again, and be added 180 parts of water, stirring it is all molten to powder Yu Shuizhong;
The preparation of S2, base paint:Blender is added in 160 parts of water, 180 parts of precipitated calcium carbonates, 5 parts of dispersants and 25 parts of resins, It is dispersed with stirring using the rotating speed of 150r/min, continues 3min, sequentially add 2 parts as the propandiol butyl ether of coalescents or third Glycol methyl ether acetate, 1.1 parts of organic polyether esters or mineral oil as antifoaming agent, the rotation of the rotating speed using 300r/min 5min adds 2 parts of talcum powder, 1 part of isothiazolinone or benzisothia as fungicide after standing 0.5min in blender Oxazoline ketone, 1 part of polyacrylamide or hydroxyethyl cellulose, 1.2 parts of PH conditioning agents as thickener use turning for 400r/min Speed stirring 10min, is made base paint;
The preparation of S3, mill base:100 parts of base paint obtained is taken, addition is mixed with 10 parts of pigment and 10 parts of acrylic acid ester emulsions Until stirring evenly mill base is made, then the mill base stirred evenly is poured into sand mill and is ground in blender;
S4, colored paint are granulated:30 parts will be taken to be added in blender by protection sol solution obtained before, it will using the sieve of 500 mesh 35 parts of mill base is sieved into protection sol solution, adds 90 parts of base paint, is run 10min using the rotating speed of 400r/min, is stirred 1.2 parts of polyacrylic acid or carboxymethyl cellulose as levelling agent are added during mixing, coating is made.
Embodiment two
S1, the preparation for protecting sol solution:13 parts of polyvinyl alcohol and 1 part of cellulose are added in grinder and are ground according to proportioning 6min, be fully ground into it is powdered after powder is added in blender again, and be added 182 parts of water, stirring it is all molten to powder Yu Shuizhong;
The preparation of S2, base paint:Blender is added in 170 parts of water, 190 parts of precipitated calcium carbonates, 6 parts of dispersants and 26 parts of resins, It is dispersed with stirring using the rotating speed of 160r/min, continues 4min, sequentially add 3 parts as the propandiol butyl ether of coalescents or third Glycol methyl ether acetate, 1.3 parts of organic polyether esters or mineral oil as antifoaming agent, the rotation of the rotating speed using 310r/min 6min adds 2.4 parts of talcum powder, 1.7 parts of isothiazolinone or benzo as fungicide after standing 0.6min in blender Isothiazolinone, 2 parts of polyacrylamide or hydroxyethyl cellulose, 1.4 parts of PH conditioning agents as thickener, use 420r/min Rotating speed stir 11min, be made base paint;
The preparation of S3, mill base:110 parts of base paint obtained is taken, addition is mixed with 12 parts of pigment and 13 parts of acrylic acid ester emulsions Until stirring evenly mill base is made, then the mill base stirred evenly is poured into sand mill and is ground in blender;
S4, colored paint are granulated:40 parts will be taken to be added in blender by protection sol solution obtained before, it will using the sieve of 1340 mesh 45 parts of mill base is sieved into protection sol solution, adds 100 parts of base paint, is run 5min using the rotating speed of 300r/min, is stirred 1.5 parts of polyacrylic acid or carboxymethyl cellulose as levelling agent are added during mixing, coating is made.
