CN108467768A - 高润滑、环保型深孔钻削专用切削油 - Google Patents
高润滑、环保型深孔钻削专用切削油 Download PDFInfo
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- 238000005553 drilling Methods 0.000 title claims abstract description 19
- 239000010730 cutting oil Substances 0.000 title claims abstract description 10
- 238000005461 lubrication Methods 0.000 title claims abstract description 8
- 239000003921 oil Substances 0.000 claims abstract description 11
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- BYMUNNMMXKDFEZ-UHFFFAOYSA-K trifluorolanthanum Chemical compound F[La](F)F BYMUNNMMXKDFEZ-UHFFFAOYSA-K 0.000 claims abstract description 8
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002367 Polyisobutene Polymers 0.000 claims abstract description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000012964 benzotriazole Substances 0.000 claims abstract description 4
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims abstract description 4
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims abstract description 4
- 229940073769 methyl oleate Drugs 0.000 claims abstract description 4
- 229940049964 oleate Drugs 0.000 claims abstract description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 4
- 239000001294 propane Substances 0.000 claims abstract description 4
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 8
- 101000823778 Homo sapiens Y-box-binding protein 2 Proteins 0.000 claims description 3
- 230000002349 favourable effect Effects 0.000 abstract description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 abstract 1
- 101100006584 Mus musculus Clnk gene Proteins 0.000 description 4
- 239000003595 mist Substances 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 231100000921 acute inhalation toxicity Toxicity 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- -1 rare earth compound Chemical class 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000001533 respiratory mucosa Anatomy 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/081—Inorganic acids or salts thereof containing halogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/026—Butene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/30—Anti-misting
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Chemical & Material Sciences (AREA)
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- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
本发明公开了一种高润滑、环保型深孔钻削专用切削油，由5#白油、46#白油、三羟甲基丙烷油酸酯、油酸甲酯、苯并三氮唑、2,6‑二叔丁基对甲酚、氟化镧、聚异丁烯组成。本发明配制方便、工作性能好。
Description
技术领域
本发明涉及一种深孔钻削用切削油。
背景技术
根据工件的形状和结构不同，金属切削加工的方法一般分为车削、钻削、镗削、刨削、拉削、铣削和磨削。本项目所述的深孔钻削属于钻削的范畴（在机械加工行业，通常把孔深与孔径之比大于6的孔称为深孔）。深孔钻削由于钻孔钻杆细长且刚性差，极易产生弯曲和振动，加上深孔钻削时加工区域温度又较高（通常在600-800℃），所以配套使用的切削油如果没有足够的润滑性能，极易导致工件划伤、刀具寿命缩短。由于工艺、技术落后等原因,现在国内使用的这类切削油大都从国外进口，目前国内也有不少厂家纷纷开发此切削油，但是存在诸多缺陷：一是润滑性较差（攻丝扭矩≥250N﹒cm），难以满足深孔钻削的加工工艺要求；二是深孔钻削时TVOC（总挥发性有机物）含量和油雾浓度普遍较高（TVOC≥0.6mg/m3，油雾浓度≥4mg/m3），对作业环境影响较大；三是配方普遍含有氯、硫等危及人体健康的有毒有害物质。这些弊端制约了产品在深孔钻削行业中的推广。
