CN108467769A - 高润滑、高频次、环保型履带销轴链冲压加工专用油 - Google Patents

高润滑、高频次、环保型履带销轴链冲压加工专用油 Download PDF

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CN108467769A
CN108467769A CN201810379710.8A CN201810379710A CN108467769A CN 108467769 A CN108467769 A CN 108467769A CN 201810379710 A CN201810379710 A CN 201810379710A CN 108467769 A CN108467769 A CN 108467769A
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俞威
阿部聪
林丽静
李思超
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QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
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QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/281Esters of (cyclo)aliphatic monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046Overbasedsulfonic acid salts
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64Environmental friendly compositions
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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  • Lubricants (AREA)

Abstract

本发明公开了一种高润滑、高频次、环保型履带销轴链冲压加工专用油,由三羟甲基丙烷油酸酯、活性硫化烯烃、高碱值石油磺酸钙、油酸甲酯、异构C14~15醇、2、6‑二叔丁基对甲酚组成。本发明种配制方便、工作性能好。

Description

高润滑、高频次、环保型履带销轴链冲压加工专用油
技术领域
本发明涉及一种履带销轴链冲压加工专用油。
背景技术
销轴链冲压油主要应用于履带销轴链冲压加工工艺,起润滑、冷却、防锈和清洗作用,以使销轴链获得更高的精密度和更好的光洁度;质量良好的冲压油还可提升冲压频次,提高生产效率。
销轴链材质一般为高锰钢,硬度超过HB220,厚度超过10mm,在冲压工艺中是属于较难加工的一类,因此它对配套使用的冲压油的润滑性能要求极高。但目前市售的冲压油,其润滑性能普遍较差(四球试验测试显示:最大无卡较负荷PB一般为1500-2450N,烧结负荷PD一般为4900-6076N),从而严重制约了国内履带销轴链精密度和光洁度的提升(精密度、光洁度差是目前国内履带销轴链加工行业普遍存在的老大难问题)。除此之外,目前市售的销轴链冲压油还存在以下两个问题亟待解决:一是配方中普遍使用植物油作为润滑剂,由于其渗透能力较差(渗透性>17min),并且在加工过程中易老化结焦、工件难清洗,导致冲压加工时冲床频次无法提升(使用市售的销轴链冲压油,冲床频次仅达到200次/min),影响生产效率的提高;二是配方中普遍含有氯化石蜡、磷系添加剂等有毒有害物质,安全卫生质量差,所以目前国内高端市场选用的履带销轴链冲压油基本上都从国外进口。
发明内容
本发明的目的在于提供一种配制方便、工作性能好的高润滑、高频次、环保型履带销轴链冲压加工专用油。
本发明的技术解决方案是:
一种高润滑、高频次、环保型履带销轴链冲压加工专用油,其特征是:由下列重量百分比的组分组成:
三羟甲基丙烷油酸酯 44%
活性硫化烯烃 34%
高碱值石油磺酸钙 10%
油酸甲酯 10%
异构C14~15醇 1.5%
2、6-二叔丁基对甲酚 0.5%。
所述高碱值石油磺酸钙是碱值卫500的石油磺酸钙。
本发明的有益效果是:
1. 配方选用高碱值(碱值500)石油磺酸钙、活性硫化烯烃、三羟甲基丙烷油酸酯等组伍,通过四球试验数据,产品PB≥3087N,PD≥7840N,其润滑性能完全可满足销轴链冲压加工工艺对精密度和光洁度的要求。
2. 配方选用油酸甲酯、异构C14~15醇等组伍,产品渗透性≤2min,冲压频次≥300次/min(较使用市售产品提升50%以上),可大幅提高冲压加工的工作效率。
3. 配方避开使用氯化石蜡等有毒有害物质(选用性能优良、可降解度高、对人和环境友好的可替代物质),产品急性经口毒性LD50≥5000mg/kg,急性吸入毒性LC50≥5000mg/m3,呼吸道粘膜刺激强度达0级,安全卫生质量高。
下面结合实施例对本发明作进一步说明。
具体实施方式
一种高润滑、高频次、环保型履带销轴链冲压加工专用油,由下列重量百分比的组分经混合搅拌制得:
三羟甲基丙烷油酸酯 44%
活性硫化烯烃 34%
高碱值石油磺酸钙 10%
油酸甲酯 10%
异构C14~15醇 1.5%
2、6-二叔丁基对甲酚 0.5%。
所述高碱值石油磺酸钙是碱值卫500的石油磺酸钙。

Claims (2)

1.一种高润滑、高频次、环保型履带销轴链冲压加工专用油,其特征是:由下列重量百分比的组分组成:
三羟甲基丙烷油酸酯 44%
活性硫化烯烃 34%
高碱值石油磺酸钙 10%
油酸甲酯 10%
异构C14~15醇 1.5%
2、6-二叔丁基对甲酚 0.5%。
2.根据权利要求1所述的高润滑、高频次、环保型履带销轴链冲压加工专用油,其特征是:所述高碱值石油磺酸钙是碱值卫500的石油磺酸钙。
CN201810379710.8A 2018-04-25 2018-04-25 高润滑、高频次、环保型履带销轴链冲压加工专用油 Pending CN108467769A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109943404A (zh) * 2019-04-24 2019-06-28 上海尤希路化学工业有限公司 高品位环保型镜面加工磨削油

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1286294A (zh) * 1999-08-31 2001-03-07 中国石油化工集团公司 一种挥发型金属加工润滑油
CN101717684A (zh) * 2009-11-20 2010-06-02 东莞市安默琳节能环保技术有限公司 用于金属材料切削加工的喷雾供给方式切削油

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1286294A (zh) * 1999-08-31 2001-03-07 中国石油化工集团公司 一种挥发型金属加工润滑油
CN101717684A (zh) * 2009-11-20 2010-06-02 东莞市安默琳节能环保技术有限公司 用于金属材料切削加工的喷雾供给方式切削油

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘长期等: "活性硫极压添加剂复合的润滑特性", 《润滑与密封》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109943404A (zh) * 2019-04-24 2019-06-28 上海尤希路化学工业有限公司 高品位环保型镜面加工磨削油

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