Embodiment three
S1, the preparation for protecting sol solution:16 parts of polyvinyl alcohol and 1 part of cellulose are added in grinder and are ground according to proportioning 5min, be fully ground into it is powdered after powder is added in blender again, and be added 180 parts of water, stirring it is all molten to powder Yu Shuizhong;
The preparation of S2, base paint:Blender is added in 210 parts of water, 200 parts of precipitated calcium carbonates, 8 parts of dispersants and 28 parts of resins, It is dispersed with stirring using the rotating speed of 200r/min, continues 4min, sequentially add 5 parts as the propandiol butyl ether of coalescents or third Glycol methyl ether acetate, 1.6 parts of organic polyether esters or mineral oil as antifoaming agent, the rotation of the rotating speed using 350r/min 6min adds 4.8 parts of talcum powder, 1.8 parts of isothiazolinone or benzisoxa as fungicide after standing 1min in blender Thiazolinone, 1 part of polyacrylamide or hydroxyethyl cellulose, 1.5 parts of PH conditioning agents as thickener, use 500r/min's Rotating speed stirs 15min, and base paint is made;
The preparation of S3, mill base:110 parts of base paint obtained is taken, addition is mixed with 12 parts of pigment and 13 parts of acrylic acid ester emulsions Until stirring evenly mill base is made, then the mill base stirred evenly is poured into sand mill and is ground in blender;
S4, colored paint are granulated:30 parts will be taken to be added in blender by protection sol solution obtained before, it will using the sieve of 500 mesh 35 parts of mill base is sieved into protection sol solution, adds 100 parts of base paint, is run 5min using the rotating speed of 450r/min, is stirred 1.5 parts of polyacrylic acid or carboxymethyl cellulose as levelling agent are added during mixing, coating is made.
Example IV
S1, the preparation for protecting sol solution:10 parts of polyvinyl alcohol and 1 part of cellulose are added in grinder and are ground according to proportioning 10min, be fully ground into it is powdered after powder is added in blender again, and be added 180 parts of water, stirring it is all molten to powder Yu Shuizhong;
The preparation of S2, base paint:Blender is added in 160 parts of water, 180 parts of precipitated calcium carbonates, 5 parts of dispersants and 25 parts of resins, It is dispersed with stirring using the rotating speed of 200r/min, continues 5min, sequentially add 2 parts as the propandiol butyl ether of coalescents or third Glycol methyl ether acetate, 1.1 parts of organic polyether esters or mineral oil as antifoaming agent, the rotation of the rotating speed using 350r/min 6min adds 2 parts of talcum powder, 1.5 parts of isothiazolinone or benzisothia as fungicide after standing 1min in blender Oxazoline ketone, 5 parts of polyacrylamide or hydroxyethyl cellulose, 1.2 parts of PH conditioning agents as thickener use turning for 500r/min Speed stirring 15min, is made base paint;
The preparation of S3, mill base:100 parts of base paint obtained is taken, addition is mixed with 10 parts of pigment and 10 parts of acrylic acid ester emulsions Until stirring evenly mill base is made, then the mill base stirred evenly is poured into sand mill and is ground in blender;
S4, colored paint are granulated:30 parts will be taken to be added in blender by protection sol solution obtained before, it will using the sieve of 1340 mesh 45 parts of mill base is sieved into protection sol solution, adds 90 parts of base paint, is run 10min using the rotating speed of 400r/min, is stirred 1.2 parts of polyacrylic acid or carboxymethyl cellulose as levelling agent are added during mixing, coating is made.
To the multicolor finish progressive scraped can be criticized made of embodiment one, embodiment two, embodiment three and example IV It can test, it is as a result as follows:
Testing result is shown:The multicolor finish viscosity height scraped can be criticized made of example IV, film adhesive is big, and covering power By force, the example IV is highly preferred embodiment of the present invention.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (5)

1. the production method for the multicolor finish scraped can be criticized, which is characterized in that include the following steps:
S1, the preparation for protecting sol solution:10-20 parts of polyvinyl alcohol and 1-2 parts of celluloses are added in grinder according to proportioning Grind 5-10min, be fully ground into it is powdered after powder is added in blender again, and 180-190 part water are added, stir extremely Powder is all soluble in water;
The preparation of S2, base paint:By 160-210 parts of water, 180-200 parts of precipitated calcium carbonates, 5-8 parts of dispersants and 25-28 parts of trees Blender is added in fat, is dispersed with stirring using the rotating speed of 150-200r/min, continues 3-5min, sequentially adds 2-5 parts of film forming and help Agent, 1.1-2.2 parts of antifoaming agent, using 300-350r/min rotating speed rotate 5-6min, stand 0.5-1min after, blender again 2-4.8 parts of talcum powder, 1.5-2 parts of fungicide, 1-2 parts of thickeners, 1.2-2.5 parts of PH conditioning agents are added, use 400-500r/ The rotating speed of min stirs 10-15min, and base paint is made;
The preparation of S3, mill base:100-110 parts of base paint obtained is taken, pigment and 10-13 part acrylate breast with 10-12 parts Blender is added in liquid mixing, until stirring evenly, mill base is made, then the mill base stirred evenly is poured into sand mill and is ground;
S4, colored paint are granulated:Will before protection sol solution obtained take 30-40 parts to be added in blender, using sieve by 35-45 The mill base of part is sieved into protection sol solution, adds 90-100 parts of base paint, and the rotating speed of 300-400r/min is used to run 5- 1.2-1.5 parts of levelling agents are added in whipping process, coating is made by 10min.
