CN108467956B - 一种Si/La15Fe2Ni72Mn7B2Mo2复合储氢合金材料的制备方法 - Google Patents
一种Si/La15Fe2Ni72Mn7B2Mo2复合储氢合金材料的制备方法 Download PDFInfo
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- CN108467956B CN108467956B CN201810240909.2A CN201810240909A CN108467956B CN 108467956 B CN108467956 B CN 108467956B CN 201810240909 A CN201810240909 A CN 201810240909A CN 108467956 B CN108467956 B CN 108467956B
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- alloy
- hydrogen occluding
- composite hydrogen
- powder
- alloy material
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- 239000000956 alloy Substances 0.000 title claims abstract description 91
- 239000002131 composite material Substances 0.000 title claims abstract description 38
- 239000001257 hydrogen Substances 0.000 title claims abstract description 35
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 35
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 66
- 239000000843 powder Substances 0.000 claims abstract description 28
- 238000002844 melting Methods 0.000 claims abstract description 15
- 230000008018 melting Effects 0.000 claims abstract description 15
- 239000004570 mortar (masonry) Substances 0.000 claims abstract description 12
- 238000003723 Smelting Methods 0.000 claims abstract description 9
- 239000004615 ingredient Substances 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 239000002159 nanocrystal Substances 0.000 claims abstract description 4
- 238000007796 conventional method Methods 0.000 claims abstract description 3
- 238000000498 ball milling Methods 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 79
- 229910052759 nickel Inorganic materials 0.000 description 15
- 229910052742 iron Inorganic materials 0.000 description 9
- 238000012360 testing method Methods 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000012300 argon atmosphere Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 238000010891 electric arc Methods 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- 229910052748 manganese Inorganic materials 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 6
- 239000011863 silicon-based powder Substances 0.000 description 6
- 238000005245 sintering Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000003466 welding Methods 0.000 description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 5
- 229910052737 gold Inorganic materials 0.000 description 5
- 239000010931 gold Substances 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 229910002335 LaNi5 Inorganic materials 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 239000001996 bearing alloy Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910000521 B alloy Inorganic materials 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 230000020411 cell activation Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- -1 there is LaNi5Phase Chemical compound 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/023—Alloys based on nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/383—Hydrogen absorbing alloys
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
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CN201810240909.2A CN108467956B (zh) | 2018-03-22 | 2018-03-22 | 一种Si/La15Fe2Ni72Mn7B2Mo2复合储氢合金材料的制备方法 |
Applications Claiming Priority (1)
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CN201810240909.2A CN108467956B (zh) | 2018-03-22 | 2018-03-22 | 一种Si/La15Fe2Ni72Mn7B2Mo2复合储氢合金材料的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN108467956A CN108467956A (zh) | 2018-08-31 |
CN108467956B true CN108467956B (zh) | 2019-11-01 |
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CN201810240909.2A Active CN108467956B (zh) | 2018-03-22 | 2018-03-22 | 一种Si/La15Fe2Ni72Mn7B2Mo2复合储氢合金材料的制备方法 |
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CN (1) | CN108467956B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110492086B (zh) * | 2019-09-09 | 2021-01-26 | 燕山大学 | 一种储氢合金复合材料的制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11246923A (ja) * | 1998-03-05 | 1999-09-14 | Mitsui Mining & Smelting Co Ltd | 水素吸蔵合金及びその製造方法 |
CN1259584A (zh) * | 2000-01-20 | 2000-07-12 | 南开大学 | 储氢合金/碳纳米管复合储氢材料 |
CN1896330A (zh) * | 2006-06-21 | 2007-01-17 | 武汉大学 | 储氢合金及其制备方法和用途 |
CN105039815A (zh) * | 2015-08-20 | 2015-11-11 | 广西大学 | 一种Mg-Li固溶体储氢材料的制备方法 |
CN107164657A (zh) * | 2017-06-15 | 2017-09-15 | 燕山大学 | 一种石墨烯/La‑Fe‑B系低温储氢合金复合材料的制备方法 |
-
2018
- 2018-03-22 CN CN201810240909.2A patent/CN108467956B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11246923A (ja) * | 1998-03-05 | 1999-09-14 | Mitsui Mining & Smelting Co Ltd | 水素吸蔵合金及びその製造方法 |
CN1259584A (zh) * | 2000-01-20 | 2000-07-12 | 南开大学 | 储氢合金/碳纳米管复合储氢材料 |
CN1896330A (zh) * | 2006-06-21 | 2007-01-17 | 武汉大学 | 储氢合金及其制备方法和用途 |
CN105039815A (zh) * | 2015-08-20 | 2015-11-11 | 广西大学 | 一种Mg-Li固溶体储氢材料的制备方法 |
CN107164657A (zh) * | 2017-06-15 | 2017-09-15 | 燕山大学 | 一种石墨烯/La‑Fe‑B系低温储氢合金复合材料的制备方法 |
Non-Patent Citations (1)
Title |
---|
La15Fe77B8型储氢合金的结构和电化学性能;闫慧忠等;《中国稀土学报》;20121031;第30卷(第5期);第587-593页 * |
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CN108467956A (zh) | 2018-08-31 |
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Effective date of registration: 20240308 Address after: 102200 8-11 / F, block a, state power investment group science and Technology Research Institute Co., Ltd., future science and Technology City, Changping District, Beijing Patentee after: STATE POWER INVESTMENT CORPORATION Research Institute Country or region after: China Address before: 066004 No. 438 west section of Hebei Avenue, seaport District, Hebei, Qinhuangdao Patentee before: Yanshan University Country or region before: China |