发明内容
本发明的目的在于提供一种配制方便、工作性能好的高润滑、环保型深孔钻削专用切削油。
本发明的技术解决方案是：
一种高润滑、环保型深孔钻削专用切削油，其特征是：由下列重量百分比的成分组成：
5#白油 30%
46#白油 18%
三羟甲基丙烷油酸酯 10%
油酸甲酯 30%
苯并三氮唑 0.5%
2,6-二叔丁基对甲酚 1%
氟化镧 8%
聚异丁烯 2.5%。
氟化镧可用氧化镧替换。
本发明的有益效果：
1、本产品选用润滑性能优良的稀土化合物（氟化镧、氧化镧）组伍，使产品的润滑性能得到较高提升（经实验室测试，攻丝扭矩（N﹒cm）≤210）。
2、本产品选用性能优良的油雾抑制剂（聚异丁烯）与低挥发、高闪点精制矿物油配伍，作业环境得到较大改善（TVOC含量≤0.4mg/m3、油雾浓度≤1mg/m3）。
3、本产品中原料不使用危及人体健康和环境安全的有害物质，使产品的安全卫生质量得到大幅提升（经检测，产品急性经口毒性LD50≥5000mg/kg，急性吸入毒性LC50≥5000mg/m3，呼吸道粘膜刺激强度为0级）。
下面结合实施例对本发明作进一步说明。
具体实施方式
一种高润滑、环保型深孔钻削专用切削油，由下列重量百分比的成分混合搅拌制成：
5#白油 30%
46#白油 18%
三羟甲基丙烷油酸酯 10%
油酸甲酯 30%
苯并三氮唑 0.5%
2,6-二叔丁基对甲酚 1%
氟化镧 8%
聚异丁烯 2.5%。
氟化镧可用氧化镧替换。
Claims (2)
1.一种高润滑、环保型深孔钻削专用切削油，其特征是：由下列重量百分比的成分组成：
5#白油 30%
46#白油 18%
三羟甲基丙烷油酸酯 10%
油酸甲酯 30%
苯并三氮唑 0.5%
2,6-二叔丁基对甲酚 1%
氟化镧 8%
聚异丁烯 2.5%。
2.根据权利要求1所述的高润滑、环保型深孔钻削专用切削油，其特征是：氟化镧可用氧化镧替换。
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| CN201810379055.6A CN108467768A (zh) | 2018-04-25 | 2018-04-25 | 高润滑、环保型深孔钻削专用切削油 |
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| CN201810379055.6A CN108467768A (zh) | 2018-04-25 | 2018-04-25 | 高润滑、环保型深孔钻削专用切削油 |
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| CN108467768A true CN108467768A (zh) | 2018-08-31 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116024032A (zh) * | 2021-10-27 | 2023-04-28 | 中国石油化工股份有限公司 | 一种切削油组合物及其制备方法和应用 |
| CN116554948A (zh) * | 2023-05-16 | 2023-08-08 | 清华大学天津高端装备研究院 | 一种具有低粘度的深孔钻油及其制备方法 |
| CN116554948B (zh) * | 2023-05-16 | 2024-10-25 | 清华大学天津高端装备研究院 | 一种具有低粘度的深孔钻油及其制备方法 |
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| CN107267267A (zh) * | 2017-07-10 | 2017-10-20 | 上海尤希路化学工业有限公司 | 抗叠印、清净、环保型轴承磨削专用油 |
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- 2018-04-25 CN CN201810379055.6A patent/CN108467768A/zh active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925264A (zh) * | 2012-10-25 | 2013-02-13 | 何国锐 | 一种长寿命环保节能植物基切削油 |
| CN107267267A (zh) * | 2017-07-10 | 2017-10-20 | 上海尤希路化学工业有限公司 | 抗叠印、清净、环保型轴承磨削专用油 |
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| 乔玉林: "《纳米微粒的润滑和自修复技术》", 30 September 2005, 国防工业出版社 * |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116024032A (zh) * | 2021-10-27 | 2023-04-28 | 中国石油化工股份有限公司 | 一种切削油组合物及其制备方法和应用 |
| CN116024032B (zh) * | 2021-10-27 | 2024-07-30 | 中国石油化工股份有限公司 | 一种切削油组合物及其制备方法和应用 |
| CN116554948A (zh) * | 2023-05-16 | 2023-08-08 | 清华大学天津高端装备研究院 | 一种具有低粘度的深孔钻油及其制备方法 |
| CN116554948B (zh) * | 2023-05-16 | 2024-10-25 | 清华大学天津高端装备研究院 | 一种具有低粘度的深孔钻油及其制备方法 |
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Application publication date: 20180831 |