2. the production method according to claim 1 that the multicolor finish scraped can be criticized, which is characterized in that the base paint Raw material is as follows by proportion by weight:340-400 parts of water, 10-20 parts of polyvinyl alcohol, 1-2 parts of cellulose, precipitated calcium carbonate 180- 200 parts, 25-28 parts of resin, 1.2-1.5 parts of levelling agent, 10-12 parts of pigment, 2-4.8 parts of talcum powder, 2-5 parts of coalescents, disappear 1.1-2.2 parts of infusion, 1.5-2 parts of fungicide, 1-5 parts of thickener, 5-8 parts of dispersant, 1.2-2.5 parts of PH conditioning agents.
3. the production method according to claim 1 that the multicolor finish scraped can be criticized, which is characterized in that described for screening The mesh number of the sieve of mill base is 500-1340 mesh.
4. the production method according to claim 1 that the multicolor finish scraped can be criticized, which is characterized in that the coalescents For propandiol butyl ether or propylene glycol methyl ether acetate, thickener is polyacrylamide or hydroxyethyl cellulose, and fungicide is different thiophene Oxazoline ketone or benzoisothiazolinone, levelling agent are polyacrylic acid or carboxymethyl cellulose, and antifoaming agent is organic polyether ester or mine Object oil.
5. the production method according to claim 1 that the multicolor finish scraped can be criticized, which is characterized in that in the grinder Added with abrasive media zirconium pearl, milling time 30-35min.
CN201810248883.6A 2018-03-25 2018-03-25 The production method for the multicolor finish scraped can be criticized Pending CN108504287A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111892876A (en) * 2020-08-11 2020-11-06 河北品致涂料有限公司 Batch-scraping type multicolor paint and construction process thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101429368A (en) * 2008-12-06 2009-05-13 王月琴 Method for producing water type multicolor paint for water drum
CN101845260A (en) * 2010-03-10 2010-09-29 杭州德尔福涂料有限公司 Full-aqueous multicolour paint and preparation method thereof
CN106147467A (en) * 2015-04-01 2016-11-23 山西亮龙涂料有限公司 A kind of water-soluble colorful coating and preparation technology thereof
CN106398366A (en) * 2016-08-30 2017-02-15 徐州聪慧装饰装潢工程有限公司 Self-leveling water-based colorful composite floor paint
CN107446449A (en) * 2017-07-27 2017-12-08 芜湖市三山龙城新材料有限公司 Colorful imitation marble paint and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101429368A (en) * 2008-12-06 2009-05-13 王月琴 Method for producing water type multicolor paint for water drum
CN101845260A (en) * 2010-03-10 2010-09-29 杭州德尔福涂料有限公司 Full-aqueous multicolour paint and preparation method thereof
CN106147467A (en) * 2015-04-01 2016-11-23 山西亮龙涂料有限公司 A kind of water-soluble colorful coating and preparation technology thereof
CN106398366A (en) * 2016-08-30 2017-02-15 徐州聪慧装饰装潢工程有限公司 Self-leveling water-based colorful composite floor paint
CN107446449A (en) * 2017-07-27 2017-12-08 芜湖市三山龙城新材料有限公司 Colorful imitation marble paint and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111892876A (en) * 2020-08-11 2020-11-06 河北品致涂料有限公司 Batch-scraping type multicolor paint and construction process thereof

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Application publication date: 20180907