CN108467769A - 高润滑、高频次、环保型履带销轴链冲压加工专用油 - Google Patents
高润滑、高频次、环保型履带销轴链冲压加工专用油 Download PDFInfo
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- 238000005461 lubrication Methods 0.000 title claims abstract description 10
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- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 5
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims abstract description 5
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims abstract description 5
- 229940073769 methyl oleate Drugs 0.000 claims abstract description 5
- 229940049964 oleate Drugs 0.000 claims abstract description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 5
- 239000001294 propane Substances 0.000 claims abstract description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims abstract description 4
- 239000003921 oil Substances 0.000 abstract description 13
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- 235000019198 oils Nutrition 0.000 description 12
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- 240000002853 Nelumbo nucifera Species 0.000 description 1
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- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 231100000921 acute inhalation toxicity Toxicity 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
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- 239000002184 metal Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
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- 239000011574 phosphorus Substances 0.000 description 1
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- 229910052700 potassium Inorganic materials 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
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- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbasedsulfonic acid salts
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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Abstract
本发明公开了一种高润滑、高频次、环保型履带销轴链冲压加工专用油,由三羟甲基丙烷油酸酯、活性硫化烯烃、高碱值石油磺酸钙、油酸甲酯、异构C14~15醇、2、6‑二叔丁基对甲酚组成。本发明种配制方便、工作性能好。
Description
技术领域
本发明涉及一种履带销轴链冲压加工专用油。
背景技术
销轴链冲压油主要应用于履带销轴链冲压加工工艺,起润滑、冷却、防锈和清洗作用,以使销轴链获得更高的精密度和更好的光洁度;质量良好的冲压油还可提升冲压频次,提高生产效率。
销轴链材质一般为高锰钢,硬度超过HB220,厚度超过10mm,在冲压工艺中是属于较难加工的一类,因此它对配套使用的冲压油的润滑性能要求极高。但目前市售的冲压油,其润滑性能普遍较差(四球试验测试显示:最大无卡较负荷PB一般为1500-2450N,烧结负荷PD一般为4900-6076N),从而严重制约了国内履带销轴链精密度和光洁度的提升(精密度、光洁度差是目前国内履带销轴链加工行业普遍存在的老大难问题)。除此之外,目前市售的销轴链冲压油还存在以下两个问题亟待解决:一是配方中普遍使用植物油作为润滑剂,由于其渗透能力较差(渗透性>17min),并且在加工过程中易老化结焦、工件难清洗,导致冲压加工时冲床频次无法提升(使用市售的销轴链冲压油,冲床频次仅达到200次/min),影响生产效率的提高;二是配方中普遍含有氯化石蜡、磷系添加剂等有毒有害物质,安全卫生质量差,所以目前国内高端市场选用的履带销轴链冲压油基本上都从国外进口。
发明内容
本发明的目的在于提供一种配制方便、工作性能好的高润滑、高频次、环保型履带销轴链冲压加工专用油。
本发明的技术解决方案是:
一种高润滑、高频次、环保型履带销轴链冲压加工专用油,其特征是:由下列重量百分比的组分组成:
三羟甲基丙烷油酸酯 44%
活性硫化烯烃 34%
高碱值石油磺酸钙 10%
油酸甲酯 10%
异构C14~15醇 1.5%
2、6-二叔丁基对甲酚 0.5%。
所述高碱值石油磺酸钙是碱值卫500的石油磺酸钙。
本发明的有益效果是:
1. 配方选用高碱值(碱值500)石油磺酸钙、活性硫化烯烃、三羟甲基丙烷油酸酯等组伍,通过四球试验数据,产品PB≥3087N,PD≥7840N,其润滑性能完全可满足销轴链冲压加工工艺对精密度和光洁度的要求。
2. 配方选用油酸甲酯、异构C14~15醇等组伍,产品渗透性≤2min,冲压频次≥300次/min(较使用市售产品提升50%以上),可大幅提高冲压加工的工作效率。
3. 配方避开使用氯化石蜡等有毒有害物质(选用性能优良、可降解度高、对人和环境友好的可替代物质),产品急性经口毒性LD50≥5000mg/kg,急性吸入毒性LC50≥5000mg/m3,呼吸道粘膜刺激强度达0级,安全卫生质量高。
下面结合实施例对本发明作进一步说明。
具体实施方式
一种高润滑、高频次、环保型履带销轴链冲压加工专用油,由下列重量百分比的组分经混合搅拌制得:
三羟甲基丙烷油酸酯 44%
活性硫化烯烃 34%
高碱值石油磺酸钙 10%
油酸甲酯 10%
异构C14~15醇 1.5%
2、6-二叔丁基对甲酚 0.5%。
所述高碱值石油磺酸钙是碱值卫500的石油磺酸钙。
Claims (2)
1.一种高润滑、高频次、环保型履带销轴链冲压加工专用油,其特征是:由下列重量百分比的组分组成:
三羟甲基丙烷油酸酯 44%
活性硫化烯烃 34%
高碱值石油磺酸钙 10%
油酸甲酯 10%
异构C14~15醇 1.5%
2、6-二叔丁基对甲酚 0.5%。
2.根据权利要求1所述的高润滑、高频次、环保型履带销轴链冲压加工专用油,其特征是:所述高碱值石油磺酸钙是碱值卫500的石油磺酸钙。
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CN109943404A (zh) * | 2019-04-24 | 2019-06-28 | 上海尤希路化学工业有限公司 | 高品位环保型镜面加工磨削油 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1286294A (zh) * | 1999-08-31 | 2001-03-07 | 中国石油化工集团公司 | 一种挥发型金属加工润滑油 |
CN101717684A (zh) * | 2009-11-20 | 2010-06-02 | 东莞市安默琳节能环保技术有限公司 | 用于金属材料切削加工的喷雾供给方式切削油 |
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2018
- 2018-04-25 CN CN201810379710.8A patent/CN108467769A/zh active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1286294A (zh) * | 1999-08-31 | 2001-03-07 | 中国石油化工集团公司 | 一种挥发型金属加工润滑油 |
CN101717684A (zh) * | 2009-11-20 | 2010-06-02 | 东莞市安默琳节能环保技术有限公司 | 用于金属材料切削加工的喷雾供给方式切削油 |
Non-Patent Citations (1)
Title |
---|
刘长期等: "活性硫极压添加剂复合的润滑特性", 《润滑与密封》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109943404A (zh) * | 2019-04-24 | 2019-06-28 | 上海尤希路化学工业有限公司 | 高品位环保型镜面加工磨削油 |
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